公开(公告)号：WO2014141050A1

公开(公告)日：2014-09-18

申请号：PCT/IB2014/059598

申请日：2014-03-10

Applicant: SAUDI BASIC INDUSTRIES CORPORATION

Inventor： AZAM, Shahid ,  SCHMIDT, Roland ,  AL-HAZMI, Mohammed

IPC: B01J31/02

CPC classification number: B01J31/0212 ,  B01J19/24 ,  B01J31/0209 ,  B01J2219/00076 ,  B01J2219/00081 ,  B01J2219/00083 ,  B01J2219/24 ,  C07F7/003 ,  C07F7/28

Abstract: Methods for generating a purified catalyst are provided. The method includes performing a reaction in a reaction vessel to generate a liquid catalyst and reaction products, purging the reaction products using an inert gas to form a purged catalyst, freezing the purged catalyst in the reaction vessel, and applying a vacuum to the reaction vessel while the purged catalyst thaws, wherein the vacuum removes residual reaction products to form a purified catalyst. Systems for generating a purified catalyst and a purified catalyst are also provided.

Abstract translation: 提供了产生纯化催化剂的方法。 该方法包括在反应容器中进行反应以产生液体催化剂和反应产物，使用惰性气体吹扫反应产物以形成净化的催化剂，将反应容器中的净化的催化剂冷冻，并向反应容器中施加真空 同时净化的催化剂解冻，其中真空除去残留的反应产物以形成纯化的催化剂。 还提供了用于产生纯化催化剂和纯化催化剂的系统。

公开(公告)号：WO2009074203A1

公开(公告)日：2009-06-18

申请号：PCT/EP2008/009585

申请日：2008-11-13

Applicant: LINDE AG ,  SAUDI BASIC INDUSTRIES CORPORATION ,  ALIYEV, Vugar ,  MOSA, Fuad ,  AL-HAZMI, Mohammed

Inventor： ALIYEV, Vugar ,  MOSA, Fuad ,  AL-HAZMI, Mohammed

IPC: B01J31/04 ,  B01J31/12 ,  B01J31/14 ,  C07C2/20

CPC classification number: B01J31/04 ,  B01J31/128 ,  B01J31/143 ,  B01J2231/20 ,  C07C2/30 ,  C07C2531/04 ,  C07C2531/14 ,  Y02P20/52

Abstract: Catalyst composition for the oligomerization of ethylene, comprising (i) an at least partially hydrolyzed transition metal compound, obtainable by controlled addition of water to a transition metal compound having the general formula MX m (OR') 4-m or MX m (OOCR') 4-m , wherein R' is an alkyl, alkenyl, aryl, aralkyl or cycloalkyl group, X is halogen, preferably Cl or Br, and m is from 0 to 4; preferably 0-3; and (ii) an organoaluminum compound as a cocatalyst, wherein the molar ratio of water and transition metal compound is within a range of between about (0.01-3): 1; a process for oligomerization of ethylene and a method for preparing the catalyst composition.

Abstract translation: 用于乙烯低聚的催化剂组合物，其包含（i）至少部分水解的过渡金属化合物，其可通过将具有通式MX m（OR'）4-m或MX m（OOCR'）的过渡金属化合物控制加入而获得， 4-m，其中R'是烷基，烯基，芳基，芳烷基或环烷基，X是卤素，优选Cl或Br，m是0-4; 优选0-3; 和（ii）作为助催化剂的有机铝化合物，其中水和过渡金属化合物的摩尔比在约（0.01-3）：1之间的范围内; 乙烯低聚方法和制备催化剂组合物的方法。

