公开(公告)号：WO2015131123A1

公开(公告)日：2015-09-03

申请号：PCT/US2015/018133

申请日：2015-02-27

Applicant: KIOR, INC.

Inventor： RAMIREZ CORREDORES, Maria Magdalena ,  MAY, Leslie

IPC: C10G11/00

CPC classification number: C10B57/10 ,  C10B53/02 ,  C10B57/06 ,  C10B57/08 ,  Y02E50/14 ,  Y02P20/145

Abstract: A process for enhancing the conversion of biomass into a bio-oil containing liquid feed wherein the processability index, PI, of the biomass is optimized prior to introducing the biomass into the biomass conversion unit where catalytic pyrolysis of the biomass occurs. The PI is dependent on the ratio (S/G) between the S-unit population and the G-unit population of the biomass as well as the weight percent acetate, the weight percent alkaline (Group I metals), the weight percent of non-metals in the biomass of Group 15, Group 16 and Group 17 elements, the weight percent of metalloids (Group 13 and Group 14 elements), the weight percent xylan and the weight percent of alkaline earth (Group II metals) in the biomass feedstream.

Abstract translation: 一种用于增强生物质转化为含生物油的液体原料的方法，其中在将生物质引入生物质转化单元之前，优化生物质的加工性指数PI，其中生物质发生催化裂解。 PI依赖于S单位群体与生物量G单位种群之间的比例（S / G）以及乙酸盐的重量百分比，碱性（I族金属）的重量百分比，非 - 在第15组，第16组和第17组元素的生物质中的金属，准金属（第13族和第14族元素）的重量百分比，木聚糖的重量百分比和碱土金属（第II族金属）在生物质原料流中的重量百分比 。

公开(公告)号：WO2013123297A3

公开(公告)日：2015-07-09

申请号：PCT/US2013026297

申请日：2013-02-15

Applicant: KIOR INC ,  STAMIRES DENNIS ,  BRADY MICHAEL

Inventor： STAMIRES DENNIS ,  BRADY MICHAEL

IPC: C01B33/36

CPC classification number: B01J31/26 ,  B01J21/16 ,  B01J29/06 ,  B01J29/08 ,  B01J29/084 ,  B01J29/18 ,  B01J29/40 ,  B01J29/70 ,  B01J29/7007 ,  B01J31/06 ,  B01J35/023 ,  B01J35/1061 ,  B01J35/1071 ,  B01J35/109 ,  B01J37/0018 ,  B01J37/0045 ,  B01J37/28 ,  B01J2229/186 ,  B01J2229/42 ,  B01J2231/005 ,  B01J2231/49 ,  C10G1/086 ,  C10G3/49 ,  Y02P30/20

Abstract: Processes for making a catalytic system and catalytic systems for converting solid biomass into fuel or specialty chemical products, or for upgrading bio-oils are described. The catalyst system may comprise a non-zeolitic matrix with a hierarchical pore structure ranging from 300 to about 104 Angstrom pore size, a zeolite, such as MFI-type or IM-5 zeolite, and a binder.

Abstract translation: 描述了制备用于将固体生物质转化为燃料或特种化学产品或用于升级生物油的催化体系和催化体系的方法。 催化剂体系可以包含具有300至约104埃孔径的分级孔结构的沸石基质，诸如MFI型或IM-5沸石的沸石和粘合剂。

公开(公告)号：WO2015081104A1

公开(公告)日：2015-06-04

申请号：PCT/US2014/067421

申请日：2014-11-25

Applicant: KIOR, INC.

Inventor： RAMIREZ-CORREDORES, Maria Magdalena ,  MAY, Leslie ,  PARADISE, Christopher ,  KENT, Nicholas ,  TONG, Xiaowei ,  BANDA, Rocio Maria ,  ROEMISCH, Royce

IPC: C10G25/00

CPC classification number: C10G25/003 ,  C07C37/82 ,  C07C45/79 ,  C07C51/47 ,  C10G25/03 ,  C07C39/04 ,  C07C39/08 ,  C07C39/07 ,  C07C49/10 ,  C07C49/205 ,  C07C47/04 ,  C07C47/06 ,  C07C53/08 ,  C07C53/122 ,  C07C49/17

Abstract: Disclosed is a process for recovering a water-soluble complex mixture of organic compounds from an aqueous stream through extraction and/or through contact of the aqueous stream with a sorbent or sorbents selected from the group consisting of polymeric microreticular sorbent resins, zeolite-based adsorbents, clay- based adsorbents, activated carbon-based sorbents, and mixtures thereof; and including methods to recover and upgrade the removed organic compounds.

