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公开(公告)号：WO2012148813A3
公开(公告)日：2013-03-28
申请号：PCT/US2012034463
申请日：2012-04-20
申请人： UOP LLC , SERBAN MANUELA , NEGIZ ANTOINE , VANDEN BUSSCHE KURT M
CPC分类号： C07C2/76 , C10G59/02 , C10G69/08 , C10G2300/1044 , C10G2400/30
摘要： A process for reforming a hydrocarbon stream is presented. The process involves splitting a naphtha feedstream to at least two feedstreams and passing each feedstream to separation reformers. The reformers are operated under different conditions to utilize the differences in the reaction properties of the different hydrocarbon components. The process utilizes a common catalyst, and common downstream processes for recovering the desired aromatic compounds generated.
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公开(公告)号：WO2011090873A3
公开(公告)日：2011-11-17
申请号：PCT/US2011021079
申请日：2011-01-13
申请人： UOP LLC , NEGIZ ANTOINE , BOLDINGH EDWIN P , GAJDA GREGORY J , RENDE DEAN E , REKOSKE JAMES E , MACKOWIAK DAVID E , BARGER PAUL T
发明人： NEGIZ ANTOINE , BOLDINGH EDWIN P , GAJDA GREGORY J , RENDE DEAN E , REKOSKE JAMES E , MACKOWIAK DAVID E , BARGER PAUL T
CPC分类号： C07C2/76 , C10G29/205 , C10G2300/104 , C10G2300/1044 , C10G2300/1081 , C10G2300/1096 , C10G2400/02 , C10G2400/30 , C07C15/06 , C07C15/08 , C07C15/073 , C07C15/02
摘要： One exemplary embodiment can be a process for increasing a mole ratio of methyl to phenyl of one or more aromatic compounds in a feed. The process can include reacting an effective amount of one or more aromatic compounds and an effective amount of one or more aromatic methylating agents to form a product having a mole ratio of methyl to phenyl of at least about 0.1:1 greater than the feed.
摘要翻译： 一个示例性实施方案可以是提高进料中一种或多种芳族化合物的甲基与苯基的摩尔比的方法。 该方法可以包括使有效量的一种或多种芳族化合物和有效量的一种或多种芳族甲基化剂反应以形成比进料大至少约0.1:1的甲基与苯基的摩尔比的产物。
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3.发明申请RHENIUM-CONTAINING TRANSALKYLATION CATALYSTS AND PROCESSES FOR MAKING AND USING THE SAME 审中-公开含铼的转化催化剂及其制备和使用方法
公开(公告)号：WO2008033673A3
公开(公告)日：2008-05-22
申请号：PCT/US2007077197
申请日：2007-08-30
申请人： UOP LLC , BOLDINGH EDWIN P , NEGIZ ANTOINE , REKOSKE JAMES E , BAKER ERIC J , LARSON ROBERT B , DEAK TERRENCE E , GUREVICH SURGEY V
发明人： BOLDINGH EDWIN P , NEGIZ ANTOINE , REKOSKE JAMES E , BAKER ERIC J , LARSON ROBERT B , DEAK TERRENCE E , GUREVICH SURGEY V
CPC分类号： B01J29/80 , B01J29/26 , B01J29/48 , B01J37/0009 , B01J37/08 , B01J37/14 , B01J37/18 , B01J37/20 , B01J2229/20 , B01J2229/42 , C07C6/123 , C07C6/126 , C07C2529/18 , C07C2529/26 , C07C2529/80 , Y02P20/52 , C07C15/08
摘要： Transalkylation catalysts containing rhenium and a molecular sieve component comprising an acidic MFI molecular sieve having a Si/Al2 molar ratio of less than 80 and mordenite provide a transalkylation product with a low content of benzene co-boilers. The invention encompasses sulfided catalyst embodiments and processes for making and using the catalysts.
摘要翻译： 包含铼和分子筛组分的烷基转移催化剂包含Si / Al 2摩尔比小于80的酸性MFI分子筛和丝光沸石，提供具有低含量苯共沸锅的烷基转移产物。 本发明包括硫化催化剂实施方案和制备和使用该催化剂的方法。
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4.发明申请
公开(公告)号：WO2007120951A3
公开(公告)日：2007-10-25
申请号：PCT/US2007/060916
申请日：2007-01-23
申请人： UOP LLC , NEGIZ, Antoine , REKOSKE, James E. , BOLDINGH, Edwin P.
摘要： Processes for making xylene isomer use integrated transalkylation (102, 204) and isomerization reaction zones (110, 206) to enhance xylene recovery and enable reduction in capital costs and energy consumption.
