Liquid compositions containing blends of carboxylic esters
    56.
    发明公开
    Liquid compositions containing blends of carboxylic esters 失效
    FlüssigeZusammensetzungen enthaltend Mischungen vonKarboxylsäureestern。

    公开(公告)号:EP0568350A1

    公开(公告)日:1993-11-03

    申请号:EP93303332.6

    申请日:1993-04-28

    IPC分类号: C09K5/04 C10M105/32

    摘要: This invention relates to a liquid composition comprising (A) at least one fluorine-containing hydrocarbon containing one to three carbon atoms; and a lubricant comprising (B) a blend of (1) at least one carboxylic ester of (I) a neo hydroxy compound selected from the group consisting of (i) a neo hydroxy compound with one to four hydroxyl groups, and (ii) a mixture of neo hydroxy compounds having an average of less than 3.5 hydroxyl groups per hydroxy compound, and (II) a monocarboxylic acylating agent selected from the group consisting of (i) a monocarboxylic acylating agent having four or five carbon atoms, and (ii) a combination of a (a) an monocarboxylic acylating agent having four or five carbon atoms and (b) an monocarboxylic acylating agent having from about 7 to about 15 carbon atoms, provided that greater than 55 % of the ester groups of (1) are derived from monocarboxylic acylating agent having four or five carbon atoms, and (2) at least one carboxylic ester of (III) a neo hydroxy compound selected from the group consisting of (iii) a neo hydroxy compound having five or more four hydroxyl groups per hydroxy compound, and (iv) a mixture of neo hydroxy compounds having an average greater than 4.5 hydroxyl groups per hydroxy compound, and (IV) a combination of a (a) an monocarboxylic acylating agent having four or five carbon atoms and (b) an monocarboxylic acylating agent having from about 7 to about 15 carbon atoms, provided that greater than 55 % of the ester groups of (2) are derived from (IVb). The liquid compositions are useful particularly as refrigeration liquids in refrigerators and air-conditioners including automotive, home and industrial air-conditioners.

    摘要翻译: 本发明涉及包含(A)至少一种含有一至三个碳原子的含氟烃的液体组合物; 和(B)(1)至少一种(I)新羟基化合物的至少一种羧酸酯的混合物,所述新羟基化合物选自(i)新羟基化合物与1-4个羟基,和(ii) 每羟基化合物平均具有少于3.5个羟基的新羟基化合物的混合物,和(II)选自(i)具有4或5个碳原子的单羧酸酰化剂和(ii)单羧酸酰化剂的单羧酸酰化剂, )(a)具有四个或五个碳原子的单羧酸酰化剂和(b)具有约7至约15个碳原子的单羧酸酰化剂的组合,条件是(1)的大于55%的酯基, 衍生自具有四个或五个碳原子的单羧酸酰化剂,和(2)至少一种(III)的新羟基化合物的羧酸酯,其选自(iii)具有五个或更多个四个羟基的新羟基化合物 每羟基化合物, 和(iv)每羟基化合物具有平均大于4.5个羟基的新羟基化合物的混合物,和(IV)(a)具有4或5个碳原子的单羧酸酰化剂和(b)单羧酸酰化剂 具有约7至约15个碳原子的试剂,条件是(2)的大于55%的酯基衍生自(IVb)。 液体组合物特别适用于包括汽车,家用和工业空调的冰箱和空调中的制冷液体。