Abstract:
Coating compositions are disclosed which include a copolymer prepared from a reaction mixture comprising an ethylenically unsaturated hydrolysable silane, an ethylenically unsaturated polyoxyalkylene, an ethylenically unsaturated fluorinated polyether and an initiator. The coating composition may also include a curable sol-gel dispersion. The coating compositions can be used to prepare hardcoats.
Abstract:
Surface-modified adhesives may be prepared by contacting an adhesive layer to an at least partially discontinuous layer on a releasing substrate and removing the adhesive layer such that at least a portion of the at least partially discontinuous layer adheres to the adhesive surface. The modified adhesive surface remains an adhesive surface. The modified adhesive layer can be used to prepare adhesive articles, including articles containing multiple surface-modified adhesive layers.
Abstract:
A process and apparatus for producing a gradient nanovoided article, a gradient nanovoided coating, and a gradient low refractive index coating is described. The process includes providing a first solution of a polymerizable material in a solvent, and providing a first environment proximate a first region of the coating and a different second environment proximate an adjacent region of the coating. The process further includes at least partially polymerizing the polymerizable material to form a composition that includes an insoluble polymer matrix and a second solution. The insoluble polymer matrix includes a plurality of nanovoids that are filled with the second solution, and a major portion of the solvent from the second solution is removed. A first volume fraction of the plurality of nanovoids proximate the first region of the coating is less than a second volume fraction of the plurality of nanovoids proximate an adjacent of the coating. An apparatus for the process is also described, and includes a web line, a coating section, a partial polymerization section, and a solvent removal section.
Abstract:
A voided diffuser and an optical construction incorporating the voided diffuser are provided. The voided diffuser includes a plurality of beads and a binder composition in contact with the plurality of beads. The binder composition includes a binder and a plurality of interconnected voids. The optical construction includes the voided diffuser disposed on a substrate.
Abstract:
Surface-modified adhesives may be prepared by contacting an adhesive layer to an electrically conductive layer on a releasing substrate and removing the adhesive layer such that at least a portion of the electrically conductive layer adheres to the adhesive surface. The modified adhesive surface becomes an electrically conductive adhesive surface. The modified adhesive layer can be used to prepare adhesive articles, including articles containing multiple surface-modified adhesive layers.
Abstract:
Lightguide is disclosed. The lightguide includes a light guiding layer for propagating light by total internal reflection, and an optical film that is disposed on the light guiding layer. The optical film includes a plurality of voids, an optical haze that is not less than about 30%, and a porosity that is not less than about 20%. Substantial portions of each two neighboring major surfaces in the lightguide are in physical contact with each other.
Abstract:
Laser-personalizable security articles include a multi-layer security document and an optically transparent processing tape. The multi-layer security document includes an optically transparent cover layer, a composite image and an imagable layer adjacent to the cover layer. The first surface of the cover layer is at least partially a microstructured surface, where the microstructured surface forms microlenses or a lenticular surface. The composite image is made by a collection of complete or partial images viewed through the microstructured surface of the cover layer. The composite image is located on or within the second surface of the cover layer. The imagable layer is a laser imagable layer. The optically transparent processing tape sufficiently wets out on the microstructured surface to render the microstructured surface invisible to a writing laser.
Abstract:
A gradient optical film and an optical construction including the gradient optical film are described. The gradient optical film includes a binder, a plurality of particles, and a plurality of interconnected voids having a local volume fraction. The local volume fraction of the plurality of interconnected voids varies along a thickness direction of the gradient optical film. The refractive index of the gradient optical film can also varies along a thickness direction of the gradient optical film, as the refractive index can also depend upon the local volume fraction of the plurality of interconnected voids.
Abstract:
A light extraction film having nanoparticles with engineered periodic structures. The light extraction film includes a substantially transparent substrate, low index one-dimensional or two-dimensional periodic structures on the substrate, and a high index planarizing backfill layer applied over the periodic structures. Light scattering nanoparticles are either applied in a layer over the periodic structures or included in the backfill layer.
Abstract:
Optical films for enhancing light extraction from self-emissive pixelated OLEDs, without introducing significant pixel blur, are disclosed. The extraction films include a flexible carrier film, and a first and second layer carried by the carrier film. The first layer has a nanovoided morphology, includes a polymer binder, and may have a refractive index less than 1.35 or 1.3. An embedded structured surface of light extraction elements is formed between the first and second layers. The extraction film includes a major coupling surface for attachment to an outer surface of the light source. The film is configured such that a land portion between the structured surface and the major coupling surface is thinner than a specified amount, for example, less than 50, 25, or 10 microns, or less than a thickness of the carrier film.