公开(公告)号：US06486332B2

公开(公告)日：2002-11-26

申请号：US09778324

申请日：2001-02-06

Applicant: Zhimin Hao ,  John S. Zambounis ,  Abul Iqbal

Inventor： Zhimin Hao ,  John S. Zambounis ,  Abul Iqbal

IPC: C07D40100

CPC classification number: C09B68/443 ,  C09B1/005 ,  C09B5/62 ,  C09B7/02 ,  C09B19/02 ,  C09B29/0033 ,  C09B47/12 ,  C09B47/26 ,  C09B48/00 ,  C09B57/04 ,  C09B67/0077 ,  C09B68/46 ,  C09B68/4677 ,  C09B69/08 ,  C09K11/06 ,  G03G5/0696 ,  G03G9/0908 ,  G03G9/0912 ,  G03G9/0918 ,  G03G9/092 ,  G03G9/0924 ,  G03G9/0926

Abstract: Compounds of formula A(B)x,  (I) wherein x is an integer from 1 to 4, A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or azo series, which radical contains x N-atoms attached to B, preferably with at least one directly adjacent or conjugated carbonyl group, B is a group of formula  and, if x is 2, 3 or 4, may also be one, two or three hydrogen atoms. The symbols Q, R1, R2, R3, R4, X, Y, Z, m and n, are as defined in claim 1. These carbamate group-containing soluble chromophores are distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated.

Abstract translation: 甲酰呋喃的化合物x为1〜4的整数，A为喹吖啶酮，蒽醌，苝，靛蓝，喹酞酮，异吲哚啉酮，异吲哚啉，二恶嗪，酞菁或偶氮系的发色团的基团，该基团含有x个N原子 至B，优选与至少一个直接相邻或共轭的羰基，B是式的基团，如果x是2,3或4，也可以是一个，两个或三个氢原子。符号Q，R1，R2 R 3，R 4，X，Y，Z，m和n如权利要求1中所定义。这些含氨基甲酸酯基团的可溶性发色团的特征在于UV范围内的突出的固态荧光以及它们可以容易地 被转化成它们所掺入的基材中的相应颜料。

公开(公告)号：US6127549A

公开(公告)日：2000-10-03

申请号：US89142

申请日：1998-06-02

Applicant: Zhimin Hao ,  John S. Zambounis ,  Abul Iqbal

Inventor： Zhimin Hao ,  John S. Zambounis ,  Abul Iqbal

IPC: C09B1/00 ,  C09B1/22 ,  C09B5/62 ,  C09B7/02 ,  C09B7/08 ,  C09B19/00 ,  C09B19/02 ,  C09B29/00 ,  C09B47/12 ,  C09B47/16 ,  C09B47/20 ,  C09B47/26 ,  C09B48/00 ,  C09B57/04 ,  C09B67/20 ,  C09B67/28 ,  C09B69/00 ,  C09B69/08 ,  C09K11/06 ,  G03G5/06 ,  G03G9/06 ,  G03G9/09 ,  C07D209/36

CPC classification number: C09B68/443 ,  C09B1/005 ,  C09B19/02 ,  C09B29/0033 ,  C09B47/12 ,  C09B47/26 ,  C09B48/00 ,  C09B5/62 ,  C09B57/04 ,  C09B67/0077 ,  C09B68/46 ,  C09B68/4677 ,  C09B69/08 ,  C09B7/02 ,  C09K11/06 ,  G03G9/0908 ,  G03G9/0912 ,  G03G9/0918 ,  G03G9/092 ,  G03G9/0924 ,  G03G9/0926 ,  G03G5/0696

Abstract: Compounds of formula:A(B).sub.x, (I),wherein x is an integer from 1 to 4,A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or azo series, which radical contains x N-atoms attached to B, preferably with at least one directly adjacent or conjugated carbonyl group,B is a group of formula: ##STR1## and, if x is 2, 3 or 4, may also be one, two or three hydrogen atoms. The symbols Q, R.sub.1, R.sub.2, R.sub.3, R.sub.4, X, Y, Z, m und n, are as defined in claim 1.These carbamate group-containing soluble chromophores are distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated.

