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14 条记录 (耗时 0.011 秒)

    CATALYTIC DEHYDRATION OF ALCOHOLS USING NON-VOLATILE ACID CATALYSTS
    6.
    发明公开
    CATALYTIC DEHYDRATION OF ALCOHOLS USING NON-VOLATILE ACID CATALYSTS 审中-公开
    醇的非挥发酸催化剂的催化脱氢

    公开(公告)号：EP2480520A1

    公开(公告)日：2012-08-01

    申请号：EP10819193.3

    申请日：2010-07-29

    申请人： Signa Chemistry, Inc.

    发明人： LEFENFELD, Michael ,  HOCH, Robert

    IPC分类号： C07C1/00 ,  C07C37/00

    CPC分类号： C07C1/24 ,  C07C2529/40 ,  C07C2529/83 ,  C07C2529/84 ,  C07C2529/85 ,  Y02P20/127 ,  C07C11/04 ,  C07C11/02

    摘要： A catalytic process for dehydration of an aliphatic C
    2 -C
    6 alcohol to its corresponding olefin is disclosed, The process continuously (lows through a reaction zone a liquid phase containing an aliphatic C
    2 -C
    6 alcohol to contact a non-volatile acid catalyst at a reaction temperature and pressure to at least partially convert the aliphatic C
    2 -C
    6 alcohol in the liquid phase to its corresponding olefin. The reaction pressure is greater than atmospheric pressure and the reaction temperature is above the boiling point of the olefin at reaction pressure, but below the critical temperature of the alcohol, and the olefin product is substantially in the gaseous phase. After the contacting step, the olefin containing gaseous phase is separated from the liquid phase. The invention also relates to catalytic processes such as a hydrolysis of an olefin to an alcohol, an esterification, a transesterification, a polymerization, an aldol condensation or an ester hydrolysis.

    TREATMENT OF ALKALI SILICA GEL AND ALKALI POROUS METAL OXIDE COMPOSITIONS
    7.
    发明公开
    TREATMENT OF ALKALI SILICA GEL AND ALKALI POROUS METAL OXIDE COMPOSITIONS 审中-公开
    碱性硅胶和碱性多孔金属氧化物组合物的处理

    公开(公告)号：EP2970337A1

    公开(公告)日：2016-01-20

    申请号：EP14767597.9

    申请日：2014-03-14

    申请人： Signa Chemistry, Inc. ,  Board Of Trustees Of Michigan State University

    发明人： LEFENFELD, Michael ,  DYE, James

    IPC分类号： C07F1/00 ,  B01J23/04 ,  B01J21/08

    CPC分类号： B01J37/14 ,  B01J21/08 ,  B01J23/04 ,  B01J33/00

    摘要： A method for treating Group 1 metal/silica gel compositions that are pyrophoric is provided to convert them into Group 1 metal/silica gel compositions that are no longer pyrophoric. A method for treating Group 1 metal/porous metal oxide compositions that are pyrophoric is provided to convert them into Group 1 metal/porous metal oxide compositions that are no longer pyrophoric. The pyrophoric Group 1 metal/silica gel composition or the pyrophoric Group 1 metal/porous metal oxide composition is treated with a low amount of dry oxygen or low concentration of dry oxygen mixture to convert them into compositions that are no longer pyrophoric or reactive with dry oxygen or air.

    摘要翻译： 提供一种处理引火的第1族金属/硅胶组合物的方法，以将它们转化为不再是引火的第1族金属/硅胶组合物。 提供用于处理发火的第1族金属/多孔金属氧化物组合物的方法，以将它们转化为不再发火的第1族金属/多孔金属氧化物组合物。 用少量的干氧或低浓度的干氧混合物处理引火第1族金属/硅胶组合物或引火第1族金属/多孔金属氧化物组合物，以将其转化为不再具有引火或与干燥反应的组合物 氧气或空气。

    HYDROGEN GENERATION SYSTEMS AND METHODS UTILIZING SODIUM SILICIDE AND SODIUM SILICA GEL MATERIALS
    8.
    发明公开
    HYDROGEN GENERATION SYSTEMS AND METHODS UTILIZING SODIUM SILICIDE AND SODIUM SILICA GEL MATERIALS 有权
    制氢系统并具有NATRIUMSILICID程序

    公开(公告)号：EP2414096A1

    公开(公告)日：2012-02-08

    申请号：EP10759306.3

    申请日：2010-03-30

    申请人： Signa Chemistry, Inc.

    发明人： WALLACE, Andrew, P. ,  MELACK, John ,  LEFENFELD, Michael

    IPC分类号： B01J7/00

    CPC分类号： B01J7/02 ,  C01B3/06 ,  C01B3/065 ,  H01M8/0606 ,  Y02E60/324 ,  Y02E60/362

    摘要： Systems, devices, and methods combine reactant materials and aqueous solutions to generate hydrogen. The reactant materials can sodium suicide or sodium silica gel. The hydrogen generation devices are used in fuels cells and other industrial applications. One system combines cooling, pumping, water storage, and other devices to sense and control reactions between reactant materials and aqueous solutions to generate hydrogen. Multiple inlets of varied placement geometries deliver aqueous solution to the reaction. The reactant materials and aqueous solution are churned to control the state of the reaction. The aqueous solution can be recycled and returned to the reaction. One system operates over a range of temperatures and pressures and includes a hydrogen separator, a heat removal mechanism, and state of reaction control devices. The systems, devices, and methods of generating hydrogen provide thermally stable solids, near-instant reaction with the aqueous solutions, and a non-toxic liquid by-product.