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    PROCESS FOR CONVERTING MIXED WASTE PLASTIC INTO LIQUID FUELS BY CATALYTIC CRACKING
    1.
    发明申请
    PROCESS FOR CONVERTING MIXED WASTE PLASTIC INTO LIQUID FUELS BY CATALYTIC CRACKING 审中-公开
    通过催化裂化将混合的废弃塑料转变成液体燃料的方法

    公开(公告)号：WO2017103015A1

    公开(公告)日：2017-06-22

    申请号：PCT/EP2016/081304

    申请日：2016-12-15

    申请人： SOLVAY SA

    发明人： STREIFF, Stéphane ,  PICCININI, Marco ,  MARX, Emmanuel ,  CORMA, Avelino ,  CERRO-ALARCÓN, Miriam ,  MENGUAL, Jesús

    IPC分类号： C10G1/10

    CPC分类号： C10G1/10 ,  C10G2300/1003 ,  C10G2300/701

    摘要： The present invention relates to a process for converting mixed waste plastic into liquid fuels by catalytic cracking. The process comprises the steps of introducing mixed waste plastic and a catalyst comprising an amorphous-type catalyst within a reactor; allowing at least a portion of the mixed waste plastic to be converted to liquid fuels within the reactor; and removing a product stream containing said liquid fuels from the reactor.

    摘要翻译： 本发明涉及通过催化裂化将混合废塑料转化成液体燃料的方法。 该方法包括以下步骤：在反应器内引入混合废塑料和包含非晶型催化剂的催化剂; 允许至少一部分混合废塑料在反应器内转化成液体燃料; 并从反应器中除去含有所述液体燃料的产物流。

    METHOD AND SYSTEM FOR TRANSFERRING PLASTIC WASTE INTO A FUEL HAVING PROPERTIES OF DIESEL/HEATING OIL
    2.
    发明申请
    METHOD AND SYSTEM FOR TRANSFERRING PLASTIC WASTE INTO A FUEL HAVING PROPERTIES OF DIESEL/HEATING OIL 审中-公开
    方法和系统用于转移废塑料转化为燃料柴油/取暖油的性质

    公开(公告)号：WO2016116114A8

    公开(公告)日：2017-03-16

    申请号：PCT/EP2015000081

    申请日：2015-01-19

    申请人： VAN DER REE TEUNIS CHRISTIAAN ,  BLUEALP INNOVATIONS B V

    发明人： VAN DER REE TEUNIS CHRISTIAAN ,  WESER GEROLD

    IPC分类号： C10G1/10 ,  C10G9/40

    CPC分类号： C10G1/10 ,  C10G7/00 ,  C10G9/00 ,  C10G9/40 ,  C10G2300/1003 ,  C10G2300/4081 ,  C10G2400/04

    摘要： The invention relates to a method for recovering hydrocarbons from plastic wastes, in particular polyolefin-rich waste, by means of purely thermolytic cracking without the use of catalysts, comprising melting the plastic waste in two heating devices (3) and (4), wherein a recycle stream derived from the cracking reactor (5) and purified in a separator system (8, 9) is admixed with the molten plastic waste from the heating device (3). The mixed plastic stream is further heated in the second heating device (4), and from there is guided into the cracking reactor (5), where the plastic materials are cracked, and by means of subsequent distillation are separated into diesel and low boilers. A special entry system allows the prior separation of water and acidic gases, and the saving of inert gas. The invention further relates to a system for carrying out the method.

    摘要翻译： 一种用于回收从废塑料烃，特别是polyolefinreichen废物，通过在不使用催化剂的裂化纯粹热分解的方法，熔融废塑料方法包括两个加热装置（3）和（4），其中，所述熔化的废塑料从加热装置（3）从裂缝反应器（ 5）衍生的（在一个分离器系统8.9）是混合entschlackter再循环流。 混合Kunststoffström是在第二加热装置（4）进一步加热并从那里进入裂化反应器（5），其中所述塑料开裂，通过在柴油和低沸随后的蒸馏分离。 一个特殊的条目系统允许事先除去水和酸性气体，以及惰性气体的节省。 一种用于执行该方法的植物还描述。

    PROCESS FOR THE PRODUCTION OF BIO-OIL FROM BIOMASS
    4.
    发明申请
    PROCESS FOR THE PRODUCTION OF BIO-OIL FROM BIOMASS 审中-公开
    从生物量生产生物油的方法

    公开(公告)号：WO2016203437A1

    公开(公告)日：2016-12-22

    申请号：PCT/IB2016/053607

    申请日：2016-06-17

    申请人： ENI S.P.A.

