-
1.发明公开PROCEDE DE FLUORATION D'UN COMPOSE COMPRENANT UN GROUPE HALOSULFONYLE OU DIHALOPHOSPHONYLE 有权方法氟化WITH A卤代磺酰基或DIHALOGENPHOSPHONYLGRUPPE连接
公开(公告)号：EP1347938A1
公开(公告)日：2003-10-01
申请号：EP01995764.6
申请日：2001-12-21
申请人： Hydro-Quebec , RHODIA CHIMIE
IPC分类号： C01B21/092 , C07C303/02 , H01M10/40 , C01B21/093 , C01B21/097
CPC分类号： C07C303/36 , C01B21/0935 , C01B21/097 , H01M10/052 , H01M10/0568 , C07C311/48
摘要： The invention concerns a fluorination method for obtaining fluorinated compounds. The method consists in reacting with an ionic fluoride of a monovalent cation a compound of formula (I), wherein: M represents H, an alkaline metal, a quaternary phosphonium group or a quaternary ammonium group; Y represents SO2, and m is 1, or Y is PO and m is 2; Z represents CR2, N or P; R1 represents a carbonaceous and/or electron-attracting group which has a Hammet parameter σ¿P? higher than 0.4; R?2¿ represents a carbonaceous and/or electron-attracting group; X represents a halogen other than a fluorine. The fluorinated compounds obtained are useful in particular as electrolyte in lithium batteries.
-
公开(公告)号：EP0889863A2
公开(公告)日：1999-01-13
申请号：EP97951051.0
申请日：1997-12-30
IPC分类号： C07D233 , B01J31 , C01B31 , C04B41 , C07B37 , C07B41 , C07B61 , C07C45 , C07C67 , C07C255 , C07C257 , C07C309 , C07C311 , C07C317 , C07D207 , C07D213 , C07D219 , C07D231 , C07D239 , C07D241 , C07D249 , C07D251 , C07D253 , C07D277 , C07D279 , C07D285 , C07D303 , C07D307 , C07D311 , C07D319 , C07D333 , C07D405 , C07D407 , C07D409 , C07D417 , C07D487 , C07F1 , C07F7 , C07F9 , C07F11 , C07F15 , C07F17 , C08F2 , C08F4 , C08F12 , C08F16 , C08F216 , C08F222 , C08F228 , C08G59 , C08G65 , C08G73 , C08G75 , C08G77 , C08G85 , C08J3 , C08J7 , C08L101 , C09B47 , C09B57 , C09B69 , C09C1 , C09C3 , C09D11 , G02F1 , H01B1 , H01B3 , H01G9 , H01M4 , H01M6 , H01M10
CPC分类号： B01J31/0224 , B01J31/0215 , B01J31/0222 , B01J31/0225 , B01J31/0227 , B01J31/0235 , B01J31/0239 , B01J31/0247 , B01J31/0251 , B01J31/0252 , B01J31/0267 , B01J31/0271 , B01J31/0281 , B01J31/0288 , B01J31/0289 , B01J31/04 , B01J31/06 , B01J31/068 , B01J31/124 , B01J31/1815 , B01J31/2208 , B01J2231/122 , B01J2231/14 , B01J2231/326 , B01J2231/341 , B01J2231/348 , B01J2231/4205 , B01J2231/543 , B01J2531/35 , B01J2531/824 , C07B37/02 , C07B37/12 , C07C45/46 , C07C45/69 , C07C67/00 , C07C255/10 , C07C255/17 , C07C255/27 , C07C255/46 , C07C255/65 , C07C257/14 , C07C311/03 , C07C311/04 , C07C311/09 , C07C311/48 , C07C317/04 , C07C317/08 , C07C317/14 , C07C317/22 , C07C317/24 , C07C317/34 , C07C317/44 , C07C2601/10 , C07C2602/42 , C07D207/452 , C07D213/76 , C07D219/10 , C07D231/18 , C07D233/90 , C07D239/60 , C07D241/42 , C07D249/04 , C07D249/10 , C07D249/12 , C07D251/70 , C07D277/64 , C07D277/82 , C07D285/125 , C07D285/135 , C07D285/15 , C07D285/16 , C07D303/34 , C07D307/54 , C07D307/64 , C07D311/52 , C07D311/58 , C07D311/82 , C07D319/06 , C07D333/16 , C07D333/24 , C07D405/06 , C07D409/12 , C07D417/10 , C07D417/14 , C07F17/02 , C08F4/04 , C08G65/3344 , C09B69/00 , C09B69/02 , C09B69/10 , G02F1/1525 , G02F2001/151 , H01B1/122 , H01B1/128 , H01G9/022 , H01G9/038 , H01G11/02 , H01G11/62 , H01M4/00 , H01M4/02 , H01M4/131 , H01M4/133 , H01M4/134 , H01M4/382 , H01M4/405 , H01M4/48 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/5815 , H01M4/5825 , H01M4/60 , H01M4/625 , H01M4/661 , H01M6/00 , H01M6/04 , H01M6/164 , H01M6/166 , H01M6/168 , H01M6/181 , H01M6/183 , H01M10/052 , H01M10/0525 , H01M10/0565 , H01M10/0567 , H01M10/0568 , Y02E60/13 , Y10S430/127 , Y10T29/49108 , Y10T428/2918 , C07C49/84 , C07C49/553
摘要： Disclosed is a method for grafting a polymer onto the surface of a carbonate material with carboxyl, amine, and/or hydroxyl functions on its surface. Said material is placed in suspension in a solution including the polymer to be grafted, which has a carboxyl, amine, and/or hydroxyl function, said solution also being comprised of a polymer solvent. A process which stimulates the dehydration into a carboxyl function of an amine and/or hydroxyl function is then performed, and the polymer is grafted onto the carbonate material using ester or amide links. The invention can be used in the cathode or naode of an electrochemical generator, in polymer materials with low polar properties, in ink, and also as a conductive coating on flexible plastic used as an electrical contact, as electromagnetic shielding, or as static protection.
摘要翻译： 电池具有包含溶剂的电解质和包含氢氧化物，亚硝鎓，铵，金属，有机或有机金属阳离子和5元（杂）环阴离子的盐（I）。 电池具有包含溶剂的电解质和包含氢氧化物，亚硝鎓，铵，金属，有机或有机金属阳离子的盐（I）和具有下式的5元（杂）环阴离子：[图像] X1-X5-N =（ - ） - ， - （ - ） - （ - ） - （ - ） - （ - ） - =，条件是不超过四个包括N，不超过两个包括S（不相邻），不超过一个包含P; Q'，Q：1-8C全卤代烷基，全卤代烯基或任选取代的6-12C芳基或芳烷基，各自任选含有O，S或N杂原子; 任选被卤素和/或醚取代的烷基，烯基，芳基，芳烷基，烷基芳基，烯基芳基，脂环族或杂环基，硫醚，胺，亚胺，酰胺，羧基，羰基，异氰酸酯，异硫氰酸酯和羟基; 具有含有杂原子的环和/或取代基的芳族基团; 聚合物组; 或具有一个或多个阳离子和/或阴离子离子基团的基团; Y：H，F，Cl，Br，CN，SCN，NCS，NCO，NO2，全氟烷基，全氟烷氧基，全氟烷基甲基，四氟乙氧基，SCF3，全氟烷硫基，四氟乙硫基，三氟乙氧基，三氟乙硫基，SO2F，SO2Q，COOQ，QN-SO2- ）或COQ; CN，CO 2，SCN，N 3，三氟乙烯基氧基，（1-12C全氟烷基）甲基，氟代烷氧基，氟烷基硫代，烷基，烯基， 氧杂烷基，氧杂链烯基，氮杂烷基，氮杂链烯基，硫杂烷基，硫杂链烯基，聚合基团和具有一个或多个阳离子和/或阴离子离子基团的基团; 或者，Y，Q，Q'和Q中的两个可以形成4-至8-元环，或者Y和Q中的一个是连接到第二个5元（杂）环阴离子上的多价基团，或Y中的一个 Q是聚合物的重复单元; 条件是至少一个Y或Q包含离解偶极子。
-
3.发明授权
公开(公告)号：EP0973734B1
公开(公告)日：2003-06-04
申请号：EP99903551.2
申请日：1999-01-29
申请人： HYDRO-QUEBEC
发明人： MICHOT, Christophe , ARMAND, Michel
IPC分类号： C07C311/48 , C07C317/00 , C07C317/18 , C07C317/22 , C07D317/42 , C08F14/18 , C08F16/32 , C25B9/00 , H01M8/10 , C07B61/00
