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公开(公告)号:US20240228279A9
公开(公告)日:2024-07-11
申请号:US17769400
申请日:2020-10-16
Applicant: BASF SE , UNIVERSITY OF CALIFORNIA, OAKLAND
Inventor: Klemens MASSONNE , Hendrik DE WINNE , Torsten MATTKE , Ahmad DEHESTANI , Sabine WEIGUNY , Stephan ZUEND , Eric Wesley MCFARLAND , Behzad TANGEYSH , Shizhao SU , Sabine FRISCHHUT
CPC classification number: C01B7/04 , B01J10/005 , B01J19/02 , B01J19/2465 , B01J27/08 , B01J2219/0263
Abstract: The invention relates to a process for preparation of chlorine from hydrogen chloride comprising circulating a liquid melt comprising copper ions Cun+ with n being a number in the range from 1 to 2, alkali cations and chloride ions Cl in a reactor system comprising three bubble lift reactors I, II and III, each comprising a reaction zone i, ii and iii respectively, wherein: ⋅(a) in the reaction zone i of the first bubble lift reactor I, a liquid melt comprising copper ions Cun+, alkali cations and chloride ions Cl— is contacted with oxygen at a temperature in the range from 395 to 405° C. so that the molar ratio Cun+:Cu+ in the liquid melt increases, obtaining a liquid melt having an increased molar ratio Cun+:Cu+ ⋅(b) the liquid melt obtained in (a) is circulated to the reaction zone ii in the second bubble lift reactor II, where the liquid melt is contacted with hydrogen chloride at a temperature in the range from 395 to 405° C. so that water is formed, obtaining a liquid melt being enriched in chloride anions (CI-) compared to the liquid melt obtained according to (a); ⋅(c) circulating the liquid melt obtained in (b) to the reaction zone iii in the third bubble lift reactor III, which is operated at a temperature in the range from 420 to 430° C. so that chlorine (Cl2) is formed, wherein Cl2 is removed from the reaction zone iii and the third bubble lift reactor III respectively in gaseous form, leaving a liquid melt depleted of Cl-compared to the liquid melt obtained according to (b). The invention further relates to a reactor system comprising three bubble lift reactors I, II and III.
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公开(公告)号:US12006274B2
公开(公告)日:2024-06-11
申请号:US18052391
申请日:2022-11-03
Applicant: THE CHEMOURS COMPANY FC, LLC
Inventor: Xuehui Sun , Mario Joseph Nappa , Karl Krause
IPC: C07C21/18 , B01J23/16 , B01J23/18 , B01J27/08 , C07C17/08 , C07C17/087 , C07C17/20 , C07C17/25 , C07C19/08 , C07C19/10
CPC classification number: C07C17/087 , B01J23/16 , B01J23/18 , B01J27/08 , C07C17/08 , C07C17/206 , C07C17/25 , C07C19/08 , C07C19/10 , C07C2527/12 , C07C2527/133 , C07C17/087 , C07C19/10 , C07C17/25 , C07C21/18 , C07C17/206 , C07C21/18 , C07C17/087 , C07C19/08
Abstract: A method hydrofluorinates an olefin of the formula: RCX=CYZ to produce a hydrofluoroalkane of formula RCXFCHYZ or RCXHCFYZ, where X, Y, and Z are independently the same or different and are selected from the group consisting of H, F, Cl, Br, and C1-C6 alkyl which is partially or fully substituted with chloro or fluoro or bromo; and R is a C1-C6 alkyl which is unsubstituted or substituted with chloro or fluoro or bromo. The method includes reacting the olefin with HF in the vapor phase, in the presence of SbF5, at a temperature ranging from about −30° C. to about 65° C. and compositions formed by the process.
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公开(公告)号:US20240132350A1
公开(公告)日:2024-04-25
申请号:US17769400
申请日:2020-10-15
Applicant: BASF SE , UNIVERSITY OF CALIFORNIA, OAKLAND
Inventor: Klemens MASSONNE , Hendrik DE WINNE , Torsten MATTKE , Ahmad DEHESTANI , Sabine WEIGUNY , Stephan ZUEND , Eric Wesley MCFARLAND , Behzad TANGEYSH , Shizhao SU , Sabine FRISCHHUT
CPC classification number: C01B7/04 , B01J10/005 , B01J19/02 , B01J19/2465 , B01J27/08 , B01J2219/0263
Abstract: The invention relates to a process for preparation of chlorine from hydrogen chloride comprising circulating a liquid melt comprising copper ions Cun+ with n being a number in the range from 1 to 2, alkali cations and chloride ions Cl in a reactor system comprising three bubble lift reactors I, II and III, each comprising a reaction zone i, ii and iii respectively, wherein: ⋅(a) in the reaction zone i of the first bubble lift reactor I, a liquid melt comprising copper ions Cun+, alkali cations and chloride ions Cl— is contacted with oxygen at a temperature in the range from 395 to 405° C. so that the molar ratio Cun+:Cu+ in the liquid melt increases, obtaining a liquid melt having an increased molar ratio Cun+:Cu+ ⋅(b) the liquid melt obtained in (a) is circulated to the reaction zone ii in the second bubble lift reactor II, where the liquid melt is contacted with hydrogen chloride at a temperature in the range from 395 to 405° C. so that water is formed, obtaining a liquid melt being enriched in chloride anions (CI-) compared to the liquid melt obtained according to (a); ⋅(c) circulating the liquid melt obtained in (b) to the reaction zone iii in the third bubble lift reactor III, which is operated at a temperature in the range from 420 to 430° C. so that chlorine (Cl2) is formed, wherein Cl2 is removed from the reaction zone iii and the third bubble lift reactor III respectively in gaseous form, leaving a liquid melt depleted of Cl-compared to the liquid melt obtained according to (b). The invention further relates to a reactor system comprising three bubble lift reactors I, II and III.
