公开(公告)号：WO2005044958A2

公开(公告)日：2005-05-19

申请号：PCT/US2004035897

申请日：2004-10-28

Applicant: TECHNOL FUEL CONDITIONERS INC ,  SPRAGUE BARRY N

Inventor： SPRAGUE BARRY N

IPC: B01F17/36 ,  C10L20060101 ,  C10L

CPC classification number: C10L1/328 ,  C10L1/10 ,  C10L1/125 ,  C10L1/1802 ,  C10L1/19 ,  C10L1/191 ,  C10L1/1983 ,  C10L1/1985 ,  C10L10/00 ,  C10L10/02 ,  C10L10/04

Abstract: Heavy oil emulsions, comprising decant oils and No. 6, No. 5 and No. 4 oils, and water are stabilized by adding certain saccharide-based esters. Preferably, the saccharide-based esters are naturally-occurring saccharide esters such as gallotannins, saponin, red gum, and the like.

Abstract translation: 包含倾析油和6号，5号和4号油的重油乳液和水通过加入某些基于糖的酯来稳定。 优选地，糖基酯是天然存在的糖类酯，例如鞣酸单宁，皂角苷，红色胶等。

公开(公告)号：WO1997036676A1

公开(公告)日：1997-10-09

申请号：PCT/US1997005468

申请日：1997-04-02

Applicant: CLEAN DIESEL TECHNOLOGIES, INC. ,  PETER-HOBLYN, Jeremy, D. ,  VALENTINE, James, M. ,  SPRAGUE, Barry, N.

Inventor： CLEAN DIESEL TECHNOLOGIES, INC.

IPC: B01J08/00

CPC classification number: C01C1/086 ,  B01D53/9431 ,  B01D53/9495 ,  B01D2251/2067 ,  F01N3/2066 ,  F01N2240/25 ,  F01N2240/40 ,  F01N2610/02 ,  F01N2610/08 ,  F01N2610/10 ,  F02B37/00 ,  Y02T10/144 ,  Y02T10/24

Abstract: Emission of NOx from diesel engines is reduced by hydrolyzing or otherwise gasifying urea on an as-needed basis. Preferably, an aqueous urea solution is introduced into a catalyzed chamber (60) maintained at least partially in contact with the exhaust system (12). The heat of the exhaust gases is utilized to gasify the urea. The gaseous breakdown products of the urea are then introduced into the exhaust gases upstream of an SCR catalyst. In one form of the invention, an oxidation catalyst (22) is provided down stream of the SCR catalyst (20) for the purpose of eliminating any ammonia which might otherwise pass through the system and provide an objectionable odor.

Abstract translation: 通过根据需要水解或气化尿素来减少来自柴油发动机的NOx的排放。 优选地，将尿素水溶液引入保持至少部分地与排气系统（12）接触的催化室（60）中。 排气的热量用于气化尿素。 然后将尿素的气态分解产物引入SCR催化剂上游的排气中。 在本发明的一种形式中，在SCR催化剂（20）的下游设置氧化催化剂（22），以消除否则可能通过该系统并提供令人不快的气味的任何氨。

公开(公告)号：WO2007011912A3

公开(公告)日：2007-11-15

申请号：PCT/US2006027783

申请日：2006-07-18

Applicant: CLEAN DIESEL TECH INC ,  VALENTINE JAMES M ,  SPRAGUE BARRY N

Inventor： VALENTINE JAMES M ,  SPRAGUE BARRY N

IPC: C10L5/16

CPC classification number: C10L1/301 ,  B01J31/2234 ,  B01J31/2239 ,  B01J31/2295 ,  B01J2531/38 ,  B01J2531/828 ,  B01J2531/842 ,  C10L1/10 ,  C10L1/14 ,  C10L1/1616 ,  C10L1/305 ,  F02M25/00 ,  F02M27/02

Abstract: Disclosed is a fuel additive concentrate having a high flash point which is characterized by a viscosity controlled for dosing in a Bernoulli feed device. The concentrate is high temperature stable and is in a form suitable for on-board dosing of fuel which can provide predictable feed rates from a feed device. It comprises a fuel soluble platinum group metal composition and/or a fuel soluble or dispersible cerium composition and/or a fuel soluble or dispersible iron compound and a high flash aromatic solvent. The solvent and the metal composition or compositions are present in relative amounts to provide a FBC concentrate having a flash point (ASTM D93-85) of greater than 140°F and, a preferred kinematic viscosity within the range of from 7 to 25 centistokes, as measured by ASTM D445 at 105°F.

