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    PROCESSES AND COMPOUNDS FOR PREPARING CYCLIC UREA FUNGICIDES
    2.
    发明申请
    PROCESSES AND COMPOUNDS FOR PREPARING CYCLIC UREA FUNGICIDES 审中-公开
    制备循环脲类杀真菌剂的方法和化合物

    公开(公告)号：WO1997019935A1

    公开(公告)日：1997-06-05

    申请号：PCT/US1996019207

    申请日：1996-12-02

    申请人： E.I. DU PONT DE NEMOURS AND COMPANY ,  BROWN, Richard, James ,  DANIEL, Dilon, J. ,  FRASIER, Deborah, Ann ,  HARTZELL, Stephen, Lee ,  KOETHER, Gerard, Michael ,  WOJTKOWSKI, Paul, Walter

    发明人： E.I. DU PONT DE NEMOURS AND COMPANY

    IPC分类号： C07D249/12

    CPC分类号： C07D249/12 ,  C07C281/06 ,  C07F9/6518

    摘要： Processes are disclosed for preparing compounds of Formula (I), for preparing a compound of Formula (II), for preparing a compound of Formula (III) and for preparing a compound of Formula (IV), wherein R and R are each independently H, halogen, cyano, nitro, C1-C6 alkyl, C1-C6 haloalkyl, C2-C6 alkenyl, C2-C6 haloalkenyl, C2-C6 alkynyl, C2-C6 haloalkynyl, C1-C6 alkoxy, C1-C6 haloalkoxy, C2-C6 alkenyloxy, C2-C4 alkoxycarbonyl; or C2-C6 alkynyloxy; R is H or C1-C3 alkyl, Lg is halogen, acetoxy, OSO2Q or (a); Q is C1-C6 alkyl, C1-C6 alkenyl, or phenyl optionally substituted with C1-C3 alkyl; R is C1-C6 alkyl, C1-C6 alkenyl or phenyl; and Z, R and R are as defined in the disclosure. Also disclosed are advantageous process sequences and process conditions; as well as novel compounds of Formula (III) and novel compounds of Formula (IV).

    摘要翻译： 公开了制备式（I）化合物，制备式（II）化合物，制备式（III）化合物和制备式（Ⅳ）化合物的方法，其中R 3和R 3， R 4各自独立地为H，卤素，氰基，硝基，C 1 -C 6烷基，C 1 -C 6卤代烷基，C 2 -C 6烯基，C 2 -C 6卤代烯基，C 2 -C 6炔基，C 2 -C 6卤代炔基，C 1 -C 6烷氧基， C 6卤代烷氧基，C 2 -C 6烯氧基，C 2 -C 4烷氧基羰基; 或C 2 -C 6炔氧基; R 5是H或C 1 -C 3烷基，L g是卤素，乙酰氧基，OSO 2 Q或（a）; Q是C 1 -C 6烷基，C 1 -C 6烯基或任选被C 1 -C 3烷基取代的苯基; R 16是C 1 -C 6烷基，C 1 -C 6烯基或苯基; 和Z，R 1和R 2如本公开所定义。 还公开了有利的工艺顺序和工艺条件; 以及式（III）的新化合物和式（IV）的新化合物。

    FUNGICIDAL 1,3,4-OXADIAZINES AND 1,3,4-THIADIAZINES
    3.
    发明申请
    FUNGICIDAL 1,3,4-OXADIAZINES AND 1,3,4-THIADIAZINES 审中-公开
    FUNGICIDAL 1,3,4-OXADIAZINES和1,3,4-THIADIAZINES

    公开(公告)号：WO1993022311A1

    公开(公告)日：1993-11-11

    申请号：PCT/US1993003583

    申请日：1993-04-22

    申请人： E.I. DU PONT DE NEMOURS AND COMPANY ,  FRASIER, Deborah, Ann ,  KOETHER, Gerard, Michael ,  CHANG, Zen-Yu

    发明人： E.I. DU PONT DE NEMOURS AND COMPANY

    IPC分类号： C07D413/04

    CPC分类号： A01N43/72 ,  A01N43/88 ,  C07D413/04 ,  C07D417/04

    摘要： Fungicidal 1,3,4-oxadiazines and 1,3,4-thiadiazines of general formula (I) are disclosed, wherein G is -CR R -, -(CHR CHR )-, -(CHR CHR CHR )-, or -(CHR CHR CHR CHR )-; G is -O-, -S-, -S(O)-, -S(O)2-, or -NR -; G is -CR R -, -(CHR CHR )-, or -(CHR CHR CHR )- or a direct bond; X is N or CR ; Y is N or CR ; and E, R , and R are various groups.

