公开(公告)号：WO02086276A3

公开(公告)日：2003-04-24

申请号：PCT/EP0204549

申请日：2002-04-24

Applicant: SHELL INT RESEARCH ,  SHELL CANADA LTD

Inventor： CRANE STEVEN DEXTER ,  DINDORUK MELIHA DENIZ SUMNU ,  KARANIKAS JOHN MICHAEL ,  MAHER KEVIN ALBERT ,  MESSIER ANN MARGARET ,  DE ROUFFIGNAC ERIC ,  VINEGAR HAROLD J ,  WELLINGTON SCOTT LEE ,  ZHANG ETUAN

IPC: E21B36/04 ,  E21B43/14 ,  E21B43/16 ,  E21B43/24 ,  E21B43/243 ,  E21B43/30 ,  E21B49/00

CPC classification number: E21B43/2406 ,  E21B36/04 ,  E21B43/14 ,  E21B43/166 ,  E21B43/2408 ,  E21B43/243

Abstract: A method for treating a tar sands formation (32) in situ includes providing heat from one or more heat sources (30) to a portion of the tar sands formation. The heat may be allowed to transfer from the heat source(s) to a selected section of the formation to pyrolyze at least some hydrocarbons within the selected section. A mixture of hydrocarbons of a selected quality may be produced from the selected section by controlling production of the mixture to adjust the time that at least some hydrocarbons are exposed to pyrolysis temperatures in the formation.

Abstract translation: 用于原位处理焦油砂形成（32）的方法包括从一个或多个热源（30）向焦油砂层的一部分提供热量。 可以允许热量从热源转移到地层的选定部分，以在所选择的部分内热解至少一些烃。 可以通过控制混合物的产生从所选择的部分产生所选质量的烃的混合物，以调节至少一些烃暴露于地层中的热解温度的时间。

公开(公告)号：WO0186115A3

公开(公告)日：2002-04-04

申请号：PCT/EP0104644

申请日：2001-04-24

Applicant: SHELL INT RESEARCH ,  SHELL CANADA LTD

Inventor： STEGEMEIER GEORGE LEO ,  WELLINGTON SCOTT LEE ,  ZHANG ETUAN ,  VINEGAR HAROLD J ,  BERCHENKO ILYA EMIL ,  DE ROUFFIGNAC ERIC

IPC: C09K8/592 ,  E21B36/00 ,  E21B36/04 ,  E21B41/00 ,  E21B43/24 ,  E21B43/243 ,  E21B43/247 ,  E21B43/30

CPC classification number: E21B43/24 ,  C09K8/592 ,  E21B36/001 ,  E21B36/04 ,  E21B41/0057 ,  E21B43/2401 ,  E21B43/243 ,  E21B43/247 ,  E21B43/30 ,  Y02C10/14 ,  Y02P20/582 ,  Y10S48/06

Abstract: A method is disclosed for treating a hydrocarbon containing formation in situ and producing a hydrocarbon fluid from the formation, wherein hydrocarbons present in the formation are pyrolysed at an elevated pressure with the application of a pressure/temperature control such that the pressure is at least the pressure which can be calculated for a selected temperature, or the temperature is at most the temperature which can be calculated for a selected pressure from the equation (I) wherein P is pressure (bar absolute), T is temperature ( DEG C), and A and B are predetermined parameters which relate to a property which is relevant to the quantity, the composition or the quality of the hydrocarbon fluids produced. Optionally the method is followed by the step of producing synthesis gas in-situ which step comprises reacting the hydrocarbon containing formation that has been treated with the method according to the invention with a synthesis gas generating fluid. Optionally converted hydrocarbons are produced by converting the synthesis gas so produced into hydrocarbons and/or energy is generated by expanding and/or combusting the synthesis gas so produced or using the synthesis gas so produced in a fuel cell.

