REDOX CURING DENTAL COMPOSITION
    2.
    发明申请

    公开(公告)号:US20220226198A1

    公开(公告)日:2022-07-21

    申请号:US17604483

    申请日:2020-04-17

    摘要: A redox curing dental composition comprising: a. one or more compounds having a radical polymerizable carbon-carbon double bond; b. a redox initiator system comprising a reducing agent which is a compound of the following formula (I): wherein R1 and R2 which may be the same or different, independently represent a C1-18 hydrocarbyl group, or R1 and R2 form together with the silicon atom to which they are bonded a 3 to 8-membered silicon-containing alicyclic ring, which groups R1 and/or R2 may be substituted with one to three substituents selected from the group consisting of a C1-6 alkoxy group, a halogen atom, or a carboxylic acid group; and (ii) an oxidizing agent adapted to oxidize the reducing agent of formula (I) in the absence of light for generating a radical capable of initiating radical polymerization of the one or more compounds having a radical polymerizable carbon-carbon double bond.

    Synergistically Active Composition

    公开(公告)号:US20210253748A1

    公开(公告)日:2021-08-19

    申请号:US16342590

    申请日:2017-11-09

    IPC分类号: C08F4/40 C08F2/22

    摘要: The invention relates to the use of a synergistically active composition which comprises at least one metal sulfite and at least one metal hydroxymethane sulfmate as reducing agent in emulsion polymerizations.The reducing power of the composition of the invention is significantly higher than the additive reducing power of the components. Furthermore, the composition results in a reduced amount of free formaldehyde.

    Water-absorbent resin particles and method for producing same

    公开(公告)号:US11084889B2

    公开(公告)日:2021-08-10

    申请号:US15764962

    申请日:2016-09-30

    摘要: Provided is a method for producing water-absorbent resin particles, which is capable of improving the gel strength for the purpose of achieving a good balance between the absorption under load and the rate of liquid permeation through gel. The present invention is a method for producing water-absorbent resin particles, which is characterized by comprising a step wherein a monomer composition containing a water-soluble vinyl monomer (a1) and/or a vinyl monomer (a2) that turns into a water-soluble vinyl monomer (a1) by means of hydrolysis and a crosslinking agent (b) is polymerized in the presence of at least one organic main group element compound selected from the group consisting of organic iodine compounds, organic tellurium compounds, organic antimony compounds, and organic bismuth compounds.

    Method for producing alkenyl ether polymer

    公开(公告)号:US10370478B2

    公开(公告)日:2019-08-06

    申请号:US15572384

    申请日:2016-05-02

    发明人: Shinji Sugihara

    摘要: To provide a method for producing a polymer that is capable of providing an alkenyl ether polymer having a molecular weight, a molecular weight distribution, and a composition that are controlled, with a vinyl ether having a hydroxyl group, and a block copolymer thereof. To provide a polymer obtained by the method as a macro chain transfer agent capable of performing reversible addition fragmentation chain transfer polymerization. Livingness can be imparted to radical polymerization of a hydroxyl group-containing vinyl ether by performing the radical polymerization in the presence of a particular RAFT agent and a radical polymerization initiator, and a block copolymer with another radically polymerizable vinyl monomer can be obtained by using the resulting living polymer as a macro chain transfer agent capable of performing reversible addition fragmentation chain transfer polymerization.