SYNTHESIS OF -S-CH2CH2-OH TELECHELIC POLYISOBUTYLENES AND THEIR USE FOR THE PREPARATION OF BIOSTABLE POLYURETHANES
    1.
    发明申请
    SYNTHESIS OF -S-CH2CH2-OH TELECHELIC POLYISOBUTYLENES AND THEIR USE FOR THE PREPARATION OF BIOSTABLE POLYURETHANES 审中-公开
    -S-CH2CH2-OH电话聚异丁烯的合成及其制备生物聚氨酯的用途

    公开(公告)号:WO2016033158A1

    公开(公告)日:2016-03-03

    申请号:PCT/US2015/046898

    申请日:2015-08-26

    Abstract: Sulfur containing, hydroxyl-telechelic PIBs, hydrolytically and oxidatively resistant, biocompatible and biostable polyurethanes (PUs) made therefrom, and methods for making both are disclosed. Well-defined hydroxyl telechelic PIBs are synthesized by a thiol-ene click photochemical reaction between PIBs carrying unsaturated end groups and 2-mercaptoethanol (HS-CH 2 CH 2 -OH). This regioselective process affords HO-CH 2 CH 2 -S-PIB-S-CH 2 CH 2 -OH (abbreviated herein as HO-S-PIB-S-OH) in high yield. In some embodiments, these HO-S-PIB-S-OH polymers may be reacted with diisocyanates and a chain extender to form sulfur containing PIB-based PUs. These sulfur containing PIB-based PUs have been found to have properties and chemical stability that are very similar to that of PUs made from di-hydroxyl terminated PIBs (OH-PIB-OHs) without sulfur, but have surprisingly increased creep resistance and are easier and less expensive to make.

    Abstract translation: 公开了含硫,羟基 - 遥爪PIB,水解和氧化抗性,由其制备的生物相容性和生物稳定性聚氨酯(PU),以及制造两者的方法。 通过携带不饱和端基和2-巯基乙醇(HS-CH2CH2-OH)的PIB之间的硫醇烯键光化学反应合成了明确定义的羟基遥爪PIB。 该区域选择性方法以高产率得到HO-CH 2 CH 2 -S-PIB-S-CH 2 CH 2 -OH(本文缩写为HO-S-PIB-S-OH)。 在一些实施方案中,这些HO-S-PIB-S-OH聚合物可以与二异氰酸酯和扩链剂反应以形成含硫的基于PIB的PU。 已经发现这些含硫的PIB基PU具有与不含硫的二羟基封端的PIB(OH-PIB-OH)制成的PU非常相似的性质和化学稳定性,但具有惊人的增强的抗蠕变性,并且更容易 并且制造成本较低。

    RUBBERY POLYSILOXANES CARRYING CYANOACRYLATE FUNCTIONS AND RELATED METHODS FOR THEIR PREPARATION AND USES THEREFOR
    2.
    发明申请
    RUBBERY POLYSILOXANES CARRYING CYANOACRYLATE FUNCTIONS AND RELATED METHODS FOR THEIR PREPARATION AND USES THEREFOR 审中-公开
    携带氰基丙烯酸酯官能团的橡胶聚硅氧烷及其制备及其用途的相关方法

    公开(公告)号:WO2015054357A1

    公开(公告)日:2015-04-16

    申请号:PCT/US2014/059643

    申请日:2014-10-08

    Abstract: A family of silicone rubbers (e.g., polydimethylsiloxane) carrying one or more cyanoacrylate groups and their methods of production are provided. These silicone rubbers endowed with cyanoacrylate groups are useful in a variety of wound care applications, including wound closures, adhesives, sealants and skin protectors. The silicone rubber moiety provides oxygen and moisture permeability (i.e., "breathability"), biocompatibility, optical transparency, and good mechanical properties, while the cyanoacrylate group imparts instantaneous adhesion/attachment to living tissues such as skin on par with that of contemporary cyanoacrylate-based wound care products.