Abstract translation: 公开了一种用于在原位处理含烃地层并从地层产生烃流体的方法，其中存在于地层中的烃通过施加压力/温度控制在升高的压力下热解，使得压力至少为 或者温度至多为从式（I）可以计算出的选定压力的温度，其中P是压力（bar绝对压力），T是温度（℃），和 A和B是与所生产的烃类流体的数量，组成或质量相关的性质的预定参数。 任选地，该方法之后是原位生产合成气的步骤，该步骤包括使已经处理的含烃地层与根据本发明的方法与合成气产生流体反应。 通过将所生成的合成气转化为烃来生产任选的转化烃，和/或通过如此生产的合成气或使用在燃料电池中制造的合成气膨胀和/或燃烧而产生能量。

公开(公告)号：WO0181717A3

公开(公告)日：2002-03-21

申请号：PCT/EP0104669

申请日：2001-04-24

Applicant: SHELL INT RESEARCH ,  SHELL CANADA LTD

Inventor： VINEGAR HAROLD J ,  WELLINGTON SCOTT LEE ,  DE ROUFFIGNAC ERIC ,  BERCHENKO ILYA EMIL ,  MAHER KEVIN ALBERT ,  ZHANG ETUAN

IPC: C09K8/592 ,  E21B36/00 ,  E21B36/04 ,  E21B41/00 ,  E21B43/24 ,  E21B43/243 ,  E21B43/247 ,  E21B43/30

CPC classification number: E21B43/24 ,  C09K8/592 ,  E21B36/001 ,  E21B36/04 ,  E21B41/0057 ,  E21B43/2401 ,  E21B43/243 ,  E21B43/247 ,  E21B43/30 ,  Y02C10/14 ,  Y02P20/582 ,  Y10S48/06

Abstract: The present invention provides a method for the production of synthesis gas from a hydrocarbon-containing subterranean formation comprising: providing heat to at least a portion of the subterranean formation such that at least a part of the heated portion reaches the pyrolysis temperature of kerogen, yielding pyrolysis products; collecting pyrolysis products from the subterranean formation; injecting a synthesis gas-generating component into the heated part of the formation, resulting in the production of synthesis gas by reaction of the synthesis gas-generating component with carbonaceous material remaining in the formation; and recovering synthesis gas. The synthesis gas thus produced can be used for Fischer-Tropsch synthesis, manufacture of ammonia, urea, methanol, methane and other hydrocarbons, or used as energy source, e.g. in fuel cells. Carbon dioxide produced in such use of the synthesis gas can be sequestered in the formation.

Abstract translation: 本发明提供了一种从含烃地层中生产合成气的方法，包括：向地层的至少一部分提供热量，使得至少一部分加热部分达到干酪根的热解温度，产生 热解产物; 从地层收集热解产物; 将合成气产生组分注入地层的加热部分，通过合成气产生组分与残留在地层中的含碳材料反应产生合成气; 并回收合成气。 如此生产的合成气可用于费 - 托合成，氨，尿素，甲醇，甲烷和其他烃的制备，或用作能量源，例如。 在燃料电池中。 在这种使用合成气中产生的二氧化碳可以隔离在地层中。

公开(公告)号：WO0183940A9

公开(公告)日：2003-05-22

申请号：PCT/EP0104657

申请日：2001-04-24

Applicant: SHELL INT RESEARCH ,  SHELL CANADA LTD

Inventor： DE ROUFFIGNAC ERIC ,  WELLINGTON SCOTT LEE ,  VINEGAR HAROLD J ,  KARANIKAS JOHN MICHAEL ,  KEEDY CHARLES ROBERT

IPC: C09K8/592 ,  E21B36/00 ,  E21B36/04 ,  E21B41/00 ,  E21B43/24 ,  E21B43/243 ,  E21B43/30

CPC classification number: E21B36/04 ,  C09K8/592 ,  E21B36/001 ,  E21B41/0057 ,  E21B43/24 ,  E21B43/2401 ,  E21B43/243 ,  E21B43/30

Abstract: A system for heating an underground hydrocarbon containing formation, such as a coal or shale-oil deposit, comprises an elongate electrical conductor within a heater well traversing the formation to provide radiant heat to at least a portion of the formation during use such that pyrolysis of hydrocarbons is initiated, which conductor is at least partly surrounded by an electrical insulation layer which comprises a granular insulating mineral material which layer is encased in a corrosion resistant sheath, thereby providing an inexpensive and durable electrical heater.