Abstract translation: 公开了具有高闪点的燃料添加剂浓缩物，其特征在于在伯努利进料装置中用于计量的粘度。 浓缩物是高温稳定的，并且是适合于车载计量燃料的形式，其可以从进料装置提供可预测的进料速率。 它包括燃料可溶性铂族金属组合物和/或燃料可溶或可分散的铈组合物和/或燃料可溶或可分散的铁化合物和高闪光芳族溶剂。 溶剂和金属组合物或组合物以相对的量存在，以提供具有大于140°F的闪点（ASTM D93-85）的FBC浓缩物，并且优选的运动粘度在7至25厘沲的范围内， 通过ASTM D445在105°F测量。

公开(公告)号：WO2006078762A1

公开(公告)日：2006-07-27

申请号：PCT/US2006/001813

申请日：2006-01-19

Applicant: CLEAN DIESEL TECHNOLOGIES, INC. ,  VALENTINE, James, M. ,  SPRAGUE, Barry, N.

Inventor： VALENTINE, James, M. ,  SPRAGUE, Barry, N.

IPC: F01N3/00 ,  C10L1/10

CPC classification number: F02M25/00 ,  C10L1/10 ,  C10L1/1241 ,  C10L1/1814 ,  C10L1/1881 ,  C10L1/1886 ,  C10L1/189 ,  C10L1/301 ,  C10L1/305 ,  C10L10/02 ,  C10L10/06 ,  F01N3/023 ,  F01N3/035 ,  F01N3/10 ,  F01N2430/04 ,  F01N2510/065 ,  F02B3/06 ,  F02M27/02 ,  F23J7/00 ,  F23K5/08 ,  F23K2301/103 ,  F23K2900/05081

Abstract: An improved diesel operation system employs a lightly diesel oxidation catalyst (DOC), preferably with a platinum containing fuel borne catalyst (FBC) in the fuel. The DOC is at least partially lightly catalyzed with precious metal catalyst, e.g., platinum group metal, having a metal loading of from about 3 to 15 grams per cubic foot to minimize formation Of NO 2 in the exhaust gas. Preferred fuel borne catalyst levels will be low, e.g., from 0.05 to 0.5 ppm for platinum and 3 to 8 ppm for cerium and/or iron, thereby providing effective engine out emissions reductions without discharging excessive amounts of metal catalysts or NO 2 to the atmosphere.

Abstract translation: 改进的柴油操作系统使用轻质柴油氧化催化剂（DOC），优选在燃料中使用含铂的燃料催化剂（FBC）。 用贵金属催化剂（例如，铂族金属）至少部分地轻微地将DOC用量从约3至15克/立方英尺的金属负载量轻微地催化，以最大程度地减少排气中NO 2的形成 。 优选的燃料催化剂水平将是低的，例如，对于铂为0.05至0.5ppm，对于铈和/或铁为3至8ppm，从而在不排放过量金属催化剂或NO 2的情况下提供有效的发动机排放减少 到大气。

公开(公告)号：WO2003067152A1

公开(公告)日：2003-08-14

申请号：PCT/US2003/003204

申请日：2003-02-03

Applicant: CLEAN DIESEL TECHNOLOGIES, INC. ,  SPRAGUE, Barry, N. ,  VALENTINE, James, M.

Inventor： SPRAGUE, Barry, N. ,  VALENTINE, James, M.