Abstract translation: A（B）x，（I）的化合物，其中x是1至4的整数，A是喹吖啶酮，蒽醌，苝，靛蓝，喹酞酮，异吲哚啉酮，异吲哚啉，二恶嗪，酞菁的发色团的基团 或偶氮系列，该基团含有与B连接的x个N原子，优选与至少一个直接相邻或共轭的羰基，B是下式的基团：并且如果x是2,3或4，也可以是一个， 两个或三个氢原子。 符号Q，R 1，R 2，R 3，R 4，X，Y，Z，m和n如权利要求1中所定义。这些含氨基甲酸酯基团的可溶性发色团的特征在于UV范围内的突出的固态荧光，以及 通过它们可以将它们转化成它们所掺入的底物中的相应颜料。

公开(公告)号：US5811543A

公开(公告)日：1998-09-22

申请号：US677486

申请日：1996-07-09

Applicant: Zhimin Hao ,  John S. Zambounis ,  Abul Iqbal

Inventor： Zhimin Hao ,  John S. Zambounis ,  Abul Iqbal

IPC: C09B1/00 ,  C09B1/22 ,  C09B5/62 ,  C09B7/02 ,  C09B7/08 ,  C09B19/00 ,  C09B19/02 ,  C09B29/00 ,  C09B47/12 ,  C09B47/16 ,  C09B47/20 ,  C09B47/26 ,  C09B48/00 ,  C09B57/04 ,  C09B67/20 ,  C09B67/28 ,  C09B69/00 ,  C09B69/08 ,  C09K11/06 ,  G03G5/06 ,  G03G9/06 ,  G03G9/09 ,  C07D487/22 ,  C09B67/50

CPC classification number: C09B68/443 ,  C09B1/005 ,  C09B19/02 ,  C09B29/0033 ,  C09B47/12 ,  C09B47/26 ,  C09B48/00 ,  C09B5/62 ,  C09B57/04 ,  C09B67/0077 ,  C09B68/46 ,  C09B68/4677 ,  C09B69/08 ,  C09B7/02 ,  C09K11/06 ,  G03G9/0908 ,  G03G9/0912 ,  G03G9/0918 ,  G03G9/092 ,  G03G9/0924 ,  G03G9/0926 ,  G03G5/0696

Abstract: Compounds of the formula A(B).sub.x (I), wherein x is an integer from 1 to 4, A is the radical of a chromophore of the phthalocyanine series, which radical contains x B groups attached to N-atoms, preferably with at least one directly adjacent to or conjugated with a carbonyl group, B is a group of the formula ##STR1## and, if x is 2,3 or 4, may also be one, two or three hydrogen atoms, wherein the symbols Q, R.sub.1, R.sub.2, R.sub.3, R.sub.4, Y, Z, m and n, are as defined in the disclosure These carbamate group-containing soluble chromophores are distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated.

Abstract translation: 式A（B）x（I）的化合物，其中x是1至4的整数，A是酞菁系发色团的基团，该基团含有与N原子连接的x B基团，优选在 至少一个直接与羰基相邻或与羰基结合，B是式（II）的化合物（III）或（IMAGE）（IV），如果x是2,3或4，可以 也可以是1,2或3个氢原子，其中符号Q，R 1，R 2，R 3，R 4，Y，Z，m和n如本公开所定义。这些含氨基甲酸酯基团的可溶性发色团的特征在于优异的固态 在UV范围内的荧光以及它们可以被转化成它们所掺入的底物中的相应颜料的容易程度。

公开(公告)号：US6040108A

公开(公告)日：2000-03-21

申请号：US204190

申请日：1998-12-03

Applicant: Ulrich Schadeli ,  John S. Zambounis ,  Abul Iqbal ,  Zhimin Hao ,  Henri Dubas

Inventor： Ulrich Schadeli ,  John S. Zambounis ,  Abul Iqbal ,  Zhimin Hao ,  Henri Dubas

