公开(公告)号：WO2011001142A1

公开(公告)日：2011-01-06

申请号：PCT/GB2010/001262

申请日：2010-06-29

Applicant: UNIVERSITY OF LEICESTER ,  ABBOTT, Andrew, Peter ,  BALLANTYNE, Andrew

Inventor： ABBOTT, Andrew, Peter ,  BALLANTYNE, Andrew

IPC: C08L1/02 ,  C08L3/02 ,  C08L3/12 ,  C08L5/00 ,  C08L5/12 ,  C08K5/19 ,  C08K5/21

CPC classification number: C08L3/02 ,  C08K5/19 ,  C08K5/21 ,  C08K5/50 ,  C08L1/02 ,  C08L3/12 ,  C08L5/00 ,  C08L5/12 ,  C08L2666/26

Abstract: There is provided a plastic or gel material comprising a mixture of: (a) a compound of formula (I) or a mixture of two or more compounds of formula (I), (R + ) n (X n- ) (I) or a hydrate thereof, wherein n, R + and X n- have meanings given in the description; (b) one or more uncharged organic compounds, each of which compounds comprises at least one oxygen atom and at least one hydrogen atom that is capable of forming a hydrogen bond with X n- ; and (c) one or more polysaccharides, wherein each polysaccharide is a polymer of pyranose monomers, at least 30% of which monomers are in the α-anomeric conformation. There is also provided articles formed from such materials, uses of such materials and processes for forming such materials.

Abstract translation: 提供一种塑料或凝胶材料，其包含以下混合物：（a）式（I）化合物或两种或更多种式（I），（R +）n（Xn-）（I）化合物或 其水合物，其中n，R +和Xn-具有在说明书中给出的含义; （b）一种或多种不带电荷的有机化合物，其中的每一种化合物包含至少一个氧原子和至少一个能够与Xn-形成氢键的氢原子; 和（c）一种或多种多糖，其中每个多糖是吡喃糖单体的聚合物，其中至少30％的单体是α-端基构象。 还提供由这种材料形成的制品，这种材料的使用和用于形成这种材料的方法。

公开(公告)号：WO0226701A3

公开(公告)日：2003-05-01

申请号：PCT/GB0104300

申请日：2001-09-26

Applicant: SCIONIX LTD ,  ABBOTT ANDREW PETER ,  DAVIES DAVID LLOYD ,  CAPPER GLEN ,  RASHEED RAYMOND KELVIN ,  TAMBYRAJAH VASUKI

Inventor： ABBOTT ANDREW PETER ,  DAVIES DAVID LLOYD ,  CAPPER GLEN ,  RASHEED RAYMOND KELVIN ,  TAMBYRAJAH VASUKI

IPC: C07H3/02 ,  B01J31/02 ,  B01J31/04 ,  C07C31/20 ,  C07C31/36 ,  C07C33/22 ,  C07C39/04 ,  C07C39/07 ,  C07C39/28 ,  C07C41/30 ,  C07C47/565 ,  C07C47/575 ,  C07C47/58 ,  C07C53/126 ,  C07C53/16 ,  C07C53/18 ,  C07C55/06 ,  C07C55/08 ,  C07C57/32 ,  C07C59/10 ,  C07C59/153 ,  C07C59/265 ,  C07C59/50 ,  C07C63/06 ,  C07C65/03 ,  C07C205/06 ,  C07C211/10 ,  C07C211/11 ,  C07C211/46 ,  C07C211/63 ,  C07C215/12 ,  C07C215/76 ,  C07C215/90 ,  C07C219/06 ,  C07C229/04 ,  C07C229/12 ,  C07C229/60 ,  C07C233/05 ,  C07C233/65 ,  C07C235/46 ,  C07C275/00 ,  C07C275/02 ,  C07C275/20 ,  C07C309/30 ,  C07C311/16 ,  C07C335/02 ,  C25C1/20 ,  C25D3/02 ,  C25F3/16

