公开(公告)号：WO2009086140A3

公开(公告)日：2009-09-03

申请号：PCT/US2008087739

申请日：2008-12-19

Applicant: CHEVRON ORONITE CO ,  CHEVRON ORONITE SA ,  CAMPBELL CURT B ,  SINQUIN GILLES P ,  SPALA EUGENE E ,  CHAPON GILBERT R

Inventor： CAMPBELL CURT B ,  SINQUIN GILLES P ,  SPALA EUGENE E ,  CHAPON GILBERT R

IPC: C10M169/04 ,  C10M129/10 ,  C10M129/50 ,  C10N30/02 ,  C10N30/04 ,  C10N40/02 ,  C10N40/04

CPC classification number: C10M159/20 ,  C10M159/22 ,  C10M2203/1025 ,  C10M2207/262 ,  C10M2215/28 ,  C10M2219/044 ,  C10M2223/045 ,  C10N2210/06 ,  C10N2220/028 ,  C10N2230/02 ,  C10N2230/04 ,  C10N2240/02 ,  C10N2240/04 ,  C10N2270/00 ,  C10N2220/022 ,  C10N2260/00 ,  C10N2260/14 ,  C10N2210/02

Abstract: A carboxylate detergent prepared by the process comprising (a) alkylating a hydroxyaromatic compound with at least one normal alpha olefin having from about 12 to about 30 carbon atoms per molecule that has been isomerized to obtain an isomerized alpha olefin having 15-98 wt% branching and a residual alpha olefin content of between from about 0.1 to about 30 wt%, thereby producing an alkylated hydroxyaromatic compound; (b) neutralizing the resulting alkylated hydroxyaromatic compound with an alkali metal base; (c) carbonating the alkali metal salt from step (b) with carbon dioxide; (d) acidifying the salt produced in step (c); and (e) overbasing the resulting alkylated hydroxyaromatic carboxylic acid.

Abstract translation: 通过该方法制备的羧酸盐洗涤剂包括（a）使羟基芳族化合物与至少一种正构的α-烯烃在每分子中具有约12至约30个碳原子进行烷基化，所述α-烯烃已被异构化，以获得具有15-98重量％支化的异构化α-烯烃 和约0.1至约30重量％之间的残余α-烯烃含量，从而产生烷基化羟基芳族化合物; （b）用碱金属碱中和得到的烷基化羟基芳族化合物; （c）用二氧化碳将步骤（b）的碱金属盐碳化; （d）酸化步骤（c）中产生的盐; 和（e）使得到的烷基化羟基芳族羧酸过碱化。

公开(公告)号：WO2007143513A3

公开(公告)日：2008-02-21

申请号：PCT/US2007070133

申请日：2007-05-31

Applicant: CHEVRON ORONITE CO ,  DRIVER MICHAEL ,  CAMPBELL CURT B ,  HARRIS THOMAS V

Inventor： DRIVER MICHAEL ,  CAMPBELL CURT B ,  HARRIS THOMAS V

IPC: C07C2/70

CPC classification number: C07C2/66 ,  C07C2/22 ,  C07C2531/14 ,  C07C15/107 ,  C07C11/02

Abstract: A process for alkylating an aromatic compound containing no hydroxyl groups comprising reacting at least one non-hydroxyl containing aromatic compound with at least one olefinic oligomer in the presence of an acidic ionic liquid catalyst, wherein the olefinic oligomer has a carbon range of from about C 12 to about C 70 and is synthesized by oligomerizing at leas one monoolefin monomer in the presence of an acidic ionic liquid catalyst.

Abstract translation: 一种烷基化不含羟基的芳族化合物的方法，包括在酸性离子液体催化剂的存在下使至少一种含非羟基的芳族化合物与至少一种烯属低聚物反应，其中烯属低聚物的碳范围为约C 通过在酸性离子液体催化剂的存在下，通过低聚单体烯烃单体合成来制备。

公开(公告)号：WO2007143513A2

公开(公告)日：2007-12-13

申请号：PCT/US2007/070133

申请日：2007-05-31

Applicant: CHEVRON ORONITE COMPANY LLC ,  DRIVER, Michael ,  CAMPBELL, Curt B. ,  HARRIS, Thomas V.

Inventor： DRIVER, Michael ,  CAMPBELL, Curt B. ,  HARRIS, Thomas V.

IPC: C07C2/66 ,  C07C15/00

CPC classification number: C07C2/66 ,  C07C2/22 ,  C07C2531/14 ,  C07C15/107 ,  C07C11/02

Abstract: A process for alkylating an aromatic compound containing no hydroxyl groups comprising reacting at least one non-hydroxyl containing aromatic compound with at least one olefinic oligomer in the presence of an acidic ionic liquid catalyst, wherein the olefinic oligomer has a carbon range of from about C 12 to about C 70 and is synthesized by oligomerizing at leas one monoolefin monomer in the presence of an acidic ionic liquid catalyst.