IPC: B41M3/00 ,  B41M5/26 ,  B41M5/30 ,  B41M5/382 ,  B41M5/46 ,  B41M5/52 ,  C09B67/28 ,  G02B5/20 ,  G03F7/00 ,  G03F7/004 ,  G03F7/033 ,  G03F7/038 ,  G03F7/039 ,  G03F7/105 ,  G03C8/02 ,  B05D3/06 ,  B41J2/315 ,  G03C5/16

CPC classification number: G03F7/105 ,  B41M3/003 ,  B41M5/265 ,  B41M5/5254 ,  B41M5/5272 ,  C09B67/0077 ,  C09B68/443 ,  C09B68/46 ,  G03F7/0007 ,  G03F7/0045 ,  B41M5/26 ,  B41M5/30 ,  B41M5/382 ,  Y10S430/145 ,  Y10S430/146 ,  Y10S430/156 ,  Y10S430/163 ,  Y10S430/165

Abstract: Compositions for making structured color images comprising(a) a soluble pigment precursor which can be transformed to an insoluble pigment by means of chemical, thermal, photolytic or radiation-induced method, and(b) a binder polymer or prepolymer, or a positive or negative resist-type resin which can be structured by crosslinking, polymerization or depolymerization by applying heat or electromagnetic irradiation.The compositions can be applied to optical and thermal recording, printing, and the production of color filters for Liquid Crystal Displays, with high accuracy, high transparency and high stability.

Abstract translation: 用于制备结构化彩色图像的组合物包括（a）通过化学，热，光解或辐射诱导的方法可转变成不溶性颜料的可溶性颜料前体，和（b）粘合剂聚合物或预聚物，或阳性或 可以通过加热或电磁照射进行交联，聚合或解聚而构成的负型抗蚀剂型树脂。 该组合物可用于液晶显示器的光学和热记录，印刷和彩色滤光片的生产，具有高精度，高透明度和高稳定性。

公开(公告)号：US5616725A

公开(公告)日：1997-04-01

申请号：US541004

申请日：1995-10-11

Applicant: John S. Zambounis ,  Zhimin Hao ,  Abul Iqbal

Inventor： John S. Zambounis ,  Zhimin Hao ,  Abul Iqbal

IPC: G03F7/004 ,  B41M5/323 ,  C07D487/04 ,  C08K5/3415 ,  C09B55/00 ,  C09B57/00 ,  C09K11/06 ,  G03G9/09 ,  G03G9/097

CPC classification number: C07D487/04 ,  C08K5/3415 ,  C09B57/004 ,  C09B68/443 ,  C09B68/46 ,  C09B68/4677 ,  C09K11/06 ,  G03G9/0906 ,  G03G9/0922 ,  G03G9/09758

Abstract: Pyrrolo[3,4-c]pyrroles of formula ##STR1## wherein D and E are each independently of the other a group of formula ##STR2## The symbols Q, R.sub.8, R.sub.9, R.sub.10, R.sub.11, X, Y, Z, m and n are as defined in claim 1.These pyrrolo[3,4-c]pyrroles are distinguished by outstanding solid state fluorescence in the UV range as well as by the ease with which they can be converted to pyrrolopyrrole pigments even in the substrate in which they are incorporated.

Abstract translation: （I）的吡咯并[3,4-c]吡咯，其中D和E各自独立地为另一个式（II）的化合物（III）或（IMAGE） 符号Q，R8，R9，R10，R11，X，Y，Z，m和n如权利要求1中所定义。这些吡咯并[3,4-c]吡咯的特征在于UV范围内的突出的固态荧光， 以及即使在它们所掺入的基材中也可以将它们转化成吡咯并吡咯颜料。