CPC分类号： H01M8/1072 , C07C311/48 , C07C317/18 , C07C317/22 , C08F16/32 , C08J5/2237 , C08J2327/12 , C25B13/08 , H01M8/0289 , H01M8/1023 , H01M8/1039 , Y02P70/56
-
公开(公告)号：EP0973809A1
公开(公告)日：2000-01-26
申请号：EP99902478.9
申请日：1999-01-29
申请人： HYDRO-QUEBEC
发明人： MICHOT, Christophe , ARMAND, Michel
CPC分类号： C08J5/225 , C08F8/44 , C08F214/18 , C08J5/2218 , C08J2327/12
摘要： The invention concerns cross-linked sulphonated polymers, optionally perfluorinated, and the method for preparing them. When they are moulded in the form of membranes, said polymers are useful in electrochemical cells, in a chlorine-sodium electrolysis process, as separator in en electrochemical preparation of organic and inorganic compounds, as separator between an aqueous phase and an organic phase, or as catalyst for Diels-Alder additions, Friedel-Craft reactions, aldol condensations, cationic polymerisation, esterification, and acetal formation.
-
5.发明授权PROCEDE DE FLUORATION D'UN COMPOSE COMPRENANT UN GROUPE HALOSULFONYLE OU DIHALOPHOSPHONYLE 有权方法氟化WITH A卤代磺酰基或DIHALOGENPHOSPHONYLGRUPPE连接
公开(公告)号：EP1347938B1
公开(公告)日：2012-03-07
申请号：EP01995764.6
申请日：2001-12-21
申请人： HYDRO-QUEBEC
IPC分类号： C01B21/092 , C07C303/02 , H01M10/50 , C01B21/093 , C01B21/097
CPC分类号： C07C303/36 , C01B21/0935 , C01B21/097 , H01M10/052 , H01M10/0568 , C07C311/48
摘要： The invention concerns a fluorination method for obtaining fluorinated compounds. The method consists in reacting with an ionic fluoride of a monovalent cation a compound of formula (I), wherein: M represents H, an alkaline metal, a quaternary phosphonium group or a quaternary ammonium group; Y represents SO2, and m is 1, or Y is PO and m is 2; Z represents CR2, N or P; R1 represents a carbonaceous and/or electron-attracting group which has a Hammet parameter σ¿P? higher than 0.4; R?2¿ represents a carbonaceous and/or electron-attracting group; X represents a halogen other than a fluorine. The fluorinated compounds obtained are useful in particular as electrolyte in lithium batteries.
-
公开(公告)号：EP0973809B1
公开(公告)日：2004-04-28
申请号：EP99902478.9
申请日：1999-01-29
申请人： HYDRO-QUEBEC
发明人： MICHOT, Christophe , ARMAND, Michel
CPC分类号： C08J5/225 , C08F8/44 , C08F214/18 , C08J5/2218 , C08J2327/12
摘要： The invention concerns cross-linked sulphonated polymers, optionally perfluorinated, and the method for preparing them. When they are moulded in the form of membranes, said polymers are useful in electrochemical cells, in a chlorine-sodium electrolysis process, as separator in en electrochemical preparation of organic and inorganic compounds, as separator between an aqueous phase and an organic phase, or as catalyst for Diels-Alder additions, Friedel-Craft reactions, aldol condensations, cationic polymerisation, esterification, and acetal formation.
