公开(公告)号：EP3102552A1

公开(公告)日：2016-12-14

申请号：EP14824195.3

申请日：2014-12-04

Applicant: ExxonMobil Research and Engineering Company

Inventor： McCARTHY, Stephen J. ,  VIJAY, Rohit ,  RATERMAN, Michael Francis ,  PETERSON, Brian ,  HICKEY, Karlton J. ,  DAAGE, Michel ,  LOVELESS, Brett ,  GUPTA, Ramesh ,  BIELENBERG, Patricia A.

IPC: C07C1/20 ,  C10G3/00

CPC classification number: B01J29/405 ,  B01J21/04 ,  B01J23/06 ,  B01J27/14 ,  B01J29/061 ,  B01J29/7049 ,  B01J29/90 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1057 ,  B01J35/108 ,  B01J35/109 ,  B01J37/0009 ,  B01J37/0201 ,  B01J38/02 ,  B01J38/12 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/42 ,  C07C1/20 ,  C07C1/22 ,  C07C2523/06 ,  C07C2529/40 ,  C07C2529/70 ,  C10G3/45 ,  C10G3/49 ,  C10G3/55 ,  C10L1/06 ,  C10L2200/0423 ,  C10L2200/0469 ,  C10L2270/023 ,  Y02P20/584 ,  Y02P30/20 ,  Y02P30/42 ,  C07C11/02 ,  C07C15/02

Abstract: A catalyst composition comprises a self-bound zeolite and a Group 12 transition metal selected from the group consisting of Zn, Cd, or a combination thereof, the zeolite having a silicon to aluminum ratio of at least about 10, the catalyst composition having a micropore surface area of at least about 340 m2/g, a molar ratio of Group 12 transition metal to aluminum of about 0.1 to about 1.3, and at least one of: (a) a mesoporosity of greater than about 20 m2/g; (b) a diffusivity for 2,2-dimethylbutane of greater than about 1×10−2 sec−1 when measured at a temperature of about 120° C. and a 2,2-dimethylbutane pressure of about 60 torr (about 8 kPa).

Abstract translation: 公开了有机化合物转化方法。 具体方法包括提供基于第一混合物的重量的包含≥10.0wt％的至少一种含氧化合物的第一混合物; 在有效将第一混合物的至少一部分转化成包含水，氢和一种或多种烃的产物流的条件下，使至少第一移动床反应器中的第一混合物与催化剂接触; 并从所述产物流（i）中分离出至少一种轻质物流，和ii）至少一种重质流，其中所述方法的特征在于再循环比为＆lt;

公开(公告)号：EP2965812A4

公开(公告)日：2016-11-30

申请号：EP13876929

申请日：2013-04-11

Applicant: SINOCAT ENVIRONMENTAL TECHNOLOGY CO LTD

Inventor： LIU ZHIKUN ,  LI YUN ,  LIN TAO ,  CHEN YAOQIANG

IPC: B01J29/46 ,  B01D53/94 ,  B01J29/10 ,  B01J29/14 ,  B01J29/76 ,  B01J37/02 ,  B01J37/08

CPC classification number: B01J29/146 ,  B01D53/9418 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/504 ,  B01J29/106 ,  B01J29/46 ,  B01J29/7615 ,  B01J37/0201 ,  B01J37/0236 ,  B01J37/08 ,  B01J2229/186 ,  Y02A50/2325 ,  Y02T10/24

Abstract: Provided are a low-temperature SCR catalyst for denitrating diesel vehicle exhaust, and preparation method thereof. The catalyst uses a molecular sieve as a carrier, and uses metallic elements such as copper and iron as active components. The catalyst preparation method comprises: preprocessing the molecular sieve; conducting multiple equal-volume impreparations; after impreparation, drying to dehydrate, and calcining; and finally pulping and coating to prepare the catalyst. The catalyst employs base metals such as copper and iron instead of precious metals as active components, thus reducing costs, being harmless to humans, and being environmentally friendly. The preparation method of the catalyst is simple and feasible with low requirements for raw materials, employs a repeated but small-quantity method of equalvolume impregnation; and enables active ions to be dispersed more uniformly as compared with the existing conventional preparation methods, thus improving utilization and improving low-temperature catalytic activity and durability.