Abstract translation: 公开了一种通过萃取和/或通过水性流与吸附剂或吸附剂的接触从水流中回收有机化合物的水溶性络合物混合物的方法，所述吸附剂或吸附剂选自聚合物微网吸附剂树脂，沸石基吸附剂 ，粘土基吸附剂，活性炭基吸附剂及其混合物; 并且包括恢复和升级除去的有机化合物的方法。

公开(公告)号：WO2015023430A1

公开(公告)日：2015-02-19

申请号：PCT/US2014/048648

申请日：2014-07-29

Applicant: KIOR, INC.

Inventor： RAMIREZ-CORREDORES, Maria, Magdalena ,  ZHANG, Changan

IPC: C10G7/00 ,  C10G3/00

CPC classification number: C10G3/50 ,  C10G2300/802 ,  Y02P30/20

Abstract: A process and system for separating a light fraction, a bio-distillate fraction, and a heavy fraction from a bio-oil, and for producing a renewable distillate including at least in part the bio-distillate fraction and a stabilizing additive, is provided. In addition, a process and system is provided for upgrading a bio-oil by use of a diluent and/or a recycle stream from the upgrading process to reduce fouling in upgrading equipment, such as a preheater and a hydrodeoxygenation unit.

Abstract translation: 提供了用于从生物油分离轻馏分，生物馏出物馏分和重馏分，以及用于生产至少部分包括生物馏分和稳定添加剂的可再生馏出物的方法和系统。 此外，提供了一种通过使用稀释剂和/或来自升级过程的再循环流来升级生物油的方法和系统，以减少升级设备如预热器和加氢脱氧单元中的结垢。

公开(公告)号：WO2014078799A1

公开(公告)日：2014-05-22

申请号：PCT/US2013/070591

申请日：2013-11-18

Applicant: KIOR, INC.

Inventor： TREWELLA, Jeffrey C. ,  SMITH, Edward J. ,  SANCHEZ, Vicente ,  MOORE, Brent ,  MCGOVERN, Stephen J. ,  BAUER, Lorenz J. ,  MAY, Leslie ,  RAMIREZ CORREDORES, Maria Magdalena ,  PARADISE, Christopher ,  KENT, Nicholas

IPC: C07C2/86 ,  C10G3/00 ,  C10G45/02 ,  C10G45/04

CPC classification number: C10G3/50 ,  C07C45/70 ,  C07C45/74 ,  C10G3/42 ,  C10G3/44 ,  C10G45/02 ,  C10G45/04 ,  C10G2300/1011 ,  C10G2400/02 ,  C10G2400/04 ,  C10L1/04 ,  C10L2200/0469 ,  C10L2290/02 ,  C10L2290/543 ,  Y02P30/20

Abstract: A renewable fuel may be obtained from a bio-oil containing C3-C5 oxygenates. In a first step, the bio-oil is subjected to a condensation reaction in which the oxygenates undergo a carbon-carbon bond forming reaction to produce a stream containing C6+ oxygenates. In a second step, the stream is hydrotreated to produce C6+ hydrocarbons.

Abstract translation: 可以从含有C3-C5氧化物的生物油获得可再生燃料。 在第一步骤中，使生物油进行缩合反应，其中含氧化合物进行碳 - 碳键形成反应以产生含有C6 +含氧化合物的物流。 在第二步中，将该物流加氢处理以产生C6 +烃。

公开(公告)号：WO2014015145A2

公开(公告)日：2014-01-23

申请号：PCT/US2013/051091

申请日：2013-07-18

Applicant: KIOR, INC.

Inventor： LIN, Ronny, W. ,  BAUER, Lorenz, J.

IPC: C10G3/00

CPC classification number: C10G3/50 ,  C10G31/09 ,  C10G2300/1011 ,  C10G2300/301 ,  C10G2300/4081 ,  C10G2400/02 ,  C10L1/06 ,  Y02P30/20

Abstract: A process for preparing a renewable biofuel consists of subjecting a bio-oil mixture to deoxygenation in a hydrotreater and then separating hydrocarbon fractions from the deoxygenated product to form the biofuel. The bio-oil mixture contains a biooil feedstream and a treated bio-oil feed. The treated bio-oil feed is a stream from which undesirable heavy materials and solid materials have been removed.

Abstract translation: 制备可再生生物燃料的方法包括在加氢处理器中对生物油混合物进行脱氧，然后从脱氧产物中分离烃馏分以形成生物燃料。 生物油混合物含有生物油进料流和经处理的生物油进料。 经处理的生物油进料是不期望的重质材料和固体材料已经被除去的物流。

公开(公告)号：WO2013165644A1

公开(公告)日：2013-11-07

申请号：PCT/US2013/035276

申请日：2013-04-04

Applicant: KIOR, INC.