    摘要翻译： 公开了通式（I）的杀真菌的1,3,4-恶二嗪和1,3,4-噻二嗪，其中G 1是-CR 1 R 7 - ， - （CHR 1 CHR 2 - ） - ， - （CHR 1 CHR 2 CHR 3） - 或 - （CHR 1 CHR 2 CHR 3 CHR 4） - ; G 2是-O - ， - S - ， - S（O） - ， - S（O）2 - 或-NR 27 - G 3是-CR 4 R 8 - ， - （CHR 5 CHR 6） - 或 - （CHR 3 CHR 5 CHR 6） - 或直接键 ; X是N或CR 13; Y是N或CR 13; 并且E，R 9和R 10是各种基团。

    ARTHROPODICIDAL AND FUNGICIDAL CYCLIC AMIDES
    5.
    发明申请
    ARTHROPODICIDAL AND FUNGICIDAL CYCLIC AMIDES 审中-公开
    抗坏血酸和杀真菌循环系统

    公开(公告)号：WO1998005652A2

    公开(公告)日：1998-02-12

    申请号：PCT/US1997012809

    申请日：1997-07-24

    申请人： E.I. DU PONT DE NEMOURS AND COMPANY ,  BROWN, Richard, James ,  CHAN, Dominic, Ming-Tak ,  CLARK, David, Alan ,  DRUMM, Joseph, Eugene, III ,  KOETHER, Gerard, Michael ,  McCANN, Stephen, Frederick ,  RORER, Morris, Padgett ,  SELBY, Thomas, Paul ,  WALKER, Michael, Paul

    发明人： E.I. DU PONT DE NEMOURS AND COMPANY

    IPC分类号： C07D249/12

    CPC分类号： C07D401/04 ,  A01N43/653 ,  A01N43/78 ,  A01N43/80 ,  A01N43/82 ,  C07D249/12 ,  C07D261/12 ,  C07D401/12 ,  C07D403/04 ,  C07D403/12 ,  C07D403/14 ,  C07D413/12 ,  C07D417/12 ,  C07D417/14 ,  C07F7/0812 ,  C07F7/1804

    摘要： Compounds of Formula (I), and their N-oxides and agriculturally suitable salts, are disclosed which are useful as fungicides and arthropodicides, wherein A is O; S; N; NR ; or CR ; G is C or N; provided that when G is C, then A is O, S or NR and the floating double bond is attached to G; and when G is N, then A is N or CR and the floating double bond is attached to A; W is O; S; NH; N(C1-C6alkyl); or NO(C1-C6alkyl); X is OR ; S(O)mR ; or halogen; R is C1-C6alkyl; C1-C6haloalkyl; C2-C6alkenyl; C2-C6haloalkenyl; C2-C6alkynyl; C2-C6haloalkynyl; C3-C6cycloalkyl; C2-C4alkylcarbonyl; or C2-C4alkoxycarbonyl; R is H; C1-C6alkyl; C1-C6haloalkyl; C2-C6alkenyl; C2-C6haloalkenyl; C2-C6alkynyl; C2-C6haloalkynyl; C3-C6cycloalkyl; C2-C4alkylcarbonyl; C2-C4alkoxycarbonyl; hydroxy; C1-C2alkoxy; or acetyloxy; m is 0, 1 or 2; and E, R , Y, Z and R are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula (I) and a method for controlling plant diseases caused by fungal plant pathogens which involves applying an effective amount of a compound of Formula (I). Also disclosed are compositions containing the compounds of Formula (I) and a method for controlling arthropods which involves contacting the arthropods or their environment with an effective amount of a compound of formula (I).

    摘要翻译： 公开了式（I）化合物及其N-氧化物和农业上合适的盐，其可用作杀真菌剂和杀节肢动物剂，其中A为O; S; N; NR <5>; 或CR <14>; G为C或N; 条件是当G为C时，A为O，S或NR 5，浮动双键连接至G; 当G为N时，A为N或CR 14，浮选双键连接至A; W是O; S; NH; N（C1-C6烷基）; 或NO（C 1 -C 6烷基）; X为OR 1; S（O）MR <1>; 或卤素; R 1是C 1 -C 6烷基; C1-C6卤代烷基; C2-C6烯基; C2-C6haloalkenyl; C2-C6炔基; C2-6卤代炔基; C3-C6环烷基; C2-C4alkylcarbonyl; 或C 2 -C 4烷氧基羰基; R 2是H; C1-C6烷基; C1-C6卤代烷基; C2-C6烯基; C2-C6haloalkenyl; C2-C6炔基; C2-6卤代炔基; C3-C6环烷基; C2-C4alkylcarbonyl; C2-C4烷氧基; 羟基; C1-C2烷氧基; 或乙酰氧基; m为0,1或2; 并且E，R 5，Y，Z和R 14如本公开所定义。 还公开了含有式（I）化合物和控制由真菌植物病原体引起的植物病害的方法的组合物，其涉及施用有效量的式（I）的化合物。 还公开了含有式（I）化合物和控制节肢动物的方法的组合物，其包括将节肢动物或其环境与有效量的式（I）化合物接触。