Abstract translation: 一种烷基化不含羟基的芳族化合物的方法，包括在酸性离子液体催化剂的存在下使至少一种含非羟基的芳族化合物与至少一种烯属低聚物反应，其中烯属低聚物的碳范围为约C 通过在酸性离子液体催化剂的存在下，通过低聚单体烯烃单体合成来制备。

公开(公告)号：WO2007075404A3

公开(公告)日：2007-12-06

申请号：PCT/US2006047892

申请日：2006-12-15

Applicant: CHEVRON ORONITE CO ,  CAMPBELL CURT B ,  HARRIS THOMAS V ,  SINQUIN GILLES

Inventor： CAMPBELL CURT B ,  HARRIS THOMAS V ,  SINQUIN GILLES

IPC: C07C303/06

CPC classification number: C07C303/06 ,  C07C309/31

Abstract: A process for preparing a synthetic petroleum sulfonate comprising (a) reacting at least one aromatic compound with a mixture of olefins selected from olefins having from about 8 to about 100 carbon atoms, in the presence of an acidic ionic liquid catalyst, wherein the resulting product comprises at least about 50 weight percent of a . 1, 2, 4 tri-substituted aromatic compound or a 1, 2, 3 tri-substituted aromatic compound or mixtures thereof; (b) reacting the product of (a) with sulfur trioxide, which has been diluted with air; and (c) neutralizing the product of (b) with an alkali or alkaline earth metal hydroxide.

Abstract translation: 一种制备合成石油磺酸盐的方法，包括（a）在酸性离子液体催化剂存在下使至少一种芳族化合物与选自约8至约100个碳原子的烯烃的烯烃混合物反应，其中所得产物 包含至少约50重量％的a。 1,2,4取代的芳族化合物或1,2,3取代的芳族化合物或其混合物; （b）使（a）的产物与已经用空气稀释的三氧化硫反应; 和（c）用碱金属或碱土金属氢氧化物中和（b）的产物。

公开(公告)号：WO2004101473A3

公开(公告)日：2005-06-09

申请号：PCT/US2004025203

申请日：2004-08-04

Applicant: CHEVRON ORONITE CO ,  CAMPBELL CURT B ,  SINQUIN GILLES P

Inventor： CAMPBELL CURT B ,  SINQUIN GILLES P

IPC: C07C20060101 ,  C09K3/00 ,  E21B21/00 ,  E21B33/00 ,  E21B33/02 ,  E21B33/10 ,  E21B43/00 ,  E21B43/16 ,  E21B43/22 ,  E21B43/25 ,  E21B43/27

CPC classification number: C09K8/584

Abstract: The present invention is directed to an under-neutralized alkylxylene sulfonic acid composition for enhanced oil recovery processes. The present invention is also directed to a method for enhancing the recovery of oil from a subterranean reservoir which method employs the under-neutralized alkylxylene sulfonic acid compositions of the present invention. The under-neutralized alkylxylene sulfonic acid compositions are employed in an aqueous media. The method optionally employs suitable co-surfactants, such as alcohols, alcohol ethers, polyalkylene glycols, poly(oxyalkylene)glycols and/or poly(oxyalkylene)glycol ethers.

Abstract translation: 本发明涉及用于增强油回收方法的中和过的烷基二甲苯磺酸组合物。 本发明还涉及一种用于增强从地下储层中回收油的方法，该方法采用本发明的过度中和的烷基二甲苯磺酸组合物。 未中和的烷基二甲苯磺酸组合物用于水性介质中。 该方法任选地使用合适的辅助表面活性剂，例如醇，醇醚，聚亚烷基二醇，聚（氧化烯）二醇和/或聚（氧化烯）二醇醚。

公开(公告)号：WO2005018300A2

公开(公告)日：2005-03-03

申请号：PCT/US2004/025328

申请日：2004-08-04

Applicant: CHEVRON ORONITE COMPANY LLC ,  CAMPBELL, Curt, B. ,  SINQUIN, Gilles, P.

Inventor： CAMPBELL, Curt, B. ,  SINQUIN, Gilles, P.

