公开(公告)号：WO2018047607A1

公开(公告)日：2018-03-15

申请号：PCT/JP2017/029622

申请日：2017-08-18

Applicant: エイコーエコスパ株式会社 ,  根石 紘一

Inventor： 根石　紘一 ,  林　茂美

IPC: C10G53/10 ,  C10G17/02 ,  C10G31/10 ,  C10M175/02 ,  C10N30/00

CPC classification number: C10G17/02 ,  C10G31/10 ,  C10G53/10 ,  C10M175/02

Abstract: 従来の技術の種々の問題点を克服し、処理油中の灰分となる金属成分や水分などを簡便な方法で効率良く低減、除去することができる廃油中の灰分の低減化処理方法を提供することを目的とする。　即ち、本発明は、使用済み潤滑油を含む廃油又は廃油の物理的処理により得られる再生重油に、炭素数３～６の脂肪族ヒドロキシカルボン酸又はそのアンモニウム塩から選ばれる低灰分化処理剤の水溶液を添加し、混合・撹拌して反応処理する第１工程；得られた混合物を静置分離して上層の処理油層と下層の灰分となる金属塩の溶解する低灰分化処理剤水溶液からなる水層とに分離し、処理油を分離回収するとともに、下層の低灰分化処理剤水溶液を回収し次のバッチの第１工程の低灰分化処理剤として使用する第２工程を含むことを特徴とする廃油又は再生重油の低灰分化処理方法である。低灰分化処理剤としては、クエン酸が最も好ましい。

Abstract translation:

克服了现有技术的各种问题，有效地通过简单的方法金属组分和水作为加工油中的灰分减少等，灰分在废油可被移除 为了减少处理时间。 即，本发明是由废油或废油的物理处理得到的重放重油包含用于润滑油，从脂肪族羟基羧酸或它的铵盐具有3至6个碳原子中选择的低灰分处理剂 由低灰分处理剂溶液以溶解所得混合物沉降远离经处理的油层的上层和下灰金属盐;用于添加的水溶液中，第一步骤的反应处理混合并搅拌以 分离成水层，经处理的油以及分离和回收，其特征在于，回收包括下一批次的第一步骤中使用的第二个步骤为低灰分处理剂下低灰分处理剂溶液 废油或再生重油。 柠檬酸作为低灰分含量处理剂是最优选的。

公开(公告)号：WO2013173087A1

公开(公告)日：2013-11-21

申请号：PCT/US2013/039420

申请日：2013-05-03

Applicant: GENERAL ELECTRIC COMPANY

Inventor： MCDANIEL, Cato, Russell

IPC: C10G31/08 ,  C10G17/02

CPC classification number: C10G17/02 ,  C10G31/08

Abstract: A process for reducing contaminants during a desalting process is disclosed. The process may comprise providing an acid buffer solution; providing a contaminated stream; and mixing the acid buffer solution with the contaminated stream.

Abstract translation: 公开了一种在脱盐过程中减少污染物的方法。 该方法可以包括提供酸缓冲溶液; 提供污染的流; 并将酸缓冲溶液与受污染的流混合。

公开(公告)号：WO2011035085A3

公开(公告)日：2011-06-16

申请号：PCT/US2010049211

申请日：2010-09-17

Applicant: NALCO CO ,  GARCIA JUAN M III ,  LORDO SAMUEL A ,  BRADEN MICAHEL L

Inventor： GARCIA JUAN M III ,  LORDO SAMUEL A ,  BRADEN MICAHEL L

IPC: C10G17/02 ,  B01J31/04 ,  B01J31/26

CPC classification number: C10G17/04 ,  C10G17/02 ,  C10G17/09 ,  C10G33/02 ,  C10G33/04 ,  C10G2300/202 ,  C10G2300/205 ,  C10G2300/80 ,  C10G2300/805

Abstract: A method of removing metals and amines from crude oil comprising adding an effective metal removing amount of one or more hydroxycarboxylic acids selected from lactic acid and malic acid and salts thereof to said crude oil; adding wash water to said crude oil; mixing said crude oil, acid and wash water to form an emulsion; and resolving said emulsion into an aqueous phase and crude oil having a reduced metals content

Abstract translation: 一种从原油中除去金属和胺的方法，包括向所述原油中加入有效金属去除量的一种或多种选自乳酸和苹果酸的羟基羧酸及其盐; 向所述原油中加入洗涤水; 将所述原油，酸和洗涤水混合以形成乳液; 并将所述乳液分解成水相和具有降低的金属含量的原油

公开(公告)号：WO2008126977A1

公开(公告)日：2008-10-23

申请号：PCT/KR2007/006800

申请日：2007-12-24

Applicant: CHOI, Hong Yoon

Inventor： CHOI, Hong Yoon

IPC: B09B5/00

CPC classification number: C10G17/02 ,  C10G29/20 ,  C10G2300/1003 ,  C10M175/0016

