Abstract:
The present invention relates to a structure comprising (i) a layer or profile (A) composed of a first material, and (ii) a polyolefin layer or profile (B) adjacent to layer or profile (A) which is composed of a composition comprising a base resin comprising a polyolefin, characterized in that the surface of any or both of layer or profile (A) and layer or profile (B) has/have been treated with a composition comprising an organosilicon compound before (A) and (B) are brought adjacent to each other, to a process for the production of such a structure, to an article, in particular a coated pipe, comprising such a structure and to the use of a composition comprising an organosilicon compound as an adhesion promoter in such a structure.
Abstract:
The present invention deals with coated pipes having a layer of multimodal polyethylene. The multimodal ethylene copolymer is a copolymer of ethylene with one or more alpha-olefin comonomers having from 6 to 10 carbon atoms and has a weight average molecular weight of from 70000 g/mol to 250000 g/mol, the ratio of the weight average molecular weight to the number average molecular weight, Mw/Mn, of from 15 to 50, a melt index MFR 2 of from 0.05 g/10 min to 5 g/10 min, a melt index MFR 5 of from 0.5 to 10 g/10 min and a density of from 930 kg/m3 to 955 kg/m 3 . The pipes can be coated with high throughput and good production economy. The coatings have good mechanical properties.
Abstract:
The present invention relates to an adhesive polymer composition comprising a) a non-elastomeric polyethylene in an amount of 40 to 97 wt.% of the total composition and b) an elastomer comprising an elastomeric ethylene copolymer with polar comonomer groups, wherein component a) has been produced in a process using a single-site catalyst and component a) or components a) and b) have been grafted with an acid grafting agent. Furthermore, the invention relates to an article, in particular a multilayer pipe, comprising an adhesive layer which comprises said adhesive polymer composition and to the use of said adhesive polymer composition for the production of an adhesive layer, in particular of an adhesive layer of a pipe.
Abstract:
The present invention relates to a method of joining polymer coated steel pipes comprising the steps of - providing polymer coated pipe segments with an uncoated length on both ends of the segments; - welding the polymer coated pipe segments together; - applying a curable polymer (A) onto the uncoated length of the welded pipe segments to form an first coating layer; and - applying a polymer composition (B) onto the first coating layer to form a topcoat layer with a thickness of 0.5 to 10 mm, wherein the polymer composition (B) has a melt flow rate MFR 2 of 1.0 to 6.0 g/10 min, determined according to ISO 1133 at a temperature of 190°C under a load of 2.16 kg, and includes a base resin comprising (B-1) a non-elastomeric polyethylene in an amount of 60 to 85 wt% of the total polymer composition being produced in a process using a single-site catalyst, and (B-2) an elastomer comprising a copolymer of ethylene and at least one polar comonomer, wherein component (B-1) or components (B-1) and (B-2) have been grafted with an acid grafting agent and the use of polymer composition (B) as topcoat layer with a thickness of 0.5 to 10 mm in a coating of coated steel pipe field-joints, a method of coating a steel pipe and the use of polymer composition (B) for the coating of steel pipe joints or steel pipes.
Abstract:
The present invention deals with coated pipes having a layer of multimodal polyethylene. The multimodal ethylene copolymer is a copolymer of ethylene with one or more alpha-olefin comonomers having from 4 to 10 carbon atoms and has a weight average molecular weight of from 70000 g/mol to 250000 g/mol, the ratio of the weight average molecular weight to the number average molecular weight, Mw/Mn, of from 15 to 50, a melt index MFR 2 of from 0.05 g/10 min to 5 g/10 min, a melt index MFR 5 of from 0.5 to 10 g/10 min and a density of from 930 kg/m 3 to 955 kg/m 3 . Further, the multimodal ethylene copolymer comprises the multimodal ethylene copolymer comprises from 49 to 59 % based on the weight of the multimodal ethylene copolymer a low molecular weight ethylene homopolymer component, said low molecular weight ethylene homopolymer having a weight average molecular weight of from 5000 g/mol to 70000 g/mol; and from 51 to 41 % based on the weight of the multimodal ethylene copolymer a high molecular weight ethylene copolymer component, said high molecular weight ethylene copolymer having a weight average molecular weight of from 100000 g/mol to 700000 g/mol. The pipes can be coated with high throughput and good production economy. The coatings have good mechanical properties.