IPC: C07C309/00 ,  C07C309/31 ,  C09K3/00 ,  C09K8/584 ,  E21B43/22

CPC classification number: C09K8/584 ,  C07C309/31

Abstract: The present invention is directed to alkylxylene sulfonate for enhanced oil recovery processes. The alkylxylene moiety in the alkylxylene sulfonate contains a high percentage of the 4-alkyl-1,2-dimethyl benzene isomer and a high percentage of alkyl group attachment to the xylene ring at positions higher than the 2-position on the alkyl carbon chain. The present invention is also directed to a method for enhancing the recovery of oil from a subterranean reservoir which method employs the alkylxylene sulfonate of the present invention. The alkylxylene sulfonate is employed in an aqueous media. The method optionally employs co-surfactants. It has surprisingly been discovered that the high percentage of the 4-alkyl-1,2-dimethyl benzene isomer and the high percentage alkyl group attachment to the xylene moiety at positions higher than the 2-position along the alkyl carbon chain on the alkylxylene sulfonate of the present invention provides an enhanced oil recovery (EOR) surfactant having low Interfacial Tension (IFT).

Abstract translation: 本发明涉及用于强化油采收过程的烷基二甲苯磺酸盐。 烷基二甲苯磺酸盐中的烷基二甲苯部分包含高百分比的4-烷基-1,2-二甲基苯异构体和高于烷基碳链2位的高百分比烷基连接到二甲苯环。 本发明还涉及一种提高从地下储层采收油的方法，该方法使用本发明的烷基二甲苯磺酸盐。 烷基二甲苯磺酸盐用于水性介质中。 该方法任选使用助表面活性剂。 令人惊讶地发现，高于烷基二甲苯磺酸盐上沿烷基碳链的2位的高比例的4-烷基-1,2-二甲基苯异构体和高百分比的烷基连接到二甲苯部分 本发明提供了具有低界面张力（IFT）的强化油采收率（EOR）表面活性剂。

公开(公告)号：WO2009085970A1

公开(公告)日：2009-07-09

申请号：PCT/US2008/087453

申请日：2008-12-18

Applicant: CHEVRON ORONITE COMPANY LLC ,  CHEVRON ORONITE S.A. ,  SINQUIN, Gilles, P. ,  CAMPBELL, Curt, B.

Inventor： SINQUIN, Gilles, P. ,  CAMPBELL, Curt, B.

IPC: C07C2/70 ,  C07C15/107

CPC classification number: C07C2/70 ,  C07C2527/03 ,  C07C2527/054 ,  C07C2527/11 ,  C07C2527/1206 ,  C07C2531/025 ,  C07C15/107

Abstract: A process for alkylating an aromatic compound comprising reacting at least one aromatic compound with a mixture of olefins having from about 8 to about 100 carbon atoms, in the presence of a strong acid catalyst wherein the resulting product comprises at least about 60 weight percent of a 1, 2, 4 tri-alkylsubstituted aromatic compound.

Abstract translation: 一种用于烷基化芳族化合物的方法，包括在强酸催化剂存在下使至少一种芳族化合物与具有约8至约100个碳原子的烯烃的混合物反应，其中所得产物包含至少约60重量％的 1,2,4烷基取代的芳族化合物。

公开(公告)号：WO2009017498A1

公开(公告)日：2009-02-05

申请号：PCT/US2007/074842

申请日：2007-07-31

Applicant: CHEVRON ORONITE COMPANY LLC ,  CAMPBELL, Curt B. ,  SINQUIN, Gilles

Inventor： CAMPBELL, Curt B. ,  SINQUIN, Gilles

IPC: C07C37/00

CPC classification number: C07C2/70 ,  C07C2527/1206 ,  C07C15/113

Abstract: A process for alkylating an aromatic compound comprising reacting (a) a first amount of at least one aromatic compound with a first amount of a mixture of olefins having from about 8 to about 100 carbon atoms, in the presence of a strong acid catalyst; and reacting the product of (a) with an additional amount of at least one aromatic compound and an additional amount of a strong acid catalyst, and optionally, with an additional amount of a mixture of olefins selected from olefins having from about 8 to about 100 carbon atoms, wherein the resulting product comprises at least about 8 to about 100 carbon atoms, wherein the resulting product comprises at least about 80 weight percent of a 1, 2, 4 tri-alkylsubstituted aromatic compound.

Abstract translation: 一种用于烷基化芳族化合物的方法，包括在强酸催化剂存在下使（a）第一量的至少一种芳族化合物与第一量的具有约8至约100个碳原子的烯烃的混合物反应; 和使（a）的产物与另外量的至少一种芳族化合物和另外量的强酸催化剂反应，和任选地与另外量的选自具有约8至约100的烯烃的烯烃混合物 碳原子，其中所得产物包含至少约8至约100个碳原子，其中所得产物包含至少约80重量％的1,2,4-三烷基取代的芳族化合物。

