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    A FAST BATCH PROCESS FOR PREPARING A ZEOLITIC MATERIAL HAVING FRAMEWORK TYPE CHA
    1.
    发明申请
    A FAST BATCH PROCESS FOR PREPARING A ZEOLITIC MATERIAL HAVING FRAMEWORK TYPE CHA 审中-公开

    公开(公告)号：WO2019122121A1

    公开(公告)日：2019-06-27

    申请号：PCT/EP2018/086184

    申请日：2018-12-20

    申请人： BASF SE ,  THE UNIVERSITY OF TOKYO

    发明人： PARVULESCU, Andrei-Nicolae ,  MUELLER, Ulrich ,  IYOKI, Kenta ,  CHAIKITTISILP, Watcharop ,  WAKIHARA, Toru

    IPC分类号： C01B39/48 ,  B01J29/70 ,  B01J29/76 ,  B01J35/02

    CPC分类号： C01B39/48 ,  B01J29/763

    摘要： A batch process for preparing a zeolitic material having framework type CHA and a framework structure comprising Si, Al, O, and H, comprising (i) providing a seeding material comprising a zeolitic material having framework type CHA and a framework structure comprising Si, Al, O, and H; (ii) preparing a mixture comprising a source of Si, a source of Al, a seeding material provided in (i), a CHA framework structure directing agent comprising a cycloalkylammonium compound, and water, wherein the cycloalkylammonium compound is a compound comprising a cation R 1 R 2 R 3 R 4 N + wherein R 1 , R 2 , R 3 are, independently from one another, an alkyl residue having from 1 to 6 carbon atoms, and R 4 is a 5- to 8-membered cycloalkyl residue, wherein in mixture, the molar ratio of water relative to Si comprised in the source of Si and in the seeding material, calculated as SiO 2 , is in the range of from 5:1 to 15:1, wherein the mixture, the molar ratio of sodium, calculated as Na 2 O, relative to Si comprised in the source of Si and in the seeding material, calculated as SiO 2 , is in the range of from 0:1 to 0.1:1; (iii) heating the mixture prepared in (ii) in its liquid state to a temperature of the mixture in the range of from 50 to 90 °C and keeping the liquid mixture at a temperature in this range for 5 to 100 h; (iv) heating the heated mixture of (iii) to a temperature of the mixture in the range of from 190 to 230 °C in a crystallization vessel and keeping the mixture at a temperature in this range under autogenous pressure in the crystallization vessel for 0.5 to 10 h, obtaining a solid material comprising a zeolitic material having framework type CHA and a framework structure comprising Si, Al, O, and H, suspended in its mother liquor.

    METHOD FOR THE DIRECT SYNTHESIS OF IRON-CONTAINING AEI-ZEOLITE CATALYST
    2.
    发明申请
    METHOD FOR THE DIRECT SYNTHESIS OF IRON-CONTAINING AEI-ZEOLITE CATALYST 审中-公开
    直接合成含铁AEI-沸石催化剂的方法

    公开(公告)号：WO2017134006A1

    公开(公告)日：2017-08-10

    申请号：PCT/EP2017/051912

    申请日：2017-01-30

    申请人： HALDOR TOPSØE A/S

    发明人： MARTÍN GARCÍA, Nuria ,  MOLINER MARÍN, Manuel ,  CORMA CANÓS, Avelino ,  THØGERSEN, Joakim Reimer ,  VENNESTRØM, Peter Nicolai Ravnborg

    IPC分类号： C01B39/02 ,  B01J29/76 ,  C01B39/06 ,  C01B39/48

    CPC分类号： C01B39/026 ,  B01D53/9418 ,  B01D2251/2062 ,  B01D2255/2027 ,  B01D2255/20738 ,  B01D2255/50 ,  B01J29/76 ,  B01J29/7615 ,  B01J29/763 ,  B01J37/0246 ,  B01J2229/183 ,  B01J2229/186 ,  C01B39/065 ,  C01B39/48

    摘要： A method for the direct synthesis of a crystalline material with the AEI zeolithic structure containing iron-species and being essentially free of alkali ions, comprising the following steps: (i) preparation of a mixture containing water, a high-silica zeolite as a main source of silica and alumina, an alkyl-substituted cyclic ammonium cation as organic structure directing agent (OSDA), a source of iron, and a source of an alkali metal ion [Alk], to obtain a final synthesis mixture having the following molar composition: SiO 2 : a AI 2 O 3 : b Fe : c OSDA : d Alk : e H 2 O wherein a is in the range from 0.001 to 0.2; wherein b is in the range from 0.001 to 0.2; wherein c is in the range from 0.01 to 2; wherein d is in the range from 0.001 to 2; wherein e is in the range from 1 to 200; (ii) crystallization of the mixture achieved in (i); (iii) recovery of the crystalline material achieved in (ii); (iv) calcination of the crystalline material from step (iii); and (v) removal of the alkali metal cation, present in the calcined crystalline material after step (iv) to obtain a final molar composition: SiO 2 : o AI 2 O 3 : p Fe : q Alk wherein o is in the range from 0.001 to 0.2, p is in the range from 0.001 to 0.2 and q is below 0.02.

    摘要翻译： 一种直接合成具有含铁物质且基本不含碱金属离子的AEI沸石结构的晶体材料的方法，其包括以下步骤：（i）制备含有水， 作为二氧化硅和氧化铝的主要来源的高硅沸石，作为有机结构导向剂（OSDA）的烷基取代的环状铵阳离子，铁的来源和碱金属离子的来源[Alk]，以获得 具有以下摩尔组成的最终合成混合物：SiO 2：Al 2 O 3：b Fe：c OSDA：d Alk：e H 其中α在0.001至0.2的范围内; 其中b在0.001至0.2的范围内; 其中c在0.01至2的范围内; 其中d在0.001至2的范围内; 其中e在1至200的范围内; （ii）（i）中实现的混合物的结晶; （iii）回收（ii）中获得的晶体材料; （iv）煅烧来自步骤（iii）的晶体材料; 和（v）在步骤（iv）之后除去存在于煅烧结晶物质中的碱金属阳离子以获得最终摩尔组成：SiO 2：Al 2 O 3 3：p Fe：q Alk其中o O在0.001至0.2的范围内，p在0.001至0.2的范围内， i> q 低于0.02。