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公开(公告)号:US20220280923A1
公开(公告)日:2022-09-08
申请号:US17387448
申请日:2021-07-28
Inventor: Sangmin Ji , Hyukjae Kwon , Minseok Koo , Sukeun Kuk , Dongsik Yang , Hyun Chul Lee , Joeng Gil Seo , Namjun So
Abstract: A composite photocatalyst, a photocatalytic filter for air purification, and an air purification device that includes the photocatalytic filter. The composite photocatalyst includes: a first metal oxide particle; and second metal oxide particles arranged on a surface of the first metal oxide particle, wherein specific surface area of the second metal oxide particles is greater than specific surface area of the first metal oxide particle, and bandgap energy of the second metal oxide particles is greater than bandgap energy of the first metal oxide particle. The composite photocatalyst structure may degrade and remove gaseous pollutants under room temperature and atmospheric pressure conditions. The composite photocatalyst may be applied to various indoor and outdoor air purification systems in the form of a photocatalytic filter.
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公开(公告)号:US20210162379A1
公开(公告)日:2021-06-03
申请号:US17100938
申请日:2020-11-22
Applicant: INSTITUTO MEXICANO DEL PETROLEO
Inventor: Javier GUZMAN PANTOJA , Edith MENESES RUIZ , Candido AGUILAR BARRERA , Andrea RODRIGUEZ HERNANDEZ , Isidoro GARCIA CRUZ , Jose Antonio MUNOZ ARROYO , Juan Carlos GAYTAN RAMOS
Abstract: This invention is related to the synthesis of organic carbonates from carbon dioxide and epoxides. It is particularly focused on the production of propylene cyclic carbonate from propylene oxide. The proposed catalytic materials includes a support made of aluminum oxyhydroxide (Catapal B®), nitric acid, acetic acid and/or phosphoric acid. An important stage is the physical and chemical conditioning of the catalytic materials and to this end, experimental methodologies such as spheronization and thermal treatments were implemented prior the evaluation process.
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公开(公告)号:US10913747B2
公开(公告)日:2021-02-09
申请号:US16619299
申请日:2018-05-15
Applicant: F.I.S. - FABBRICA ITALIANA SINTETICI S.P.A.
Inventor: Ottorino De Lucchi , Pierluigi Padovan , Elena Brasola
IPC: C07D487/04 , B01J27/08
Abstract: Object of the present invention is an efficient process for the preparation of the active pharmaceutical ingredient Sitagliptine and the 2,4,5-trifluorophenylacetic acid (TFAA) and salt thereof, which is a key intermediate for the synthesis of Sitagliptine.
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公开(公告)号:US10888847B2
公开(公告)日:2021-01-12
申请号:US16063921
申请日:2016-12-06
Applicant: Envision SQ Inc.
Inventor: Scott Shayko , Cheng Lu , Xin Qiu
IPC: B01J27/08 , B01D53/00 , B01D53/86 , B01D53/88 , B01J21/18 , B01J35/00 , B01J37/02 , B01J37/03 , B01J37/04 , B01J37/06 , B01J37/10 , B01J35/02 , B01J21/06 , B01J23/18 , B01J19/12
Abstract: The present disclosure relates to a UV- and visible-light photocatalytic titanium dioxide composite material. In particular, the disclosure relates to a 5 photocatalytic titanium oxide composite material for the decomposition of airborne pollutants.
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公开(公告)号:US20200299161A1
公开(公告)日:2020-09-24
申请号:US16946202
申请日:2020-06-10
Inventor: Yoel Sasson , Hani Gnayem
Abstract: The invention provides a process for the preparation of bismuth oxyhalide, comprising a precipitation of bismuth oxyhalide in an acidic aqueous medium in the presence of a reducing agent. Also provided are bismuth oxyhalide compounds doped with elemental bismuth Bi(0). The use of Bi(0)doped-bismuth oxyhalide as photocatalysts in water purification is also described.
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公开(公告)号:US20200270267A1
公开(公告)日:2020-08-27
申请号:US16651187
申请日:2018-09-26
Applicant: Ben William GREATREX
Inventor: Ben William GREATREX , Julian KLEPP
IPC: C07D493/08 , B01J27/135 , B01J27/125 , B01J27/08 , B01J31/14
Abstract: The present invention relates to chiral auxiliaries and the syntheses thereof and uses thereof.
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公开(公告)号:US10286387B2
公开(公告)日:2019-05-14
申请号:US15817316
申请日:2017-11-20
Applicant: The Procter & Gamble Company
Inventor: Juan Esteban Velasquez , Dimitris Ioannis Collias , Jane Ellen Godlewski , Fred Christian Wireko
IPC: B01J27/08 , B01J27/187 , B01J27/188 , B01J27/195 , B01J27/18 , B01J27/16 , B01J37/04 , B01J37/08 , B01J23/20 , B01J35/02 , B01J37/00 , C07C51/00
Abstract: Hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof are dehydrated using a catalyst and a method to produce bio-acrylic acid, acrylic acid derivatives, or mixtures thereof. A method to produce the dehydration catalyst is also provided.
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