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1.发明申请
公开(公告)号：WO2011035852A2
公开(公告)日：2011-03-31
申请号：PCT/EP2010005427
申请日：2010-09-03
IPC分类号： B01J19/12
CPC分类号： B01J19/126 , B01J23/44 , B01J23/462 , B01J23/882 , B01J35/04 , B01J2219/00033 , B01J2219/0892 , B01J2219/1215 , B01J2219/1227 , C07C29/143 , C07C67/03 , C07C2601/14 , C10G32/02 , C10G2300/1055 , C10G2300/202 , C10G2400/04 , H05B6/806 , C07C35/08 , C07C69/52
摘要： The invention relates to an apparatus for continuously carrying out heterogeneously catalyzed chemical reactions, comprising a microwave-transparent tube, the longitudinal axis of which extends in the direction of propagation of the microwaves of a single-mode microwave applicator and which is filled with an open-cell foam that carries or is made of catalytically active species.
摘要翻译： 本发明涉及一种用于连续地进行非均相催化的化学反应，包括一个微波透明管，其纵向轴线位于一个单模微波的微波的传播方向，与开孔的微波透明管，催化活性物质的轴承或淘汰现有泡沫的 被填满。
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2.发明申请POLYMERS CARRYING HYDROXYL GROUPS AND ESTER GROUPS AND METHOD FOR THE PRODUCTION THEREOF 审中-公开羟基基团和携带聚合物的酯基团及其制备方法
公开(公告)号：WO2012089298A2
公开(公告)日：2012-07-05
申请号：PCT/EP2011006174
申请日：2011-12-08
IPC分类号： C08F8/14
CPC分类号： C08F216/06 , B01J19/126 , B01J2219/0884 , B01J2219/0888 , B01J2219/0892 , B01J2219/1215 , B01J2219/1227 , B01J2219/1287 , C08F8/00 , C08F8/14 , C08F2810/20 , H05B6/806 , C08F16/06
摘要： The invention relates to polymers carrying ester/hydroxyl groups, containing repetitive structural units of formulae (I) and (II) in a block-wise, alternating or statistical sequence, wherein D represents a direct bond between the polymer backbone and the hydroxyl group, a C1-to C6-alkene group, a C5- to C12-arylene group, an oxyalkene group of formula -O-R2-, an ester group of formula -C(O)-O-R2- or an amide group of formula -C(O)-N(R3)R2-, E represents a hydrocarbon group having 1 to 50 C-atoms, R2 represents a C2- to C10-alkene group, R3 represents hydrogen or a C1- to C10-alkyl group, which can carry substituents, k represents a number between 1 and 1000, n represents a number from 0 to 4999, m represents a number from 1 to 5000, and n+m represents a number between 10 to 5000, under the proviso that a) the molar portion of the structural units (I) on the polymer is between 0 and 99.9 mol-%, and b) the molar portion of the structural units (II) on the polymer is between 0.1 and 100 mol-% of the repetitive units. The invention also relates to a method for the production of said polymers using microwaves.