公开(公告)号：WO2005018300A3

公开(公告)日：2005-06-23

申请号：PCT/US2004025328

申请日：2004-08-04

Applicant: CHEVRON ORONITE CO ,  CAMPBELL CURT B ,  SINQUIN GILLES P

Inventor： CAMPBELL CURT B ,  SINQUIN GILLES P

IPC: C07C309/00 ,  C07C309/31 ,  C09K3/00 ,  C09K8/584 ,  E21B43/22

CPC classification number: C09K8/584 ,  C07C309/31

Abstract: The present invention is directed to alkylxylene sulfonate for enhanced oil recovery processes. The alkylxylene moiety in the alkylxylene sulfonate contains a high percentage of the 4-alkyl-1,2-dimethyl benzene isomer and a high percentage of alkyl group attachment to the xylene ring at positions higher than the 2-position on the alkyl carbon chain. The present invention is also directed to a method for enhancing the recovery of oil from a subterranean reservoir which method employs the alkylxylene sulfonate of the present invention. The alkylxylene sulfonate is employed in an aqueous media. The method optionally employs co-surfactants. It has surprisingly been discovered that the high percentage of the 4-alkyl-1,2-dimethyl benzene isomer and the high percentage alkyl group attachment to the xylene moiety at positions higher than the 2-position along the alkyl carbon chain on the alkylxylene sulfonate of the present invention provides an enhanced oil recovery (EOR) surfactant having low Interfacial Tension (IFT).

Abstract translation: 本发明涉及用于增强采油工艺的烷基二甲苯磺酸盐。 烷基二甲苯磺酸中的烷基二甲苯部分含有高百分比的4-烷基-1,2-二甲基苯异构体，并且在高于烷基碳链上的2-位的位置上高的百分比的烷基连接到二甲苯环。 本发明还涉及一种用于增强从地下储层中回收油的方法，该方法采用本发明的烷基二甲苯磺酸盐。 烷基二甲苯磺酸盐用于水性介质中。 该方法任选地使用助表面活性剂。 令人惊讶地发现，高烷基1,2-二甲基苯异构体的高百分比和在烷基二甲苯磺酸盐上沿着烷基碳链的2-位高的二甲苯部分附着的高百分比烷基 的本发明提供了具有低界面张力（IFT）的增强油回收（EOR）表面活性剂。

公开(公告)号：WO2009086140A2

公开(公告)日：2009-07-09

申请号：PCT/US2008/087739

申请日：2008-12-19

Applicant: CHEVRON ORONITE COMPANY LLC ,  CHEVRON ORONITE S.A. ,  CAMPBELL, Curt B. ,  SINQUIN, Gilles P. ,  SPALA, Eugene E. ,  CHAPON, Gilbert R.

Inventor： CAMPBELL, Curt B. ,  SINQUIN, Gilles P. ,  SPALA, Eugene E. ,  CHAPON, Gilbert R.

IPC: C10M169/04 ,  C10M129/10 ,  C10M129/50

CPC classification number: C10M159/20 ,  C10M159/22 ,  C10M2203/1025 ,  C10M2207/262 ,  C10M2215/28 ,  C10M2219/044 ,  C10M2223/045 ,  C10N2210/06 ,  C10N2220/028 ,  C10N2230/02 ,  C10N2230/04 ,  C10N2240/02 ,  C10N2240/04 ,  C10N2270/00 ,  C10N2220/022 ,  C10N2260/00 ,  C10N2260/14 ,  C10N2210/02

Abstract: A carboxylate detergent prepared by the process comprising (a) alkylating a hydroxyaromatic compound with at least one normal alpha olefin having from about 12 to about 30 carbon atoms per molecule that has been isomerized to obtain an isomerized alpha olefin having 15-98 wt% branching and a residual alpha olefin content of between from about 0.1 to about 30 wt%, thereby producing an alkylated hydroxyaromatic compound; (b) neutralizing the resulting alkylated hydroxyaromatic compound with an alkali metal base; (c) carbonating the alkali metal salt from step (b) with carbon dioxide; (d) acidifying the salt produced in step (c); and (e) overbasing the resulting alkylated hydroxyaromatic carboxylic acid.

Abstract translation: 通过包括以下步骤的方法制备的羧酸盐清净剂：（a）用至少一种每分子具有约12至约30个碳原子的正构α-烯烃将羟基芳族化合物烷基化，所述正构α-烯烃已被异构化以获得异构化的α α-烯烃具有15-98wt％的支链和残余α-烯烃含量为约0.1-约30wt％，从而产生烷基化的羟基芳族化合物; （b）用碱金属碱中和得到的烷基化羟基芳族化合物; （c）用二氧化碳碳酸化来自步骤（b）的碱金属盐; （d）酸化步骤（c）中产生的盐; 和（e）高碱化得到的烷基化羟基芳族羧酸。