CPC classification number: C25D3/02 ,  B01J31/006 ,  B01J31/0249 ,  B01J31/0279 ,  B01J31/0284 ,  B01J31/04 ,  B01J2231/125 ,  B01J2231/4261 ,  C07C41/30 ,  C07C275/02 ,  C25F3/16 ,  H01M2300/0025 ,  Y02P20/542 ,  C07C43/215

Abstract: Ionic compounds with a freezing point of up to 100 DEG C are formed by the reaction of an one amine salt of formula (I) R R R R N X , such as choline chloride with an organic compound (II) capable of forming a hydrogen bond with X , such as urea, wherein the molar ratio of I to II is from 1:1.5 to 1:2.5. R , R , R and R may be H, optionally substituted C1 to C5 alkyl, optionally substituted C6 to C10 cycloalkyl, optionally substituted C6 to C12 aryl, optionally substituted C7 to C12 alkaryl, or R and R taken together may represent a C4 to C10 optionally substituted alkylene group, thereby forming with the N atom of formula I a 5 to 11-membered heterocyclic ring and all of R , R , R and R are not identical, X may be NO3 , F, CI , Br , I , BF4 , CIO4 , CN , SO3CF3 , or COOCF3 . The ionic compounds are useful as solvents, and electrolytes for example in electroplating, electrowinning, and electropolishing, and as catalysts.

Abstract translation: 通过一种式（I）的胺盐R 1 R 2 R 3，R 4，N +，X 4， >，如具有与X'形成氢键的有机化合物（II）的氯化胆碱，例如脲，其中I与II的摩尔比为1:1.5至1:2.5。 R 1，R 2，R 3和R 4可以是H，任选取代的C 1 -C 5烷基，任选取代的C 6至C 10环烷基，任选取代的C 6至C 12芳基，任选取代的C 7至C 12烷芳基 或R 1和R 2一起可以表示C4至C10任选取代的亚烷基，从而与式I的N原子形成5至11元杂环，并且所有R 1，R R 3和R 4不相同，X可以是NO 3 - ，F，Cl - ，Br - ，I - ，BF 4 - ， - CIO4 - ，CN - ，SO3CF3 - 或COOCF3 - 。 离子化合物可用作溶剂，例如在电镀，电解冶金和电解抛光中的电解质，以及作为催化剂。

公开(公告)号：WO2011064556A2

公开(公告)日：2011-06-03

申请号：PCT/GB2010/002195

申请日：2010-11-25

Applicant: UNIVERSITY OF LEICESTER ,  ABBOTT, Andrew, Peter ,  ABOOD, Hadi

Inventor： ABBOTT, Andrew, Peter ,  ABOOD, Hadi

CPC classification number: C07C233/05 ,  C07C275/02 ,  C07C275/06 ,  C25D3/44 ,  C25D3/665

Abstract: There is provided a mixture having a freezing point of up to 100°C formed by a process comprising the step of contacting: (A) from 1 to 2 equivalents of a compound of formula (I) AIX 3 (I) wherein each X independently represents Cl, Br or F; with (B) 1 equivalent of a compound of formula (II) R 1 -C(O)-N(R 2 )(R 3 ) (II) wherein R 1 to R 3 have meanings given in the description. There is also provided further mixtures containing additional components, as well as methods of using the mixtures in various applications, such as for the electroreduction of the mixtures to produce aluminium metal.