摘要翻译： 本发明涉及一种酯含有式（I）和repetitierende结构单元带有羟基的聚合物（II）中由嵌段，交替或无规序列d的块是在聚合物主链和羟基基团，C1至C6亚烷基，C 5至C之间的直接键 C12亚芳基，氧化烯基的式-O-R 2，下式的Estergruppe的-C（O）-O-R 2或下式的酰胺基团-C（O）-N（R 3）R 2，e是一个烃基 碳原子数为1〜50的可携带的C2至C10的亚烷基，R3是氢或C1-C10烷基，取代基R 2，k是一个从1到1000，n是从0到的数 4999，m是一个从1到5000，n + m是从10至5000的数被提供，条件是：a）结构单元（I），以从0聚合物的〜99.9％（摩尔）的摩尔比例， 和b）聚合物上结构单元（II）的摩尔分数为重复的0.1至100摩尔％ 以及通过使用微波制造它的方法。
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公开(公告)号：WO2011000463A3
公开(公告)日：2011-03-31
申请号：PCT/EP2010003446
申请日：2010-06-09
CPC分类号： C07C67/08 , B01J19/126 , B01J2219/1215 , B01J2219/1227 , B01J2219/1272 , B01J2219/1281 , B01J2219/1284 , B01J2219/129 , H05B6/701 , H05B6/806 , C07C69/68 , C07C69/54 , C07C69/14 , C07C69/24
摘要： The invention relates to a continuous method for producing aliphatic carbonic acid esters by reacting at least one aliphatic carboxylic acid of formula (I) R1-COOH (I), wherein R1 represents hydrogen or an optionally substituted aliphatic hydrocarbon group with 1 to 50 carbon atoms, with at least one alcohol of formula (II) R2-(OH)n (II), wherein R2 represents an optionally substituted hydrocarbon group with 1 to 100 C atoms and n is an integer from 1 to 10, in the presence of at least one transesterification catalyst in a reaction tube the longitudinal axis of which extends in the direction of propagation of the microwaves of a monomode microwave applicator, under microwave irradiation to form the ester.
摘要翻译： 本发明涉及一种通过式（I）的至少一种脂族羧酸反应制备脂族羧酸酯的方法R1-COOH（I）其中R1是氢或具有碳原子数为1〜50的任选被取代的脂族烃基，具有至少一个醇 式（II）R 2 - （OH）N（II）其中R 2代表具有1至100个碳原子和n任选取代的烃基团是从1到10，在至少一种酯化催化剂的微波照射下存在下，在反应管中，该 纵轴处于单模微波的微波的传播方向，转换为酯。
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4.发明申请
公开(公告)号：WO2011000461A3
公开(公告)日：2011-03-31
申请号：PCT/EP2010003444
申请日：2010-06-09
IPC分类号： C07C231/02 , C07C233/47 , C07C233/53 , C07C303/22 , C07C309/14
CPC分类号： C07C231/02 , B01J19/126 , B01J2219/00033 , B01J2219/0888 , B01J2219/0892 , B01J2219/1227 , C07C303/22 , H05B6/701 , H05B6/806 , C07C233/47 , C07C233/54 , C07C309/14 , C07C309/15
摘要： The invention relates to a continuous method for N-acylating amino group-carrying organic acids by reacting at least one carboxylic acid of formula (I) R1-COOH (I), wherein R1 represents hydrogen or an optionally substituted hydrocarbon group with 1 to 50 carbon atoms, with at least one at least one amino group-carrying organic acid of formula (II) R2NH-A-X (II), wherein A represents an optionally substituted hydrocarbon group with 1 to 50 carbon atoms, X represents an acid group or the metal salt thereof and R2 represents hydrogen, an optionally substituted hydrocarbon group with 1 to 50 C atoms or a group of the formula -A-X, wherein A and X independently are defined as above, in a reaction tube the longitudinal axis of which extends in the direction of propagation of the microwaves of a monomode microwave applicator, under microwave irradiation to form amide.