Abstract: The present invention relates to a method for treating waste petroleum, and more specifically relates to providing a method for treating various waste petroleum (such as a lubricating oil, a re¬ frigeration oil, an insulating oil and the like used in general machinery and equipment as well as in particular radioactive waste petroleum) into eco-friendly solid that leaching of oil would not occur. That is, the method of the present invention comprises mixing 85-90% by weight of waste petroleum and 10-15% by weight of a mixed solution in which a concentrated sulfuric acid is mixed with a concentrated nitric acid at a mixing ratio of 1:2; producing precipitates and filtrates (3H+3, SO4 2, and NO3" ) and modified waste oil obtained by the mixing step (a); adding 85-90% by weight of the mixed solution in which the precipitates and the filtrates are mixed homo¬ geneously to 10-15% by weight of a saturated aqueous sodium hydroxide solution (Na+OH +H+2 O 2), thereby carrying out a second polymerization reaction to produce solid particles; col- loidizing a mixture obtained by uniformly stirring the solid particles; adding 10-15% by weight of a diisocyanate compound to 85-90% by weight of the colloidized mixture before reactor cooling of the colloidized mixture, thereby carrying out a third polymerization reaction serially to obtain a mixture in the form of powder with a gas; purifying the gas generated in the third polymerization reaction and discharging the purified gas into the atmosphere by way of a complex salt reaction; and filling the compound into a resin as a filling material and compression molding and reclaiming the filled compound. As described above, the method of the present invention can treat radioactive waste petroleum used in a nuclear power station as well as various waste petroleum, thereby stabilizing waste petroleum chemically and physically, wherein the method comprises mixing waste petroleum with a concentrated sulfuric acid and a concentrated nitric acid; adding sodium hydroxide, thereby carrying out a second polymerization reaction to produce solid particles; colloidizing a mixture obtained by uniformly stirring the solid particles; adding a diisocyanate compound in reactor, thereby carrying out a third polymerization reaction to obtain a new compound in the form of powder; discharging a generated gas into the atmosphere; and filling the compound into a resin as a filling material and compression molding and reclaiming the filled compound. Further, a new compound produced by treating waste petroleum according to the present invention, can be compression-molded as block with various resins and be reclaimed readily. Also, there are no problems caused by leaching of oil. Accordingly, the present invention is excellent invention that can prevent industrial pollutions caused by waste petroleum, specifically waste petroleum used in a nuclear power station.

Abstract translation: 本发明涉及一种处理废石油的方法，更具体地涉及提供一种用于一般机械设备中使用的各种废石油（例如润滑油，再生油，绝缘油等）的处理方法 特别是放射性废物石油）转化为环保固体，不会发生浸出油。 也就是说，本发明的方法包括将85-90重量％的废石油和10-15重量％的混合溶液混合，其中将浓硫酸与浓硝酸混合，混合比为1 ：2; 生成沉淀物和滤液（3H + 3，SO4 2和NO 3“）和通过混合步骤（a）获得的改性废油;加入85-90重量％的混合溶液，其中沉淀物和滤液混合均匀 10〜15重量％的饱和氢氧化钠水溶液（Na + OH + H + 2O 2），进行第二次聚合反应，制成固体颗粒;将通过均匀搅拌得到的混合物 固体颗粒;在反应器冷却胶体化混合物之前，将10-15重量％的二异氰酸酯化合物加入到85-90重量％的胶体化混合物中，从而连续进行第三次聚合反应，得到粉末形式的混合物 用气体净化在第三聚合反应中产生的气体，并通过复盐反应将净化气体排放到大气中;将化合物填充到作为填充材料的树脂中，并进行压缩和回收 填充化合物。 如上所述，本发明的方法可以处理在核电站中使用的放射性废石油以及各种废石油，从而稳定化学和物理上的废石油，其中所述方法包括将废石油与浓硫酸和 浓硝酸; 加入氢氧化钠，由此进行第二聚合反应以产生固体颗粒; 胶体化通过均匀搅拌固体颗粒获得的混合物; 在反应器中加入二异氰酸酯化合物，进行第三次聚合反应，得到粉末形式的新化合物; 将产生的气体排放到大气中; 并将化合物填充到作为填充材料的树脂中并压缩成型并回收填充的化合物。 此外，通过处理根据本发明的废石油生产的新化合物可以用各种树脂压模成块，并容易回收。 此外，没有油浸出问题。 因此，本发明是能够防止由废石油，特别是核电站使用的废油引起的工业污染的优良发明。

公开(公告)号：WO2005113707A1

公开(公告)日：2005-12-01

申请号：PCT/US2005/016706

申请日：2005-05-12

Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY ,  VARADARAJ, Ramesh ,  SISKIN, Michael