IPC: F23J7/00

CPC classification number: C10L10/06 ,  C10L1/10 ,  C10L1/1241 ,  C10L1/125 ,  C10L1/1608 ,  C10L1/1814 ,  C10L1/1881 ,  C10L1/1886 ,  C10L1/1888 ,  C10L1/2222 ,  C10L1/301 ,  C10L1/305 ,  C10L10/02 ,  C10L10/14 ,  F01N3/023 ,  F01N2430/04 ,  F23J7/00 ,  F23K5/08 ,  F23K2301/103 ,  F23K2900/05081

Abstract: Residual fuels, as well as lighter distillate fuels, are combusted with greater efficiency by utilizing low concentrations of specific bimetallic or trimetallic fuel-borne catalysts. The catalysts reduce fouling of heat transfer surfaces by unburned carbon while limiting the amount of secondary additive ash which may itself cause overloading of particulate collector devices or emissions of toxic ultra fine particles when used in forms and quantities typically employed. By utilizing a fuel containing a fuel-soluble catalyst comprised of platinum and at least one additional metal comprising cerium and/or iron, production of pollutants of the type generated by incomplete combustion is reduced. Ultra low levels of nontoxic metal combustion catalysts are able to be employed for improved heat recovery and lower emissions of regulated pollutants.

Abstract translation: 通过利用低浓度的特定双金属或三金属燃料催化剂，残余燃料以及较轻馏分燃料通过更高效率燃烧。 催化剂减少了未燃烧的碳的传热表面的结垢，同时限制了二次添加剂灰分的量，其本身可能导致颗粒收集器装置的过载或当以通常使用的形式和数量使用时有毒超细颗粒的排放。 通过利用含有由铂和至少一种包含铈和/或铁的附加金属组成的燃料可溶性催化剂的燃料，由不完全燃烧产生的类型的污染物的产生减少了。 超低含量的无毒金属燃烧催化剂能够用于改善热回收和降低受规管污染物的排放。

公开(公告)号：WO1997028358A1

公开(公告)日：1997-08-07

申请号：PCT/US1997001606

申请日：1997-01-30

Applicant: CLEAN DIESEL TECHNOLOGIES, INC. ,  PETER-HOBLYN, Jeremy, D. ,  VALENTINE, James, M. ,  SPRAGUE, Barry, N.

Inventor： CLEAN DIESEL TECHNOLOGIES, INC. ,  PETER-HOBLYN, Jeremy, D.

IPC: F01N03/28

CPC classification number: C10L1/1828 ,  B01D53/944 ,  B01D53/9495 ,  C10L1/10 ,  C10L1/1208 ,  C10L1/1225 ,  C10L1/1233 ,  C10L1/1241 ,  C10L1/1266 ,  C10L1/1275 ,  C10L1/1616 ,  C10L1/1814 ,  C10L1/188 ,  C10L1/1881 ,  C10L1/1886 ,  C10L1/1888 ,  C10L1/205 ,  C10L1/231 ,  C10L1/2437 ,  C10L1/2641 ,  C10L1/301 ,  C10L1/305 ,  C10L10/02 ,  F01N3/023 ,  F01N3/029 ,  F01N3/035 ,  F01N3/206 ,  F01N2430/04 ,  F01N2610/01 ,  F02D19/12 ,  Y02A50/2341 ,  Y02T10/121

Abstract: Emissions of pollutants from diesel engines (10) are reduced by a regimen for catalytically treating engine exhaust and, preferably, also the combustion of the fuel. The balance point of a diesel trap (30) is reduced to permit more efficient regeneration, preferably self-regeneration, while also reducing emissions of carbon monoxide and hydrocarbons by a combination of mechanical devices and fuel additives. The regimen requires the introduction of from 0.05 to 1 ppm of a platinum group metal catalyst (based on the volume of fuel combusted) into the particulates, by introducing at least half of the platinum group metal catalyst (50) directly into the hot exhaust gases (52, 20). Preferably, the platinum group metal catalyst is employed with a combustible organic liquid to aid in either progressively loading the trap (30) with the combustible organics or to combust in the hot combustion gases to facilitate burning of the particulates on the trap (30) for more effective regeneration. The judicious selection and use of an auxiliary catalyst metal (e.g., copper), preferably adding at least half of its total to the fuel as a fuel additive, is a preferred part of the regimen to achieve the lowest trap balance point.