Abstract translation: 用于加热地下含烃地层（例如煤或页岩油沉积物）的系统包括穿过地层的加热井内的细长电导体，以在使用期间向地层的至少一部分提供辐射热，使得热解 引发烃，该导体至少部分地被电绝缘层包围，该电绝缘层包括颗粒绝缘矿物材料，该层被包裹在耐腐蚀的护套中，由此提供廉价且耐用的电加热器。

公开(公告)号：WO0183940A8

公开(公告)日：2001-12-20

申请号：PCT/EP0104657

申请日：2001-04-24

Applicant: SHELL INT RESEARCH ,  SHELL CANADA LTD

Inventor： DE ROUFFIGNAC ERIC ,  WELLINGTON SCOTT LEE ,  VINEGAR HAROLD J ,  KARANIKAS JOHN MICHAEL ,  KEEDY CHARLES ROBERT

IPC: C09K8/592 ,  E21B36/00 ,  E21B36/04 ,  E21B41/00 ,  E21B43/24 ,  E21B43/243 ,  E21B43/30

CPC classification number: E21B36/04 ,  C09K8/592 ,  E21B36/001 ,  E21B41/0057 ,  E21B43/24 ,  E21B43/2401 ,  E21B43/243 ,  E21B43/30

Abstract: A system for heating an underground hydrocarbon containing formation, such as a coal or shale-oil deposit, comprises an elongate electrical conductor within a heater well traversing the formation to provide radiant heat to at least a portion of the formation during use such that pyrolysis of hydrocarbons is initiated, which conductor is at least partly surrounded by an electrical insulation layer which comprises a granular insulating mineral material which layer is encased in a corrosion resistant sheath, thereby providing an inexpensive and durable electrical heater.

Abstract translation: 用于加热地下含烃地层（例如煤或页岩油沉积物）的系统包括穿过地层的加热井内的细长电导体，以在使用期间向地层的至少一部分提供辐射热，使得热解 引发烃，该导体至少部分地被电绝缘层包围，该电绝缘层包括颗粒绝缘矿物材料，该层被包裹在耐腐蚀的护套中，由此提供廉价且耐用的电加热器。

公开(公告)号：WO0181715A3

公开(公告)日：2002-04-25

申请号：PCT/EP0104641

申请日：2001-04-24

Applicant: SHELL INT RESEARCH ,  SHELL CANADA LTD

Inventor： BERCHENKO ILYA EMIL ,  HARDEVELD VAN ROBERT MARTIJN ,  KARANIKAS JOHN MICHAEL ,  KEEDY CHARLES ROBERT ,  MAHER KEVIN ALBERT ,  ROUFFIGNAC DE ERIC ,  RYAN ROBERT CHARLES ,  SCHOELING LANNY GENE ,  SHAHIN GORDON THOMAS ,  STEGEMEIER GEORGE LEO ,  VINEGAR HAROLD J ,  WELLINGTON SCOTT LEE ,  ZHANG ETUAN ,  COLES JOHN MATTHEW ,  FOWLER THOMAS DAVID ,  MADGAVKAR AJAY MADHAV ,  MENOTTI JAMES LOUIS ,  HUNSUCKER BRUCE GERARD ,  BIELAMOWICZ LAWRENCE JAMES

IPC: C09K8/592 ,  E21B36/00 ,  E21B36/04 ,  E21B41/00 ,  E21B43/24 ,  E21B43/243 ,  E21B43/247 ,  E21B43/30

CPC classification number: E21B43/24 ,  C09K8/592 ,  E21B36/001 ,  E21B36/04 ,  E21B41/0057 ,  E21B43/2401 ,  E21B43/243 ,  E21B43/247 ,  E21B43/30 ,  Y02C10/14 ,  Y02P20/582 ,  Y10S48/06

Abstract: A method is disclosed for treating a hydrocarbon containing formation in situ and producing a hydrocarbon fluid from the formation, which method comprises pyrolysing hydrocarbons present in the formation during the production of the hydrocarbon fluid from the formation with the application of a pressure/temperature control such that the pressure is at least the pressure which can be calculated for a selected temperature, or the temperature is at most the temperature which can be calculated for a selected pressure from the equation (I) wherein P is pressure (bar absolute), T is temperature (°C), and A and B are predetermined parameters which relate to a property which is relevant to the quantity, the composition or the quality of the hydrocarbon fluids produced. Optionally, the method is followed by the step of in-situ producing synthesis gas, which step comprises providing a partly depleted hydrocarbon containing formation which is treated according to the said method for treating a hydrocarbon containing formation in-situ, and reacting the hydrocarbon containing formation with a synthesis gas generating fluid. Optionally the synthesis gas so produced is converted into hydrocarbons; and/or energy is generated by expanding and/or combusting the synthesis gas so produced or using the synthesis gas so produced in a fuel cell.