公开(公告)号：EP3092072A1

公开(公告)日：2016-11-16

申请号：EP14878159.4

申请日：2014-06-12

Applicant: Fujian Institute Of Research On The Structure Of Matter, Chinese Academy Of Sciences

Inventor： XU, Zhong-Ning ,  GUO, Guo-Cong ,  PENG, Si-Yan ,  WANG, Zhi-Qiao ,  CHEN, Qing-Song ,  WANG, Ming-Sheng ,  YAO, Yuan-Gen

IPC: B01J23/89 ,  B01J23/44 ,  B01J37/02 ,  C07C69/06 ,  C07C67/36

CPC classification number: C07C67/36 ,  B01J21/04 ,  B01J21/063 ,  B01J21/066 ,  B01J21/08 ,  B01J21/10 ,  B01J21/18 ,  B01J23/02 ,  B01J23/06 ,  B01J23/40 ,  B01J23/44 ,  B01J23/462 ,  B01J23/464 ,  B01J23/466 ,  B01J23/468 ,  B01J23/89 ,  B01J23/8906 ,  B01J23/8913 ,  B01J23/892 ,  B01J23/8926 ,  B01J23/8946 ,  B01J23/8953 ,  B01J35/0013 ,  B01J35/006 ,  B01J35/023 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/0207 ,  B01J37/024 ,  B01J37/088 ,  B01J37/16 ,  B01J37/343 ,  B01J2523/00 ,  C07C69/06 ,  B01J2523/22 ,  B01J2523/824 ,  B01J2523/828 ,  B01J2523/847 ,  B01J2523/822 ,  B01J2523/48 ,  B01J2523/821 ,  B01J2523/47 ,  B01J2523/827 ,  B01J2523/41 ,  B01J2523/825 ,  B01J2523/27 ,  B01J2523/31 ,  B01J2523/842 ,  B01J2523/845 ,  B01J2523/17

Abstract: A process for vapor-phase carbonylation of methanol to methyl formate, whereby a feed gas containing methanol, carbon monoxide, hydrogen and oxygen is passed through a reactor loaded with a supported nano-scaled platinum group metal heterogeneous catalyst to produce methyl formate by a vapor-phase carbonylation reaction, under reaction conditions with a space velocity of 500-5000 h−1, a temperature of 50-150° C. and a pressure of 0.01-2 MPa. Supported nano-scaled platinum group metal heterogeneous catalysts are prepared via ultrasonic dispersion and calcination. Methyl formate is produced and isolated under relatively mild conditions.

公开(公告)号：EP2969187A4

公开(公告)日：2016-11-02

申请号：EP14773341

申请日：2014-03-13

Applicant: HONEYWELL INT INC

Inventor： WANG HAIYOU ,  TUNG HSUEH SUNG

IPC: B01J21/10 ,  B01J23/44 ,  C07C17/087 ,  C07C17/20 ,  C07C17/25 ,  C07C19/08

CPC classification number: B01J23/58 ,  B01J21/10 ,  B01J23/44 ,  B01J23/96 ,  B01J37/0201 ,  B01J38/02 ,  B01J38/10 ,  B01J38/12 ,  B01J38/18 ,  C07C17/087 ,  C07C17/206 ,  C07C17/25 ,  Y02P20/582 ,  Y02P20/584 ,  C07C21/18 ,  C07C19/10

公开(公告)号：EP2964592A4

公开(公告)日：2016-11-02

申请号：EP14761016

申请日：2014-02-27

Applicant: GREYROCK ENERGY INC

Inventor： SCHUETZLE ROBERT ,  SCHUETZLE DENNIS

IPC: C07C1/04 ,  C07C27/00 ,  C10G2/00 ,  C10L1/16

CPC classification number: C10G2/332 ,  B01J23/8913 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/0066 ,  B01J35/023 ,  B01J35/026 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/1071 ,  B01J35/1076 ,  B01J37/0201 ,  C10G2/32 ,  C10G2/33 ,  C10G2/331 ,  C10G2/333 ,  C10G7/00 ,  C10G45/00 ,  C10G45/02 ,  C10G45/62 ,  C10G2300/1022 ,  C10G2300/70 ,  C10G2300/703 ,  C10G2400/04 ,  C10L1/08 ,  C10L2200/0492 ,  C10L2270/026 ,  C10L2290/42 ,  C10L2290/543