公开(公告)号：WO2011009509A1

公开(公告)日：2011-01-27

申请号：PCT/EP2010/003285

申请日：2010-05-28

Applicant: LINDE AG ,  SAUDI BASIC INDUSTRIES CORPORATION ,  FRITZ, Peter, M. ,  BÖLT, Heinz ,  MEISWINKEL, Andreas ,  TAUBE, Carsten ,  WINKLER, Florian ,  GÖKE, Volker ,  MÜLLER, Wolfgang ,  WÖHL, Anina ,  SCHNEIDER, Richard ,  ROSENTHAL, Uwe ,  FRITZ, Helmut ,  MÜLLER, Bernd, H. ,  PEULECKE, Normen ,  PEITZ, Stephan ,  ALURI, Bhaskar, Reddy ,  AL-HAZMI, Mohammed ,  AZAM, Shahid, Majeed ,  MOSA, Fuad ,  AL-DUGATHIER, Abdellah

Inventor： FRITZ, Peter, M. ,  BÖLT, Heinz ,  MEISWINKEL, Andreas ,  TAUBE, Carsten ,  WINKLER, Florian ,  GÖKE, Volker ,  MÜLLER, Wolfgang ,  WÖHL, Anina ,  SCHNEIDER, Richard ,  ROSENTHAL, Uwe ,  FRITZ, Helmut ,  MÜLLER, Bernd, H. ,  PEULECKE, Normen ,  PEITZ, Stephan ,  ALURI, Bhaskar, Reddy ,  AL-HAZMI, Mohammed ,  AZAM, Shahid, Majeed ,  MOSA, Fuad ,  AL-DUGATHIER, Abdellah

IPC: C07C2/30 ,  C07C11/02

CPC classification number: C07C2/30 ,  C07C2531/025 ,  C07C2531/04 ,  C07C2531/14 ,  C07C11/02

Abstract: The present invention relates to a method for preparing linear alpha-olefins (LAO) by oligomerization of ethylene in the presence of a solvent and homogeneous catalyst, comprising the steps of: (i) feeding ethylene, solvent and catalyst into an oligomerization reactor, (ii) oligomerizing the ethylene in the reactor, (iii) removing a reactor outlet stream comprising solvent, linear alpha-olefins, optionally unreacted ethylene and catalyst from the reactor via a reactor outlet piping system, (iv) dosing at least one additive selected from the group consisting of alcohols, polyethylene glycols, polyethylene glycol monoethers, polyethylene glycol diethers, polyamines, amines, amino alcohols and surfactants, (v) transferring the reactor outlet stream containing the additive to a catalyst deactivation and removal section, and (vi) deactivating the catalyst with caustic and removing the deactivated catalyst from the reactor outlet stream, wherein the residence time of the additive in the reactor outlet stream prior to mixing with caustic is at least 1 second preferably at least 5 seconds, more preferably at least 10 seconds.

Abstract translation: 本发明涉及通过在溶剂和均相催化剂存在下使乙烯低聚制备线性α-烯烃（LAO）的方法，包括以下步骤：（i）将乙烯，溶剂和催化剂进料到低聚反应器中（ ii）使反应器中的乙烯低聚，（iii）通过反应器出口管道系统从反应器中除去包含溶剂，线性α-烯烃，任选未反应的乙烯和催化剂的反应器出口流，（iv）给予至少一种选自 由醇，聚乙二醇，聚乙二醇单醚，聚乙二醇二醚，多胺，胺，氨基醇和表面活性剂组成的组，（v）将含有添加剂的反应器出口流转移到催化剂失活和除去部分，和（vi） 具有苛性碱的催化剂和从反应器出口流中除去失活的催化剂，其中添加剂在反应器中的停留时间 在与苛性碱混合之前，出口流优选为至少1秒，优选至少5秒，更优选至少10秒。

公开(公告)号：WO2009121456A1

公开(公告)日：2009-10-08

申请号：PCT/EP2009/001518

申请日：2009-03-04

Applicant: LINDE AG ,  SAUDI BASIC INDUSTRIES CORPORATION ,  ALIYEV, Vugar, O. ,  AL-HAZMI, Mohammed ,  MOSA, Fuad ,  ROSENTHAL, Uwe ,  MÜLLER, Bernd, H. ,  HAPKE, Marko ,  PEULECKE, Normen ,  WÖHL, Anina ,  FRITZ, Peter, M. ,  BÖLT, Heinz ,  MÜLLER, Wolfgang ,  WINKLER, Florian ,  WELLENHOFER, Anton

