Method of making a heat-mode lithographic printing plate precursor
    1.
    发明申请
    Method of making a heat-mode lithographic printing plate precursor 失效
    制备热模式平版印刷版原版的方法

    公开(公告)号:US20030013044A1

    公开(公告)日:2003-01-16

    申请号:US10174249

    申请日:2002-06-18

    申请人: AGFA-GEVAERT N.V.

    摘要: A cost efficient method of making a lithographic printing plate precursor is disclosed, the method comprising the steps of coating a silver halide emulsion layer on a hydrophilic base which is provided with physical development nuclei; simultaneously with the preceding step, coating on the emulsion layer a solution that induces silver salt diffusion transfer reversal development of the silver halide; allowing diffusion of complexed silver ions to the physical development nuclei, thereby forming silver metal that is deposited on the hydrophilic base; a wash-off step wherein the emulsion layer is removed from the silver metal. The material thus obtained can be exposed image-wise in heat-mode, e.g. by means of an infrared laser, thereby ablating the silver metal and revealing the hydrophilic base at exposed areas. Immediately after exposure, it can be used as a lithographic printing plate without the need for a wet processing step.

    摘要翻译: 公开了制备平版印刷版前体的成本有效的方法,所述方法包括以下步骤:在设置有物理显影核的亲水基底上涂覆卤化银乳剂层; 与上述步骤同时地,在乳剂层上涂覆引起银盐扩散转移反转显影的溶液; 允许络合的银离子扩散到物理显影核,从而形成沉积在亲水基底上的银金属; 洗涤步骤,其中从银金属除去乳剂层。 如此获得的材料可以以热模式,例如, 通过红外激光,从而消除银金属并在暴露的区域露出亲水基底。 曝光后立即可以将其用作平版印刷版,而不需要湿法处理步骤。

    Thermal imaging material containing combustible nitro-resin particles
    2.
    发明申请
    Thermal imaging material containing combustible nitro-resin particles 失效
    含有可燃硝基树脂颗粒的热成像材料

    公开(公告)号:US20040234887A1

    公开(公告)日:2004-11-25

    申请号:US10441547

    申请日:2003-05-20

    IPC分类号: G03F007/14

    摘要: A heat-sensitive composition can be used to make a heat-sensitive imaging material. The composition includes a water-soluble or water-dispersible binder and dispersed therein, a photothermal conversion material, and hybrid particles of a combustible nitro-resin and an addition polymer derived from one or more ethylenically unsaturated polymerizable monomers. The hybrid particles preferably have a core-shell structure with the combustible nitro-resin comprising the core and the addition polymer providing the shell. These imaging materials are particularly useful as nulldirect-writenull thermally imageable elements useful to provide lithographic printing plates without ablation or the need for alkaline development.

    摘要翻译: 可以使用热敏组合物来制造热敏成像材料。 该组合物包括水溶性或水分散性粘合剂并分散在其中,光热转换材料,以及可燃硝基树脂和衍生自一种或多种烯属不饱和可聚合单体的加成聚合物的混合颗粒。 杂化颗粒优选具有核 - 壳结构,其中可燃硝基树脂包含芯,加成聚合物提供壳。 这些成像材料特别适用于“直写式”可热成像元件,可用于提供平版印刷版,而不需要消融或碱性显影。

    HEAT SENSITIVE PRINTING PLATE PRECURSORS
    3.
    发明申请
    HEAT SENSITIVE PRINTING PLATE PRECURSORS 失效
    热敏印刷机前置器

    公开(公告)号:US20030003400A1

    公开(公告)日:2003-01-02

    申请号:US10174277

    申请日:2002-06-18

    申请人: AGFA-GEVAERT

    摘要: The present invention provides a method of preparing a lithographic printing plate, said method comprising: providing a lithographic printing plate precursor comprising: i) a grained and anodized aluminum substrate where the anodic weight is between 6.0 and 20 g/m2, having coated thereon; ii) a metallic layer; and image-wise exposing the precursor on an external drum thermal imaging device. The method provides press ready plates showing high image quality, good press properties and high durability on press without the requirement for the use of costly intermediate film and developer chemistry, and the attendant inconvenience resulting from the use of these materials.

    摘要翻译: 本发明提供一种制备平版印刷版的方法,所述方法包括:提供平版印刷版前体,其包括:i)在其上涂覆有阳极重量为6.0至20g / m 2的颗粒和阳极氧化铝基材; ii)金属层; 并且在外部鼓热成像装置上成像地将前体曝光。 该方法提供了印刷机准备板,其显示出高图像质量,良好的压制性能和高耐久性,而不需要使用昂贵的中间膜和显影剂化学品,以及由于使用这些材料而引起的不便。

    Positive working thermal imaging assembly or structure, method for the manufacture thereof and products used as lithographic printing plates and the like
    6.
    发明申请
    Positive working thermal imaging assembly or structure, method for the manufacture thereof and products used as lithographic printing plates and the like 失效
    正性工作热成像组件或结构,其制造方法和用作平版印刷版的产品等