Abstract translation: 来自柴油发动机（10）的污染物的排放通过用于催化处理发动机排气的方案减少，并且优选地还被燃料的燃烧。 柴油收集器（30）的平衡点被减少以允许更有效的再生，优选自再生，同时还通过机械装置和燃料添加剂的组合减少一氧化碳和烃的排放。 该方案需要将0.05至1ppm的铂族金属催化剂（基于燃烧的燃料的体积）引入颗粒中，通过将至少一半的铂族金属催化剂（50）直接引入热废气中 （52,20）。 优选地，将铂族金属催化剂与可燃有机液体一起使用以帮助将捕集器（30）逐渐加载到可燃的有机物上，或者在热燃烧气体中燃烧，以便于将微粒燃烧在捕集器（30）上 更有效的再生。 辅助催化剂金属（例如铜）的合理选择和使用，优选将其总量的至少一半添加到作为燃料添加剂的燃料中，是实现最低陷阱平衡点的方案的优选部分。

公开(公告)号：WO2006078764A3

公开(公告)日：2007-10-04

申请号：PCT/US2006001815

申请日：2006-01-19

Applicant: CLEAN DIESEL TECH INC ,  VALENTINE JAMES M ,  SPRAGUE BARRY N ,  PETER-HOBLYN JEREMY D

Inventor： VALENTINE JAMES M ,  SPRAGUE BARRY N ,  PETER-HOBLYN JEREMY D

IPC: C10L1/30

CPC classification number: C10L10/02 ,  C10L1/10 ,  C10L1/1241 ,  C10L1/125 ,  C10L1/1814 ,  C10L1/1881 ,  C10L1/1886 ,  C10L1/1888 ,  C10L1/189 ,  C10L1/301 ,  C10L1/305 ,  C10L10/06 ,  F01N3/023 ,  F01N3/035 ,  F01N3/106 ,  F01N2430/04 ,  F02D19/0652 ,  F02M25/14 ,  F02M27/02 ,  Y02T10/121 ,  Y02T10/36

Abstract: Diesel fuels containing low concentrations of specific bimetallic or trimetallic fuel-borne catalysts reduce particulates and other emissions without the use of after treatment devices, such as filters or catalysts, e.g., diesel particulate filters (DPF's) or diesel oxidation catalysts (DOCs) in the case of diesel engines. By utilizing a fuel containing a fuel-soluble catalyst comprised of platinum and at least one additional metal comprising cerium and/or iron, production of pollutants of the type generated by incomplete combustion is reduced. Preferred fuel borne catalyst levels will be low, e.g., from 0.05 to 0.5 ppm for platinum and 3 to 8 ppm for cerium and/or iron, thereby providing effective engine out emissions reductions without any aftertreatment device. Performance of lightly catalyzed aftertreatment devices will be improved with the subject invention.

Abstract translation: 含有低浓度特定双金属或三金属燃料载体催化剂的柴油燃料可减少颗粒物和其他排放物，而不需要使用后处理装置，如过滤器或催化剂，例如柴油机颗粒过滤器（DPF）或柴油机氧化催化剂（DOC） 柴油机案例 通过利用含有由铂和至少一种包含铈和/或铁的附加金属组成的燃料可溶性催化剂的燃料，由不完全燃烧产生的类型的污染物的产生减少。 优选的燃料催化剂水平将是低的，例如铂的0.05至0.5ppm，对于铈和/或铁为3至8ppm，从而在没有任何后处理装置的情况下提供有效的发动机排出减排。 本发明将提高轻催化后处理装置的性能。

公开(公告)号：WO2007011912A2

公开(公告)日：2007-01-25

申请号：PCT/US2006/027783

申请日：2006-07-18

Applicant: CLEAN DIESEL TECHNOLOGIES, INC. ,  VALENTINE, James, M. ,  SPRAGUE, Barry, N.