Inventor： ALIYEV, Vugar, O. ,  AL-HAZMI, Mohammed ,  MOSA, Fuad ,  ROSENTHAL, Uwe ,  MÜLLER, Bernd, H. ,  HAPKE, Marko ,  PEULECKE, Normen ,  WÖHL, Anina ,  FRITZ, Peter, M. ,  BÖLT, Heinz ,  MÜLLER, Wolfgang ,  WINKLER, Florian ,  WELLENHOFER, Anton

IPC: B01J31/16 ,  B01J31/18

CPC classification number: B01J31/1658 ,  B01J31/189 ,  B01J2231/20 ,  B01J2531/62

Abstract: The present invention relates to a catalyst for oligomerization of ethylene, comprising a functionalized solid support; a ligand immobilized on the solid support by chemical bonding, wherein the immobilized ligand has, the structure (R 1 )(R 2 )P-N(R 3 )-P(R 4 )-Y-support or (R 1 )(R 2 )P-N(R 3 )-P(R 4 )-N(R 5 )-P(R 6 )-Y-support, wherein R 1 R 2 , R 3 , R 4 , R 5 and R 6 are independently selected from aliphatic group, aryl group, amino group and trimethylsilyl group and Y is the functional group of the support or a derivative thereof; and a chromium compound reacted with the ligand.; and to a method for its preparation and a process for oligomerization of ethylene utilizing the catalyst.

Abstract translation: 本发明涉及乙烯低聚催化剂，其包括官能化固体载体; 结构（R1）（R2）PN（R3）-P（R4）-Y-支持或（R1）（R2）PN（R3） - 的固定化配位体固定在固体载体上的配体， P（R4）-N（R5）-P（R6）-Y-支持物，其中R1R2，R3，R4，R5和R6独立地选自脂族基团，芳基，氨基和三甲基甲硅烷基，Y是官能团 一组支持或其衍生物; 与配位体反应的铬化合物。 以及其制备方法和利用该催化剂使乙烯低聚的方法。

公开(公告)号：WO2014191874A1

公开(公告)日：2014-12-04

申请号：PCT/IB2014/061614

申请日：2014-05-22

Applicant: SAUDI BASIC INDUSTRIES CORPORATION

Inventor： CHU, Wei ,  AL-HAZMI, Mohammed ,  MUSSA, Majed ,  ODEDAIRO, Taiwo

IPC: B01J29/076 ,  B01J29/48 ,  B01J37/02 ,  B01J23/28 ,  B01J23/84 ,  B01J23/881 ,  B01J23/882 ,  B01J23/883 ,  B01J23/885 ,  C07C2/76 ,  C07C15/00 ,  C07C15/04

CPC classification number: C07C2/76 ,  B01J23/28 ,  B01J23/6525 ,  B01J23/686 ,  B01J23/88 ,  B01J29/48 ,  B01J2229/186 ,  C07C2523/02 ,  C07C2523/06 ,  C07C2523/10 ,  C07C2523/28 ,  C07C2523/652 ,  C07C2523/68 ,  C07C2523/881 ,  C07C2523/882 ,  C07C2523/883 ,  C07C2523/885 ,  Y02P20/52 ,  C07C15/04 ,  C07C15/06 ,  C07C15/08 ,  C07C15/24

Abstract: The present disclosure relates to a catalyst composition having a high selectivity converting methane to an aromatic compound. The disclosed catalyst composition comprises an inorganic support; a molybdenum; and at least one promoter selected from copper, iron, silver, zinc, calcium, cobalt, nickel, platinum, lanthanum, and cerium; wherein the total amount of the promoter is present in an amount that ranges from greater than 0.01 wt. % to 0 wt.%, based on the total weight of the catalyst composition; wherein when the at least one promoter is zinc, the molybdenum is not in the form of molybdenum oxalate; and wherein the catalyst composition converts methane to an aromatic compound. Also disclosed is a method for preparing the catalyst composition and a method of using the same to produce an aromatic compound.