Abstract: A unique process and catalyst is described that operates efficiently for the direct production of a high cetane diesel type fuel or diesel type blending stock from stoichiometric mixtures of hydrogen and carbon monoxide. This invention allows for, but is not limited to, the economical and efficient production high quality diesel type fuels from small or distributed fuel production plants that have an annual production capacity of less than 10,000 barrels of product per day, by eliminating traditional wax upgrading processes. This catalytic process is ideal for distributed diesel fuel production plants such as gas to liquids production and other applications that require optimized economics based on supporting distributed feedstock resources.

Abstract translation: 描述了独特的方法和催化剂，其有效地用于从氢和一氧化碳的化学计量混合物直接生产高十六烷值柴油型燃料或柴油型混合原料。 本发明通过消除传统的蜡升级过程而允许但不限于经济和有效地生产来自小型或分布式燃料生产设备的高品质柴油型燃料，其年生产能力低于10,000桶产品 。 这种催化过程对于分布式柴油发电厂如气体到液体的生产以及需要基于支持分布的原料资源优化经济性的其他应用是理想的。

公开(公告)号：EP3079817A2

公开(公告)日：2016-10-19

申请号：EP14825506.0

申请日：2014-12-11

Applicant: Saudi Basic Industries Corporation

Inventor： GHOSH, Ashim Kumar ,  STEVENSON, Scott ,  SULLIVAN, David ,  MIHUT, Corina ,  KULKARNI, Neeta ,  SIMMONS, Meghann ,  MIER, Michael

IPC: B01J37/04 ,  B01J37/30 ,  B01J21/08 ,  B01J29/04 ,  B01J29/44 ,  B01J35/00 ,  B01J35/02 ,  B01J37/00 ,  B01J37/02 ,  C07C2/00 ,  C10G35/095

CPC classification number: B01J29/44 ,  B01J21/08 ,  B01J29/047 ,  B01J35/0013 ,  B01J35/023 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/04 ,  B01J37/30 ,  B01J2229/186 ,  B01J2229/40 ,  B01J2229/42 ,  C10G3/44 ,  C10G3/49 ,  C10G3/57 ,  C10G3/60 ,  C10G35/09 ,  C10G35/095 ,  C10G45/70 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2400/30 ,  Y02P30/20

Abstract: A method for forming a catalyst can comprise: heating a Ge-ZSM-5 zeolite powder at a temperature of 400 to 600C; ion-exchanging the heat-treated zeolite powder with an alkali metal and impregnating the heat-treated zeolite powder with noble metal; heating the ion-exchanged, impregnated zeolite powder to a temperature of 250 to 350C; mixing the second heat-treated zeolite powder with a solid silica binder and a colloidal silica binder to form a mixture, wherein if the solid silica has a purity of less than or equal to 66 wt% of silica oxide based on the total weight of the solid silica, then the mixture is free of an extrusion aide and the colloidal silica has a particle size of less than 20 nm as measured along a major axis; forming the mixture into a shaped body; and heating the shaped body to result in the catalyst.

Abstract translation: 形成催化剂的方法可以包括：在400至600℃的温度下加热Ge-ZSM-5沸石粉末; 将经过热处理的沸石粉末与碱金属离子交换，并用贵金属浸渍经过热处理的沸石粉末; 加热离子交换的浸渍沸石粉末至250至350℃的温度; 将所述第二热处理沸石粉末与固体二氧化硅粘合剂和胶态二氧化硅粘合剂混合以形成混合物，其中如果所述固体二氧化硅的纯度基于所述二氧化硅的总重量计小于或等于二氧化硅的66wt％ 固体二氧化硅，则该混合物不含挤出助剂，并且胶体二氧化硅沿主轴测量具有小于20nm的粒度; 将混合物成形为成形体; 和加热成形体以产生催化剂。

