Abstract:
La présente invention concerne une membrane de filtration de gaz moléculaires tels que l'hydrogène, comprenant un support poreux céramique constitué essentiellement de spinelle alumino-magnésique, ledit support étant imprégné d'une couche de xerogel à base de silice. L'invention a également pour objet un procédé de préparation d'une telle membrane. L'invention concerne également l'utilisation d'un support constitué essentiellement de spinelle alumino-magnésique dans une membrane de filtration de l'hydrogène.
Abstract:
The invention relates to a process for making SAPO-34 membranes with less than 2 micron thickness and good H2 selectivity, and the use of these membranes as hb-selective zeolite membranes in the PDH process.
Abstract:
The invention is directed to a method for improving the filtration efficiency of an altered substrate filter element comprising a porous solid substrate, one side of which is impregnated with sintered solid particles, by treating the solids-oxide-impregnated side with an aqueous suspension of small non-agglomerated solid particles which are deposited upon the sintered solid particles.
Abstract:
A process for preparing a porous amorphous silica-alumina refractory oxide is described in which a source of silica, such as tetra ethyl ortho silicate, in a non-aqueous solvent, such as an alcohol, is hydrolysed by adding an aqueous solution containing aluminium ions, in particular a solution of aluminium nitrate, thereby to form a sol and calcining the sol at, for example, 200 °C to 600 °C. The product, which may have a microporous or mesoporous structure, is useful in the separation of fluids, especially the separation of carbon dioxide from natural gas.
Abstract:
A hand-carry gravity-driven water filter with high throughput and water disinfection performance is formed. Membranes used for this water filter can be fabricated using electrospun method and non-solvent induced phase inversion method. A novel composite membrane structure (interwoven composite structure) was designed for further enhances water permeability and mechanical strength. The composite membrane can be composed of nanofibers with different diameter from the same polymer or different polymers. Membrane porosity and surface pore size can be controlled. Silver nanoparticles can be in-situ loaded on the surface of the membranes. The developed filter is effective for removal of a wide range of contaminants (e.g., pathogens, suspended solids and heavy metals). The purification process can be carried out under the drive of gravity (with an option for mechanically-enhanced filtration) without electricity.
Abstract:
A method including contacting a support with a composition including an aluminum, silicon, phosphorous (SAPO) gel and/or an aluminophosphate (AlPO) gel; heating the support and the composition; and forming SAPO and/or AlPO crystals from the composition on the support; and after forming the crystals, modifying the contact between the support and the composition within a time to inhibit solubilization of a portion of the crystals. A method including seeding a support with an amount of uncalcined silicoaluminophosphate (SAPO) and/or aluminophosphate (AlPO) molecular sieve crystals;after seeding the support, contacting the support with a composition including a SAPO or AlPO gel; and heating the support and the composition to form SAPO and/or AlPO molecular sieve crystals from the gel on the support.
Abstract:
Hybrid membranes based on crystalline titanium dioxide containing fluorine atoms within the crystalline lattice comprising atoms of titanium and oxygen are described; these hybrid membranes are particularly suitable for the production of fuel cells and electrolysers. The titanium dioxide contained in them may be produced by a process comprising the following stages: (a) a titanium ore is reacted with a NH 4 HF 2 aqueous solution of; (b) the aqueous dispersion so obtained is filtered with subsequent separation of a solid residue and an aqueous solution containing titanium salts; (c) the aqueous solution so obtained is subjected to hydrolysis, said hydrolysis comprising a first stage at pH 6.5-8.0 and a second stage at pH 9-11; (d) the aqueous dispersion thus obtained is filtered and the solid residue is subjected to pyrohydrolysis at a maximum temperature of approximately 500°C, preferably approximately 450°C.
Abstract:
The present invention relates to composite ceramic membranes for use in chemical processes such as the separation of molecules, sometimes referred to as molecular sieving, preferably in combination with chemical conversion of molecules selected from a composition of different molecules, e.g. the selective partial or full oxidation. The composite membrane of the invention offers a combination of molecular sieving and oxygen transport that makes the composite membrane suitable for the selective oxidation of hydrocarbons from a feed comprising a mixture hydrocarbons. The composite membrane of the invention comprises a first layer containing an oxygen transporting material (OTM), e.g. perovskite, and, in association with the first layer, a second layer, containing a molecular sieve layer, e.g. a zeolite.