Abstract translation: 本公开内容涉及具有将甲烷转化为芳族化合物的高选择性的催化剂组合物。 所公开的催化剂组合物包含无机载体; 钼; 和选自铜，铁，银，锌，钙，钴，镍，铂，镧和铈中的至少一种助催化剂; 其中促进剂的总量以大于0.01重量％的量存在。 ％至0重量％，基于催化剂组合物的总重量; 其中当所述至少一种促进剂是锌时，所述钼不是草酸钼的形式; 并且其中所述催化剂组合物将甲烷转化为芳族化合物。 还公开了制备催化剂组合物的方法及其使用方法来制备芳族化合物。

公开(公告)号：WO2014181241A1

公开(公告)日：2014-11-13

申请号：PCT/IB2014/061215

申请日：2014-05-05

Applicant: SAUDI BASIC INDUSTRIES CORPORATION

Inventor： CHU, Wei ,  AL-HAZMI, Mohammed ,  MUSSA, Majed ,  ODEDAIRO, Taiwo

IPC: C07C2/76 ,  C07C15/00 ,  B01J23/28 ,  B01J23/84 ,  B01J23/881 ,  B01J23/882 ,  B01J23/883 ,  B01J23/885 ,  B01J23/887 ,  B01J23/89 ,  B01J29/076 ,  B01J29/48 ,  C07C15/04 ,  B01J37/02

CPC classification number: C07C2/76 ,  B01J23/28 ,  B01J23/88 ,  B01J23/8873 ,  B01J29/48 ,  B01J2229/186 ,  B01J2523/00 ,  C07C2529/48 ,  Y02P20/52 ,  C07C15/04 ,  B01J2523/27 ,  B01J2523/68 ,  B01J2523/847 ,  B01J2523/17

Abstract: The present disclosure relates to a catalyst composition having a high selectivity converting methane to an aromatic compound. The disclosed catalyst composition comprises an inorganic support; molybdenum; and at least two promoters selected from copper, iron, silver, zinc, calcium, cobalt, nickel, platinum, lanthanum, and cerium. Also disclosed is a method for preparing the catalyst composition and a method of using the same to produce an aromatic compound.

Abstract translation: 本公开内容涉及具有将甲烷转化为芳族化合物的高选择性的催化剂组合物。 所公开的催化剂组合物包含无机载体; 钼; 和选自铜，铁，银，锌，钙，钴，镍，铂，镧和铈中的至少两种助催化剂。 还公开了制备催化剂组合物的方法及其使用方法来制备芳族化合物。

公开(公告)号：WO2010115520A1

公开(公告)日：2010-10-14

申请号：PCT/EP2010/001842

申请日：2010-03-24

Applicant: LINDE AG ,  SAUDI BASIC INDUSTRIES CORPORATION ,  WÖHL, Anina ,  ROSENTHAL, Uwe ,  MÜLLER, Bernd, H. ,  PEULECKE, Normen ,  PEITZ, Stephan ,  MÜLLER, Wolfgang ,  BÖLT, Heinz ,  MEISWINKEL, Andreas ,  ALURI, Bashkar, Reddy ,  AL-HAZMI, Mohammed ,  AL-MASNED, Mohammed ,  AL-EIDAN, Khalid ,  MOSA, Fuad

Inventor： WÖHL, Anina ,  ROSENTHAL, Uwe ,  MÜLLER, Bernd, H. ,  PEULECKE, Normen ,  PEITZ, Stephan ,  MÜLLER, Wolfgang ,  BÖLT, Heinz ,  MEISWINKEL, Andreas ,  ALURI, Bashkar, Reddy ,  AL-HAZMI, Mohammed ,  AL-MASNED, Mohammed ,  AL-EIDAN, Khalid ,  MOSA, Fuad