公开(公告)号：EP3078419A1

公开(公告)日：2016-10-12

申请号：EP16000547.6

申请日：2016-03-07

Applicant: Instytut Nowych Syntez Chemicznych ,  Uniwersytet Jagiellonski

Inventor： Wilk, Marcin ,  Inger, Marek ,  Ruszak, Monika ,  Saramok, Magdalena ,  Kowalik, Pawel ,  Antoniak-Jurak, Katarzyna ,  Sojka, Zbigniew ,  Kotarba, Andrzej ,  Grzybek, Gabriela ,  Stelmachowski, Pawel ,  Gudyka, Sylwia ,  Indyka, Paulina

IPC: B01J37/03 ,  B01J21/04 ,  B01J23/00 ,  B01D53/86 ,  B01J23/80 ,  B01J35/00 ,  B01J37/00 ,  B01J37/02

CPC classification number: B01J23/80 ,  B01D53/8628 ,  B01D2255/2022 ,  B01D2255/20746 ,  B01D2255/20792 ,  B01D2255/2092 ,  B01D2255/405 ,  B01J21/04 ,  B01J23/005 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/0207 ,  B01J37/031 ,  B01J37/035

Abstract: The subject of the present invention is a supported catalyst for the abatement of nitrogen(I) oxide especially from nitric acid plants as well as from other sources of gases emitted to atmosphere, and a method for its manufacture. The method for the preparation of the catalyst is characterised in that it contains an active phase of a spinel structure composed of cobalt oxide and zinc oxide at a weight ratio of 4-8:1 in terms of straight oxides Co 3 O 4 :ZnO and an alkaline promoter in the form of potassium at a weight ratio of 50-120:1 with respect to Co 3 O 4 , loaded on a formed support composed of α-Al 2 O 3 , whereas the amount of the active phase is 1-25% wt., preferably 5-20% wt. of the catalyst.

Abstract translation: 本发明的主题是一种用于氮（I）氧化物爱的特别是从硝酸植物以及从排放到大气中的气体的其他来源的消减的负载型催化剂，以及用于其制造的方法。 用于催化剂的制备方法是DASS它包含在以4-8重量比氧化钴和氧化锌组成的尖晶石结构的活性相：在直氧化物换算的Co 3 O 4 1：ZnO和 在50〜120的重量比在钾的形式碱性启动子：1相对于Co 3 O 4，装在载体上形成由±-Al 2 O 3的，而主动相的量是1- 25％（重量），催化剂的优选5-20％（重量）。

公开(公告)号：EP2351495A4

公开(公告)日：2016-10-05

申请号：EP09824831

申请日：2009-11-05

Applicant: JAPAN TOBACCO INC

Inventor： INOUE YASUNOBU ,  SASAKAWA KIYOHIRO ,  SUGAI KAZUNORI ,  NISHIMURA KENICHI ,  NAKAHARA YOSHIO

IPC: A24B15/28 ,  A24D1/02 ,  B01J21/04 ,  B01J21/06 ,  B01J23/02 ,  B01J23/06 ,  B01J23/28 ,  B01J23/40 ,  B01J23/70 ,  B01J23/745 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  B01J37/04

CPC classification number: A24B15/28 ,  A24B15/282 ,  A24B15/287 ,  A24B15/288 ,  A24D1/02 ,  B01J21/04 ,  B01J21/06 ,  B01J21/063 ,  B01J23/02 ,  B01J23/06 ,  B01J23/28 ,  B01J23/40 ,  B01J23/70 ,  B01J35/1009 ,  B01J35/1014 ,  B01J37/0036 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/0215 ,  B01J37/0234 ,  B01J37/04 ,  B01J37/08

Abstract: A smoking article characterized by comprising a carbon monoxide reducing agent comprising particles comprising a calcium aluminate represented by the formula (CaO) m (Al 2 O 3 ) n , where 1/6 ‰¤ m/n ‰¤ 4/1, wherein the particles have a BET specific surface area of 2 m 2 /g or more and less than 20 m 2 /g.