    Abstract translation: 提供携带一个或多个氰基丙烯酸酯基团的硅橡胶(例如聚二甲基硅氧烷)族及其制备方法。 这些具有氰基丙烯酸酯基团的硅橡胶可用于各种伤口护理应用,包括伤口闭合物,粘合剂,密封剂和皮肤保护剂。 硅橡胶部分提供氧和透湿性(即“透气性”),生物相容性,光学透明性和良好的机械性能,而氰基丙烯酸酯基团将活性组织例如皮肤的瞬时粘附/附着与当代氰基丙烯酸酯 - 基于伤口护理产品。

    NOVEL POLYISOBUTYLENE-BASED THERMOPLASTIC ELASTOMERS
    3.
    发明申请
    NOVEL POLYISOBUTYLENE-BASED THERMOPLASTIC ELASTOMERS 审中-公开
    新型聚异丁烯基热塑性弹性体

    公开(公告)号:WO2014025986A2

    公开(公告)日:2014-02-13

    申请号:PCT/US2013054111

    申请日:2013-08-08

    Abstract: The present invention is directed to a new class of thermoplastic elastomers (TPEs) and processes for making them. In some embodiments of the present invention, the end groups of the multi-arm PIB copolymer is a conjugated diene, whereas the other component is a multi-functional dienophile. The components of the TPE of the present invention are chemically connected via the well-known Diels-Alder reaction which is thermally reversible (by the retro-Diels-Alder reaction) at moderately elevated temperatures. The reversibility of the Diels-Alder retro-Diels-Alder reactions allows the recovery of the original components of the TPE and thus its recyclability and also gives the TPE the ability to be reshaped or reformed.

    Abstract translation: 本发明涉及一类新型热塑性弹性体(TPE)及其制备方法。 在本发明的一些实施方案中,多臂PIB共聚物的端基是共轭二烯,而另一组分是多官能亲双烯体。 本发明的TPE的组分通过公知的Diels-Alder反应进行化学连接,该反应在适度升高的温度下是热可逆的(通过狄尔斯 - 阿尔德反应)。 Diels-Alder retro-Diels-Alder反应的可逆性允许回收TPE的原始组分,从而回收TPE的可回收性,并且还使TPE具有改性或改性的能力。

    PROCESSABLE INORGANIC AND ORGANIC POLYMER FORMULATIONS, METHODS OF PRODUCTION AND USES THEREOF
    4.
    发明申请
    PROCESSABLE INORGANIC AND ORGANIC POLYMER FORMULATIONS, METHODS OF PRODUCTION AND USES THEREOF 审中-公开
    可加工的无机和有机聚合物配方,生产方法及其用途

    公开(公告)号:WO2009108574A2

    公开(公告)日:2009-09-03

    申请号:PCT/US2009034655

    申请日:2009-02-20

    Abstract: Polymer formulations are disclosed and described herein that comprise: at least one polymer comprising at least one hydroxy functional group, at least one acid source, and at least one acid-activated crosslinker that reacts with the polymer. In contemplated embodiments, these polymer formulations are curable at relatively low temperatures, as compared to those polymer formulations not comprising contemplated crosslinkers. Transparent films formed from these contemplated formulations are also disclosed. Organic transparent film compositions are also disclosed that comprise: at least one at least one phenol-based polymer, at least one solvent; at least one acid-activated crosslinker; and at least one acid source. Methods of forming organic transparent films with improved transmittance by depositing on a substrate the formulations disclosed herein and curing the formulations or compositions at a temperature of less than about 200°C. Inorganic transparent film compositions are disclosed that include: at least one silanol-based polymer, at least one solvent; at least one acid-activated crosslinker; and at least one acid source. Methods of forming inorganic transparent films are disclosed by depositing on a substrate the formulations disclosed herein and curing the formulations or compositions at a temperature of 200°C or less.