IPC: B01J31/14 ,  B01J31/18

CPC classification number: B01J31/189 ,  B01J31/143 ,  B01J31/1885 ,  B01J2231/20 ,  B01J2531/0258 ,  B01J2531/62 ,  C07C2/36 ,  C07C2531/14 ,  C07C2531/24 ,  C07C11/02

Abstract: The present invention relates to a catalyst composition for oligomerization of ethylene, com¬ prising a chromium compound; a ligand of the general structure R 1 R 2 P-N(R 3 )-P(R 4 )-N(R 5 )-H, wherein R 1 , R 2 , R 3 , R 4 and R 5 are independently selected from halogen, amino, trimethylsilyl, C 1 -C 10 -alkyl, aryl and substituted aryl; a modifier containing organic or inorganic halide; and an activator or co-catalyst; and a process for oligomerization utilizing that catalyst.

Abstract translation: 本发明涉及一种用于低聚乙烯的催化剂组合物，其中包括铬化合物; 通式结构R1R2P-N（R3）-P（R4）-N（R5）-H的配体，其中R1，R2，R3，R4和R5独立地选自卤素，氨基，三甲基甲硅烷基，C1-C10-烷基 ，芳基和取代的芳基; 含有机或无机卤化物的改性剂; 和活化剂或助催化剂; 以及利用该催化剂的低聚方法。

公开(公告)号：WO2009083163A1

公开(公告)日：2009-07-09

申请号：PCT/EP2008/010802

申请日：2008-12-18

Applicant: LINDE AG ,  SAUDI BASIC INDUSTRIES CORPORATION ,  MÜLLER, Wolfgang ,  FRITZ, Peter, M. ,  BÖLT, Heinz ,  WELLENHOFER, Anton ,  MEISWINKEL, Andreas ,  TAUBE, Carsten ,  SCHNEIDER, Richard ,  WINKLER, Florian ,  FRITZ, Helmut ,  HOFMANN, Karl-Heinz ,  ZANDER, Hans-Jörg ,  ULBRICH, Peter ,  SEGATZ, Jan ,  MOUSA, Fuad ,  AL-HAZMI, Mohammed ,  AL-THAUYYAN, Abdullah ,  AL-MUSNED, Mohammed

Inventor： MÜLLER, Wolfgang ,  FRITZ, Peter, M. ,  BÖLT, Heinz ,  WELLENHOFER, Anton ,  MEISWINKEL, Andreas ,  TAUBE, Carsten ,  SCHNEIDER, Richard ,  WINKLER, Florian ,  FRITZ, Helmut ,  HOFMANN, Karl-Heinz ,  ZANDER, Hans-Jörg ,  ULBRICH, Peter ,  SEGATZ, Jan ,  MOUSA, Fuad ,  AL-HAZMI, Mohammed ,  AL-THAUYYAN, Abdullah ,  AL-MUSNED, Mohammed

IPC: C07C2/08 ,  C08F6/02 ,  B01J19/18

CPC classification number: B01J19/18 ,  B01J19/1806 ,  C07C2/22 ,  C07C11/04 ,  C07C2521/06 ,  C07C2531/14 ,  Y02P20/52

Abstract: The present invention relates to a method for the oligomerisation of ethylene, comprising the steps of: (i) oligomerising ethylene in a reactor in the presence of a solvent and a catalyst composition; (ii) discharging a catalyst composition containing outlet stream from the reactor; (iii) deactivating and extracting the catalyst composition with a polar phase, wherein the outlet stream and the polar phase are mixed in a dynamic mixing device having rotor and stator elements comprising concentric tool rings as well as to a reactor system therefore.