Abstract translation: 本发明提供了一种通过包括以下步骤的方法形成的具有高达100℃的冰点的混合物：（A）1至2当量的式（I）化合物 （I）其中每个X独立地代表Cl，Br或F; 与（B）1当量的式（II）的化合物R 1 -C（O）-N（R 2）（R 3） （II）其中R 1至R 3具有在说明书中给出的含义。 还提供了含有附加组分的其他混合物，以及在各种应用中使用混合物的方法，例如用于电还原混合物以生产铝金属的方法。

公开(公告)号：WO0226381A3

公开(公告)日：2002-06-27

申请号：PCT/GB0104306

申请日：2001-09-26

Applicant: SCIONIX LTD ,  ABBOTT ANDREW PETER ,  DAVIES DAVID LLOYD ,  CAPPER GLEN ,  RASHEED RAYMOND KELVIN ,  TAMBYRAJAH VASUKI

Inventor： ABBOTT ANDREW PETER ,  DAVIES DAVID LLOYD ,  CAPPER GLEN ,  RASHEED RAYMOND KELVIN ,  TAMBYRAJAH VASUKI

IPC: B01J31/04 ,  B01J31/02 ,  B01J31/26 ,  B01J31/30 ,  B01J31/32 ,  B01J31/34 ,  C07B37/12 ,  C07B61/00 ,  C07C45/69 ,  C07C47/42 ,  C07C47/445 ,  C07C49/543 ,  C07C49/553 ,  C07C209/68 ,  C07C211/62 ,  C07C211/63 ,  C07C211/64 ,  C07C215/90 ,  C25D3/02 ,  C25D3/66 ,  C25D21/14 ,  C25F3/20 ,  C25F3/24 ,  H01M6/16 ,  H01M10/36

CPC classification number: B01J31/0284 ,  B01J31/006 ,  B01J31/0279 ,  B01J31/26 ,  B01J2231/125 ,  B01J2231/326 ,  C07B37/12 ,  C07C45/69 ,  C07C211/63 ,  C07C215/90 ,  C07C2601/16 ,  C07C2602/42 ,  C07C2602/44 ,  C25D3/02 ,  C25D3/665 ,  C25F3/20 ,  C25F3/24 ,  H01M6/164 ,  H01M6/166 ,  H01M10/36 ,  C07C47/42 ,  C07C49/543 ,  C07C49/553 ,  C07C47/445

Abstract: Ionic compounds having a freezing point of no more than 50 DEG C, formed by the reaction of at least one amine salt of the formula R R R R N X (I) with at least one hydrated salts, which is a chloride, nitrate, sulphate or acetate of Li, Mg, Ca, Cr, Mn, Fe, Co, Ni, Cu, Zn, Cd, Pb, Bi, La or Ce; wherein R , R and R are each independently a C1 to C5 alkyl or a C6 to C10 cycloalkyl group, or wherein R and R taken together represent a C4 to C10 alkylene group, thereby forming with the N atom of formula (I) a 5 to 11 membered heterocyclic ring, and wherein R is hydrogen, or phenyl, or C1 to C12 alkyl or cycloalkyl group, optionally substituted with at least one group selected from OH, Cl, Br, F, I, phenyl, NH2, CN, NO2, COOR , CHO, COR and OR , wherein R is a C1 to C10 alkyl or cycloalkyl group, and X is an anion capable of being complexed by the said hydrated salt. The compounds are useful as solvents, electrolytes, and catalyts, and have particular application in solvents/electrolytes for metal plating and electropolishing processes, in particular in chromium plating.

Abstract translation: 由至少一种通式为R 1 R 2 R 3 R 4 N + X - 的胺盐反应形成的冰点不超过50℃的离子化合物， （I）与至少一种水合盐反应，所述水合盐是Li，Mg，Ca，Cr，Mn，Fe，Co，Ni，Cu，Zn，Cd，Pb，Bi，La的氯化物，硝酸盐，硫酸盐或乙酸盐或 策; 其中R 1，R 2和R 3各自独立地为C 1至C 5烷基或C 6至C 10环烷基，或者其中R 2和R 3合在一起表示C 4至C 10亚烷基 从而与式（I）的N原子形成5至11元杂环，并且其中R 4为氢或苯基或C 1至C 12烷基或环烷基，其任选地被至少一个选自下列的基团取代： OH，Cl，Br，F，I，苯基，NH 2，CN，NO 2，COOR 5，CHO，COR 5和OR 5，其中R 5为C 1至C 10烷基或环烷基 并且X-是能够被所述水合盐络合的阴离子。 这些化合物可用作溶剂，电解质和催化剂，并且特别用于金属电镀和电解抛光工艺的溶剂/电解质中，特别是用于镀铬。