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公开(公告)号：WO2005097714A1
公开(公告)日：2005-10-20
申请号：PCT/US2005/009367
申请日：2005-03-22
IPC分类号： C07C4/24
CPC分类号： C07C6/126 , C07C2529/26 , C07C15/08
摘要： A catalyst, and a process for using the catalyst, that effectively converts and transalkylates indane and C 10 and heavier polycyclic aromatics into C 8 aromatics is herein disclosed. The catalyst comprises a solid-acid support such as mordenite plus a metal component such as rhenium. The catalyst provides excellent conversion of such heavy aromatic species as naphthalene, which is also observed by a decrease in the ending-boiling-point of a hydrocarbon stream passed over the catalyst. The same catalyst is also effective for transalkylation of lighter aromatics, thus yielding a valuable xylenes product stream out of the process.
摘要翻译： 本文公开了一种催化剂和使用该催化剂的方法，其有效地将茚满和C 10和较重的多环芳烃烷基化为C8芳族化合物。 催化剂包括固体酸载体如丝光沸石和金属组分如铼。 该催化剂提供了诸如萘之类的重芳族物质的极好的转化率，这也是通过在催化剂上通过的烃流的终沸点降低而观察到的。 相同的催化剂对于较轻的芳族化合物的烷基转移也是有效的，因此在工艺中产生有价值的二甲苯产物流。
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公开(公告)号：WO2012148813A2
公开(公告)日：2012-11-01
申请号：PCT/US2012/034463
申请日：2012-04-20
CPC分类号： C07C2/76 , C10G59/02 , C10G69/08 , C10G2300/1044 , C10G2400/30
摘要： A process for reforming a hydrocarbon stream is presented. The process involves splitting a naphtha feedstream to at least two feedstreams and passing each feedstream to separation reformers. The reformers are operated under different conditions to utilize the differences in the reaction properties of the different hydrocarbon components. The process utilizes a common catalyst, and common downstream processes for recovering the desired aromatic compounds generated.
摘要翻译： 提出了一种重整烃流的方法。 该方法包括将石脑油进料流分成至少两个进料流并将每个进料流通过分离重整器。 改性剂在不同条件下运行，以利用不同烃组分的反应性质的差异。 该方法利用普通的催化剂和用于回收生成的所需芳族化合物的常见的下游方法。
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公开(公告)号：WO2011090877A3
公开(公告)日：2011-11-24
申请号：PCT/US2011021092
申请日：2011-01-13
申请人： UOP LLC , NEGIZ ANTOINE , BOLDINGH EDWIN P , GAJDA GREGORY J , RENDE DEAN E , REKOSKE JAMES E , MACKOWIAK DAVID E , BARGER PAUL T , BOGDAN PAULA L
发明人： NEGIZ ANTOINE , BOLDINGH EDWIN P , GAJDA GREGORY J , RENDE DEAN E , REKOSKE JAMES E , MACKOWIAK DAVID E , BARGER PAUL T , BOGDAN PAULA L
摘要： One exemplary embodiment can be a process using an aromatic methylating agent. Generally, the process includes reacting an effective amount of the aromatic methylating agent having at least one of an alkane, a cycloalkane, an alkane radical, and a cycloalkane radical with one or more aromatic compounds. As such, at least one of the one or more aromatic compounds may be converted to one or more higher methyl substituted aromatic compounds to provide a product having a greater mole ratio of methyl to phenyl than a feed.
摘要翻译： 一个示例性实施方案可以是使用芳族甲基化剂的方法。 通常，该方法包括将有效量的具有烷烃，环烷烃，烷烃基和环烷烃基团中的至少一种的芳族甲基化试剂与一种或多种芳族化合物反应。 因此，一种或多种芳族化合物中的至少一种可以转化为一种或多种高级甲基取代的芳族化合物，以提供与进料相比甲基与苯基摩尔比大的产物。
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公开(公告)号：WO2011090877A2
公开(公告)日：2011-07-28
申请号：PCT/US2011/021092
申请日：2011-01-13
申请人： UOP LLC , NEGIZ, Antoine , BOLDINGH, Edwin P. , GAJDA, Gregory J. , RENDE, Dean E. , REKOSKE, James E. , MACKOWIAK, David E. , BARGER, Paul T. , BOGDAN, Paula L.
发明人： NEGIZ, Antoine , BOLDINGH, Edwin P. , GAJDA, Gregory J. , RENDE, Dean E. , REKOSKE, James E. , MACKOWIAK, David E. , BARGER, Paul T. , BOGDAN, Paula L.
摘要： One exemplary embodiment can be a process using an aromatic methylating agent. Generally, the process includes reacting an effective amount of the aromatic methylating agent having at least one of an alkane, a cycloalkane, an alkane radical, and a cycloalkane radical with one or more aromatic compounds. As such, at least one of the one or more aromatic compounds may be converted to one or more higher methyl substituted aromatic compounds to provide a product having a greater mole ratio of methyl to phenyl than a feed.