Inventor： VALENTINE, James, M. ,  SPRAGUE, Barry, N.

IPC: B01J31/00

CPC classification number: C10L1/301 ,  B01J31/2234 ,  B01J31/2239 ,  B01J31/2295 ,  B01J2531/38 ,  B01J2531/828 ,  B01J2531/842 ,  C10L1/10 ,  C10L1/14 ,  C10L1/1616 ,  C10L1/305 ,  F02M25/00 ,  F02M27/02

Abstract: Disclosed is a fuel additive concentrate having a high flash point which is characterized by a viscosity controlled for dosing in a Bernoulli feed device. The concentrate is high temperature stable and is in a form suitable for on-board dosing of fuel which can provide predictable feed rates from a feed device. It comprises a fuel soluble platinum group metal composition and/or a fuel soluble or dispersible cerium composition and/or a fuel soluble or dispersible iron compound and a high flash aromatic solvent. The solvent and the metal composition or compositions are present in relative amounts to provide a FBC concentrate having a flash point (ASTM D93-85) of greater than 140°F and, a preferred kinematic viscosity within the range of from 7 to 25 centistokes, as measured by ASTM D445 at 105°F.

Abstract translation: 公开了一种具有高闪点的燃料添加剂浓缩物，其特征在于在伯努利加料装置中控制用于定量给料的粘度。 该浓缩物是高温稳定的，并且处于适合于可以从供给装置提供可预测的供给速率的燃料的车载配量的形式。 它包含燃料可溶性铂族金属组合物和/或燃料可溶性或可分散性铈组合物和/或燃料可溶性或可分散性铁化合物和高闪点芳族溶剂。 溶剂和金属组合物或组合物以相对量存在以提供闪点（ASTM D93-85）大于140°F和优选的运动粘度在7-25厘range范围内的FBC浓缩物， 如通过ASTM D445在105°F下测量的

公开(公告)号：WO1997004045A1

公开(公告)日：1997-02-06

申请号：PCT/US1996011908

申请日：1996-07-18

Applicant: CLEAN DIESEL TECHNOLOGIES, INC. ,  PETER-HOBLYN, Jeremy, D. ,  VALENTINE, James, M. ,  SPRAGUE, Barry, N. ,  EPPERLY, W., Robert

Inventor： CLEAN DIESEL TECHNOLOGIES, INC.

IPC: C10L01/30

CPC classification number: F01N3/029 ,  C10L1/10 ,  C10L1/1208 ,  C10L1/1225 ,  C10L1/1233 ,  C10L1/1241 ,  C10L1/125 ,  C10L1/1266 ,  C10L1/1275 ,  C10L1/14 ,  C10L1/1608 ,  C10L1/1616 ,  C10L1/1691 ,  C10L1/1814 ,  C10L1/1824 ,  C10L1/1828 ,  C10L1/1852 ,  C10L1/1855 ,  C10L1/1857 ,  C10L1/188 ,  C10L1/1881 ,  C10L1/1883 ,  C10L1/1886 ,  C10L1/1888 ,  C10L1/191 ,  C10L1/198 ,  C10L1/1985 ,  C10L1/2222 ,  C10L1/2225 ,  C10L1/224 ,  C10L1/23 ,  C10L1/231 ,  C10L1/232 ,  C10L1/238 ,  C10L1/2437 ,  C10L1/26 ,  C10L1/2608 ,  C10L1/301 ,  C10L1/305 ,  C10L10/02 ,  C10L10/06 ,  F01N3/023 ,  F01N3/035 ,  F01N2430/04 ,  F02D41/0065 ,  F05C2201/0427

Abstract: Emissions of pollutants from diesel engines are reduced by a combination of mechanical devices and fuel additives. In one series of embodiments, diesel emissions of NOx and particulates are reduced, simultaneously with gaseous hydrocarbons and carbon monoxide, by the combined use of exhaust gas recirculation or engine timing modification, with a particulate trap and a platinum group metal catalyst composition. In another embodiment, a multi-metal catalyst composition, comprising a combination of a platinum metal catalyst composition and at least one auxiliary catalyst metal composition, especially cerium or copper, is employed to provide catalyst metal to the exhaust system including a diesel trap to lower the balance point of the particulate trap (the temperature at which the rate of trap loading equals the rate of regeneration) while also lowering the emissions of carbon monoxide and unburned hydrocarbons. Data for platinum, copper and cerium catalysts establishes effective amounts. Tests also show selective maintenance of low oxidation of SO2 to SO3.