公开(公告)号：WO2011064556A3

公开(公告)日：2011-11-10

申请号：PCT/GB2010002195

申请日：2010-11-25

Applicant: UNIV LEICESTER ,  ABBOTT ANDREW PETER ,  ABOOD HADI

Inventor： ABBOTT ANDREW PETER ,  ABOOD HADI

IPC: C25D3/44 ,  C07C233/05 ,  C07C275/02 ,  C07C275/06 ,  C25D3/66

CPC classification number: C07C233/05 ,  C07C275/02 ,  C07C275/06 ,  C25D3/44 ,  C25D3/665

Abstract: There is provided a mixture having a freezing point of up to 100°C formed by a process comprising the step of contacting: (A) from 1 to 2 equivalents of a compound of formula (I) AIX3 (I) wherein each X independently represents Cl, Br or F; with (B) 1 equivalent of a compound of formula (II) R1-C(O)-N(R2)(R3) (II) wherein R1 to R3 have meanings given in the description. There is also provided further mixtures containing additional components, as well as methods of using the mixtures in various applications, such as for the electroreduction of the mixtures to produce aluminium metal.

Abstract translation: 提供具有高达100℃的凝固点的混合物，该混合物通过包括以下步骤的方法形成，该方法包括使（A）1至2当量的式（I）化合物（其中每个X独立地表示 Cl，Br或F; 与（B）1当量的式（II）化合物R 1 -C（O）-N（R 2）（R 3）（II）其中R 1至R 3具有在说明书中给出的含义。 还提供了含有另外的组分的另外的混合物，以及在各种应用中使用混合物的方法，例如电解还原混合物以产生铝金属。

公开(公告)号：WO2007003956A3

公开(公告)日：2007-06-28

申请号：PCT/GB2006002515

申请日：2006-07-06

Applicant: UNIV LEICESTER ,  ABBOTT ANDREW PETER

Inventor： ABBOTT ANDREW PETER

IPC: C25C3/00 ,  B01J31/02 ,  C25D3/02 ,  C25D3/22 ,  C25D3/30 ,  C25D3/66 ,  C25F3/00

CPC classification number: C25D3/02 ,  C25C3/00 ,  C25D3/22 ,  C25D3/30 ,  C25F3/00 ,  H01M2300/0022 ,  H01M2300/0025

Abstract: There is provided a mixture having a freezing point of up to 50°C, formed by reaction between: (A) one molar equivalent of a salt of formula I (M n+ )(X - ) n I or a hydrate thereof; and (B) from one to eight molar equivalents of a complexing agent comprising one or more uncharged organic compounds, each of which compounds has (i) a hydrogen atom that is capable of forming a hydrogen bond with the anion X - ; and (ii) a heteroatom selected from the group consisting of O, S, N and P that is capable of forming a coordinative bond with the metal ion M n+ , which reaction is performed in the absence of extraneous solvent, wherein M, X - and n have meaning given in the description.

Abstract translation: 提供具有高达50℃的凝固点的混合物，其通过以下反应形成：（A）一摩尔当量的式I的盐（M ^{n +），（X - 或其水合物;或其水合物;和/或其水合物; 和（B）1至8摩尔当量的包含一种或多种不带电荷的有机化合物的络合剂，其中每种化合物具有（i）能够与阴离子X - 形成氢键的氢原子， / SUP>; 和（ii）选自O，S，N和P的杂原子，其能够与金属离子M n + +形成配位键，该反应在不存在外来的情况下进行 溶剂，其中M，X-O和n具有在说明书中给出的含义。}