摘要翻译： 因此，本发明是一种用于的N-酰化的连续方法的带有氨基的有机酸的由式（I）的至少一种羧酸R1-COOH（I）其中R1是氢或具有碳原子数为1〜50的任选取代的烃基，其中至少 被至少一个氨基的轴承式的有机酸（II）R 2 NH-AX（II）其中a表示任选被取代的烃基，其具有碳原子数为1〜50，X为酸性基团或它们的金属盐和R2是氢，具有1个到任选取代的烃基 50个C原子或下式基团-AX的其中一个，以及X彼此独立地具有在一个反应管中，其纵向轴线在从单模微波施加的微波的传播方向，而得到酰胺如上所述的含义，是，在微波照射下 实施 是。
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5.发明申请POLYMERS COMPRISING HYDROXYL GROUPS AND ESTER GROUPS AND METHOD FOR THE PRODUCTION THEREOF 审中-公开羟基基团和携带聚合物的酯基团及其制备方法
公开(公告)号：WO2012089300A3
公开(公告)日：2012-09-27
申请号：PCT/EP2011006176
申请日：2011-12-08
CPC分类号： C08F218/04 , C08F8/14 , C08G81/025 , C08J5/18 , C08F16/06
摘要： The invention relates to polymers comprising ester/hydroxyl groups, containing repetitive structural units of formulae (I) and (II) in blocks, alternatively or statistically in her Abfolge (I), (II) wherein D represents a direct bond between the polymer backbone and the hydroxyl group, a C-1-to C6-alkylene group, a C5- to C12-arylene group, a oxyalkylene group of formula -O-R2-, an ester group of formula -C(O)-O-R2- or an amide group of formula -C(O)-N(R3)R2-, E represents a hydrocarbon group having 1 to 10 C-atoms, R1 represents hydrogen, a hydrocarbon group having 1 to 50 C-atoms or an acyl group of formula -C(O)-R4, R2 represents a C2- to C10-alkylene group, R3 represents hydrogen or a C1- to C10-alkyl group, which can have substituents, R4 represents a hydrocarbon group having 1 to 50 C-atoms, A represents a C2- to C10-alkylene group, k represents a number between 1 and 100, n represents a number from 0 to 4999, m represents a number from 1 to 5000, n+m for a number from 10 to 5000, under the proviso that a) the molar fraction of the structural units (I) on the polymer is between 0 and 99,9 mol-%, and b) the molar fraction of the structural units (II) on the polymers between 0.1 and 100 mol-% of repetitive units. The invention also relates to a method for the production of said polymers by exposing a polymer reaction mixture containing hydroxyl groups and ether carbon esters to microwaves.
摘要翻译： 本发明涉及一种酯含有式（I）和repetitierende结构单元带有羟基的聚合物（II）中由嵌段，交替或无规序列（I），嵌段（II），其中，d是聚合物主链和羟基之间的直接键，C-1 - 双C6亚烷基，C 5至C 12的亚芳基，氧化烯基的式-O-R 2的，下式的Estergruppe -C（O）-O-R 2或下式的酰胺基团-C（O）-N （R 3）R 2，e是碳原子数为1〜10的烃基，R 1表示氢，具有1至50个碳原子或酰基的式-C（O）的-R 4 R 2是C2-C10的烃基 亚烷基基团，R3为氢或C1至C10烷基，其可以具有取代基，R4，一个烃基，其具有碳原子数1〜50，表示C2至C10的亚烷基，k是1和100之间的数 n是从0到4999的数字，m是从1到5000的数字，n + m是从10 bi开始的数字 s为5000，条件是：a）结构单元（I）与聚合物的摩尔比为0〜99.9摩尔％，0.1和100之间的聚合物中的结构单元（II）的B）的摩尔比例 摩尔％的重复单元，以及通过用微波照射含羟基聚合物和醚羧酸的反应混合物来制备它们的方法。
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公开(公告)号：WO2012089296A2
公开(公告)日：2012-07-05
申请号：PCT/EP2011006172
申请日：2011-12-08
IPC分类号： C08F8/14
摘要： The invention relates to a method for reacting polymers (A) comprising hydroxyl groups and which have repetitive structural units of general formula (I), wherein D represents a direct bond between the polymer backbone and a hydroxyl group, a C1-to C6-alkene group, a C5- to C12-arylene group, an oxyalkylene group of formula -O-R2-, an ester group of formula -C(O)-O-R2- or an amide group of formula -C(O)-N(R8)R2-, R2 represents a C2- to C10-alkene group, R8 represents hydrogen or an optionally substituted C2- to C10-alkyl group and n represents a number between 3 and 5000, with carboxylic acids B1 ) of formula (II) or carboxylic acid esters B2) of formula (III) R1-COOH (II) R1-COOR7 (III), wherein R1 represents a hydrocarbon group having 2 to 50 C atoms, and R7 represents a C1C4-alkyl group, in which the polymers (A) comprising the hydroxyl groups are exposed to microwaves in the presence of carboxylic acids of formula (II) or carboxylic acid esters of formula (III) and in the presence of water. The reaction mixture is heated to temperatures over 100 °C by microwave rays.