    FUNGICIDAL CYCLIC AMIDES
    6.
    发明申请
    FUNGICIDAL CYCLIC AMIDES 审中-公开
    杀真菌剂

    公开(公告)号：WO1996036633A1

    公开(公告)日：1996-11-21

    申请号：PCT/US1996006533

    申请日：1996-05-08

    申请人： E.I. DU PONT DE NEMOURS AND COMPANY ,  BROWN, Richard, James ,  DANIEL, Dilon, Jancey ,  FRASIER, Deborah, Ann ,  HOWARD, Michael, Henry, Jr. ,  KOETHER, Gerard, Michael ,  RORER, Morris, Padgett

    发明人： E.I. DU PONT DE NEMOURS AND COMPANY

    IPC分类号： C07D405/04

    CPC分类号： C07D401/04 ,  A01N43/653 ,  A01N43/82 ,  A01N55/00 ,  C07D401/14 ,  C07D405/04 ,  C07D405/14 ,  C07D409/04 ,  C07D413/14 ,  C07D417/12 ,  C07D417/14 ,  C07F7/0812

    摘要： Compounds of Formula (I), and their N-oxides and agriculturally suitable salts, are disclosed which are useful as fungicides. In said formula, E is a ring system selected from certain 5- to 12-membered monocyclic and fused bicyclic aromatic heterocyclic ring systems, or an optionally substituted naphthalene ring as defined in the disclosure; A is O; S; N; NR ; or CR ; G is C or N; provided that when G is C, then A is O, S or NR and the floating double bond is attached to G; and when G is N, then A is N or CR and the floating double bond is attached to A; W is O; S; NH; N(C1-C6 alkyl); or NO(C1-C6 alkyl); X is OR ; S(O)mR ; or halogen; R is C1-C6 alkyl; C1-C6 haloalkyl; C2-C6 alkenyl; C2-C6 haloalkenyl; C2-C6 alkynyl; C2-C6 haloalkynyl; C3-C6 cycloalkyl; C2-C4 alkylcarbonyl; or C2-C4 alkoxycarbonyl; R is H; C1-C6 alkyl; C1-C6 haloalkyl; C2-C6 alkenyl; C2-C6 haloalkenyl; C2-C6 alkynyl; C2-C6 haloalkynyl; C3-C6 cycloalkyl; C2-C4 alkylcarbonyl; C2-C4 alkoxycarbonyl; hydroxy; C1-C2 alkoxy; or acetyloxy; R is H; C1-C6 alkyl; C1-C6 haloalkyl; C2-C6 alkenyl; C2-C6 haloalkenyl; C2-C6 alkynyl; C2-C6 haloalkynyl; C3-C6 cycloalkyl; C2-C4 alkylcarbonyl; or C2-C4 alkoxycarbonyl; and Y, Z, R and m are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula (I) and a method for controlling plant diseases caused by fungal plant pathogens which involves applying an effective amount of a compound of Formula (I).

    摘要翻译： 公开了式（I）化合物及其N-氧化物和农业上合适的盐，其可用作杀真菌剂。 在所述式中，E是选自某些5-至12-元单环和稠合双环芳族杂环系统或本公开中所定义的任选取代的萘环的环系; A是O S; N; NR <5>; 或CR <14>; G为C或N; 条件是当G为C时，A为O，S或NR 5，浮动双键连接至G; 当G为N时，A为N或CR 14，浮选双键连接至A; W是O; S; NH; N（C 1 -C 6烷基）; 或NO（C 1 -C 6烷基）; X为OR 1; S（O）MR <1>; 或卤素; R 1是C 1 -C 6烷基; C1-C6卤代烷基; C2-C6烯基; C2-C6卤代烯基; C2-C6炔基; C 2 -C 6卤代炔基; C3-C6环烷基; C 2 -C 4烷基羰基; 或C 2 -C 4烷氧基羰基; R 2是H; C1-C6烷基; C1-C6卤代烷基; C2-C6烯基; C2-C6卤代烯基; C2-C6炔基; C 2 -C 6卤代炔基; C3-C6环烷基; C 2 -C 4烷基羰基; C 2 -C 4烷氧基羰基; 羟基; C1-C2烷氧基; 或乙酰氧基; R 5为H; C1-C6烷基; C1-C6卤代烷基; C2-C6烯基; C2-C6卤代烯基; C2-C6炔基; C 2 -C 6卤代炔基; C3-C6环烷基; C 2 -C 4烷基羰基; 或C 2 -C 4烷氧基羰基; 和Y，Z，R 14和m如本公开所定义。 还公开了含有式（I）化合物的组合物和控制由真菌植物病原体引起的植物病害的方法，其涉及施用有效量的式（I）的化合物。