公开(公告)号：US5561232A

公开(公告)日：1996-10-01

申请号：US319399

申请日：1994-10-06

Applicant: Zhimin Hao ,  John S. Zambounis ,  Abul Iqbal

Inventor： Zhimin Hao ,  John S. Zambounis ,  Abul Iqbal

IPC: C09B1/00 ,  C09B1/22 ,  C09B5/62 ,  C09B7/02 ,  C09B7/08 ,  C09B19/00 ,  C09B19/02 ,  C09B29/00 ,  C09B47/12 ,  C09B47/16 ,  C09B47/20 ,  C09B47/26 ,  C09B48/00 ,  C09B57/04 ,  C09B67/20 ,  C09B67/28 ,  C09B69/00 ,  C09B69/08 ,  C09K11/06 ,  G03G5/06 ,  G03G9/06 ,  G03G9/09 ,  C07D471/04

CPC classification number: C09B68/443 ,  C09B1/005 ,  C09B19/02 ,  C09B29/0033 ,  C09B47/12 ,  C09B47/26 ,  C09B48/00 ,  C09B5/62 ,  C09B57/04 ,  C09B67/0077 ,  C09B68/46 ,  C09B68/4677 ,  C09B69/08 ,  C09B7/02 ,  C09K11/06 ,  G03G9/0908 ,  G03G9/0912 ,  G03G9/0918 ,  G03G9/092 ,  G03G9/0924 ,  G03G9/0926 ,  G03G5/0696

Abstract: Compounds of formulaA(B).sub.x, (I),whereinx is an integer from 1 to 4,A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or azo series, which radical contains x N-atoms attached to B, preferably with at least one directly adjacent or conjugated carbonyl group,B is a group of formula ##STR1## and, if x is 2, 3 or 4, may also be one, two or three hydrogen atoms. The symbols Q, R.sub.1, R.sub.2, R.sub.3, R.sub.4, X, Y, Z, m and n, are as defined in claim 1. These carbamate group-containing soluble chromophores am distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated.

Abstract translation: 式A（B）x，（I）的化合物，其中x为1至4的整数，A为喹吖啶酮，蒽醌，苝，靛蓝，喹酞酮，异吲哚啉酮，异吲哚啉，二恶嗪，酞菁或偶氮的发色团的基团 该基团含有连接到B上的x个N原子，优选与至少一个直接相邻的或共轭的羰基相连，B是下式的基团：（III）（IV）和 如果x是2,3或4，也可以是一个，两个或三个氢原子。 符号Q，R1，R2，R3，R4，X，Y，Z，m和n如权利要求1中所定义。这些含氨基甲酸酯基团的可溶性发色团的特征在于UV范围内出色的固态荧光，以及 通过它们可以将它们转化成它们所掺入的底物中的相应颜料。

公开(公告)号：US5484943A

公开(公告)日：1996-01-16

申请号：US319406

申请日：1994-10-06

Applicant: John S. Zambounis ,  Zhimin Hao ,  Abul Iqbal

Inventor： John S. Zambounis ,  Zhimin Hao ,  Abul Iqbal

IPC: G03F7/004 ,  B41M5/323 ,  C07D487/04 ,  C08K5/3415 ,  C09B55/00 ,  C09B57/00 ,  C09K11/06 ,  G03G9/09 ,  G03G9/097 ,  C07D403/04

CPC classification number: C07D487/04 ,  C08K5/3415 ,  C09B57/004 ,  C09B68/443 ,  C09B68/46 ,  C09B68/4677 ,  C09K11/06 ,  G03G9/0906 ,  G03G9/0922 ,  G03G9/09758

Abstract: Pyrrolo[3,4-c]pyrroles of formula ##STR1## wherein D and E are each independently of the other a group of formula ##STR2## The symbols Q, R.sub.8, R.sub.9, R.sub.10, R.sub.11, X, Y, Z, m and n are as defined in claim 1.These pyrrolo[3,4-c]pyrroles are distinguished by outstanding solid state fluorescence in the UV range as well as by the ease with which they can be converted to pyrrolopyrrole pigments even in the substrate in which they are incorporated.