    Abstract translation: 本文公开和描述的聚合物制剂包含:至少一种包含至少一种羟基官能团的聚合物,至少一种酸源和至少一种与聚合物反应的酸活化的交联剂。 在预期的实施方案中,与不包含预期的交联剂的那些聚合物配方相比,这些聚合物制剂在相对低的温度下是可固化的。 还公开了由这些预期制剂形成的透明膜。 还公开了有机透明膜组合物,其包含:至少一种至少一种苯酚基聚合物,至少一种溶剂; 至少一种酸活化的交联剂; 和至少一种酸源。 通过在基底上沉积本文公开的制剂来形成有机透明薄膜的方法,所述制剂或组合物在小于约200℃的温度下固化。 公开了无机透明膜组合物,其包括:至少一种硅烷醇基聚合物,至少一种溶剂; 至少一种酸活化的交联剂; 和至少一种酸源。 通过在衬底上沉积本文公开的制剂并在200℃或更低的温度下固化该制剂或组合物来公开形成无机透明膜的方法。

    COATING COMPOSITION OPTIMIZATION FOR VIA FILL AND PHOTOLITHOGRAPHY APPLICATIONS AND METHODS OF PREPARATION THEREOF
    5.
    发明申请
    COATING COMPOSITION OPTIMIZATION FOR VIA FILL AND PHOTOLITHOGRAPHY APPLICATIONS AND METHODS OF PREPARATION THEREOF 审中-公开
    涂料组合物通过薄膜和光刻胶应用的优化及其制备方法

    公开(公告)号:WO2005041255A3

    公开(公告)日:2009-04-02

    申请号:PCT/US2004025231

    申请日:2004-08-04

    Abstract: A sacrificial coating material includes: at least one inorganic compound, and at least one material modification agent, wherein the sacrificial coating material is dissolvable in an alkaline-based chemistry or a fluorine-based chemistry. A method of producing a sacrificial coating material includes: providing at least one inorganic compound, providing at least one material modification agent, combining the at least one inorganic compound with the at least one material modification agent to form the sacrificial coating material, wherein the sacrificial coating material is dissolvable in an alkaline-based chemistry or a fluorine-based chemistry, but not organic casting solvents commonly used in organic BARC materials.

    Abstract translation: 牺牲涂层材料包括:至少一种无机化合物和至少一种材料改性剂,其中牺牲涂层材料可溶于碱性化学或氟基化学。 制造牺牲涂料的方法包括:提供至少一种无机化合物,提供至少一种材料改性剂,将至少一种无机化合物与至少一种材料改性剂组合以形成牺牲涂料,其中牺牲 涂料可溶于碱性化学物质或氟基化学物质,但不溶于有机BARC材料中通常使用的有机浇铸溶剂。

    AMPHIPHILIC NETWORKS, PROCESS FOR PRODUCING SAME, AND PRODUCTS MADE THEREFROM
    6.
    发明申请
    AMPHIPHILIC NETWORKS, PROCESS FOR PRODUCING SAME, AND PRODUCTS MADE THEREFROM 审中-公开
    制造网络,其生产方法以及其制造的产品

    公开(公告)号:WO2008124093A1

    公开(公告)日:2008-10-16

    申请号:PCT/US2008/004444

    申请日:2008-04-04

    Abstract: The present invention relates to the production of amphiphilic copolymer networks, or co-networks, and to methods for preparing amphiphilic co-networks. Furthermore, the present invention relates to products and/or films made from the amphiphilic co-networks produced in accordance with the synthesis methods of the present invention. In one embodiment, the present invention is related to crosslinkable and/or polymerizable compositions that can be utilized to form amphiphilic co-networks, where such compositions are block copolymer compositions that are formed from the combination of at least one hydrophilic segment, at least one hydrophobic segment, and at least one crosslinkable and/or polymerizable segment. In yet another embodiment, the present invention relates to amphiphilic co-networks that are optically clear and highly oxyphilic.

