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1.发明公开METHOD FOR PRODUCING INTERNAL OLEFIN, INTERNAL OLEFIN MIXTURE, AND OIL DRILLING FLUID CONTAINING INTERNAL OLEFIN MIXTURE 有权用于制备内烯烃的方法，结构和内烯烃ÖLBOHRFLÜSSIGKEIT一个包含内烯烃混合物
公开(公告)号：EP1842840A1
公开(公告)日：2007-10-10
申请号：EP05844846.5
申请日：2005-12-28
IPC分类号： C07C5/25
CPC分类号： C09K8/34 , C07C5/2518 , C07C11/02
摘要： A method for producing an internal olefin by stably isomerizing an α-olefin by using an inexpensive zeolite catalyst while preventing an oligomerization reaction is provided. The method for producing an internal olefin comprises a step of isomerizing an α-olefin having from 16 to 18 carbon atoms by passing through a zeolite catalyst bed, wherein the α-olefin having from 16 to 18 carbon atoms is circulated through and brought into contact with the zeolite catalyst bed before starting the isomerization reaction.
摘要翻译： 一种用于通过使用便宜的，提供了预防到低聚反应，同时，以沸石催化剂在±烯烃稳定在异构化的内烯烃的制造方法。 在内部烯烃的制造方法包括：通过异构化穿过沸石催化剂床，worin具有16至18个碳原子的烯烃±通过循环并接触到±具有16至18个碳原子烯烃的步骤 与开始异构化反应之前床沸石催化剂。
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2.发明公开ADAMANTANE DERIVATIVE, COMPOSITION COMPRISING THE DERIVATIVE, AND OPTICAL AND ELECTRONIC MEMBER USING THE COMPOSITION 审中-公开金刚烷的衍生物，包括成分和光学和电子件，由它使用该组合物
公开(公告)号：EP1985617A1
公开(公告)日：2008-10-29
申请号：EP07707867.3
申请日：2007-02-01
IPC分类号： C07D303/30 , C07D305/06 , C08G59/24 , C08G65/18 , C07B61/00
CPC分类号： C07D303/30 , C07D305/06 , C08G59/24 , C08G59/42
摘要： To provide an adamantane derivative, a compound having an adamantane skeleton, compositions containing them that can provide a cured product having excellent optical properties such as transparency and light resistance, long-term heat resistance and electric characteristics such as dielectric permittivity, and optical electronic members using the compositions.
An adamantane derivative represented by the general formula (I), a compound with an adamantane skeleton represented by the general formula (VII) or (VIII), compositions containing them, and optical electronic members using the resin compositions. In the formulas, W represents, for example, a hydrogen atom, X represents, for example, a group represented by the general formula (II), Yrepresentsagrouprepresented by the formula (V) or (VI), R 1 represents a methyl group or an ethyl group, R 2 represents a C 1 to C 10 hydrocarbon group which may contain O or S, m is an integer of 2 to 4, k is an integer of 0 to (16-m) and p and q are each an integer of 1 to 5.摘要翻译： 以提供金刚烷衍生物，具有金刚烷骨架的化合物，含有它们的组合物也可提供具有优异的光学特性的固化产物：如透明度和耐光性，长期耐热性和电特性：如介电常数和光学电子部件 使用该组合物。 由通式（I）表示的金刚烷衍生物，具有金刚烷在骨架由通式（VII）或（VIII）表示，组合物含有它们，并使用该树脂组合物的光学电子部件的化合物。 在该式中，W darstellt，例如，氢原子，X darstellt，例如，由通式（II）表示的基团，由式（V）或（VI）Yrepresentsagrouprepresented中，R 1表示甲基或 乙基的，R 2表示C 1至C 10烃基，其可以含有O或S，m为2〜4的整数，k为0〜（16-M），p和q的整数各自在 的1至5整数