Abstract:
The present invention concerns the use of a particular ethylene polymer for providing coating compositions displaying improved values for elongation at break at -45°C, rendering coating compositions prepared in accordance with the present invention suitable for low temperature applications.
Abstract:
Conventional coating compositions have the disadvantage of being insufficiently coatable and having an unsatisfactory environmental stress cracking resistance. Now a coating composition has been found which has both good coating processability and environmental stress cracking resistance. It comprises a multimodal ethylene polymer, which contains from 80 to 100 % by weight of ethylene repeating units and from 0 to 20 % by weight of C3-C10 alpha -olefin repeating units, has a density of between 0.915 g/cm and 0.955 g/cm , and is a blend of at least a first ethylene polymer having a first average molecular weight and a first molecular weight distribution and a second ethylene polymer having a second average molecular weight, which is higher than said first average molecular weight, and a second molecular weight distribution, said blend having a third average molecular weight and a third molecular weight distribution.
Abstract translation:常规涂料组合物的缺点是可涂覆性不足,并且具有不令人满意的耐环境应力开裂性。 现在已经发现涂料组合物具有良好的涂覆加工性和耐环境应力开裂性。 其包含多峰乙烯聚合物,其含有80至100重量%的乙烯重复单元和0至20重量%的C 3 -C 10α-烯烃重复单元,其密度为0.915g / cm 3 和0.955g / cm 3,并且是至少具有第一平均分子量和第一分子量分布的第一乙烯聚合物和具有第二平均分子量的第二乙烯聚合物的共混物,其具有高于所述第一 平均分子量和第二分子量分布,所述共混物具有第三平均分子量和第三分子量分布。
Abstract:
Coating composition comprising an ethylene copolymer containing not more than 5 mole-% comonomer, whereby the fraction of the ethylene copolymer having a molecular weight of 300 000 g/mol - 600 000 g/mol has a methyl branching of more than 4.0 Methyl per 1000C as determined by SEC/FT-IR analysis.
Abstract:
The present invention deals with coated pipes having a layer of multimodal polyethylene. The multimodal ethylene copolymer is a copolymer of ethylene with one or more alpha-olefin comonomers having from 4 to 10 carbon atoms and has a weight average molecular weight of from 70000 g/mol to 250000 g/mol and a melt index MFR2 of from 0.05 g/10 min to 5 g/10 min, a melt index MFR5 of from 0.5 to 10 g/10 min and a density of from 945 kg/m3 to 958 kg/m3. The coatings have a high stiffness, good properties at elevated temperatures and acceptable stress-cracking properties.
Abstract translation:本发明涉及具有多峰聚乙烯层的涂覆管。 多峰乙烯共聚物是乙烯与一种或多种具有4-10个碳原子的α-烯烃共聚单体的共聚物,其重均分子量为70000g / mol至250000g / mol,熔体指数MFR2为0.05 g / 10分钟至5g / 10min,熔体指数MFR5为0.5至10g / 10min,密度为945kg / m 3至958kg / m 3。 涂层具有高刚度,在高温下具有良好的性能和可接受的应力开裂性能。
Abstract:
The present invention deals with coated pipes having a layer of multimodal polyethylene. The multimodal ethylene copolymer is a copolymer of ethylene with one or more alpha-olefin comonomers having from 4 to 10 carbon atoms and has a weight average molecular weight of from 70000 g/mol to 250000 g/mol, the ratio of the weight average molecular weight to the number average molecular weight, Mw/Mn, of from 15 to 50, a melt index MFR 2 of from 0.05 g/10 min to 5 g/10 min, a melt index MFR 5 of from 0.5 to 10 g/10 min and a density of from 930 kg/m 3 to 955 kg/m 3 . The pipes can be coated with high throughput and good production economy. The coatings have good mechanical properties.