    发明人： CHIABERGE, Stefano Carlo ,  BURATTINI, Mauro ,  MIGLIO, Roberta ,  CABRINI, Marina

    IPC分类号： C10G1/02

    CPC分类号： C10G1/02 ,  C10G2300/1003 ,  C10G2300/1011 ,  C10G2300/4006 ,  C10G2300/4012 ,  Y02P30/20

    摘要： Process for the production of bio-oil from biomass comprising the following steps: (a) feeding a biomass to a liquefaction reactor, said biomass having a protein content higher than or equal to 1% by weight, preferably ranging from 5% by weight to 50% by weight, with respect to the weight (dry weight) of said biomass, a lipid content higher than or equal to 1% by weight, preferably ranging from 5% by weight to 60% by weight, with respect to the weight (dry weight) of said biomass, a pH higher than or equal to 4, preferably ranging from 4.5 to 10; (b) subjecting said biomass to liquefaction operating at a temperature ranging from 220°C to 350°C, preferably ranging from 230°C to 310°C, even more preferably ranging from 240°C to 300°C, at a pressure higher than the vapour pressure of water at the temperature in which said liquefaction is carried out, for a time ranging from 30 minutes to 300 minutes, preferably ranging from 50 minutes to 270 minutes, obtaining a mixture comprising an oily phase consisting of bio-oil, a solid phase, a gaseous phase and an aqueous phase. The bio-oil (or bio-crude) thus obtained can be advantageously used as such, or, after optional upgrading treatments, in the production of biofuels or biocombustibles that can, in turn, be used as such or in a mixture with other fuels, for motor vehicles. Or, said bio-oil (or bio-crude) can be used in a mixture with fossil fuels (fuel oil, coal, etc.) for the generation of electric energy or heat.

    摘要翻译： 用于从生物质生产生物油的方法，包括以下步骤：（a）将生物质送入液化反应器，所述生物质的蛋白质含量高于或等于1重量％，优选为5重量％至5重量％ 50重量％，相对于所述生物质的重量（干重），脂质含量相对于重量为高于或等于1重量％，优选为5重量％至60重量％ 干重），pH高于或等于4，优选为4.5至10; （b）使所述生物质在220℃至350℃，优选230℃至310℃，甚至更优选240℃至300℃的温度范围内，在较高的压力下进行液化 比在所述液化进行的温度下的水的蒸气压高30分钟至300分钟，优选为50分钟至270分钟的时间，获得包含由生物油， 固相，气相和水相。 如此获得的生物油（或生物粗品）可以有利地使用，或者在任选的升级处理之后，在生物燃料或生物燃料的生产中，其可以依次使用或与其它燃料混合使用 ，用于机动车辆。 或者，所述生物油（或生物粗品）可用于与化石燃料（燃料油，煤等）的混合物中以产生电能或热量。

    CONVERSION OF BIOMASS OR RESIDUAL WASTE MATERIAL TO BIOFUELS
    5.
    发明申请
    CONVERSION OF BIOMASS OR RESIDUAL WASTE MATERIAL TO BIOFUELS 审中-公开
    生物量或残留废物转化为生物燃料

    公开(公告)号：WO2016173958A1

    公开(公告)日：2016-11-03

    申请号：PCT/EP2016/059116

    申请日：2016-04-25

    申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. ,  SHELL OIL COMPANY

    发明人： URADE, Vikrant Nanasaheb ,  DEL PAGGIO, Alan Anthony ,  CHILKOOR SOUNDARARAJAN, Laxmi Narasimhan

