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    VERFAHREN ZUR HERSTELLUNG VON ALKALIMETALL−DIALKYLAMIDEN
    2.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON ALKALIMETALL−DIALKYLAMIDEN 有权
    用于生产碱金属 - 烷基酰胺

    公开(公告)号：EP1451141A2

    公开(公告)日：2004-09-01

    申请号：EP02798307.1

    申请日：2002-11-08

    申请人： BASF AKTIENGESELLSCHAFT

    发明人： STEINBRENNER, Ulrich ,  BÖHLING, Ralf ,  FUNKE, Frank ,  HARDER, Wolfgang

    IPC分类号： C07C209/00 ,  C07C211/65

    CPC分类号： C07C209/00 ,  C07C211/65

    摘要： The present invention relates to a method for producing dialkylamides of the alkali metals by reacting the corresponding dialkylamine with the corresponding alkali metal in the presence of an electron donor substance of the group 1,3-butadiene, isoprene, naphthalene and/or styrene with the formation of low quantities of butenyl dialkylamine. According to said method, the corresponding alkali metal is introduced and suspended in a solvent and the dialkylamine and the electron donor substance are added, such that the dialkylamine is present in an amount up to 45 wt. %, preferably up to 25 wt. %, in particular up to 15 wt. % and the butadiene is present in an amount up to 5 wt. %, preferably up to 3 wt. %, in particular up to 1.5 wt. %.

    VERFAHREN ZUR HERSTELLUNG VON ALKOHOLEN UND/ODER ALDEHYDEN
    6.
    发明授权
    VERFAHREN ZUR HERSTELLUNG VON ALKOHOLEN UND/ODER ALDEHYDEN 失效
    用于生产醇类和/或醛

    公开(公告)号：EP0750602B1

    公开(公告)日：1998-08-19

    申请号：EP95912212.8

    申请日：1995-03-06

    申请人： BASF AKTIENGESELLSCHAFT

    发明人： KNEUPER, Heinz-Josef ,  ARON, Maik ,  KORGITZSCH, Frank-Michael ,  NILLES, Michael ,  HARDER, Wolfgang ,  RÖPER, Michael ,  PACIELLO, Rocco

    IPC分类号： C07C45/50 ,  C07C27/22 ,  C07C29/16 ,  C07C47/02

    CPC分类号： B01J31/20 ,  B01J23/464 ,  B01J31/181 ,  B01J31/1815 ,  B01J31/1825 ,  B01J31/183 ,  B01J31/4046 ,  B01J2231/321 ,  B01J2531/822 ,  C07C29/141 ,  C07C29/16 ,  C07C45/50 ,  C07C45/80 ,  C07C51/235 ,  C07C209/00 ,  Y02P20/584 ,  C07C31/125 ,  C07C47/02

    摘要： A process for producing aldehydes by the hydroformylation of olefins with more than 3 carbon atoms, comprising the hydroformylation stage by means of a rhodium catalyst uniformly dissolved in the reaction medium, the separation of the rhodium catalyst from the product from the hydroformylation reaction and its return to the hydroformylation stage, in which the rhodium catalyst is extracted into the aqueous phase by means of an aqueous solution of a nitrogen-containing complexing agent from the group of sulphonated pyridines, sulphonated quinolines, possibly substituted sulphonated or sulphonated component-containing 2,2' bipyridines, 1,10 phenanthrolines, 1,1' biquinolines, 2,2', 6', 2'' terpyridines and porphines, and/or from the group of carboxylated pyridines, carboxylated quinolines, possibly substituted, carboxylated or carboxylated substance-containing 2,2' bipyridines, 1,10 phenanthrolines, 2,2' biquinolines, 2,2', 6', 2'' terpyridines and porphines, and the alcohol and/or aldehyde is isolated and from the extracted hydroformylation product, the aqueous rodhium-containing extract is taken to a pre-carbonylation stage and subjected to a pre-carbonylation in said stage in the presence of a substantially water-soluble organic fluid and in the presence of carbon monoxide, synthesis gas or a carbon monoxide-containing gas mixture at a pressure of 50 to 100 bars and a temperature of 50 to 180 DEG C, the product from the pre-carbonylation stage is separated into an organic part containing the majority of the rhodium and an aqueous phase containing the complexing agents and the organic phase for the hydroformylation of the olefin is taken to the hydroformylation stage at 50 to 100 bars and a temperature of 50 to 180 DEG C.

    VERFAHREN ZUR HERSTELLUNG VON ALIPHATISCHEN ALPHA,OMEGA-AMINONITRILEN
    7.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON ALIPHATISCHEN ALPHA,OMEGA-AMINONITRILEN 失效
    VERFAHREN ZUR HERSTELLUNG VON ALIPHATIS​​CHEN ALPHA，OMEGA-AMINONITRILEN

    公开(公告)号：EP0800508A1

    公开(公告)日：1997-10-15

    申请号：EP95941718.0

    申请日：1995-12-16

    申请人： BASF AKTIENGESELLSCHAFT

    发明人： MELDER, Johann-Peter ,  SCHNURR, Werner ,  FLICK, Klemens ,  EBEL, Klaus ,  WITZEL, Tom ,  FISCHER, Rolf ,  HARDER, Wolfgang ,  REHFINGER, Alwin

    IPC分类号： B01J23 ,  B01J27 ,  B01J37 ,  C07B61 ,  C07C253 ,  C07C255

    CPC分类号： B01J23/8898 ,  B01J23/76 ,  B01J23/8892 ,  B01J37/0201 ,  C07C253/30 ,  C07C255/24

    摘要： Aliphatic alpha,omega-aminonitriles are prepared by partially hydrogenating aliphatic alpha,omega-dinitriles at an increased temperature and pressure in the presence of a solvent and a catalyst. The catalyst contains (a) a compound based on a metal selected from the group made up of nickel, cobalt, iron, ruthenium and rhodium; (b) 0.01 to 25 % by weight in relation to (a) of a promoter based on a metal selected from the group comprising of palladium, platinum, iridium, osmium, copper, silver, gold, chromium, molybdenum, tungsten, manganese, rhenium, zinc, cadmium, lead, aluminium, tin, phosphorus, arsenic, antimony, bismuth, silicium, titanium, zirconium and rare earth metals; and (c) 0 to 5 % by weight in relation to (a) of a compound based on an alkaline or alkaline-earth metal, provided that component (a) not be based on iron or iron and a metal selected from the group comprising cobalt, ruthenium and rhodium when (b) is a promoter based on a metal selected from the group comprising titanium, manganese, chromium and molybdenum. Moreover, when component (a) is a compound based only on ruthenium or on rhodium, ruthenium and rhodium, or nickel and rhodium, promoter (b) may be dispensed with.

    摘要翻译： 通过在溶剂和催化剂存在下在升高的温度和压力下部分氢化脂族α，ω-二腈来制备脂族α，ω-氨基腈。 该催化剂含有（a）基于选自镍，钴，铁，钌和铑的金属的化合物; （b）相对于（a）0.01至25重量％的基于选自钯，铂，铱，锇，铜，银，金，铬，钼，钨，锰， 铼，锌，镉，铅，铝，锡，磷，砷，锑，铋，硅，钛，锆和稀土金属; 和（c）相对于（a）基于碱或碱土金属的化合物为0-5重量％，条件是组分（a）不基于铁或铁以及选自 （b）是基于选自钛，锰，铬和钼的金属的促进剂时，钴，钌和铑。 此外，当组分（a）是仅基于钌或铑，钌和铑或者镍和铑的化合物时，可以省去助催化剂（b）。