PLASTICIZED CELLULOSE ESTER COMPOSITIONS
    32.
    发明申请

    公开(公告)号:WO2021252251A1

    公开(公告)日:2021-12-16

    申请号:PCT/US2021/035598

    申请日:2021-06-03

    Abstract: Disclosed is a plasticized cellulose ester composition. The plasticized cellulose ester composition of the present invention includes at least one cellulose ester and a plasticizer system. The plasticizer system includes epoxidized bio-derived oil in an amount of from 2% to 32% by weight based on the total weight of the plasticizer system. Flooring articles with at least one layer formed from the composition are also described.

    COMPRESSION-INDUCED CRYSTALLIZATION OF CRYSTALLIZABLE POLYMERS
    37.
    发明申请
    COMPRESSION-INDUCED CRYSTALLIZATION OF CRYSTALLIZABLE POLYMERS 审中-公开
    可结晶聚合物的压缩诱导结晶

    公开(公告)号:WO2005072928A1

    公开(公告)日:2005-08-11

    申请号:PCT/US2005/002523

    申请日:2005-01-27

    Abstract: A crystallization process comprising passing a mass of amorphous crystallizäble polymer having a first thickness (ft) through the nip gap of counter-rotating rolls having a nip gap (ng)at an ft:ng ratio of at least 1.2 to crystallize the polymer to a degree of crystallinity of at least 15% and thereby produce a semi-crystalline polymer, and particulating the semi-crystalline polymer. Strain crystallizing a sheet or fiber by using a drafting step to elongate the sheet or fiber is no longer needed. A high degree of crystallinity is imparted almost instantaneously, even in slow to crystallize copolyesters. The process allows one to extrude a thinner crystallizable sheet, substantially retains the dimensiona) width of the sheet as it is passed through the compression rolls, and produces substantially optically clear sheet and pellets. Suitable polymers include polyethylene terephthalate or naphthalate homopolymers or copolymers.

    Abstract translation: 结晶方法包括将具有第一厚度(ft)的大量无定形结晶聚合物通过具有至少1.2的ft / ng比率的压区间隙(ng)的反向旋转辊的辊隙间隔,以将聚合物结晶至 结晶度至少为15%,从而产生半结晶聚合物,并使半结晶聚合物微粒化。 不再需要通过使用牵伸步骤来使片材或纤维细长的应变片材或纤维。 即使在缓慢结晶共聚酯中,也几乎瞬间赋予高度的结晶度。 该方法允许挤出较薄的可结晶片材,当片材通过压缩辊时基本上保持片材的尺寸宽度,并且产生基本上光学透明的片材和丸粒。 合适的聚合物包括聚对苯二甲酸乙二醇酯或萘二甲酸酯均聚物或共聚物。

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