公开(公告)号：WO2012168355A1

公开(公告)日：2012-12-13

申请号：PCT/EP2012/060790

申请日：2012-06-07

Applicant: ANTECY B.V. ,  O'CONNOR, Paul ,  GARCIA GÓMEZ, Hermenegildo ,  CORMA CAMOS, Avelino

Inventor： O'CONNOR, Paul ,  GARCIA GÓMEZ, Hermenegildo ,  CORMA CAMOS, Avelino

IPC: B01J21/16 ,  B01J23/02 ,  B01J23/10 ,  B01J35/00 ,  B01J35/02 ,  B01J21/06 ,  C01B3/06

CPC classification number: B01J19/127 ,  B01J21/063 ,  B01J21/16 ,  B01J23/02 ,  B01J23/10 ,  B01J35/002 ,  B01J35/004 ,  B01J35/023 ,  C07C29/159 ,  Y02P20/52 ,  C07C31/04

Abstract: A photocatalytic process is disclosed for the reduction of carbon dioxide and water. The process comprises reacting carbon dioxide and water in the presence of a photocatalytic composition that is irradiated with electromagnetic radiation having a wavelength in the range of from 200 to 700 nm. The photocatalytic composition is capable of chemisorbing carbon dioxide.

Abstract translation: 公开了用于还原二氧化碳和水的光催化方法。 该方法包括在光波导组合物存在下使二氧化碳和水反应，所述光催化组合物用波长在200-700nm范围内的电磁辐射照射。 光催化组合物能够化学吸收二氧化碳。

公开(公告)号：WO2009118363A3

公开(公告)日：2009-10-01

申请号：PCT/EP2009/053550

申请日：2009-03-25

Applicant: KIOR, INC. ,  O'CONNOR, Paul ,  DAAMEN, Sjoerd ,  CORMA CAMOS, Avelino

Inventor： O'CONNOR, Paul ,  DAAMEN, Sjoerd ,  CORMA CAMOS, Avelino

IPC: C10B53/00 ,  C10B53/02 ,  C10B49/00

Abstract: Disclosed is a pyrolysis product of a biomass material. This product, referred to as bio-crude, has a total acid number (TAN) of less than 10, and is suitable for processing in stainless steel equipment. A process for making the bio-crude comprises pyrolysis of a biomass in the presence of a particulate catalyst. The TAN of the bio-crude may be reduced further by reducing the bio-crude with coke and or CO produced in the process.

公开(公告)号：WO1997019021A1

公开(公告)日：1997-05-29

申请号：PCT/ES1996000218

申请日：1996-11-19

Applicant: CONSEJO SUPERIOR INVESTIGACIONES CIENTIFICAS ,  UNIVERSIDAD POLITECNICA DE VALENCIA ,  DIAZ CABANAS, Mª José ,  CAMBLOR FERNANDEZ, Miguel Angel ,  CORELL MARTIRES, Catalina ,  CORMA CAMOS, Avelino

Inventor： CONSEJO SUPERIOR INVESTIGACIONES CIENTIFICAS ,  UNIVERSIDAD POLITECNICA DE VALENCIA

IPC: C01B37/02

CPC classification number: C10G47/16 ,  B01J29/035 ,  B01J29/04 ,  B01J29/70 ,  C01B37/005 ,  C01B37/02 ,  C01B39/48 ,  C07C4/06 ,  C07C5/2775 ,  C07C7/13 ,  C07C2529/70 ,  C10G11/05 ,  C10G45/64 ,  C07C11/02

Abstract: The present invention relates to a microporous crystalline material of zeolitic nature, called ITQ-1A, to the process for its preparation and its use in processes of separation and transformation of organic compounds. In the roasted and anhydrous stage, the chemical composition of the material corresponds to the empirical formula: x(M1/nXO2):yYO2:SIO2, wherein x has a value smaller than 0.02 and may equal 0; y has a value smaller than 0.04 and may equal 0; m is H or an inorganic cation with the charge +n; X is a chemical element with an oxidation status +3 (Al, Ga, B, Cr) and Y is a chemical element with an oxidation status +4 (Ti, Ge, V). When x = 0 and y = 0, the material may be described as a new polymorphe form of microporous silica. The material of this invention is characterized also by its X ray diffraction pattern. The process for the preparation of said zeolite is characterized by the use of one or a plurality of organic additives in a reaction mixture which is crystallized through heating.