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3.发明公开
公开(公告)号：EP1985616A1
公开(公告)日：2008-10-29
申请号：EP07707083.7
申请日：2007-01-19
IPC分类号： C07D303/30 , C07C39/14 , C07D301/28 , C08G59/20 , G03F7/004
CPC分类号： C07C39/17 , C07C37/16 , C07C37/20 , C07C2603/74 , C07D301/28 , C07D303/30 , C08G59/24 , C08G59/4215 , C08G59/4223 , C08G59/621 , G03F7/038 , Y10T428/1073 , Y10T428/31511
摘要： Disclosed is an adamantane derivative which provides a cured product excellent in optical characteristics such as transparency and light resistance, long-term heat resistance, electrical characteristics such as and dielectric constant, and low water absorption. Also disclosed are a resin composition containing the adamantane derivative, a sealing agent for electronic circuits, optical electronic member, semiconductor device and copper-clad laminate all using the resin composition, and a radiation-sensitive resin composition which contains the above-mentioned adamantane derivative as a crosslinking agent. Specifically disclosed are an adamantane derivative represented by the formula (I-1) below, a resin composition containing the adamantane derivative, a sealing agent for electronic circuits, optical electronic member, semiconductor device and copper-clad laminate, all using the resin composition, and a radiation-sensitive resin composition which contains the above-mentioned adamantane derivative as a crosslinking agent.
摘要翻译： 公开的是提供具有优异的光学特性的固化产物的金刚烷衍生物：如透明度和耐光性，长期耐热性，电特性：如介电常数和，以及低吸水性。 所以游离缺失盘是含有金刚烷衍生物，用于电子电路，光学电子部件，半导体装置和包铜层压体的所有使用该树脂组合物的密封剂，并且其含有上述金刚烷衍生物的辐射敏感树脂组合物的树脂组合物 作为交联剂。 具体地说游离缺失盘是在由下式表示的金刚烷衍生物（I-1）所示，将含有金刚烷衍生物的树脂组合物，用于电子电路，光学电子部件，半导体装置和包铜层压板，所有使用该树脂组合物的密封剂， 且其含有作为交联剂的上述金刚烷衍生物的辐射敏感树脂组合物。
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4.发明公开
公开(公告)号：EP2014639A1
公开(公告)日：2009-01-14
申请号：EP07742063.6
申请日：2007-04-20
IPC分类号： C07C69/653 , C07C31/44 , C07C67/14 , C07D301/24 , C07D303/30 , C08L101/00 , G02B1/04 , G02B1/11
CPC分类号： C07C31/44 , C07C69/653 , C07C2603/74 , C07D301/24 , C07D305/06 , C08F220/24 , C08F222/1006
摘要： To provide a polymerizable group-containing and fluorine-containing adamantane derivative capable of affording a cured product having good heat resistance, good mechanical properties such as mar resistance and a low refractive index, a resin composition containing such a polymerizable group-containing adamantane derivative, and a fluorine-containing adamantane derivative which is useful as a reaction intermediate used for the production of the polymerizable group-containing and fluorine-containing adamantane derivative.