摘要翻译： 因此，本发明涉及一种用于带有羟基的聚合物A）中，通式（I），其中D是在聚合物主链和羟基之间的直接键的repetitierende结构单元的反应，C1至C6亚烷基，C5至C12 亚芳基，氧化烯基的式-O-R 2，下式的酯基团-C（O）-O-R 2或酰胺基的式-C（O）-N（R 8）R 2，R 2是C2 是至C10亚烷基，R 8是氢或任选取代的C2至C10烷基，n是3和5.000之间的数字，与下式的羧酸B1）（II）或羧酸酯的式B2）（III）R1-COOH （II）R 1 COOR 7（III）其中R 1表示碳原子数为2〜50的烃基，R 7表示，其中的羟基聚合物a）如式羧酸的存在带有C 1 -C 4 - 烷基（II）或羧酸酯 式（III）的和在存在 其中所述反应混合物通过微波辐射在温度超过100℃下加热是辐射用的水微波。
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公开(公告)号：WO2011000464A2
公开(公告)日：2011-01-06
申请号：PCT/EP2010003447
申请日：2010-06-09
IPC分类号： C07C67/08
CPC分类号： B01J19/126 , B01J2219/1215 , B01J2219/1227 , B01J2219/1272 , B01J2219/1281 , B01J2219/1284 , C07C67/08 , C07D213/79 , H05B6/701 , H05B6/806 , C07C69/78 , C07C69/82 , C07C69/76 , C07C69/84
摘要： The invention relates to a continuous method for producing aromatic carboxylic acid esters by reacting at least one aromatic carboxylic acid of formula (I) Ar-COOH (I), wherein Ar represents an optionally substituted aryl group with 5 to 50 atoms, with at least one alcohol of formula (II) R2-(OH)n (II), wherein R2 represents an optionally substituted hydrocarbon group with 1 to 100 C atoms and n is an integer from 1 to 10, in the presence of at least one transesterification catalyst in a reaction tube, the longitudinal axis of which extends in the direction of propagation of the microwaves of a monomode microwave applicator, under microwave irradiation to form the ester.
摘要翻译： 本发明涉及一种通过式（I）的至少一种芳族羧酸制备的芳族Carbonsäureestern的连续方法的Ar-COOH（I）其中Ar表示具有5至50个原子（与所述式的至少一种醇的任选取代的芳基 II）R2（OH）N（II）其中R 2代表具有1至100个碳原子和n任选取代的烃基团是从1到10，在至少一种酯化催化剂的微波照射下存在下，在反应管中，其纵向轴线 在单模微波施加器的微波传播方向上被转换为酯。
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8.发明申请
公开(公告)号：WO2011000460A2
公开(公告)日：2011-01-06
申请号：PCT/EP2010003443
申请日：2010-06-09
IPC分类号： B01J19/12
CPC分类号： C07C1/321 , B01J19/126 , B01J2219/0871 , B01J2219/1227 , C07C67/08 , C07C231/02 , C07C2531/24 , C07D307/60 , H05B6/80 , H05B6/806 , C07C15/14 , C07C69/24 , C07C69/52 , C07C233/05 , C07C233/09 , C07C233/36
摘要： The invention relates to a device for continuously carrying out chemical reactions. The device comprises a microwave generator, a microwave applicator accommodating a microwave-transparent tube, and an isothermal reaction section which is arranged such that the material to be reacted is guided inside the microwave-transparent tube through a microwave applicator which is used as the heating zone and in which it is heated to reaction temperature by means of microwaves that are emitted from the microwave generator into the microwave applicator. The material to be reacted, which is heated and optionally under pressure, is transferred from the microwave applicator to an isothermal reaction zone once it has left the heating zone, said reaction zone being arranged downstream of the heating zone, and is cooled once it has left the isothermal reaction zone.