    IPC分类号： C10G1/06 ,  C10G1/08 ,  C10G3/00 ,  C10G1/00

    CPC分类号： C10G1/06 ,  C10G1/002 ,  C10G1/086 ,  C10G3/50 ,  C10G2300/1003 ,  C10G2300/1014 ,  C10G2300/1018 ,  Y02P30/20

    摘要： The present invention provides a process for producing liquid hydrocarbon products from solid biomass and/or residual waste feedstocks, said process comprising the steps of: a) a first stage of hydropyrolysing the solid feedstock in a hydropyrolysis reactor vessel in the presence of molecular hydrogen and one or more deoxygenation catalysts, producing a product stream comprising partially deoxygenated hydropyrolysis product, H 2 O, H 2 , CO 2 , CO, C 1 - C 3 gases, char and catalyst fines; b) removing said char and catalyst fines from said product stream; c) a second stage of hydroconverting said partially deoxygenated hydropyrolysis product in a hydroconversion reactor vessel in the presence of one or more hydroconversion catalysts and of the H 2 O, CO 2 , CO, H 2 , and C 1 - C 3 gas generated in step a), producing a vapour phase product comprising substantially fully deoxygenated hydrocarbon product, H 2 O, CO, CO 2 , and C 1 – C 3 gases; d) condensing the vapour phase product of step d) to 20 provide a liquid phase product comprising substantially fully deoxygenated C4+ hydrocarbon liquid and aqueous material and separating said liquid phase product from a gas phase product comprising H 2 , CO, CO 2 , and C 1 – C 3 gases; e) removing the aqueous material from the substantially fully deoxygenated C4+ hydrocarbon liquid; and f) a third stage comprising combining an aliphatic hydrocarbon precursor or an aromatic hydrocarbon precursor with at least a portion of the substantially fully deoxygenated C4+ hydrocarbon liquid and co- processing the resultant liquid in a hydroprocessing reactor vessel in the presence of hydrogen and one or more hydroprocessing catalysts.

    摘要翻译： 本发明提供了一种从固体生物质和/或残余废物原料生产液体烃产物的方法，所述方法包括以下步骤：a）在分子氢存在下在加氢热解反应器容器中加氢热解固体原料的第一阶段，以及 一种或多种脱氧催化剂，产生包含部分脱氧加氢热解产物，H 2 O，H 2，CO 2，CO，C 1 -C 3气体，炭和催化剂细粉的产物流; b）从所述产品流中除去所述焦炭和催化剂细粉; c）在一种或多种加氢转化催化剂和步骤a）中产生的H 2 O，CO 2，CO，H 2和C 1 -C 3气体的存在下，在加氢转化反应器容器中加氢转化所述部分脱氧加氢热解产物的第二阶段， 气相产物包含基本上完全脱氧的烃产物，H 2 O，CO，CO 2和C 1 -C 3气体; d）冷凝步骤d）至20的气相产物提供了包含基本上完全脱氧的C4 +烃液体和水性材料的液相产物，并将所述液相产物与包含H 2，CO，CO 2和C 1 -C 3的气相产物分离 气体; e）从基本上完全脱氧的C4 +烃液体中除去水性物质; 和f）第三阶段，包括将脂族烃前体或芳族烃前体与至少一部分基本上完全脱氧的C4 +烃液体组合并在氢处理反应器容器中在氢气存在下共同处理所得液体， 更多的加氢处理催化剂。

    VERFAHREN ZUR AUFBEREITUNG UND/ODER RÜCKGEWINNUNG UND/ODER WIEDERVERWERTUNG VON RÜCKSTÄNDEN INSBESONDERE AUS RAFFINERIEPROZESSEN
    7.
    发明申请
    VERFAHREN ZUR AUFBEREITUNG UND/ODER RÜCKGEWINNUNG UND/ODER WIEDERVERWERTUNG VON RÜCKSTÄNDEN INSBESONDERE AUS RAFFINERIEPROZESSEN 审中-公开
    程序进行处理和/或恢复和/或循环再造的废物炼油工艺特别

    公开(公告)号：WO2016078994A1

    公开(公告)日：2016-05-26

    申请号：PCT/EP2015/076377

    申请日：2015-11-12

    申请人： LIST HOLDING AG

    发明人： FLEURY, Pierre-Alain ,  LIECHTI, Pierre ,  SCHLAGER, George

    IPC分类号： C10G31/06 ,  B01F7/02

    CPC分类号： C10G31/06 ,  C10G2300/1003

    摘要： Bei einem Verfahren zur Aufbereitung und/oder Rückgewinnung und/oder Wiederverwertung von Rückständen insbesondere aus Raffinerieprozessen, welche eine Grundsubstanz, insbesondere mit Kohlenwasserstoff, wie zum Beispiel Kerosin, und Öl sowie metallische Rückstände enthalten, sollen die Rückstände in einen ersten Reaktor (5) eingegeben werden, in welchem ein Teil der flüchtigen Bestandteile verdampft und danach in einen zweiten Reaktor (10) übergeführt und dort durch Kühlung, die optional mit Wasserverdampfung unterstützt wird, verfestigt werden.

