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    PROCESSES FOR THE PREPARATION OF OCTAFLUORO- 2,2]PARACYCLOPHANE
    11.
    发明公开
    PROCESSES FOR THE PREPARATION OF OCTAFLUORO- 2,2]PARACYCLOPHANE 失效
    用于生产八氟2.2环芳

    公开(公告)号：EP1021389A1

    公开(公告)日：2000-07-26

    申请号：EP96936589.9

    申请日：1996-10-18

    申请人： SPECIALTY COATING SYSTEMS, INC.

    发明人： DOLBIER, William, R., Jr. ,  RONG, Xiao X.

    IPC分类号： C07C17/269 ,  C07C23/18

    CPC分类号： C07C17/269 ,  C07C23/18

    摘要： A process for the preparation of octafluoro-[2,2]paracyclophane includes contacting a reactant selected from the group consisting of 1,4-bis(bromodifluoromethyl)benzene (dibromide), 1,4-bis(chlorodifluoromethyl)benzene (dichloride), and 1,4-bis(iododifluoromethyl)benzene (diiodide) with trimethylsilyltributyltin (TMSTBT) (a reducing agent) and fluoride ions in a refluxing solution of hexamethylphosphoramide (HMPA) or dimethylsulfoxide (DMSO) in tetrahydrofuran (THF) at conditions effective to promote a reaction product comprising octafluoro-[2,2]paracyclophane.

    INTEGRATED PROCESS FOR THE PRODUCTION OF Z-1,1,1,4,4,4-HEXAFLUORO-2-BUTENE
    14.
    发明公开
    INTEGRATED PROCESS FOR THE PRODUCTION OF Z-1,1,1,4,4,4-HEXAFLUORO-2-BUTENE 审中-公开
    综合征VERFAHREN ZUR HERSTELLUNG VON Z-1,1,1,4,4,4-HEXAFLUOR-2-BUTEN

    公开(公告)号：EP3102556A1

    公开(公告)日：2016-12-14

    申请号：EP15706590.5

    申请日：2015-02-06

    申请人： The Chemours Company FC, LLC

    发明人： BALDYCHEV, Ivan Sergeyvich ,  BRANDSTADTER, Stephan M. ,  CHEUNG, Patricia ,  NAPPA, Mario Joseph ,  PENG, Sheng ,  TOTON, Donald J.

    IPC分类号： C07C17/23 ,  C07C17/269 ,  C07C17/281 ,  C07C17/354 ,  C07C19/12 ,  C07C21/09 ,  C07C21/18

    CPC分类号： C07C17/25 ,  C07C17/23 ,  C07C17/281 ,  C07C17/354 ,  Y02P20/125 ,  Y02P20/582 ,  C07C21/18

    摘要： Disclosed is a process for the preparation of cis-1,1,1,4,4,4-hexafluoro-2-butene comprising contacting 1,1,1-trifluorotrichloroethane with hydrogen in the presence of a catalyst comprising ruthenium to produce a product mixture comprising 1316mxx, recovering said 1316mxx as a mixture of Z- and E-isomers, contacting said 1316mxx with hydrogen, in the presence of a catalyst selected from the group consisting of copper on carbon, nickel on carbon, copper and nickel on carbon and copper and palladium on carbon, to produce a second product mixture, comprising E- or Z-CFC-1326mxz, and subjecting said second product mixture to a separation step to provide E- or Z-1326mxz. The E- or Z-1326mxz can be dehydrochlorinated in an aqueous basic solution with an alkali metal hydroxide in the presence of a phase transfer catalyst to produce hexafluoro-2-butyne, which can then be selectively hydrogenated to produce Z-1,1,1,4,4,4-hexafluoro-2-butene using either Lindlar's catalyst, or a palladium catalyst further comprising a lantanide element or silver.