Abstract translation: （I）的吡咯并[3,4-c]吡咯，其中D和E各自独立地为另一个式（II）的基团。 符号Q，R 8，R 9，R 10，R 11，X，Y，Z，m和n如权利要求1中所定义。这些吡咯并[3,4-c]吡咯在紫外范围内还有突出的固态荧光 因为即使在其中掺入吡咯并吡咯颜料的基质中也可以将它们转化成吡咯并吡咯颜料。

公开(公告)号：US06180315B2

公开(公告)日：2001-01-30

申请号：US09458771

申请日：1999-12-10

Applicant: Ulrich Sch{umlaut over (a)}deli ,  John S. Zambounis ,  Abul Iqbal ,  Zhimin Hao ,  Henri Dubas

Inventor： Ulrich Sch{umlaut over (a)}deli ,  John S. Zambounis ,  Abul Iqbal ,  Zhimin Hao ,  Henri Dubas

IPC: G03C802

CPC classification number: G03F7/105 ,  B41M3/003 ,  B41M5/26 ,  B41M5/265 ,  B41M5/30 ,  B41M5/382 ,  B41M5/5254 ,  B41M5/5272 ,  C09B67/0077 ,  C09B68/443 ,  C09B68/46 ,  G03F7/0007 ,  G03F7/0045 ,  Y10S430/145 ,  Y10S430/146 ,  Y10S430/156 ,  Y10S430/163 ,  Y10S430/165

Abstract: Novel compositions for making structured color images and application thereof Compositions for making structured color images comprising (a) a soluble pigment precursor which can be transformed to an insoluble pigment by means of chemical, thermal, photolytic or radiation-induced method, and (b) a binder polymer or prepolymer, or a positive or negative resist-type resin which can be structured by crosslinking, polymerization or depolymerization by applying heat or electromagnetic irradiation. The compositions can be applied to optical and thermal recording, printing, and the production of color filters for Liquid Crystal Displays, with high accuracy, high transparency and high stability.

Abstract translation: 用于制造结构化彩色图像的新型组合物及其应用用于制备结构化彩色图像的组合物包括（a）可通过化学，热，光解或辐射诱导方法转化为不溶性颜料的可溶性颜料前体，和（b） 粘合剂聚合物或预聚物，或正或负的抗蚀剂型树脂，其可以通过施加热或电磁辐射的交联，聚合或解聚来构成。组合物可以应用于光学和热记录，印刷和生产滤色器 用于液晶显示器，具有高精度，高透明度和高稳定性。

公开(公告)号：US6013777A

公开(公告)日：2000-01-11

申请号：US095618

申请日：1998-06-10

Applicant: Zhimin Hao ,  John S. Zambounis ,  Abul Iqbal

Inventor： Zhimin Hao ,  John S. Zambounis ,  Abul Iqbal

IPC: C09B1/00 ,  C09B1/22 ,  C09B5/62 ,  C09B7/02 ,  C09B7/08 ,  C09B19/00 ,  C09B19/02 ,  C09B29/00 ,  C09B47/12 ,  C09B47/16 ,  C09B47/20 ,  C09B47/26 ,  C09B48/00 ,  C09B57/04 ,  C09B67/20 ,  C09B67/28 ,  C09B69/00 ,  C09B69/08 ,  C09K11/06 ,  G03G5/06 ,  G03G9/06 ,  G03G9/09 ,  C07D209/77 ,  C07D221/18 ,  C07D403/02 ,  C07D471/04 ,  C07D487/22

CPC classification number: C09B68/443 ,  C09B1/005 ,  C09B19/02 ,  C09B29/0033 ,  C09B47/12 ,  C09B47/26 ,  C09B48/00 ,  C09B5/62 ,  C09B57/04 ,  C09B67/0077 ,  C09B68/46 ,  C09B68/4677 ,  C09B69/08 ,  C09B7/02 ,  C09K11/06 ,  G03G9/0908 ,  G03G9/0912 ,  G03G9/0918 ,  G03G9/092 ,  G03G9/0924 ,  G03G9/0926 ,  G03G5/0696

Abstract: Compounds of formulaA(B).sub.x, (I),wherein x is an integer from 1 to 4,A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or azo series, which radical contains x N-atoms attached to B, preferably with at least one directly adjacent or conjugated carbonyl group,B is a group of formula ##STR1## and, if x is 2, 3 or 4, may also be one, two or three hydrogen atoms. The symbols Q, R.sub.1, R.sub.2, R.sub.3, R.sub.4, X, Y, Z, m and n, are as defined in claim 1.These carbamate group-containing soluble chromophores are distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated.

