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    VERFAHREN ZUR HERSTELLUNG VON FORMAMIDEN UND AMEISENSÄUREESTERN
    5.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON FORMAMIDEN UND AMEISENSÄUREESTERN 审中-公开
    用于生产甲酸酯和甲酰胺

    公开(公告)号：EP2736872A1

    公开(公告)日：2014-06-04

    申请号：EP12737838.8

    申请日：2012-07-24

    Applicant: BASF SE

    Inventor： SCHAUB, Thomas ,  PACIELLO, Rocco ,  PAZICKY, Marek ,  FACHINETTI, Giuseppe ,  PRETI, Debora

    IPC: C07C67/00 ,  C07C231/10 ,  C07C69/06 ,  C07C233/03

    CPC classification number: C07C67/00 ,  B01J21/063 ,  B01J23/52 ,  B01J31/0202 ,  B01J31/0237 ,  B01J31/0238 ,  B01J35/0013 ,  B01J35/006 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1023 ,  B01J2231/625 ,  C07C231/10 ,  C07C233/03 ,  C07C69/06

    Abstract: The invention relates to a method for producing carboxylic acid derivatives of general formula (1a): H-(C=0)-R (la), in which R is selected from the group comprising OR
    1 and NR
    2 R
    3 , wherein R
    1 is unsubstituted or at least monosubstituted C
    1 -C
    15 alkyl, C
    5 -C
    10 cycloalkyl, C
    5 -C
    10 heterocyclyl, C
    5 -C
    10 aryl, or C
    5 -C
    10 heteroaryl, wherein the substituents are selected from the group comprising C
    1 -C
    15 alkyl, C
    1 -C
    6 alkoxy, C
    5 -C
    10 cycloalkyl, and C
    5 -C
    10 aryl; R
    2 and R
    3 , independently of one another, are hydrogen or unsubstituted or at least monosubstituted C
    1 -C
    15 alkyl, C
    5 -C
    10 cycloalkyl, C
    5 -C
    10 heterocyclyl, C
    5 -C
    10 aryl, or C
    5 -C
    10 heteroaryl, wherein the substituents are selected from the group comprising C
    1 -C
    15 alkyl, C
    5 -C
    10 cycloalkyl, and C
    5 -C
    10 aryl, or R
    2 and R
    3 form a five- or six-membered ring together with the nitrogen atom, which ring optionally additionally contains one or more heteroatoms selected from O, S, and N, which heteroatom bears the substituent R
    4 , wherein R
    4 is hydrogen or C
    1 -C
    6 alkyl; by reacting a reaction mixture (Rg) containing carbon dioxide, hydrogen, and an alcohol of general formula (Ib): R
    1 -OH (Ib), in which R
    1 has the aforementioned meanings, or an amine of general formula (Ic): NHR
    2 R
    3 (Ic), in which R
    2 and R
    3 , independently of each other, have the aforementioned meanings, in a hydrogenation reactor in the presence of a catalyst containing gold at a pressure in the range of 0.2 to 30 MPa and a temperature in the range of 20 to 200 °C.

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