Inventor： VARADARAJ, Ramesh ,  SISKIN, Michael

IPC: C10B55/00

CPC classification number: C10B55/00 ,  C10B57/06 ,  C10G9/005 ,  C10G17/02 ,  C10G17/06 ,  C10G17/07 ,  C10G19/02 ,  C10G29/00 ,  C10G2300/1033 ,  C10G2300/1077 ,  C10G2300/80 ,  C10G2300/807

Abstract: A method for upgrading the viscoelastic properties of a heavy oil by altering its elastic modulus. An effective amount of one or more elastic modulus lowering agents are used, wherein preferred elastic modulus lowering agents include mineral and organic acids and bases, preferably strong bases, such as hydroxides of metals selected from the alkali and alkaline-earth metals.

Abstract translation: 通过改变其弹性模量来提高重油的粘弹性的方法。 使用有效量的一种或多种弹性模量降低剂，其中优选的弹性模量降低剂包括矿物和有机酸和碱，优选强碱，例如选自碱金属和碱土金属的金属的氢氧化物。

公开(公告)号：WO2014082770A1

公开(公告)日：2014-06-05

申请号：PCT/EP2013/069932

申请日：2013-09-25

Applicant: SAUDI BASIC INDUSTRIES CORPORATION ,  LINDE AG

Inventor： MOSA, Fuad ,  AZAM, Shahid ,  AL-OTAIBE, Sultan ,  FRITZ, Peter ,  BÖLT, Heinz ,  MEISWINKEL, Andreas ,  TAUBE, Carsten ,  WINKLER, Florian ,  MÜLLER, Wolfgang ,  WÖHL, Anina ,  GÖKE, Volker ,  SCHNEIDER, Richard ,  FRITZ, Helmut

IPC: C07C7/17 ,  C07C7/171 ,  C10G17/06 ,  C10G17/07 ,  C02F1/58 ,  C07C11/02

CPC classification number: C07C209/86 ,  C07C7/17 ,  C07C7/171 ,  C10G17/02 ,  C10G50/00 ,  C10G57/02 ,  C10G2300/202 ,  C07C11/02

Abstract: The present invention relates to a method for removal and recovery of an organic amine from a hydrocarbon stream containing the amine, comprising the steps of: i) mixing the hydrocarbon stream containing the amine with an aqueous inorganic acid in a volumetric ratio of hydrocarbon stream: aqueous inorganic acid of >1:1-5:1, preferably 1.5:1-4:1, more preferably 3:1, ii) phase separating of hydrocarbon and aqueous phase; hi) removing the hydrocarbon phase and optionally further purifying thereof, iv) optionally recycling at least a part of the hydrocarbon phase obtained in step (iii) into mixing step (i), v) mixing the aqueous phase obtained in step (iii) with an aqueous alkaline solution, vi) phase separating of an aqueous phase and an organic phase formed, vii) removing the organic phase obtained in step (vi) and optionally further purifying thereof.

Abstract translation: 本发明涉及从含有胺的烃流中除去和回收有机胺的方法，包括以下步骤：i）将含有胺的烃流与烃流体积比的无机酸水溶液混合： 水分无机酸> 1：1-5：1，优选1.5：1-4：1，更优选3：1，ii）烃和水相的相分离; ⅰ）除去烃相和任选地进一步纯化，ⅳ）任选地将步骤（ⅲ）中获得的烃相的至少一部分再循环混合到混合步骤（ⅰ）中，v）将步骤（iii）中获得的水相与 水性碱性溶液，vi）水相和形成的有机相的相分离，vii）除去步骤（vi）中获得的有机相，并任选进一步纯化。

公开(公告)号：WO2013155498A1

公开(公告)日：2013-10-17

申请号：PCT/US2013/036503

申请日：2013-04-12

Applicant: OTG RESEARCH, LLC

Inventor： BOE, Philip, Allen

IPC: C10G50/00

CPC classification number: C10L1/08 ,  C10G17/02 ,  C10G19/02 ,  C10G27/14 ,  C10G53/00 ,  C10G53/14 ,  C10G2300/1007 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/04 ,  C10L2270/026 ,  C10L2270/04 ,  C10L2290/06 ,  C10L2290/24 ,  C10M175/0016

Abstract: Methods and system for obtaining long chain carbons that generally include forming a conversion mixture of an alcohol and a base, adding the conversion mixture to oil ( such as petroleum based oil, crude oil, used oil, used motor oil, and new motor oil) to form a reaction mixture, adding a high nitrate compound the reaction mixture, and separating out the long chain carbons for use as an input by other processing such as pharmaceutical and/or additional petro-chemical processing. Additional cooling and/or filtering processes may be utilized to complete and/or optimize oil conversion.