    摘要翻译： 公开了一种制备顺式-1,1,1,4,4,4-六氟-2-丁烯的方法，其包括在包含钌的催化剂存在下将1,1,1-三氟三氯乙烷与氢气接触以产生产物 混合物，其包含1316mxx，以Z和E异构体的混合物回收所述1316mxx，使所述1316mxx与氢接触，在选自碳上的碳，碳上的镍，碳上的铜和镍上的催化剂存在下，以及 铜和钯碳，以产生包含E-或Z-CFC-1326mxz的第二产物混合物，并使所述第二产物混合物进行分离步骤以提供E-或Z-1326mxz。 E-或Z-1326mxz可以在碱性金属氢氧化物的碱性水溶液中在相转移催化剂存在下脱氯化氢以产生六氟-2-丁炔，然后可以选择性氢化生成Z-1,1， 使用Lindlar催化剂的1,4,4,4-六氟-2-丁烯或进一步包含兰丹尼特元素或银的钯催化剂。

    COMPOSITE CONTAINING CATALYTIC METAL NANOPARTICLES, AND USE FOR SAME
    16.
    发明公开
    COMPOSITE CONTAINING CATALYTIC METAL NANOPARTICLES, AND USE FOR SAME 审中-公开
    VERBUNDSTOFF MIT KATALYTISCHEN METALLNANOPARTIKELN SOWIE VERWENDUNGDAFÜR

    公开(公告)号：EP2985078A2

    公开(公告)日：2016-02-17

    申请号：EP14774636.6

    申请日：2014-03-28

    申请人： Japan Science and Technology Agency ,  Furuya Metal Co., Ltd.

    发明人： ARISAWA, Mitsuhiro ,  SHUTO, Satoshi ,  HOSHIYA, Naoyuki ,  ARAI, Satoshi

    IPC分类号： B01J31/28 ,  C07C17/269 ,  C07C25/18 ,  C07C45/61 ,  C07C49/784 ,  C07D295/02 ,  C07B61/00

    CPC分类号： C07D295/033 ,  B01J23/44 ,  B01J23/462 ,  B01J23/464 ,  B01J23/468 ,  B01J23/52 ,  B01J23/745 ,  B01J23/75 ,  B01J23/755 ,  B01J31/06 ,  B01J31/165 ,  B01J31/28 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/006 ,  B01J2231/4205 ,  B01J2231/4211 ,  B01J2231/4255 ,  B01J2231/4261 ,  B01J2231/4266 ,  B01J2231/4283 ,  B82Y30/00 ,  C07B37/04 ,  C07D295/023

    摘要： Provided is a material that, when compared with SAPd, exhibits the similar activity in cross-coupling (CC) reactions, can decrease the amount of catalytic metal that is mixed into the reaction product, and increases the number of times use can be repeated. Provided are a catalyst and a catalyst precursor that use a catalytic metal other than Pd and that exhibit the CC reaction activity similar to when Pd is used. Provided are a catalyst and a catalyst precursor that exhibit the similar CC reaction activity when using Pd or a catalytic metal other than Pd, without using a carrier such as metal and without using piranha solution. A composite wherein catalytic metal nanoparticles are dispersed in a continuous phase comprising a polymer having C2-6 alkylene group units and phenylene group units (an alkylene group unit being bonded to at least the first and fourth position of the phenylene group unit). The particle diameter of the catalytic metal nanoparticles is at most 20nm. A composite structure including a substrate, and the aforementioned composite provided to the surface of the substrate. A method for manufacturing the composite structure by dehydrocondensating, in the presence of a catalytic metal compound, a benzene compound having at least two alkyl groups (two of the alkyl groups being at the first and fourth position) in order to form the composite on the substrate surface.

    摘要翻译： 提供了当与SAPd比较时，在交叉偶联（CC）反应中表现出相似的活性的材料，可以减少混入反应产物中的催化金属的量，并且可以重复使用次数。 提供了催化剂和催化剂前体，其使用除Pd以外的催化金属，并且显示出与使用Pd类似的CC反应活性。 提供了当使用Pd或除Pd之外的催化金属时，不使用载体如金属并且不使用食人鱼溶液时，催化剂和催化剂前体显示出类似的CC反应活性。 一种其中催化金属纳米颗粒分散在包含具有C 2-6亚烷基单元和亚苯基单元的聚合物（亚烷基单元至少连接至亚苯基单元的第一和第四位置）的连续相中的复合物。 催化金属纳米粒子的粒径为20nm以下。 一种复合结构体，包括基材和提供给基材表面的前述复合​​材料。 在催化金属化合物的存在下，通过脱气缩合制备复合结构体的方法，其中具有至少两个烷基的苯化合物（两个烷基在第一和第四位置）以形成复合材料 基材表面。