摘要翻译： 本发明涉及一种装置，用于连续进行化学反应，包括微波发生器，微波施加器，其中一个微波透明管位于和等温反应区，其被布置为使得将反应混合物通过作为加热区微波在微波透明管中进行 其中通过微波，这是从所述微波发生器的微波施加引导的手段，离开加热区在后续的加热区等温反应区和后后直接被加热至反应温度，并且在加热和任选的加压反应混合物转化 离开等温反应区被冷却。
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9.发明申请ADDITIVES FOR IMPROVING THE COLD FLOW PROPERTIES AND THE STORAGE STABILITY OF CRUDE OIL 审中-公开添加剂以改善低温流动性能和原油保质期
公开(公告)号：WO0196503A3
公开(公告)日：2003-01-09
申请号：PCT/EP0106414
申请日：2001-06-06
CPC分类号： C10L1/143 , C10L1/1641 , C10L1/1963 , C10L1/1966 , C10L1/1973 , C10L1/1981 , C10L1/2437
摘要： Additives for improving the flowability of mineral oils, containing A) 1 -40 wt. % of at least one copolymer, which is oil-soluble and improves the cold flow properties of mineral oil, B) 20 - 80 wt. % of at least one poly- alpha -olefin with a molecular weight of 250 -5000, derived from monoolefins with 3 - 5 C atoms, and C) 5 - 70 wt. % of at least one organic acid selected from C1) alkylphenol-aldehyde resins and C2) aliphatic and/or aromatic sulfonic acids.
摘要翻译： 添加剂用于改善矿物油，包括A）的流动性，从1至40重量％的至少一种共聚物的％，这是油溶性和矿物油冷流改进，B）20至80重量的具有至少一种聚-α-烯烃％ 分子量为250〜5,000，它是从具有3至5个碳原子的单烯烃衍生的，以及C）5〜70重量从C1中的至少一种有机酸）烷基酚 - 醛树脂C2）脂肪族和/或芳族磺酸的％。
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10.发明申请MULTIFUNCTIONAL COOLING ADDITIVES FOR MIDDLE DISTILLATES, HAVING AN IMPROVED FLOW CAPABILITY 审中-公开多功能冷却添加剂中间馏出物具有改进的流动性
公开(公告)号：WO2011076337A3
公开(公告)日：2011-09-01
申请号：PCT/EP2010007406
申请日：2010-12-07
发明人： KRULL MATTHIAS , REIMANN WERNER , DILSKY STEFAN , GOETZKE SABINE
CPC分类号： C10L1/143 , C10L1/1608 , C10L1/1616 , C10L1/1641 , C10L1/1963 , C10L1/1973 , C10L1/1981 , C10L1/1983 , C10L1/1985 , C10L1/224 , C10L10/14 , C10L10/16
摘要： The present invention relates to cooling additives for middle distillates, containing A) at least one polyester of formula (A1) wherein one of the radicals R1 to R4 represents a linear C16-C40 alkyl or alkenyl radical and the remainder of the radicals R1 to R4 represent, independently of one another, hydrogen or an alkyl radical having 1 to 3 C atoms, R5 is a C-C bond or an alkylene radical having 1 to 6 C atoms, R16 is a hydrocarbon group having 2 to 10 carbon atoms, n is an integer from 1 to 100, m is an integer from 3 to 250, p is 0 or 1, and q is 0 or 1, B) at least one copolymer of ethylene and of at least one ethylenically unsaturated ester, the copolymer having a melt viscosity, measured at 140 °C, of at most 5000 mPas, and C) at least one organic solvent.
摘要翻译： 本发明涉及一种冷添加剂的中间馏分，其包含A）的式（A1），其中基团R 1至R 4中的一个独立地代表直链C16-C40烷基或链烯基和基团R 1至R 4中的其余部分代表氢中的至少一种聚酯 或烷基具有1至3个碳原子，R 5代表一个C-C键合或碳原子数1〜6的亚烷基，R 16为碳原子数2〜10的烃基，n是一个从1到100，m是一个 数为3〜250，p为0或1，并且q为至少乙烯和0或1的至少一种烯属不饱和酯，B），其中共聚物具有在140℃下测得的熔体至多5000毫帕·秒的粘度和 C）至少一种有机溶剂。
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