Abstract translation: 用于获得长链碳的方法和系统通常包括形成醇和碱的转化混合物，将转化混合物加入到油中（例如石油基油，原油，二手油，二手机油和新机油） 形成反应混合物，加入高硝酸盐化合物反应混合物，分离出长链碳，用作输入物，通过其他加工如药物和/或其他石油化学处理。 可以利用额外的冷却和/或过滤方法来完成和/或优化油转化。

公开(公告)号：WO2010068261A2

公开(公告)日：2010-06-17

申请号：PCT/US2009/006460

申请日：2009-12-08

Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY ,  LEVINE, Steven, W. ,  BRONS, Glen, B. ,  LUTZ, George, A., II ,  LETA, Daniel, P. ,  WALTERS, Clifford, C.

Inventor： LEVINE, Steven, W. ,  BRONS, Glen, B. ,  LUTZ, George, A., II ,  LETA, Daniel, P. ,  WALTERS, Clifford, C.

IPC: C10L1/02 ,  C10G17/02

CPC classification number: C10G75/04 ,  C10G17/02 ,  C10G2300/1033 ,  C10G2300/4075

Abstract: High molecular weight naphthenic tetra-acids are added to a base crude oil to prevent and/or reduce fouling of crude oil refinery equipment. The method includes adding an effective amount of a high molecular weight naphthenic tetra-acid to the base crude oil to form a crude oil mixture and feeding the crude oil mixture to a crude oil refinery component. Particularly, the high molecular weight naphthenic tetra- acids include ARN acids.

Abstract translation: 将高分子量环烷四酸加入基础原油中以防止和/或减少原油炼油设备的结垢。 该方法包括向基础原油中加入有效量的高分子量环烷酸四酸以形成原油混合物并将原油混合物加入原油精炼组分中。 特别是高分子量环烷四酸包括ARN酸。

公开(公告)号：WO02072734A3

公开(公告)日：2002-12-27

申请号：PCT/US0202002

申请日：2002-01-25

Applicant: EXXONMOBIL RES & ENG CO

Inventor： VARADARAJ RAMESH

IPC: C10G17/02 ,  C10G17/04 ,  C10G31/00 ,  C10G15/08 ,  C10G17/00

CPC classification number: C10G17/02 ,  C10G17/04 ,  C10G31/00

Abstract: The invention describes a method for decreasing the viscosity of crude oils and residuum utilizing a combination of acid and sonic treatment.

Abstract translation: 本发明描述了一种利用酸和声波处理的组合来降低原油和渣油粘度的方法。

公开(公告)号：WO9320507A3

公开(公告)日：1994-01-06

申请号：PCT/JP9300417

申请日：1993-03-30

Applicant: SEIKO EPSON CORP

Inventor： COON BRETT ,  MIYAYAMA YOSHIYUKI ,  NGUYEN LE TRONG ,  WANG JOHANNES

IPC: C10G1/00 ,  C10G17/02 ,  G06F9/22 ,  G06F9/30 ,  G06F9/318 ,  G06F9/38 ,  G06F15/76

CPC classification number: G06F9/30101 ,  C10G1/00 ,  C10G17/02 ,  G06F9/30145 ,  G06F9/30149 ,  G06F9/30152 ,  G06F9/30163 ,  G06F9/30167 ,  G06F9/3017 ,  G06F9/30174 ,  G06F9/30185 ,  G06F9/3816 ,  G06F9/382 ,  G06F9/3853

Abstract: A system and method for extracting complex, variable length computer instructions from a stream of complex instructions each subdivided into a variable number of instruction bytes, and aligning instruction bytes of individual ones of the complex instructions. The system receives a portion of the stream of complex instructions and extracts a first set of instruction bytes starting with the first instruction bytes, using an extract shifter. The set of instruction bytes are then passed to an align latch where they are aligned and output to a next instruction detector. The next instruction detector determines the end of the first instruction based on said set of instruction bytes. An extract shifter is used to extract and provide the next set of instruction bytes to an align shifter which aligns and outputs the next instruction. The process is then repeated for the remaining instruction bytes in the stream of complex instructions. The isolated complex instructions are decoded into nano-instructions which are processed by a RISC processor core.

Abstract translation: 一种用于从复杂指令流中提取复杂的可变长度计算机指令的系统和方法，每个细分流被分成可变数量的指令字节，并且对齐复杂指令中各个指令的指令字节。 系统接收复指令流的一部分，并使用提取移位器从第一指令字节开始提取第一组指令字节。 然后将该组指令字节传递到对齐锁存器，在该锁存器中它们对准并输出到下一个指令检测器。 下一个指令检测器基于所述指令字节集来确定第一指令的结束。 提取移位器用于提取并提供下一组指令字节到对齐移位器，对准移位器对齐并输出下一条指令。 然后对复杂指令流中的剩余指令字节重复该过程。 孤立的复杂指令被解码成由RISC处理器核心处理的纳米指令。