公开(公告)号：WO02070402A3

公开(公告)日：2002-11-28

申请号：PCT/EP0202367

申请日：2002-03-04

Applicant: SHELL INT RESEARCH ,  SHELL CANADA LTD

Inventor： MATZAKOS ANDREAS NIKOLAOS ,  MIKUS THOMAS ,  WARD JOHN MICHAEL ,  WELLINGTON SCOTT LEE

IPC: B01D53/22 ,  B01D69/10 ,  B01D71/02 ,  B01J8/00 ,  B01J8/02 ,  B01J8/06 ,  B01J19/24 ,  B01J23/755 ,  B01J35/06 ,  C01B3/32 ,  C01B3/38 ,  C01B3/48 ,  C01B3/50 ,  C01B3/56 ,  C01B32/50 ,  H01M8/06 ,  C01B31/20

CPC classification number: B01D53/22 ,  B01D63/062 ,  B01D2313/38 ,  B01D2313/42 ,  B01J8/009 ,  B01J8/0214 ,  B01J8/0257 ,  B01J8/0278 ,  B01J8/0285 ,  B01J8/062 ,  B01J19/2475 ,  B01J23/755 ,  B01J35/065 ,  B01J2208/00212 ,  B01J2208/00309 ,  B01J2208/00495 ,  B01J2208/00504 ,  B01J2208/0053 ,  B01J2219/00006 ,  C01B3/323 ,  C01B3/384 ,  C01B3/48 ,  C01B3/501 ,  C01B32/50 ,  C01B2203/0227 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/041 ,  C01B2203/0445 ,  C01B2203/047 ,  C01B2203/06 ,  C01B2203/065 ,  C01B2203/066 ,  C01B2203/068 ,  C01B2203/0805 ,  C01B2203/0811 ,  C01B2203/0838 ,  C01B2203/0866 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1082 ,  C01B2203/1205 ,  C01B2203/1211 ,  C01B2203/1264 ,  C01B2203/84 ,  C01B2203/86 ,  H01M8/0612 ,  H01M8/0631 ,  H01M8/0662 ,  H01M2300/0051 ,  Y02C10/10 ,  Y02E60/526 ,  Y02P20/126 ,  Y02P20/129 ,  Y02P20/152 ,  Y02P20/52 ,  Y02P30/30

Abstract: Disclosed is a new process and apparatus for steam reforming of any vaporizable hydrocarbon to produce H2 and CO2, with minimal CO, and no CO in the H2 stream, using a membrane steam reforming (MSR) reactor and flame-less distributed combustion (FDC) which provides great improvements in heat exchange efficiency and load following capabilities to drive the steam reforming reaction. The invention also pertains to a zero emission hybrid power system wherein the produced hydrogen is used to power a high-pressure internally manifolded molten carbonate fuel cell. In addition, the design of the FDC-MSR powered fuel cell makes it possible to capture good concentrations of CO2 for sequestration or use in other processes.

Abstract translation: 公开了一种用于使用膜蒸汽重整（MSR）反应器和无焰分布燃烧（FDC））的任何可汽化烃的蒸汽重整以产生H 2和CO 2，具有最小CO并且在H 2流中不含CO的新方法和装置， 这提供了热交换效率和负载跟随能力以驱动蒸汽重整反应的巨大改进。 本发明还涉及一种零排放混合动力系统，其中所产生的氢气用于为高压内部歧管的熔融碳酸盐燃料电池供电。 此外，FDC-MSR动力燃料电池的设计使得可以捕获良好的二氧化碳浓度以进行封存或用于其他工艺。