    摘要翻译： 在用于在第一反应器中的处理和/或回收和/或从精炼工艺，其含有碱性物质，特别是烃，如煤油，石油和金属残留物，所述残留物中的特定残基的回收的方法（5）被输入 是，其中通过蒸发出挥发性组分的一部分，然后在第二反应器（10），并有通过冷却，其任选通过水蒸发支持固化。

    CONVERSION OF SOLID BIOMASS INTO A LIQUID HYDROCARBON MATERIAL
    10.
    发明申请
    CONVERSION OF SOLID BIOMASS INTO A LIQUID HYDROCARBON MATERIAL 审中-公开
    将固体生物质转化为液体碳氢化合物

    公开(公告)号：WO2016001134A1

    公开(公告)日：2016-01-07

    申请号：PCT/EP2015/064691

    申请日：2015-06-29

    申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. ,  SHELL OIL COMPANY

    发明人： URADE, Vikrant, Nanasaheb ,  CHILKOOR SOUNDARARAJAN, Laxmi, Narasimhan ,  PANCHAGNULA, Madhusudhan, Rao ,  DEL PAGGIO, Alan, Anthony

    IPC分类号： C10K1/00 ,  C10K3/04 ,  C10G1/06 ,  C10G1/08 ,  C10G1/10 ,  C10G3/00

    CPC分类号： C10G1/002 ,  C10G1/02 ,  C10G1/06 ,  C10G1/086 ,  C10G1/10 ,  C10G3/42 ,  C10G3/45 ,  C10G3/47 ,  C10G3/48 ,  C10G3/50 ,  C10G3/52 ,  C10G2300/1003 ,  C10G2300/1014 ,  C10G2300/202 ,  C10K1/004 ,  C10K3/04 ,  Y02P30/20

    摘要： The present invention provides a process for producing liquid hydrocarbon products from a solid biomass feedstock, said process comprising the steps of: a) providing in a first hydropyrolysis reactor vessel a first hydropyrolysis catalyst composition, said composition comprising one or more active metals selected from cobalt, molybdenum, nickel, tungsten, ruthenium, platinum, palladium, iridium and iron on an oxide support, wherein at least a portion of the active metals are present in fully reduced metallic form; b) contacting the solid biomass feedstock with said first hydropyrolysis catalyst composition and molecular hydrogen in said first hydropyrolysis reactor vessel at a temperature in the range of from 350 to 600°C and a pressure in the range of from 0.50 to 7.50MPa, to produce a product stream comprising partially deoxygenated hydropyrolysis product, H2O, H2, CO2, CO, C1 - C3 gases, char and catalyst fines; c) removing said char and catalyst fines from said product stream; d) hydroconverting said partially deoxygenated hydropyrolysis product in a hydroconversion reactor vessel in the presence of one or more hydroconversion catalyst and of the H2O, CO2, CO, H2, and C1 - C3 gas generated in step a), to produce a vapour phase product comprising substantially fully deoxygenated hydrocarbon product, H2O, CO, CO2, and C1 – C3 gases.

    摘要翻译： 本发明提供了一种从固体生物质原料生产液态烃产物的方法，所述方法包括以下步骤：a）在第一加氢热解反应器容器中提供第一加氢热解催化剂组合物，所述组合物包含一种或多种选自钴 ，钼，镍，钨，钌，铂，钯，铱和铁在氧化物载体上，其中至少一部分活性金属以完全还原的金属形式存在; b）将所述固体生物质原料与所述第一加氢热解催化剂组合物和所述第一加氢热解反应器容器中的分子氢在350至600℃的温度和0.50至7.50MPa的压力范围内接触，以产生 包含部分脱氧加氢热解产物，H 2 O，H 2，CO 2，CO，C 1 -C 3气体，炭和催化剂细粉的产物流; c）从所述产品流中除去所述焦炭和催化剂细粒; d）在一种或多种加氢转化催化剂和步骤a）中产生的H 2 O，CO 2，CO，H 2和C 1 -C 3气的存在下，在加氢转化反应器容器中加氢转化所述部分脱氧加氢热解产物，以产生气相产物 包括基本上完全脱氧的烃产物，H 2 O，CO，CO 2和C 1 -C 3气体。