-
7.发明公开
公开(公告)号：EP0973734A1
公开(公告)日：2000-01-26
申请号：EP99903551.2
申请日：1999-01-29
申请人： HYDRO-QUEBEC
发明人： MICHOT, Christophe , ARMAND, Michel
IPC分类号： C07C311/48 , C07C317/00 , C07C317/18 , C07C317/22 , C07D317/42 , C08F14/18 , C08F16/32 , C25B9/00 , H01M8/10 , C07B61/00
CPC分类号： H01M8/1072 , C07C311/48 , C07C317/18 , C07C317/22 , C08F16/32 , C08J5/2237 , C08J2327/12 , C25B13/08 , H01M8/0289 , H01M8/1023 , H01M8/1039 , Y02P70/56
摘要： The invention concerns novel ion-exchanging membranes, the method for preparing them and their uses. The membranes are made up of a polymer obtained from a monomer or a bifunctional mixture of monomers of general formula [T-SO2-Y-SO2T']- M-+. Moreover said polymers are useful in electrochemical cells, in a chlorine-sodium electrolysis process, as separator in an electrochemical preparation of organic and inorganic compounds, as separator between an aqueous phase and an organic phase, or as catalyst for Diels-Alder additions, Friedel-Craft reactions, aldol condensations, cationic polymerisation, and acetal formation.
-
公开(公告)号：EP0890176A1
公开(公告)日：1999-01-13
申请号：EP97951052.0
申请日：1997-12-30
IPC分类号： C07D233 , B01J31 , C01B31 , C04B41 , C07B37 , C07B41 , C07B61 , C07C45 , C07C67 , C07C255 , C07C257 , C07C309 , C07C311 , C07C317 , C07D207 , C07D213 , C07D219 , C07D231 , C07D239 , C07D241 , C07D249 , C07D251 , C07D253 , C07D277 , C07D279 , C07D285 , C07D303 , C07D307 , C07D311 , C07D319 , C07D333 , C07D405 , C07D407 , C07D409 , C07D417 , C07D487 , C07F1 , C07F7 , C07F9 , C07F11 , C07F15 , C07F17 , C08F2 , C08F4 , C08F12 , C08F16 , C08F216 , C08F222 , C08F228 , C08G59 , C08G65 , C08G73 , C08G75 , C08G77 , C08G85 , C08J3 , C08J7 , C08L101 , C09B47 , C09B57 , C09B69 , C09C1 , C09C3 , C09D11 , G02F1 , H01B1 , H01B3 , H01G9 , H01M4 , H01M6 , H01M10
CPC分类号： B01J31/0224 , B01J31/0215 , B01J31/0222 , B01J31/0225 , B01J31/0227 , B01J31/0235 , B01J31/0239 , B01J31/0247 , B01J31/0251 , B01J31/0252 , B01J31/0267 , B01J31/0271 , B01J31/0281 , B01J31/0288 , B01J31/0289 , B01J31/04 , B01J31/06 , B01J31/068 , B01J31/124 , B01J31/1815 , B01J31/2208 , B01J2231/122 , B01J2231/14 , B01J2231/326 , B01J2231/341 , B01J2231/348 , B01J2231/4205 , B01J2231/543 , B01J2531/35 , B01J2531/824 , C07B37/02 , C07B37/12 , C07C45/46 , C07C45/69 , C07C67/00 , C07C255/10 , C07C255/17 , C07C255/27 , C07C255/46 , C07C255/65 , C07C257/14 , C07C311/03 , C07C311/04 , C07C311/09 , C07C311/48 , C07C317/04 , C07C317/08 , C07C317/14 , C07C317/22 , C07C317/24 , C07C317/34 , C07C317/44 , C07C2601/10 , C07C2602/42 , C07D207/452 , C07D213/76 , C07D219/10 , C07D231/18 , C07D233/90 , C07D239/60 , C07D241/42 , C07D249/04 , C07D249/10 , C07D249/12 , C07D251/70 , C07D277/64 , C07D277/82 , C07D285/125 , C07D285/135 , C07D285/15 , C07D285/16 , C07D303/34 , C07D307/54 , C07D307/64 , C07D311/52 , C07D311/58 , C07D311/82 , C07D319/06 , C07D333/16 , C07D333/24 , C07D405/06 , C07D409/12 , C07D417/10 , C07D417/14 , C07F17/02 , C08F4/04 , C08G65/3344 , C09B69/00 , C09B69/02 , C09B69/10 , G02F1/1525 , G02F2001/151 , H01B1/122 , H01B1/128 , H01G9/022 , H01G9/038 , H01G11/02 , H01G11/62 , H01M4/00 , H01M4/02 , H01M4/131 , H01M4/133 , H01M4/134 , H01M4/382 , H01M4/405 , H01M4/48 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/5815 , H01M4/5825 , H01M4/60 , H01M4/625 , H01M4/661 , H01M6/00 , H01M6/04 , H01M6/164 , H01M6/166 , H01M6/168 , H01M6/181 , H01M6/183 , H01M10/052 , H01M10/0525 , H01M10/0565 , H01M10/0567 , H01M10/0568 , Y02E60/13 , Y10S430/127 , Y10T29/49108 , Y10T428/2918 , C07C49/84 , C07C49/553