    Abstract translation: 本发明涉及两亲性共聚物网络或共同网络的制备以及用于制备两亲性共网络的方法。 此外,本发明涉及由根据本发明的合成方法制备的两亲性共网络制成的产品和/或膜。 在一个实施方案中,本发明涉及可用于形成两亲性共网络的可交联和/或可聚合组合物,其中这样的组合物是由至少一个亲水链段至少一个 疏水链段和至少一个可交联和/或可聚合链段。 在另一个实施方案中,本发明涉及光学透明且高亲氧性的两亲性共网络。

    AMPHIPHILIC GRAFTS AND CO-NETWORKS AND PROCESS FOR MAKING SAME
    7.
    发明申请
    AMPHIPHILIC GRAFTS AND CO-NETWORKS AND PROCESS FOR MAKING SAME 审中-公开
    两亲植物和共同网络及其制造方法

    公开(公告)号:WO2008019044A3

    公开(公告)日:2008-07-10

    申请号:PCT/US2007017312

    申请日:2007-08-03

    CPC classification number: C08L33/26 C08K5/549 C08L83/04 C08L2312/00 C08L83/00

    Abstract: The present invention generally relates to amphiphilic grafts and co-networks made from at least one hydrophilic polymer and at least one hydrophobic polymer, and to processes for preparing such amphiphilic grafts and co-networks. In another embodiment, the present invention relates to amphiphilic co-networks formed from the combination of at least one polysiloxane and at least one polyacrylamide. In yet another embodiment, the present invention relates to amphiphilic co-networks formed from the combination of at least one polysiloxane, at least one polyacrylamide and at least one crosslinking agent.

    Abstract translation: 本发明一般涉及由至少一种亲水聚合物和至少一种疏水聚合物制成的两亲接枝物和共网络物,并且涉及制备这种两亲接枝物和共网络物的方法。 在另一个实施方案中,本发明涉及由至少一种聚硅氧烷和至少一种聚丙烯酰胺的组合形成的两亲共网络。 在又一个实施方案中,本发明涉及由至少一种聚硅氧烷,至少一种聚丙烯酰胺和至少一种交联剂的组合形成的两亲共网络。

    SYSTEM AND METHOD OF OPERATION FOR NETWORK OVERLAY GEOLOCATION SYSTEM WITH REPEATERS USING AM GOLAY HADAMARD SIGNATURES
    9.
    发明申请
    SYSTEM AND METHOD OF OPERATION FOR NETWORK OVERLAY GEOLOCATION SYSTEM WITH REPEATERS USING AM GOLAY HADAMARD SIGNATURES 审中-公开
    网络覆盖系统的系统和操作方法,使用AM高尔夫标记符号

    公开(公告)号:WO2005048610A3

    公开(公告)日:2006-01-26

    申请号:PCT/US2004031606

    申请日:2004-09-24

    CPC classification number: H04B7/155 G01S5/0221 G01S5/0273 G01S5/06

    Abstract: A system and method for a network overlay geolocation system operating in a host wireless communication system with repeaters. enable a wireless communication system to determine if signals being received by system receivers arrive directly from a target mobile (701) or if the signals are passing through or via a repeater (702). The system's repeaters use a co-channel AM Golay Hadamard sequence multiplied by an uplink signal to watermark the repeated signal. The system uses the known AM Golay Hadamard sequences of the repeaters and the uplink signal to detect whether a repeater has operated on the signal and which repeater operated on the uplink signal. Management data can be used to provide more accurate geolocation of mobiles served by the repeater stations.

    Abstract translation: 一种用于具有中继器的主机无线通信系统中操作的网络覆盖地理位置系统的系统和方法。 使得无线通信系统能够确定系统接收器正在接收的信号是否直接从目标移动台(701)到达,或者信号是否经过中继器(702)。 系统的中继器使用与上行链路信号相乘的同频道AM Golay Hadamard序列来对重复的信号进行水印。 该系统使用中继器和上行链路信号的已知AM Golay Hadamard序列来检测中继器是否对信号进行操作,哪个中继器在上行链路信号上操作。 管理数据可用于提供由中继站服务的移动台的更准确的地理位置。

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