摘要翻译： 一个示例性实施方案可以是使用芳族甲基化剂的方法。 通常，该方法包括使有效量的具有烷烃，环烷烃，烷烃残基和环烷烃残基中的至少一种的芳族甲基化剂与一种或多种芳族化合物反应。 这样，一种或多种芳族化合物中的至少一种可以转化成一种或多种高级甲基取代的芳族化合物，以提供具有比进料更大的甲基与苯基摩尔比的产物。
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9.发明申请PROCESS FOR INCREASING METHYL TO PHENYL MOLE RATIOS AND REDUCING BENZENE CONTENT IN A MOTOR FUEL PRODUCT 审中-公开将甲基增加至苯基摩尔比并降低电动机燃料产品中苯含量的方法
公开(公告)号：WO2011090872A2
公开(公告)日：2011-07-28
申请号：PCT/US2011021070
申请日：2011-01-13
申请人： UOP LLC , NEGIZ ANTOINE , BOLDINGH EDWIN P , GAJDA GREGORY J , RENDE DEAN E , REKOSKE JAMES E , MACKOWIAK DAVID E , BARGER PAUL T
发明人： NEGIZ ANTOINE , BOLDINGH EDWIN P , GAJDA GREGORY J , RENDE DEAN E , REKOSKE JAMES E , MACKOWIAK DAVID E , BARGER PAUL T
CPC分类号： C10G29/205
摘要： One exemplary embodiment can be a process for increasing a mole ratio of methyl to phenyl of one or more aromatic compounds in a feed. The process can include reacting an effective amount of one or more aromatic compounds and an effective amount of one or more non-aromatic compounds to convert 90%, by weight, of one or more C6+ non-aromatic compounds.
摘要翻译： 一个示例性实施方式可以是用于增加进料中一种或多种芳族化合物的甲基与苯基的摩尔比的方法。 该方法可以包括使有效量的一种或多种芳族化合物和有效量的一种或多种非芳族化合物反应以转化90重量％的一种或多种C6 +非芳族化合物。
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10.发明申请PROCESS FOR PREPARING A LAYERED CATALYST COMPOSITION FOR A SELECTIVE HYDROGENATION PROCESS 审中-公开制备选择性加氢过程的层状催化剂组合物的方法
公开(公告)号：WO2010050950A1
公开(公告)日：2010-05-06
申请号：PCT/US2008/081741
申请日：2008-10-30
申请人： UOP LLC , NEGIZ, Antoine , GAJDA, Gregory J.
发明人： NEGIZ, Antoine , GAJDA, Gregory J.
CPC分类号： B01J35/008 , B01J23/58 , B01J23/8946 , B01J35/023 , B01J35/1014 , B01J35/1038 , B01J35/1061 , B01J35/108 , B01J37/0242 , C07C5/05 , C07C2521/04 , C07C2521/06 , C07C2521/12 , C07C2521/16 , C07C2523/04 , C07C2523/58 , C07C2523/89 , C07C2527/224 , C07C2529/03 , C07C2529/08 , C07C2529/84 , C07C2529/85 , C07C2602/28 , C07C2603/68 , C10G45/34 , C07C13/48 , C07C11/10 , C07C13/61
摘要： A process for preparing a layered catalyst for selectively hydrogenating C 5 -C 11 diolefins in a hydrocarbon mixture to one or more respective C 5 -C 11 monoolefins is disclosed. The layered catalyst comprises an inner core having a first inorganic oxide and an outer layer bonded to the inner core. The outer layer has a non-refractory second inorganic oxide with at least one Group 1-2 metal and at least one Group 8-10 metal dispersed thereon. The catalyst is prepared by coating the inner core with a slurry of the second inorganic oxide, depositing the metals in the presence of a liquid phase, drying the coated core and calcining at 400 - 900°C for a time sufficient to bond the outer layer to eth inner core. The calcined catalyst is reduced under reducing conditions.
摘要翻译： 公开了一种制备用于将烃混合物中的C 5 -C 11二烯烃选择性氢化成一种或多种各自的C 5 -C 11单烯烃的层状催化剂的方法。 层状催化剂包括具有第一无机氧化物的内芯和与内芯结合的外层。 外层具有非难熔第二无机氧化物，其具有分散在其上的至少一种第1-2族金属和至少一种第8-10族金属。 催化剂是通过用第二无机氧化物的浆料涂覆内芯，在液相存在下沉积金属，干燥涂覆的芯并在400-900℃下煅烧足以粘结外层的时间 到内核。 煅烧的催化剂在还原条件下还原。
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