公开(公告)号：WO0181716A3

公开(公告)日：2002-03-28

申请号：PCT/EP0104666

申请日：2001-04-24

Applicant: SHELL INT RESEARCH ,  SHELL CANADA LTD

Inventor： VINEGAR HAROLD J ,  WELLINGTON SCOTT LEE ,  BERCHENKO ILYA EMIL ,  MAHER KEVIN ALBERT ,  DE ROUFFIGNAC ERIC ,  BAXLEY PHILLIP TEMMONS ,  ZHANG ETUAN ,  KARANIKAS JOHN MICHAEL

IPC: C09K8/592 ,  E21B36/00 ,  E21B36/04 ,  E21B41/00 ,  E21B43/24 ,  E21B43/243 ,  E21B43/247 ,  E21B43/30

CPC classification number: E21B43/24 ,  C09K8/592 ,  E21B36/001 ,  E21B36/04 ,  E21B41/0057 ,  E21B43/2401 ,  E21B43/243 ,  E21B43/247 ,  E21B43/30 ,  Y02C10/14 ,  Y02P20/582 ,  Y10S48/06

Abstract: A method for sequestering a fluid is disclosed, which method comprises sequestering the fluid within a portion of an in-situ heat treated hydrocarbon containing formation, such as a coal seam in which hydrocarbons have been pyrolysed, of which at least a portion has preferably a permeability of at least 100 millidarcy.

Abstract translation: 公开了一种隔离流体的方法，该方法包括在原位热处理的含烃地层的一部分内封闭流体，例如其中已经热解烃的煤层，其中至少一部分优选具有 渗透率至少为100毫达西。

公开(公告)号：WO2011091206A3

公开(公告)日：2012-08-09

申请号：PCT/US2011021972

申请日：2011-01-21

Applicant: SHELL OIL CO ,  SHELL INT RESEARCH ,  MILAM STANLEY NEMEC ,  REYNOLDS MICHAEL ANTHONY ,  WELLINGTON SCOTT LEE

Inventor： MILAM STANLEY NEMEC ,  REYNOLDS MICHAEL ANTHONY ,  WELLINGTON SCOTT LEE

IPC: C10G47/00 ,  C10G47/02 ,  C10G47/06 ,  C10L1/04

CPC classification number: C10L1/04 ,  C10G47/00 ,  C10G47/02 ,  C10G47/06 ,  C10G2300/301 ,  C10G2400/30

Abstract: A hydrocarbon composition is provided containing: at least 5 wt.% of hydrocarbons having boiling point in the range from an initial boiling point of the composition up to 204°C; at least 10 wt.% of hydrocarbons having a boiling point in the range from 204°C up to 260°C; at least 25 wt.% of hydrocarbons having a boiling point in the range from 260°C up to 343°C; at least 30 wt.% gram of hydrocarbons having a boiling point in the range from 343°C to 538°C; and at most 3 wt.% of hydrocarbons having a boiling point of greater than 538°C; wherein the composition contains aromatic hydrocarbons including mono-aromatic hydrocarbons, di-aromatic hydrocarbons, and polyaromatic hydrocarbons, where the combined mono-aromatic hydrocarbon compounds and di-aromatic hydrocarbon compounds are present in a weight ratio relative to the polyaromatic hydrocarbon compounds of at least 1.5 : 1.0.

Abstract translation: 提供了一种烃组合物，其含有：至少5重量％的沸点在组合物的初始沸点至204℃范围内的烃; 至少10重量％的沸点在204℃至260℃范围内的烃; 至少25重量％的沸点在260℃至343℃范围内的烃; 至少30重量％的沸点在343℃至538℃范围内的烃; 和至多3重量％的沸点大于538℃的烃; 其中所述组合物包含芳族烃，包括单芳族烃，二芳族烃和多芳族烃，其中组合的单芳族烃化合物和二芳族烃化合物以至少相对于多芳族烃化合物的重量比存在 1.5：1.0。

