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    PROCESS FOR THE PREPARATION OF ZIRCONIUM BASED MOFS.
    1.
    发明申请
    PROCESS FOR THE PREPARATION OF ZIRCONIUM BASED MOFS. 审中-公开
    制备锆基MOFS的方法。

    公开(公告)号：WO2018046930A1

    公开(公告)日：2018-03-15

    申请号：PCT/GB2017/052620

    申请日：2017-09-07

    Applicant: UNIVERSITETET I OSLO ,  GOLDING, Louise

    Inventor： LILLERUD, Karl Petter ,  OLSBYE, Unni ,  CHAVAN, Sachin

    IPC: C07F7/00

    CPC classification number: C07F7/003

    Abstract: There is provided a process for preparing a zirconium-based metal organic framework (Zr-MOF), comprising the steps: (i) mixing a Zr-MOF having fcu topology with aqueous solvent, wherein said Zr-MOF comprises n linkers L1 and 12-n linkers L2; (ii) isolating a Zr-MOF having bcu topology from the mixture in step (i), wherein said Zr-MOF having bcu topology comprises n-4 linkers L1 and 12-n linkers L2; and (iii) preparing a reaction mixture comprising the Zr-MOF having bcu topology and either linker L2 or linker L3 in a solvent; wherein linkers L1, L2 and L3 are a first, second and third linker which are all different and n is 4, 8 or 12. There is further provided a process for the preparation of a Zr-MOF having fcu topology comprising the steps: (i) mixing a Zr-MOF having bcu topology with an alkali metal salt in a solvent, wherein said Zr-MOF comprises 8 linkers L1 and at least one charge balancing anion coordinated to the Zr cluster; (ii) isolating a Zr- MOF having bcu topology from the mixture in step (i), wherein said Zr-MOF having bcu topology does not comprise any charge balancing anions coordinated to the Zr cluster; and (iii) preparing a reaction mixture comprising the Zr-MOF having bcu topology from step (ii) and either linker L1 or linker L2 in a solvent; wherein linkers L1 and L2 are a first and second linker which are different.

    Abstract translation: 提供了用于制备锆基金属有机骨架（Zr-MOF）的方法，其包括以下步骤：（i）将具有fcu拓扑的Zr-MOF与水性溶剂混合，其中所述Zr -MOF包含n个连接子L1和12-n连接子L2; （ii）从步骤（i）中的混合物分离具有bcu拓扑结构的Zr-MOF，其中所述具有bcu拓扑结构的Zr-MOF包含n-4个连接子L1和12-n连接子L2; 和（iii）在溶剂中制备包含具有bcu拓扑结构和连接体L2或连接体L3的Zr-MOF的反应混合物; 其中接头L1，L2和L3是全都不同的第一，第二和第三接头，n是4,8或12.还提供了制备具有fcu拓扑的Zr-MOF的方法，其包括以下步骤:( i）将具有bcu拓扑结构的Zr-MOF与碱金属盐在溶剂中混合，其中所述Zr-MOF包含8个连接基团L1和至少一个与Zr团簇配位的电荷平衡阴离子; （ii）从步骤（i）中的混合物分离具有bcu拓扑的Zr-MOF，其中所述具有bcu拓扑的Zr-MOF不包含与Zr簇配位的任何电荷平衡阴离子; 和（iii）制备反应混合物，所述反应混合物包含来自步骤（ii）的具有bcu拓扑结构的Zr-MOF以及连接基L1或连接基L2在溶剂中; 其中接头L1和L2是不同的第一和第二接头。

    SYSTEM AND METHOD FOR GENERATING A PURIFIED CATALYST
    3.
    发明申请
    SYSTEM AND METHOD FOR GENERATING A PURIFIED CATALYST 审中-公开
    用于生成纯化催化剂的系统和方法

    公开(公告)号：WO2014141050A1

    公开(公告)日：2014-09-18

    申请号：PCT/IB2014/059598

    申请日：2014-03-10

    Applicant: SAUDI BASIC INDUSTRIES CORPORATION

    Inventor： AZAM, Shahid ,  SCHMIDT, Roland ,  AL-HAZMI, Mohammed

    IPC: B01J31/02

    CPC classification number: B01J31/0212 ,  B01J19/24 ,  B01J31/0209 ,  B01J2219/00076 ,  B01J2219/00081 ,  B01J2219/00083 ,  B01J2219/24 ,  C07F7/003 ,  C07F7/28

    Abstract: Methods for generating a purified catalyst are provided. The method includes performing a reaction in a reaction vessel to generate a liquid catalyst and reaction products, purging the reaction products using an inert gas to form a purged catalyst, freezing the purged catalyst in the reaction vessel, and applying a vacuum to the reaction vessel while the purged catalyst thaws, wherein the vacuum removes residual reaction products to form a purified catalyst. Systems for generating a purified catalyst and a purified catalyst are also provided.