Abstract translation: 本发明涉及沸石性质的微孔结晶材料，称​​为ITQ-1A，用于其制备方法及其在有机化合物的分离和转化过程中的应用。 在焙炒和无水阶段，材料的化学成分对应于经验公式：x（M1 / nXO2）：yYO2：SIO2，其中x的值小于0.02，可以等于0; y的值小于0.04，可以等于0; m是H +或电荷+ n的无机阳离子; X是氧化态为+3（Al，Ga，B，Cr）的化学元素，Y是氧化态为+4（Ti，Ge，V）的化学元素。 当x = 0和y = 0时，材料可以被描述为新的多孔形式的微孔二氧化硅。 本发明的材料的特征在于其X射线衍射图。 制备所述沸石的方法的特征在于在通过加热结晶的反应混合物中使用一种或多种有机添加剂。

公开(公告)号：WO2008052993A2

公开(公告)日：2008-05-08

申请号：PCT/EP2007/061695

申请日：2007-10-30

Applicant: BIOECON INTERNATIONAL HOLDING N.V. ,  O'CONNOR, Paul ,  CORMA CAMOS, Avelino ,  HUBER, George ,  SAVANAUD, Louis, Andre

Inventor： O'CONNOR, Paul ,  CORMA CAMOS, Avelino ,  HUBER, George ,  SAVANAUD, Louis, Andre

IPC: C07C47/22 ,  C07C45/52

CPC classification number: C07C45/52 ,  C07C47/263 ,  C07C47/06 ,  C07C47/22 ,  C07C49/08

Abstract: Disclosed is a process for the production of acrolein and other oxygenated compounds from glycerol. Use is made of an acidic catalyst in a moving bed reactor at 200 - 650°C.

Abstract translation: 公开了从甘油生产丙烯醛和其它含氧化合物的方法。 在200-650℃的移动床反应器中使用酸性催化剂。

公开(公告)号：WO2008020047A2

公开(公告)日：2008-02-21

申请号：PCT/EP2007/058467

申请日：2007-08-15

Applicant: BIOECON INTERNATIONAL HOLDING N.V. ,  O'CONNOR, Paul ,  HUBER, George, W. ,  CORMA CAMOS AVELINO, Avelino ,  SAVANAUD, Laurent, Louis, André

Inventor： O'CONNOR, Paul ,  HUBER, George, W. ,  CORMA CAMOS AVELINO, Avelino ,  SAVANAUD, Laurent, Louis, André

IPC: C10G3/00 ,  C10G11/02 ,  C10G11/18 ,  C10G51/02

CPC classification number: C10G3/57 ,  C10G3/46 ,  C10G3/47 ,  C10G3/49 ,  C10G11/18 ,  C10G51/026 ,  C10G2300/1011 ,  C10G2300/1074 ,  C10G2300/4006 ,  C10G2300/805 ,  Y02E50/10 ,  Y02E50/30 ,  Y02P30/20

Abstract: A process is disclosed for fluid catalytic cracking of oxygenated hydrocarbon compounds such as glycerol and bio-oil. In the process the oxygenated hydrocarbon compounds are contacted with a fluid cracking catalyst material for a period of less than 3 seconds. In a preferred process a crude-oil derived material, such as VGO, is also contacted with the catalyst.

Abstract translation: 公开了用于氧化烃化合物如甘油和生物油的流体催化裂化的方法。 在该方法中，含氧烃化合物与流体裂化催化剂材料接触少于3秒的时间。 在优选的方法中，原油衍生的材料如VGO也与催化剂接触。

公开(公告)号：WO2008006904A1

公开(公告)日：2008-01-17

申请号：PCT/EP2007/057257

申请日：2007-07-13

Applicant: BIOECON INTERNATIONAL HOLDING N.V. ,  O'CONNOR, Paul ,  CORMA CAMOS AVELINO, Avelino ,  HUBER, George W.

Inventor： O'CONNOR, Paul ,  CORMA CAMOS AVELINO, Avelino ,  HUBER, George W.

IPC: C01B3/44 ,  C10G11/18

CPC classification number: C10G11/182 ,  C01B3/44 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/1211 ,  C10G2300/1014 ,  C10G2300/708 ,  C10G2300/80 ,  C10G2300/807 ,  Y02P20/142 ,  Y02P20/145 ,  Y02P20/52 ,  Y02P30/20

Abstract: A method is disclosed for producing a mixture of CO and H 2 (syn-gas). The method comprises contacting particles containing a coke deposit with oxygenated molecules derived from biomass. In a preferred embodiment the particles are catalyst particles. The method may be carried out in the regenerator of a conventional fluid catalytic cracking (FCC) unit.

Abstract translation: 公开了一种用于生产CO和H 2 H 2（合成气）的混合物的方法。 该方法包括将含有焦炭沉积物的颗粒与衍生自生物质的氧化分子接触。 在优选的实施方案中，颗粒是催化剂颗粒。 该方法可以在常规流化催化裂化（FCC）单元的再生器中进行。

公开(公告)号：WO2009118363A2

公开(公告)日：2009-10-01

申请号：PCT/EP2009053550

申请日：2009-03-25

Applicant: KIOR INC ,  O'CONNOR PAUL ,  DAAMEN SJOERD ,  CORMA CAMOS AVELINO

Inventor： O'CONNOR PAUL ,  DAAMEN SJOERD ,  CORMA CAMOS AVELINO

IPC: C10B53/00 ,  C10B49/00 ,  C10B53/02

CPC classification number: C10B53/02 ,  C10C5/00 ,  C10G3/42 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/203 ,  C10L1/02 ,  Y02E50/14 ,  Y02P30/20

Abstract: Disclosed is a pyrolysis product of a biomass material. This product, referred to as bio-crude, has a total acid number (TAN) of less than 10, and is suitable for processing in stainless steel equipment. A process for making the bio-crude comprises pyrolysis of a biomass in the presence of a particulate catalyst. The TAN of the bio-crude may be reduced further by reducing the bio-crude with coke and or CO produced in the process.