    公开(公告)号:US20040152018A1

    公开(公告)日:2004-08-05

    申请号:US10726623

    申请日:2003-12-04

    摘要: The invention relates to Positive working thermal imaging assembly comprising: A) a substrate; and B) a thermally sensitive imaging element of a composite layer structure comprising: (i) a first layer on the substrate of a polymeric material soluble in aqueous alkali solution, optionally containing compounds that absorb and convert light to heat and/or a coloured dye or pigment; said first layer being converted at its surface by treatment with solutions at elevated temperatures that contain an active compound or compounds capable of rendering said first polymeric material insoluble to aqueous alkali developer at the point of contact ; the first layer being oleophilic; (ii) optionally, a first intermediate layer between the substrate and the said first layer with a second polymeric material which is soluble or dispersible in aqueous solution optionally containing compounds that absorb and convert light or radiation to heat and/or a coloured dye or pigment coated from a solvent that does not substantially dissolve the first layer; and (iii) optionally, a third or top layer over the converted first layer and composed of a second polymeric material which is soluble or dispersible in aqueous solution optionally containing compounds that absorb and convert light or radiation to heat and/or a visible coloured dye or pigment; the first intermediate layer and the third layer being applied with a solvent that does not substantially dissolve the converted first layer. The assembly is useful as off-set lithographic printing plates, for color proofing films and photoresist. The invention also refers to the process for making such assembly and products formed therefrom.

    摘要翻译: 本发明涉及正工作热成像组件,其包括:A)衬底; 和B)复合层结构的热敏成像元件,包括:(i)基底上的可溶于碱水溶液的聚合材料的第一层,任选地含有吸收和转化光的化合物和/或着色染料 或颜料; 所述第一层在其表面上通过在高温下用溶液处理而被转化,所述溶液含有活性化合物或能够使所述第一聚合物材料在接触点处不溶于碱性显影剂的化合物; 第一层是亲油的; (ii)任选地,在所述基材和所述第一层之间的第一中间层具有可溶于或分散于水溶液中的第二聚合物材料,所述第二聚合物材料任选地含有吸收并将光或辐射转化成热和/或着色染料或颜料的化合物 由基本不溶解第一层的溶剂涂布; 和(iii)可选地,在转化的第一层上方的第三层或顶层,并且由可溶或可分散在水溶液中的第二聚合物材料组成,任选地含有吸收和转换光或辐射至热的化合物和/或可见的着色染料 或颜料; 第一中间层和第三层被施加有基本上不溶解转化的第一层的溶剂。 该组件可用作偏光平版印刷版,用于防色膜和光致抗蚀剂。 本发明还涉及用于制造这样的组装和由其形成的产品的方法。

    HEAT MODE SENSITIVE IMAGING ELEMENT FOR MAKING POSITIVE WORKING PRINTING PLATES
    7.
    发明申请
    HEAT MODE SENSITIVE IMAGING ELEMENT FOR MAKING POSITIVE WORKING PRINTING PLATES 有权
    用于制作正式印刷版的热模感光成像元件

    公开(公告)号:US20010001699A1

    公开(公告)日:2001-05-24

    申请号:US09260062

    申请日:1999-03-02

    申请人: Joan Vermeersch

    IPC分类号: G03F007/038 G03F007/14

    摘要: According to the present invention there is provided a heat mode imaging element for making a lithographic printing plate having on a lithographic base with a hydrophilic surface a first layer including a polymer soluble in an aqueous alkaline solution, and a top layer on the same side of the lithographic base as the first layer that is IR-sensitive and unpenetrable for an aqueous alkaline developer wherein said first layer and said top layer may be one and the same layer; characterized in that the surface of said element upon exposure and treatment with an aqueous alkaline developer is such that a) the contact angle between the unexposed areas of the imaging element and the aqueous alkaline developer changes for at most 6null during the first minute of contact with said developer; b) the contact angle between the exposed areas of the imaging element and the aqueous alkaline developer changes more than 15null during the first minute of contact with said developer; c) the difference in contact angle between on the one side the unexposed areas and on the other side the exposed areas of the imaging element with the aqueous alkaline solution at the onset of the measurement is not higher than 10null.

    摘要翻译: 根据本发明,提供了一种用于制造平版印刷版的热模式成像元件,该平版印刷版在具有亲水表面的光刻基底上具有包含可溶于碱性水溶液的聚合物的第一层, 作为第一层的平版印刷基底,其对于碱性水溶液的IR敏感性和不透气性,其中所述第一层和所述顶层可以是同一层; 其特征在于,当用碱性显影剂水溶液曝光和处理时,所述元件的表面使得a)成像元件的未曝光区域与含水碱性显影剂之间的接触角在接触的第一分钟期间改变至多6° 与开发商 b)在与所述显影剂接触的第一分钟期间,成像元件的暴露区域和含水碱性显影剂之间的接触角变化大于15°; c)在开始测量时,未曝光区域和另一侧之间的接触角与碱性水溶液的曝光区域的差异不大于10°。