POLY a-AMINO ACID AND FERROELECTRIC MEMORY ELEMENT USING SAME
    1.
    发明申请
    POLY a-AMINO ACID AND FERROELECTRIC MEMORY ELEMENT USING SAME 审中-公开
    使用相同的聚氨酯酸和电磁记忆元件

    公开(公告)号:WO2012153855A8

    公开(公告)日:2013-01-17

    申请号:PCT/JP2012062232

    申请日:2012-05-11

    Abstract: Provided are a poly a-amino acid having good film-producing capability, and a ferromagnetic memory element having excellent moldability and workability and further, excellent operating stability when exposed to high temperatures. The ferromagnetic memory element comprises a poly a-amino acid that is a copolymer formed from glutamic acid-?-ester units represented by formula (I) (I) (where R1 is an optionally substituted C1-8 alkyl group or benzyl group optionally substituted by a halogen atom, alkoxy group or nitro group) and glutamic acid-?-ester units represented by formula (II) (II) (where R2 is not the same as R1 and is an unsubstituted C3-16 alkyl group or C1-6 alkyl group wherein a portion or all of the hydrogen atoms are optionally substituted by halogen atoms, C3-12 acyclic hydrocarbon groups, C1-6 alkoxy groups, cyano groups, phenyl groups (where a portion or all of the hydrogen atoms are optionally substituted by halogen atoms or alkoxy groups), phenyl alkoxy groups (where a portion or all of the hydrogen atoms are optionally substituted by halogen atoms or alkoxy groups), or phenyl alkyl carbamate groups (where a portion or all of the hydrogen atoms are optionally substituted by halogen atoms or alkoxy groups)) and has a ratio of units represented by formula (I) and units represented by formula (II) ((I)/(II)) that is between 10/90 and 90/10 by molar ratio.

    Abstract translation: 提供了具有良好的膜生产能力的聚α-氨基酸和具有优异的成型性和加工性的铁磁记忆元件,并且当暴露于高温时具有优异的操作稳定性。 铁磁存储元件包括由式(I)(I)表示的谷氨酸-β-酯单元形成的共聚物的聚α-氨基酸(其中R 1是任选取代的C 1-8烷基或任选取代的苄基) 通过卤素原子,烷氧基或硝基)和由式(II)(II)表示的谷氨酸-β-酯单元(其中R 2不与R 1相同,为未取代的C 3-6-16烷基或C 1-6 烷基,其中一部分或全部氢原子任选地被卤素原子取代,C 3-12无环烃基,C 1-6烷氧基,氰基,苯基(其中部分或全部氢原子任选地被 卤素原子或烷氧基),苯基烷氧基(其中一部分或全部氢原子任选被卤素原子或烷氧基取代)或苯基烷基氨基甲酸酯基(其中部分或全部氢原子任选被 卤素原子或烷氧基 y)),并且具有由式(I)表示的单元与式(II)((I)/(II))表示的单元的摩尔比为10/90至90/10的比例。

    AMINO ACID DERIVATIVE AND ANTI-ACTIVE-OXYGEN AGENT
    3.
    发明申请
    AMINO ACID DERIVATIVE AND ANTI-ACTIVE-OXYGEN AGENT 审中-公开
    氨基酸衍生物和抗活性氧化剂

    公开(公告)号:WO1994014755A1

    公开(公告)日:1994-07-07

    申请号:PCT/JP1993001842

    申请日:1993-12-20

    Abstract: A novel anti-active-oxygen agent which inhibits the generation of active oxygen species, is highly safe, can be preparated at a rather low cost, and contains an amino acid derivative represented by general formula (I) or a salt thereof as the active ingredient, wherein Ar represents 2-hydroxyphenyl, 2-hdyroxy-1-naphthyl or pyridyl provided that the aromatic rings of these groups may be substituted by halogen, alkyl, hydroxy, hydroxyalkyl, nitro, alkoxy or carboxy; R represents the side chain of an amino acid; X represents -CH2-NH- or -CH = N-; Y represents hydrogen, -COOR , -SO3H, -CON(R )R , -CONHCH(R )COOR or -CH2OH, wherein R to R represent each hydrogen or alkyl, and R represents the side chain of an amino acid; and n represents an integer of 0 or 1.

    Abstract translation: 抑制活性氧生成的新型抗活性氧剂是高度安全的,可以以相当低的成本制备,并且含有由通式(I)表示的氨基酸衍生物或其盐作为活性物质 其中Ar表示2-羟基苯基,2-羟基-1-萘基或吡啶基,条件是这些基团的芳环可以被卤素,烷基,羟基,羟基烷基,硝基,烷氧基或羧基取代; R表示氨基酸的侧链; X表示-CH 2 -NH-或-CH = N-; Y表示氢,-COOR 1,-SO 3 H,-CON(R 2)R 3,-CONHCH(R 5)COOR 4或-CH 2 OH,其中R 1至R“ 4>表示每个氢或烷基,R 5表示氨基酸的侧链; n表示0或1的整数。

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