公开(公告)号：WO2011091201A3

公开(公告)日：2012-04-19

申请号：PCT/US2011021966

申请日：2011-01-21

Applicant: SHELL OIL CO ,  SHELL INT RESEARCH ,  MILAM STANLEY NEMEC ,  REYNOLDS MICHAEL ANTHONY ,  WELLINGTON SCOTT LEE

Inventor： MILAM STANLEY NEMEC ,  REYNOLDS MICHAEL ANTHONY ,  WELLINGTON SCOTT LEE

IPC: C10G47/06 ,  B01J27/02 ,  B01J27/04 ,  B01J27/047 ,  B01J27/051 ,  B01J27/057 ,  B01J35/02 ,  C01G3/12 ,  C01G39/06 ,  C10G47/26

CPC classification number: C10G47/06 ,  B01J27/04 ,  B01J27/047 ,  B01J27/051 ,  B01J35/002 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/031 ,  B82Y30/00 ,  C01G39/006 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C10G47/26 ,  C10G2300/202 ,  C10G2300/206 ,  C10G2300/207 ,  C10G2300/301 ,  C10G2300/4006 ,  C10G2300/4012

Abstract: A process for treating a hydrocarbon-containing feed is provided in which a hydrocarbon-containing feed comprising at least 20 wt.% of heavy hydrocarbons is mixed with hydrogen, hydrogen sulfide, and a catalyst to produce a hydrocarbon-containing product, where hydrogen sulfide is provided at a mole ratio relative to hydrogen of at least 0.5:9.5. The catalyst is comprised of a material comprised of a first metal and a second metal, where the first metal is selected from the group consisting of Cu, Fe, Ni, Co, Bi, Ag, Mn, Zn, Sn, Ru, La, Ce, Pr, Sm, Eu, Yb, Lu, Dy, Pb, and Sb and the second metal is Mo, W, V, Sn, and Sb. The material of the catalyst may have a structure according to formula (I), formula (II), formula (III), or formula (IV): where M is either the first metal or the second metal, and at least one M is the first metal and at least one M is the second metal; where M is either the first metal or the second metal, and at least one M is the first metal and at least one M is the second metal, and X is selected from the group consisting of SO4, PO4, oxalate (C2O4), acetylacetonate, acetate, citrate, tartrate, Cl, Br, I, ClO4, and NO3; where M is either the first metal or the second metal, and at least one M is the first metal and at least one M is the second metal, and X is selected from the group consisting of SO4, PO4, oxalate (C2O4), acetylacetonate, acetate, citrate, tartrate, Cl, Br, I, ClO4, and NO3; where M is either the first metal or the second metal, and at least one M is the first metal and at least one M is the second metal, and X is selected from the group consisting of SO4, PO4, oxalate (C2O4), acetylacetonate, acetate, citrate, tartrate, Cl, Br, I, ClO4, and NO3.

Abstract translation: 提供了一种处理含烃进料的方法，其中将包含至少20重量％重烃的含烃进料与氢气，硫化氢和催化剂混合以产生含烃产物，其中硫化氢 以相对于氢的摩尔比提供至少0.5:9.5。 催化剂由包含第一金属和第二金属的材料组成，其中第一金属选自Cu，Fe，Ni，Co，Bi，Ag，Mn，Zn，Sn，Ru，La， Ce，Pr，Sm，Eu，Yb，Lu，Dy，Pb和Sb，第二金属是Mo，W，V，Sn和Sb。 催化剂的材料可以具有根据式（I），式（II），式（III）或式（IV）的结构：其中M是第一种金属或第二种金属，至少一种M是 第一金属和至少一个M是第二金属; 其中M是第一金属或第二金属，并且至少一个M是第一金属，并且至少一个M是第二金属，X选自SO 4，PO 4，草酸盐（C 2 O 4），乙酰丙酮化物 ，乙酸盐，柠檬酸盐，酒石酸盐，Cl，Br，I，ClO4和NO3; 其中M是第一金属或第二金属，并且至少一个M是第一金属，并且至少一个M是第二金属，X选自SO 4，PO 4，草酸盐（C 2 O 4），乙酰丙酮化物 ，乙酸盐，柠檬酸盐，酒石酸盐，Cl，Br，I，ClO4和NO3; 其中M是第一金属或第二金属，并且至少一个M是第一金属，并且至少一个M是第二金属，X选自SO 4，PO 4，草酸盐（C 2 O 4），乙酰丙酮化物 ，乙酸盐，柠檬酸盐，酒石酸盐，Cl，Br，I，ClO4和NO3。