Inventor： CORREDORES, Maria Magdalena, Ramirez ,  TONG, Xiaowei ,  SORRELLS, Jennifer

IPC: C10L1/32 ,  C10G3/00

CPC classification number: B01D1/225 ,  B01D3/009 ,  B01D3/12 ,  B01D5/006 ,  C10B53/02 ,  C10B57/06 ,  C10G7/04 ,  C10G7/06 ,  C10G2300/203 ,  C10G2300/301 ,  Y02E50/14 ,  Y02P20/145 ,  Y02P30/20

Abstract: Disclosed is a process/system for the fractionation of bio-oil, produced from the thermo-catalytic conversion of biomass, into boiling point fractions. The fractionation of the bio-oil is performed using molecular distillation under conditions which minimize the thermal stress to the bio-oil and fractions obtained therefrom.

Abstract translation: 公开了一种用于将由生物质的热催化转化产生的生物油分馏成沸点馏分的方法/系统。 在使生物油的热应力最小化和从其获得的馏分最小化的条件下，使用分子蒸馏进行生物油的分馏。

公开(公告)号：WO2013123299A1

公开(公告)日：2013-08-22

申请号：PCT/US2013/026300

申请日：2013-02-15

Applicant: KIOR, INC. ,  STAMIRES, Dennis ,  BRADY, Michael

Inventor： STAMIRES, Dennis ,  BRADY, Michael

IPC: C01B33/36

CPC classification number: C10G3/49 ,  B01J21/16 ,  B01J29/084 ,  B01J29/40 ,  B01J29/7007 ,  B01J29/82 ,  B01J35/109 ,  B01J37/0018 ,  B01J37/0045 ,  B01J2229/16 ,  B01J2229/186 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/38 ,  B01J2229/42 ,  Y02P30/20

Abstract: Processes for making a catalytic system and catalytic systems for converting solid biomass into fuel of specialty chemical products are described. The catalyst system may comprise a non-zeolitic matrix and an in situ grown zeolite, such as MFI-type zeolite, with a meso-micro hierarchical pore structure. In some embodiments, the non-zeolitic matrix has a meso-macro hierarchical pore structure.

Abstract translation: 描述了制备用于将固体生物质转化为特种化学产品的燃料的催化体系和催化体系的方法。 催化剂体系可以包含非沸石基质和原位生长的沸石，例如MFI型沸石，具有中等微观层次的孔结构。 在一些实施方案中，非沸石基质具有中等 - 宏分级孔结构。

公开(公告)号：WO2013062972A2

公开(公告)日：2013-05-02

申请号：PCT/US2012/061493

申请日：2012-10-23

Applicant: TREWELLA, Jeffrey C. ,  KIOR, INC.

Inventor： TREWELLA, Jeffrey C.

IPC: C10L1/06

CPC classification number: C10G1/002 ,  C10G1/006 ,  C10G3/40 ,  C10G3/42 ,  C10G3/50 ,  C10G35/04 ,  C10G35/085 ,  C10G35/09 ,  C10G59/00 ,  C10G2300/1014 ,  C10G2300/301 ,  C10G2300/305 ,  C10G2400/02 ,  C10G2400/30 ,  C10L1/06 ,  Y02P30/20

Abstract: Naphtha compositions with enhanced reformability are provided. The naphtha compositions can be derived from biomass, can exhibit improved N + 2A values, and can be used as a reformer feedstock with little or no processing.

Abstract translation: 提供了具有增强的可重新性的石脑油组合物。 石脑油组合物可以衍生自生物质，可以显示出改善的N + 2A值，并且可以用作很少或不加工的重整器原料。

公开(公告)号：WO2012109034A2

公开(公告)日：2012-08-16

申请号：PCT/US2012/022945

申请日：2012-01-27

Applicant: KIOR, INC. ,  CORREDORES, Maria Magdalena Ramirez ,  SANCHEZ, Vicente

Inventor： CORREDORES, Maria Magdalena Ramirez ,  SANCHEZ, Vicente

IPC: C10G3/00 ,  C10L1/02 ,  B09B3/00

CPC classification number: C10L1/02 ,  Y02P30/20

Abstract: More stable and valuable bio-oil produced from biomasses are provided. More specifically, more stable and valuable bio-oil useful as heating oil is provided. Particularly, various embodiments of the present invention provide for a bio-oil having sufficient heating value and stability to be useful as heating oil without the need to hydrotreat the bio-oil or use a similar deoxygenating process.

Abstract translation: 提供了由生物质产生的更稳定和有价值的生物油。 更具体地说，提供了用作加热油的更稳定和有价值的生物油。 特别地，本发明的各种实施方案提供了具有足够的热值和稳定性的生物油，以用作加热油而无需加氢处理生物油或使用类似的脱氧工艺。