摘要： Disclosed is a proton conductor in liquid form, comprised of a mixture of the following components: (a) a salt combined with a nitrogenated base along with an acid, according to formula (I), wherein Z1, Z2, Z3, and Z4, whether identical or different, represent a group -N= or -C(Zi)=, wherein Zi represents a hydrogen atom, a linear or branched alkyl radical with from 1 to 20 carbon atoms, a fluoroalkyl radical with from 1 to 20 carbon atoms, or an oxoalkyl or azaalkyl radical with from 1 to 20 carbon atoms, as long as at least one and at most two of the groups Z1, Z2, Z3, and Z4 represent -N=; two adjacent carbon atoms are possibly hydrogenated; the nitrogenated base possibly forms part of a polymeric matrix; and X- represents an anion derivative of an acid selected from the group formed by the sulphonic acids of the formula R?FSO3H, the sulphonimides of the formula (RFSO2) (R'FSO2)NH and the methylures of the formula (RFSO2) (R'FSO2)CH2 or (RFSO2) (R'FSO2) (R'FSO2)CH, wherein RF, R'F or R'F independently represent a radical F(CF2)n-, n being comprised between 0 and 6, and the acid possibly forming part of a polymeric matrix; and (b) a nitrogenated base according to formula (II), wherein Z1, Z2, Z3, and Z4 have the above-mentioned significance, and the nitrogenated base is possibly part of a polymeric matrix. The components (a) and (b) are present in proportions allowing for the formation of a composition with a melting point of less than 25 °C. The proton conductor disclosed in the invention can be used as a liquid, gel, or polymer electrolyte in various electrochemical systems.
-
9.发明公开
公开(公告)号：EP0699349A1
公开(公告)日：1996-03-06
申请号：EP95914390.0
申请日：1995-03-21
CPC分类号： H01G9/038 , C01B21/0935 , C07C307/00 , H01B1/122 , H01G11/20 , H01G11/56 , H01M6/181 , H01M10/052 , H01M10/0525 , H01M10/0565 , H01M10/0567 , H01M10/0568 , H01M10/0569 , Y02E60/13
摘要： An ionic conducting material, the preparation thereof and uses of said material are disclosed. The material includes at least one solution of at least one ionic compound in an aprotic solvent, which compound is selected from compounds (1/mM)+[(ZY)2N]-, (1/mM)+[(ZY)3C]-, (1/mM)+[(ZY)2CQ]-, Wherein Y is SO¿2? or POZ; Q is -H, -COZ or Z; each substituent Z is independently a fluorine atom or an optionally perfluorinated organic group optionally having at least one polymerisable function, one of substitutents Z being a fluorine atom; and M is a cation. The material is useful in electrochemical generators, supercapacitors, polymer doping and electrochromic devices.
-
10.发明公开
公开(公告)号：EP1933966A1
公开(公告)日：2008-06-25
申请号：EP06775050.5
申请日：2006-07-28
申请人： HYDRO-QUEBEC
发明人： ZAGHIB, Karim , JALBERT, Jocelyn , GUERFI, Abdelbast , MICHOT, Christophe , GAUTHIER, Michel , DONTIGNY, Martin , CHAREST, Patrick
CPC分类号： H01M10/4242 , B01D15/00 , H01M10/0565 , H01M10/0566 , H01M2300/0085
摘要： The invention relates to a method of purifying an ionic electrolyte containing at least one alkaline earth salt, said method comprising at least one contact step involving particles of at least one calcium salt. The inventive method can be used to obtain novel electrolytes which are especially characterised by the particularly-low water content thereof. The corresponding electrochemical generators that contain the electrolyte as a component are characterised by excellent stability and are very secure.
-
-
-
-
-
-
-
-
-
搜索结果
18 条记录 (耗时 0.02 秒)