Abstract translation: 本发明涉及乙烯低聚方法，包括以下步骤：（i）在溶剂和催化剂组合物存在下，在反应器中使乙烯低聚; （ii）从反应器排出含有出口物流的催化剂组合物; （iii）用极性相去活化和萃取催化剂组合物，其中出口流和极性相在具有包括同心工具环的转子和定子元件以及反应器系统的动态混合装置中混合。

公开(公告)号：WO2014181293A1

公开(公告)日：2014-11-13

申请号：PCT/IB2014/061309

申请日：2014-05-08

Applicant: SAUDI BASIC INDUSTRIES CORPORATION

Inventor： AL-YASSIR, Nabil ,  AL-HAZMI, Mohammed ,  SIDDIQUI, Mohammed Abdul Bari ,  JIN, Yaming ,  AITANI, Abdullah ,  AL-KHATTAF, Sulaiman

IPC: B01J29/40 ,  B01J29/42 ,  B01J29/44 ,  B01J29/46 ,  B01J29/48 ,  B01J29/064 ,  B01J29/068 ,  B01J29/072 ,  B01J29/076 ,  B01J37/02 ,  B01J37/06 ,  C10G11/05 ,  C07C4/06 ,  C07C11/02 ,  C07C11/04

CPC classification number: B01J37/06 ,  B01J29/061 ,  B01J29/064 ,  B01J29/068 ,  B01J29/072 ,  B01J29/076 ,  B01J29/405 ,  B01J29/42 ,  B01J29/44 ,  B01J29/46 ,  B01J29/48 ,  B01J29/89 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/30 ,  B01J2229/16 ,  B01J2229/18 ,  B01J2229/183 ,  B01J2229/186 ,  B01J2229/38 ,  C10G11/05 ,  C10G35/095 ,  C10G45/68 ,  C10G2400/20 ,  C10G2400/30

Abstract: The invention pertains to a zeolite catalyst, methods of making same, and its use in the catalytic cracking of naphtha for the production of lower molecular weight olefins and alkanes, while minimizing production less desirable products. A zeolite is modified by base leaching and by the addition of a metal cation, thereby lowering the Si/Al 2 ratio and improving the stability of the formed catalyst.

Abstract translation: 本发明涉及一种沸石催化剂，其制备方法，以及其在用于生产低分子量烯烃和烷烃的石脑油的催化裂化中的用途，同时使生产不太理想的产物最小化。 通过碱浸出和金属阳离子改性沸石，从而降低Si / Al 2比例并提高形成的催化剂的稳定性。

公开(公告)号：WO2014177988A1

公开(公告)日：2014-11-06

申请号：PCT/IB2014/061049

申请日：2014-04-28

Applicant: SAUDI BASIC INDUSTRIES CORPORATION

Inventor： AL-HAZMI, Mohammed ,  ODEDAIRO, Taiwo, A. ,  AL-ZENAIDI, Ahmed ,  AL-KHATTAF, Sulaiman ,  AL-YASSIR, Nabil ,  AITANI, Abdullah ,  SIDDIQUI, M., Abdulbari

IPC: B01J29/06 ,  B01J29/076 ,  B01J29/40 ,  B01J29/48 ,  B01J37/02 ,  C10G11/05 ,  C07C11/02 ,  C07C11/04 ,  C07C11/06 ,  C07C4/06

CPC classification number: B01J29/405 ,  B01J29/061 ,  B01J29/076 ,  B01J29/40 ,  B01J29/48 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/30 ,  B01J2229/18 ,  B01J2229/186 ,  B01J2229/42 ,  C10G11/05 ,  C10G2300/1044 ,  C10G2300/1092

Abstract: The inventions described herein relate to catalysts comprising a zeolite comprising at least one metal or ion thereof, wherein the at least one metal or ion thereof comprises barium, strontium, titanium, tungsten, or a mixture thereof, and wherein the zeolite does not comprise molybdenum, or phosphorus, and methods related thereto.

Abstract translation: 本文所述的发明涉及包含包含至少一种金属或其离子的沸石的催化剂，其中至少一种金属或其离子包括钡，锶，钛，钨或其混合物，并且其中沸石不包含钼 ，或磷，以及与之相关的方法。