Abstract translation: 公开了一种生物质材料的热解产物。 该产品称为生物粗品，总酸值（TAN）小于10，适用于不锈钢设备加工。 制备生物粗品的方法包括在颗粒催化剂存在下热解生物质。 生物粗品的TAN可以通过在该过程中产生的焦炭和/或CO来减少生物粗品而进一步减少。

公开(公告)号：WO2008052993A3

公开(公告)日：2008-07-17

申请号：PCT/EP2007061695

申请日：2007-10-30

Applicant: BIOECON INT HOLDING NV ,  O'CONNOR PAUL ,  CORMA CAMOS AVELINO ,  HUBER GEORGE ,  SAVANAUD LOUIS ANDRE

Inventor： O'CONNOR PAUL ,  CORMA CAMOS AVELINO ,  HUBER GEORGE ,  SAVANAUD LOUIS ANDRE

IPC: C07C47/22 ,  C07C45/52

CPC classification number: C07C45/52 ,  C07C47/263 ,  C07C47/06 ,  C07C47/22 ,  C07C49/08

Abstract: Disclosed is a process for the production of acrolein and other oxygenated compounds from glycerol. Use is made of an acidic catalyst in a moving bed reactor at 200 - 650°C.

Abstract translation: 公开了一种由甘油制备丙烯醛和其他含氧化合物的方法。 在200-650℃的移动床反应器中使用酸性催化剂。

公开(公告)号：WO2008020048A3

公开(公告)日：2008-04-24

申请号：PCT/EP2007058468

申请日：2007-08-15

Applicant: BIOECON INT HOLDING NV ,  O'CONNOR PAUL ,  STAMIRES DENNIS ,  CORMA CAMOS AVELINO AVELINO ,  HUBER GEORGE W

Inventor： O'CONNOR PAUL ,  STAMIRES DENNIS ,  CORMA CAMOS AVELINO AVELINO ,  HUBER GEORGE W

IPC: C10G3/00 ,  C07C5/02 ,  C07C9/22 ,  C10G45/02 ,  C10L1/08

CPC classification number: C10G3/50 ,  C10G3/46 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/1059 ,  C10G2300/4012 ,  C10G2300/805 ,  C10G2400/04 ,  Y02P30/20

Abstract: A process is disclosed for mild hydro-conversion of oxygenated hydrocarbon compounds. The oxygenated hydrocarbon compounds are contacted with a hydro- conversion catalyst material at a reaction pressure below 100 bar. Preferred oxygenated hydrocarbon compounds are those obtained by the liquefaction of biomass. In a specific embodiment the process is used for production of normal alkanes by hydrotreating mixtures of triglycerides (or compounds derived-from triglycerides, including free fatty acids) and vacuum gasoil.

Abstract translation: 公开了用于含氧烃化合物的温和加氢转化的方法。 含氧烃化合物在低于100巴的反应压力下与加氢转化催化剂材料接触。 优选的含氧烃化合物是通过液化生物质获得的那些。 在一个具体的实施方案中，该方法用于通过加氢处理甘油三酯（或来自甘油三酯，包括游离脂肪酸的化合物）和真空瓦斯油的混合物来生产正烷烃。

公开(公告)号：WO2008020047A3

公开(公告)日：2008-04-03

申请号：PCT/EP2007058467

申请日：2007-08-15

Applicant: BIOECON INT HOLDING NV ,  O'CONNOR PAUL ,  HUBER GEORGE W ,  CORMA CAMOS AVELINO AVELINO ,  SAVANAUD LAURENT LOUIS ANDRE

Inventor： O'CONNOR PAUL ,  HUBER GEORGE W ,  CORMA CAMOS AVELINO AVELINO ,  SAVANAUD LAURENT LOUIS ANDRE

IPC: C10G3/00 ,  C10G11/02 ,  C10G11/18 ,  C10G51/02

CPC classification number: C10G3/57 ,  C10G3/46 ,  C10G3/47 ,  C10G3/49 ,  C10G11/18 ,  C10G51/026 ,  C10G2300/1011 ,  C10G2300/1074 ,  C10G2300/4006 ,  C10G2300/805 ,  Y02E50/10 ,  Y02E50/30 ,  Y02P30/20

Abstract: A process is disclosed for fluid catalytic cracking of oxygenated hydrocarbon compounds such as glycerol and bio-oil. In the process the oxygenated hydrocarbon compounds are contacted with a fluid cracking catalyst material for a period of less than 3 seconds. In a preferred process a crude-oil derived material, such as VGO, is also contacted with the catalyst.

Abstract translation: 公开了一种用于含氧化合物如甘油和生物油的流化催化裂化的方法。 在该过程中，氧化烃化合物与流体裂解催化剂材料接触少于3秒的时间。 在优选的方法中，原油衍生的材料，例如VGO，也与催化剂接触。