Abstract translation: 通过机械装置和燃料添加剂的组合来减少来自柴油发动机的污染物的排放。 在一系列实施例中，通过与颗粒捕集器和铂族金属催化剂组合物的组合使用废气再循环或发动机正时修改，与气态烃和一氧化碳同时地减少了NOx和颗粒的柴油排放。 在另一个实施方案中，使用包含铂金属催化剂组合物和至少一种辅助催化剂金属组合物，特别是铈或铜的组合的多金属催化剂组合物，以向排气系统提供催化剂金属，所述催化剂金属包括柴油收集器以降低 颗粒捕集器的平衡点（捕集装载速率等于再生速率的温度）同时也降低了一氧化碳和未燃碳氢化合物的排放。 铂，铜和铈催化剂的数据建立有效量。 测试还显示选择性维持SO2的低氧化为SO3。

公开(公告)号：WO2006078764A2

公开(公告)日：2006-07-27

申请号：PCT/US2006/001815

申请日：2006-01-19

Applicant: CLEAN DIESEL TECHNOLOGIES, INC. ,  VALENTINE, James, M. ,  SPRAGUE, Barry, N. ,  PETER-HOBLYN, Jeremy, D.

Inventor： VALENTINE, James, M. ,  SPRAGUE, Barry, N. ,  PETER-HOBLYN, Jeremy, D.

IPC: C10L1/30

CPC classification number: C10L10/02 ,  C10L1/10 ,  C10L1/1241 ,  C10L1/125 ,  C10L1/1814 ,  C10L1/1881 ,  C10L1/1886 ,  C10L1/1888 ,  C10L1/189 ,  C10L1/301 ,  C10L1/305 ,  C10L10/06 ,  F01N3/023 ,  F01N3/035 ,  F01N3/106 ,  F01N2430/04 ,  F02D19/0652 ,  F02M25/14 ,  F02M27/02 ,  Y02T10/121 ,  Y02T10/36

Abstract: Diesel fuels containing low concentrations of specific bimetallic or trimetallic fuel-borne catalysts reduce particulates and other emissions without the use of after treatment devices, such as filters or catalysts, e.g., diesel particulate filters (DPF's) or diesel oxidation catalysts (DOCs) in the case of diesel engines. By utilizing a fuel containing a fuel-soluble catalyst comprised of platinum and at least one additional metal comprising cerium and/or iron, production of pollutants of the type generated by incomplete combustion is reduced. Preferred fuel borne catalyst levels will be low, e.g., from 0.05 to 0.5 ppm for platinum and 3 to 8 ppm for cerium and/or iron, thereby providing effective engine out emissions reductions without any aftertreatment device. Performance of lightly catalyzed aftertreatment devices will be improved with the subject invention.

Abstract translation: 含有低浓度特定双金属或三金属燃料载体催化剂的柴油燃料可减少颗粒物和其他排放物，而不需要使用后处理装置，如过滤器或催化剂，例如柴油机颗粒过滤器（DPF）或柴油机氧化催化剂（DOC） 柴油机案例 通过利用含有由铂和至少一种包含铈和/或铁的附加金属组成的燃料可溶性催化剂的燃料，由不完全燃烧产生的类型的污染物的产生减少了。 优选的燃料催化剂水平将是低的，例如铂的0.05至0.5ppm，对于铈和/或铁为3至8ppm，从而在没有任何后处理装置的情况下提供有效的发动机排出减排。 本发明将提高轻催化后处理装置的性能。