Abstract translation: 式A（B）x，（I）的化合物，其中x是1至4的整数，A是喹吖啶酮，蒽醌，苝，靛蓝，喹酞酮，异吲哚啉酮，异吲哚啉，二恶嗪，酞菁或偶氮的发色团的基团 该基团包含与B连接的x个N原子，优选与至少一个直接相邻或共轭的羰基，B是式的基团，如果x是2,3或4，也可以是一个，两个或三个 氢原子。 符号Q，R1，R2，R3，R4，X，Y，Z，m和n如权利要求1中所定义。这些含氨基甲酸酯基团的可溶性发色团的特征在于UV范围内的优异的固态荧光，以及 通过它们可以将它们转化成它们所掺入的底物中的相应颜料。

公开(公告)号：US5874580A

公开(公告)日：1999-02-23

申请号：US89143

申请日：1998-06-02

Applicant: Zhimin Hao ,  John S. Zambounis ,  Abul Iqbal

Inventor： Zhimin Hao ,  John S. Zambounis ,  Abul Iqbal

IPC: C09B1/00 ,  C09B1/22 ,  C09B5/62 ,  C09B7/02 ,  C09B7/08 ,  C09B19/00 ,  C09B19/02 ,  C09B29/00 ,  C09B47/12 ,  C09B47/16 ,  C09B47/20 ,  C09B47/26 ,  C09B48/00 ,  C09B57/04 ,  C09B67/20 ,  C09B67/28 ,  C09B69/00 ,  C09B69/08 ,  C09K11/06 ,  G03G5/06 ,  G03G9/06 ,  G03G9/09 ,  C07D221/18

CPC classification number: C09B68/443 ,  C09B1/005 ,  C09B19/02 ,  C09B29/0033 ,  C09B47/12 ,  C09B47/26 ,  C09B48/00 ,  C09B5/62 ,  C09B57/04 ,  C09B67/0077 ,  C09B68/46 ,  C09B68/4677 ,  C09B69/08 ,  C09B7/02 ,  C09K11/06 ,  G03G9/0908 ,  G03G9/0912 ,  G03G9/0918 ,  G03G9/092 ,  G03G9/0924 ,  G03G9/0926 ,  G03G5/0696

Abstract: Compounds of formulaA(B).sub.x, (I),wherein x is an integer from 1 to 4, A is the radical of a chromophore of the quinacridone, anthraquinone, perylene, indigo, quinophthalone, isoindolinone, isoindoline, dioxazine, phthalocyanine or azo series, which radical contains x N-atoms attached to B, preferably with at least one directly adjacent or conjugated carbonyl group,B is a group of formula ##STR1## and, if x is 2,3 or 4, may also be one, two or three hydrogen atoms. The symbols Q, R.sub.1, R.sub.2, R.sub.3, R.sub.4, X, Y, Z, m und n, are as defined in claim 1.These carbamate group-containing soluble chromophores are distinguished by outstanding solid state fluorescence in the UV range as well as the by ease with which they can be converted to the corresponding pigments in the substrate in which they are incorporated.

Abstract translation: 式A（B）x，（I）的化合物，其中x是1至4的整数，A是喹吖啶酮，蒽醌，苝，靛蓝，喹酞酮，异吲哚啉酮，异吲哚啉，二恶嗪，酞菁或偶氮的发色团的基团 该基团含有连接到B上的x个N原子，优选与至少一个直接相邻的或共轭的羰基相连，B是下式的基团：（III）（IV）和 如果x是2,3或4，也可以是一个，两个或三个氢原子。 符号Q，R 1，R 2，R 3，R 4，X，Y，Z，m和n如权利要求1中所定义。这些含氨基甲酸酯基团的可溶性发色团的特征在于UV范围内的突出的固态荧光，以及 通过它们可以将它们转化成它们所掺入的底物中的相应颜料。