公开(公告)号：EP3072592A1

公开(公告)日：2016-09-28

申请号：EP14862864.7

申请日：2014-11-18

Applicant: JX Nippon Oil & Energy Corporation

Inventor： TAKAHAMA, Koshi ,  NAGAYASU, Yoshiyuki ,  HAYASAKA, Kazuaki

IPC: B01J37/18 ,  B01J23/46 ,  B01J23/75 ,  C07C1/06 ,  C07C9/00 ,  C07B61/00

CPC classification number: B01J23/75 ,  B01J21/06 ,  B01J21/08 ,  B01J23/462 ,  B01J23/8913 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1061 ,  B01J37/0201 ,  B01J37/18 ,  C10G2/332 ,  C10G2/333 ,  C10G2300/703

Abstract: A method for producing a catalyst for a Fischer-Tropsch synthesis, comprising a reduction step of obtaining the catalyst for a Fischer-Tropsch synthesis through a reduction treatment of an unreduced catalyst, wherein the unreduced catalyst comprises a carrier obtained by calcining a carrier precursor containing silica and a zirconium compound, and cobalt oxide and/or ruthenium oxide carried on the carrier; the content of zirconium in the unreduced catalyst is 0.01 to 7% by mass in terms of zirconium oxide relative to the total mass of the unreduced catalyst; and in the reduction step, a reducing gas is brought into contact with the unreduced catalyst under the conditions of a GHSV of 200 h -1 or more and 1500 h -1 or less and a linear velocity of 20 mm/s or more to perform the reduction treatment of the unreduced catalyst.

Abstract translation: 一种生产用于费 - 托合成的催化剂，包括：获得用于费 - 托合成的催化剂，通过进行还原处理的催化剂，以未还原的，worin未还原催化剂的还原工序的方法包括通过煅烧的载体前体含有获得了载体 担载在载体上的二氧化硅和锆化合物，和氧化钴和/或钌氧化物; 锆中的未还原的催化剂的含量为0时01分至7质量％，相对于未还原的催化剂的总质量氧化锆计; 并且在还原步骤中，还原性气体被带入与的200个小时-1以上且1500小时-1或更小的GHSV和20mm / s以上的线速度的条件下未还原的催化剂进行接触 还原处理的未还原的催化剂。

公开(公告)号：EP3065868A1

公开(公告)日：2016-09-14

申请号：EP14795604.9

申请日：2014-11-04

Applicant: Shell Internationale Research Maatschappij B.V.

Inventor： WINTER, Ferry ,  VAN WELSENES, Jan Arend ,  RIGUTTO, Marcello Stefano ,  GILTAY, Patricia Johanna Anne Maria ,  VAN VLAANDEREN, Johannes Jacobus Maria ,  AZGHAY, Ali

IPC: B01J37/20 ,  B01J37/00 ,  B01J37/02 ,  B01J27/19 ,  C10G45/08 ,  B01J23/883 ,  B01J37/28 ,  B01J35/10 ,  B01J35/00 ,  B01J31/04

CPC classification number: B01J27/19 ,  B01J21/04 ,  B01J23/883 ,  B01J31/0202 ,  B01J31/04 ,  B01J35/0006 ,  B01J35/0026 ,  B01J35/026 ,  B01J35/1019 ,  B01J35/1061 ,  B01J37/0018 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/0215 ,  B01J37/0236 ,  B01J37/024 ,  B01J37/08 ,  B01J37/086 ,  B01J37/088 ,  B01J37/20 ,  B01J37/28 ,  B01J2523/00 ,  C10G45/08 ,  B01J2523/31 ,  B01J2523/51 ,  B01J2523/68 ,  B01J2523/845 ,  B01J2523/847

Abstract: Process for preparing a hydrotreating catalyst comprising of from 5 wt % to 50 wt % of molybdenum, of from 0.5 wt % to 20 wt % of cobalt, and of from 0 to 5 wt % of phosphorus, all based on total dry weight of catalyst, which process comprises (a) treating a nickel containing carrier with molybdenum, cobalt and of from 1 to 60% wt of gluconic acid, based on weight of carrier, and optionally phosphorus, (b) optionally drying the treated carrier at a temperature of from 40 to 200° C., and (c) calcining the treated and optionally dried carrier at a temperature of from 200 to 650° C. to obtain the calcined treated carrier.