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    VERFAHREN ZUR HERSTELLUNG VON PORÖSEN METALLORGANISCHEN GERÜSTMATERIALIEN
    71.
    发明授权
    VERFAHREN ZUR HERSTELLUNG VON PORÖSEN METALLORGANISCHEN GERÜSTMATERIALIEN 有权
    VERFAHREN ZUR HERSTELLUNG VONPORÖSENMETALLORGANISCHENGERÜSTMATERIALIEN

    公开(公告)号：EP2027307B1

    公开(公告)日：2009-11-04

    申请号：EP07729006.2

    申请日：2007-05-11

    Applicant: BASF SE

    Inventor： PÜTTER, Hermann ,  SCHUBERT, Markus ,  RICHTER, Ingo ,  MÜLLER, Ulrich ,  TRUKHAN, Natalia

    IPC: C25B3/12

    CPC classification number: C25B3/12

    Abstract: The present invention relates to a process for preparing a porous metal organic framework comprising at least two organic compounds coordinated to at least one metal ion, which comprises the steps (a) oxidation of at least one anode containing metal corresponding to the at least one metal ion in a reaction medium in the presence of at least a first organic compound, where the first organic compound is an optionally substituted monocyclic, bicyclic or polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbons are replaced by heteroatoms selected from the group consisting of N, O and S, to form a reaction intermediate containing at least one metal ion and the first organic compound; and (b) reaction of the reaction intermediate at a prescribed temperature with an at least second organic compound which coordinates to the at least one metal ion, where the second organic compound is derived from a dicarboxylic, tricarboxylic or tetracarboxylic acid.

    Abstract translation: 本发明涉及制备包含至少两种与至少一种金属离子配位的有机化合物的多孔金属有机骨架的方法，该方法包括以下步骤：（a）氧化至少一种含有对应于至少一种金属 离子在至少第一有机化合物存在下在反应介质中反应，其中第一有机化合物是任选取代的单环，双环或多环饱和或不饱和烃，其中至少两个环碳被选自以下的杂原子替代： 的N，O和S，以形成含有至少一种金属离子和第一有机化合物的反应中间体; 和（b）使反应中间体在规定温度下与配位于至少一种金属离子的至少第二种有机化合物反应，其中第二种有机化合物衍生自二羧酸，三羧酸或四羧酸。

    VERFAHREN ZUR HERSTELLUNG VON PROPEN AUS PROPAN
    74.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON PROPEN AUS PROPAN 审中-公开

    公开(公告)号：EP2010470A2

    公开(公告)日：2009-01-07

    申请号：EP07726856.3

    申请日：2007-03-13

    Applicant: BASF SE

    Inventor： SCHUBERT, Markus ,  MÜLLER, Ulrich ,  KIENER, Christoph ,  TEICH, Friedhelm ,  CRONE, Sven ,  SIMON, Falk ,  PASTRE, Jörg

    IPC: C07C7/12 ,  C07C7/13

    CPC classification number: C07C5/333 ,  C07C7/12 ,  C07C7/13 ,  C07C11/06

    Abstract: The invention relates to a method for producing propene from propane. Said method comprises the following steps: A) a feed gas stream (a) containing propane is prepared; B) the feed gas stream (a) containing propane, is introduced with optionally water vapour and optionally, an oxygen-containing gas stream into a dehydrogenation zone and then the propane is dehydrogenated to form propene, and a product gas stream (b) containing propane, propene, methane, ethane, ethene, hydrogen, optionally carbon monoxide, carbon dioxide, water vapour and oxygen, is obtained; C) the product gas stream (b) is cooled, optionally compressed and then water vapour is separated by condensation and a product gas stream (c) depleted in water vapour is obtained; D) the product gas stream (c) is brought into contact with a selectively active adsorber which selectively adsorbs propene in the selected adsorption conditions, and an adsorber charged with propene and a gas stream (d2) depleted in propene and containing propane, methane, ethane, ethene and hydrogen, carbon monoxide and carbon dioxide are obtained; E) a gas stream (e1) containing propene is released from the adsorber charged with propene by reducing the pressure and/or heat of the adsorber.

    Abstract translation: 本发明涉及一种由丙烷生产丙烯的方法。 所述方法包括以下步骤：A）制备含有丙烷的进料气流（a）; B）将含有丙烷的进料气流（a）与任选的水蒸气和任选的含氧气流一起引入脱氢区，然后将丙烷脱氢以形成丙烯，并且产物气流（b）含有 丙烷，丙烯，甲烷，乙烷，乙烯，氢气，任选的一氧化碳，二氧化碳，水蒸气和氧气; C）冷却产物气流（b），任选压缩，然后通过冷凝分离水蒸气，并获得贫含水蒸气的产物气流（c）; D）使产物气流（c）与在选择的吸附条件下选择性吸附丙烯的选择性吸附剂接触，以及装载丙烯和贫丙烯气体流（d2）并含有丙烷，甲烷， 乙烷，乙烯和氢气，得到一氧化碳和二氧化碳; E）通过降低吸附器的压力和/或热量，从装有丙烯的吸附器释放含有丙烯的气流（e1）。

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