    FUNGICIDAL CYCLIC AMIDES
    8.
    发明申请
    FUNGICIDAL CYCLIC AMIDES 审中-公开
    杀真菌剂

    公开(公告)号：WO1996036616A1

    公开(公告)日：1996-11-21

    申请号：PCT/US1996006534

    申请日：1996-05-08

    申请人： E.I. DU PONT DE NEMOURS AND COMPANY ,  BROWN, Richard, James ,  FRASIER, Deborah, Ann ,  HOWARD, Michael, Henry, Jr. ,  KOETHER, Gerard, Michael ,  RORER, Morris, Padgett

    发明人： E.I. DU PONT DE NEMOURS AND COMPANY

    IPC分类号： C07D249/12

    CPC分类号： C07D401/12 ,  A01N43/653 ,  C07D249/12

    摘要： Compounds of Formula (I), and their N-oxides and agriculturally suitable salts are disclosed which are useful as fungicides, wherein E is 1,2-phenylene optionally substituted with one of R , R , or both R and R ; A is O; S; N; NR ; or CR ; G is C or N; provided that when G is C, then A is O, S or NR and the floating double bond is attached to G; and when G is N, then A is N or CR and the floating double bond is attached to A; W is O; S; NH; N(C1-C6 alkyl); or NO(C1-C6 alkyl); X is OR ; S(O)mR ; or halogen; R is C1-C6 alkyl; C1-C6 haloalkyl; C2-C6 alkenyl; C2-C6 haloalkenyl; C2-C6 alkynyl; C2-C6 haloalkynyl; C3-C6 cycloalkyl; C2-C4 alkylcarbonyl; or C2-C4 alkoxycarbonyl; R is H; C1-C6 alkyl; C1-C6 haloalkyl; C2-C6 alkenyl; C2-C6 haloalkenyl; C2-C6 alkynyl; C2-C6 haloalkenyl; C3-C6 cycloalkyl; C2-C4 alkylcarbonyl; C2-C4 alkoxycarbonyl; hydroxy; C1-C2 alkoxy; or acetyloxy; and Y, Z, R , R , R , R and m are as defined in the disclosure. Also disclosed are compositions containing the compounds of Formula (I) and a method for controlling plant diseases caused by fungal plant pathogens which involves applying an effective amount of a compound of Formula (I).

    摘要翻译： 公开了式（I）化合物及其N-氧化物和农业上合适的盐，其可用作杀真菌剂，其中E为任选被R 3，R 4或R 2中的一个取代的1,2-亚苯基 3和R 4; A是O S; N; NR <5>; 或CR <14>; G为C或N; 条件是当G为C时，A为O，S或NR 5，浮动双键连接至G; 当G为N时，A为N或CR 14，浮选双键连接至A; W是O; S; NH; N（C 1 -C 6烷基）; 或NO（C 1 -C 6烷基）; X为OR 1; S（O）MR <1>; 或卤素; R 1是C 1 -C 6烷基; C1-C6卤代烷基; C 2 -C 6烯基; C2-C6卤代烯基; C2-C6炔基; C 2 -C 6卤代炔基; C3-C6环烷基; C 2 -C 4烷基羰基; 或C 2 -C 4烷氧基羰基; R 2是H; C1-C6烷基; C1-C6卤代烷基; C 2 -C 6烯基; C2-C6卤代烯基; C2-C6炔基; C2-C6卤代烯基; C3-C6环烷基; C 2 -C 4烷基羰基; C 2 -C 4烷氧基羰基; 羟基; C1-C2烷氧基; 或乙酰氧基; 和Y，Z，R 3，R 4，R 5，R 14和m如本公开所定义。 还公开了含有式（I）化合物和控制由真菌植物病原体引起的植物病害的方法的组合物，其涉及施用有效量的式（I）的化合物。