公开(公告)号：WO2007003956A2

公开(公告)日：2007-01-11

申请号：PCT/GB2006/002515

申请日：2006-07-06

Applicant: UNIVERSITY OF LEICESTER ,  ABBOTT, Andrew, Peter

Inventor： ABBOTT, Andrew, Peter

IPC: C25C3/00 ,  C25D3/02 ,  C25D3/22 ,  C25D3/30 ,  C25F3/00

CPC classification number: C25D3/02 ,  C25C3/00 ,  C25D3/22 ,  C25D3/30 ,  C25F3/00 ,  H01M2300/0022 ,  H01M2300/0025

Abstract: There is provided a mixture having a freezing point of up to 50°C, formed by reaction between: (A) one molar equivalent of a salt of formula I (M n+ )(X - ) n I or a hydrate thereof; and (B) from one to eight molar equivalents of a complexing agent comprising one or more uncharged organic compounds, each of which compounds has (i) a hydrogen atom that is capable of forming a hydrogen bond with the anion X - ; and (ii) a heteroatom selected from the group consisting of O, S, N and P that is capable of forming a coordinative bond with the metal ion M n+ , which reaction is performed in the absence of extraneous solvent, wherein M, X - and n have meaning given in the description.

Abstract translation: 通过如下反应形成冰点达50℃的混合物：（A）1摩尔当量的式I盐 >）（X→ - ）n -I或其水合物; 和（B）1至8摩尔当量的包含一种或多种不带电荷的有机化合物的络合剂，所述络合剂中的每一种化合物具有（i）能够与阴离子X - 形成氢键的氢原子 - / SUP>; 和（ii）选自O，S，N和P的杂原子，其能够与金属离子M n +形成配位键，该反应在不存在无关的情况下进行 溶剂，其中M，X sup和n具有在说明书中给出的含义。

公开(公告)号：WO2003095084A3

公开(公告)日：2003-11-20

申请号：PCT/GB2003/002067

申请日：2003-05-14

Applicant: ADVANCED PHYTONICS LIMITED ,  ABBOTT, Andrew ,  ELTRINGHAM, Wayne ,  NICOLA, Mazin

Inventor： ABBOTT, Andrew ,  ELTRINGHAM, Wayne ,  NICOLA, Mazin

IPC: C07B35/02

Abstract: A process for hydrogenating one or more functional groups in a compound, for example an alkene, involves contacting the compound with a hydrogen source in the presence of a reaction solvent and suitably in the presence of a catalyst, such as Wilkinson's catalyst. The reaction solvent may be a C 1 - 4 fluorinated hydrocarbon or a C 1 - 4 hydrofluorocarbon ether, with difluoromethane, tetrafluoroethane and heptafluoropropane being preferred solvents.

公开(公告)号：WO2003095084A2

公开(公告)日：2003-11-20

申请号：PCT/GB2003/002067

申请日：2003-05-14

Applicant: ADVANCED PHYTONICS LIMITED ,  ABBOTT, Andrew ,  ELTRINGHAM, Wayne ,  NICOLA, Mazin

Inventor： ABBOTT, Andrew ,  ELTRINGHAM, Wayne ,  NICOLA, Mazin

IPC: B01J

CPC classification number: C07B35/02 ,  Y02P20/544

Abstract: A process for hydrogenating one or more functional groups in a compound, for example an alkene, involves contacting the compound with a hydrogen source in the presence of a reaction solvent and suitably in the presence of a catalyst, such as Wilkinson's catalyst. The reaction solvent may be a C 1 - 4 fluorinated hydrocarbon or a C 1 - 4 hydrofluorocarbon ether, with difluoromethane, tetrafluoroethane and heptafluoropropane being preferred solvents.

Abstract translation: 用于氢化化合物（例如烯烃）中的一个或多个官能团的方法包括在反应溶剂存在下，适当地在催化剂如Wilkinson催化剂存在下使化合物与氢源接触。 反应溶剂可以是C 1→4 <氟化烃或C 1→4 <氢氟烃醚，其中二氟甲烷，四氟乙烷和七氟丙烷是优选的溶剂。