    Abstract translation: 提供了产生纯化催化剂的方法。 该方法包括在反应容器中进行反应以产生液体催化剂和反应产物，使用惰性气体吹扫反应产物以形成净化的催化剂，将反应容器中的净化的催化剂冷冻，并向反应容器中施加真空 同时净化的催化剂解冻，其中真空除去残留的反应产物以形成纯化的催化剂。 还提供了用于产生纯化催化剂和纯化催化剂的系统。

    CYCLIC METAL AMIDES AND VAPOR DEPOSITION USING THEM
    6.
    发明申请
    CYCLIC METAL AMIDES AND VAPOR DEPOSITION USING THEM 审中-公开
    循环金属粉末和蒸气沉积使用它们

    公开(公告)号：WO2011123675A1

    公开(公告)日：2011-10-06

    申请号：PCT/US2011/030771

    申请日：2011-03-31

    Applicant: PRESIDENT AND FELLOWS OF HARVARD COLLEGE ,  GORDON, Roy Gerald ,  HOCK, Adam S. ,  HEO, Jaeyeong ,  SINSERMSUKSAKUL, Prasert

    Inventor： GORDON, Roy Gerald ,  HOCK, Adam S. ,  HEO, Jaeyeong ,  SINSERMSUKSAKUL, Prasert

    IPC: C07C211/09 ,  C07F7/22 ,  C07F7/24 ,  C23C16/30

    CPC classification number: C07F7/003 ,  C23C16/18 ,  C23C16/305 ,  C23C16/407 ,  C23C16/45553

    Abstract: Novel cyclic amides containing tin or lead are disclosed. These cyclic amides can be used for atomic layer deposition or chemical vapor deposition of tin or lead as well as their oxides, sulfides, selenides, nitrides, phosphides, carbides, silicides or borides or other compounds. Tin(TV) oxide, SnO 2 , films were deposited by reaction of a cyclic tin amide/vapor and H 2 O 2 or NO 2 as oxygen sources. The films have high purity, smoothness, transparency, electrical conductivity, density, and uniform thickness even inside very narrow holes or trenches. Deposition temperatures are low enough for thermally sensitive substrates such as plastics. Suitable applications of these films include displays, light-emitting diodes, solar cells and gas sensors. Doping SnO 2 with aluminum was used to reduce its conductivity, making material suitable as the active semiconductor layer in electron multipliers or transparent transistors. Deposition Using the same tin precursor and H 2 S deposited tin monosulfide, SnS, a material suitable for solar cells. The figure shows the preferred tin compound.

    Abstract translation: 公开了含有锡或铅的新型环状酰胺。 这些环状酰胺可用于锡或铅及其氧化物，硫化物，硒化物，氮化物，磷化物，碳化物，硅化物或硼化物或其它化合物的原子层沉积或化学气相沉积。 通过环状锡酰胺/蒸气和H 2 O 2或NO 2作为氧源的反应沉积氧化锡（TV），SnO 2，膜。 即使在非常狭窄的孔或沟槽内，这些膜也具有高纯度，平滑度，透明度，导电性，密度和均匀的厚度。 沉积温度对于热敏基材如塑料来说足够低。 这些膜的合适应用包括显示器，发光二极管，太阳能电池和气体传感器。 使用铝掺杂SnO2以降低其导电性，使得材料适合作为电子倍增器或透明晶体管中的有源半导体层。 沉积使用相同的锡前体和H2S沉积锡一硫化物SnS，适合太阳能电池的材料。 该图显示了优选的锡化合物。

    BIREFRINGENT METAL-CONTAINING COORDINATION POLYMERS
    9.
    发明申请
    BIREFRINGENT METAL-CONTAINING COORDINATION POLYMERS 审中-公开
    双金属含量协调聚合物

    公开(公告)号：WO2007090295A1

    公开(公告)日：2007-08-16

    申请号：PCT/CA2007/000216

    申请日：2007-02-09

    Applicant: SIMON FRASER UNIVERSITY ,  LEZNOFF, Daniel Bernard ,  KATZ, Michael Iacov

    Inventor： LEZNOFF, Daniel Bernard ,  KATZ, Michael Iacov

    IPC: C07F1/12 ,  C07F1/10 ,  C07F13/00 ,  C07F3/06 ,  C07F7/24 ,  C07F9/94 ,  C09K11/06 ,  G02B1/04 ,  G02F1/13363

    CPC classification number: C07F7/003 ,  C07F1/005 ,  C07F11/005 ,  C08G79/00 ,  C08L65/00 ,  C08L79/04

    Abstract: This application relates to metal-containing coordination polymers having high birefringent values. For example, polymers having birefringent values within the range of 0.07 to 0.45 are described. The polymers may comprise units having the formula M(L) X [M'(Z) Y ] N , wherein M and M' are the same or different metals capable of forming a coordinate complex with the Z moiety; L is a ligand; Z is selected from the group consisting of halides, pseudohalides, thiolates, alkoxides and amides; X is between 0 - 12; Y is between 2 - 9; and N is between 1 - 5. In particular embodiments of the invention L may be a highly anisotropic organic ligand, such as terpyridine, and Z may be a pseudohalide, such as CN. The invention also includes methods for synthesizing the coordination polymers and use of the polymers in birefringent materials and devices. In one embodiment the polymers may be processible into thin films.

    Abstract translation: 本申请涉及具有高双折射值的含金属配位聚合物。 例如，描述了双折射值在0.07至0.45范围内的聚合物。 聚合物可以包含具有式M（L）的单元X [M'（Z）Y] N N，其中M和M'是 能够与Z部分形成配位络合物的相同或不同的金属; L是配体; Z选自卤化物，拟卤化物，硫醇盐，醇盐和酰胺; X在0-12之间; Y在2到9之间; 并且N在1-5之间。在本发明的特定实施方案中，L可以是高度各向异性的有机配体，例如三联吡啶，Z可以是拟卤化物，例如CN。 本发明还包括用于合成配位聚合物的方法和聚合物在双折射材料和装置中的应用。 在一个实施方案中，聚合物可以加工成薄膜。

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