Specifically provided are a fluorine-containing adamantane derivative represented by the general formula (I) below, a polymerizable group-containing and fluorine-containing adamantane derivative represented by the general formula (II) below, and a resin composition containing such a polymerizable group-containing and fluorine-containing adamantane derivative. In the formula, R 1 and R 2 are each a hydrogen atom, for example, n is an integer of 0 or more, X 1 is a polymerizable group represented by the formula (III-a), for example, Y is a hydrogen atom, for example, s and t are each an integer of 1 to 15, and u is an integer of 0 to 14, with the proviso that s + t + u = 16.摘要翻译： 提供和含氟金刚烷衍生物能够得到具有良好耐热性的固化物的含有聚合性基团的，良好的机械性能：如耐擦伤性和低折射率，含寻求含聚合性基团的金刚烷衍生物的树脂组合物， 和含氟金刚烷衍生物所有作为中间体的反应用于生产含聚合性基团的含氟金刚烷衍生物的，这是有用。 下面具体地提供了由通式（I）表示的含氟金刚烷衍生物，含有聚合性基团和由下面的通式（II）表示的含氟金刚烷衍生物，和树脂组合物包含寻求可聚合基团 - 含有氟和含金刚烷衍生物。 氢在该式中，R 1和R 2各自为氢原子，对于实施例中，n是0以上的整数，X 1是由式（III-A）表示的聚合性基团，例如，Y是 核，例如，s和t各自为1至15的整数，u是0〜14的整数，前提条件做S + T + U = 16
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5.发明公开INTERNAL-OLEFIN COMPOSITION AND BASE OIL COMPRISING THE COMPOSITION FOR OIL DRILLING 审中-公开ZUSAMMENSETZUNG AUSINNENSTÄNDIGEMOLEFIN UND SIE ENTHALTENDESBASISÖLFÜRÖLBOHRUNGEN
公开(公告)号：EP1795572A1
公开(公告)日：2007-06-13
申请号：EP05781368.5
申请日：2005-09-02
IPC分类号： C09K8/32
CPC分类号： C09K8/32 , C10M105/04 , C10M2203/0206 , C10N2220/028 , C10N2220/10
摘要： The present invention provides an internal olefin composition comprising a mixture of 60 to 80% by mass of an olefin having 16 carbon atoms and 40 to 20% by mass of an olefin having 18 carbon atoms wherein a content of an α-olefin in the mixture is 10% by mass or less, and a content of a branched olefin in the mixture is 10% by mass or less, which has a good biodegradability even when discharged into the environments, a less toxicity against marine organisms, etc., and a sufficient fluidity when used as a base oil for oil drilling, etc.
摘要翻译： 本发明提供一种内部烯烃组合物，其含有60〜80质量％的碳原子数为16〜80的烯烃和40〜20质量％的碳原子数18的烯烃的混合物，其中混合物中的α-烯烃的含量 为10质量％以下，混合物中的支化烯烃的含量为10质量％以下，即使排出到环境中也具有良好的生物降解性，对海洋生物等的毒性小， 用作石油钻井等基础油时的充分流动性
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6.发明授权METHOD FOR PRODUCING INTERNAL OLEFIN, INTERNAL OLEFIN MIXTURE, AND OIL DRILLING FLUID CONTAINING INTERNAL OLEFIN MIXTURE 有权用于制备内烯烃的方法，结构和内烯烃ÖLBOHRFLÜSSIGKEIT一个包含内烯烃混合物
公开(公告)号：EP1842840B1
公开(公告)日：2016-05-04
申请号：EP05844846.5
申请日：2005-12-28
CPC分类号： C09K8/34 , C07C5/2518 , C07C11/02
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7.发明公开FLUORINE-CONTAINING ADAMANTANE DERIVATIVE, FLUORINE-CONTAINING ADAMANTANE DERIVATIVE HAVING POLYMERIZABLE GROUP, AND RESIN COMPOSITION CONTAINING SAME 审中-公开荧光素酶ADAMANTANDERIVAT，FLUORINHALTIGES ADAMANTANDERIVAT MIT POLYMERISIERBARER GRUPPE UND HARZZUSAMMENSETZUNG，DIE DEESESENTHÄLT
公开(公告)号：EP1950190A1
公开(公告)日：2008-07-30
申请号：EP06782702.2
申请日：2006-08-11
IPC分类号： C07C31/44 , C07C67/14 , C07C69/653 , C07D303/22 , C07D305/08 , C08F20/28 , G03F7/11 , H01L21/027
CPC分类号： C07D407/12 , C07C43/196 , C07C69/653 , C07C2603/74 , C07D303/28 , C08F222/1006 , G03F7/0007 , G03F7/091
摘要： Provided are a polymerizable group-containing and fluorine-containing adamantane derivative capable of affording a cured product having good heat resistance, good mechanical properties such as surface hardness and a low refractive index, a resin composition containing such a polymerizable group-containing adamantane derivative, and a fluorine-containing adamantane derivative which is useful as a reaction intermediate used for the production of the polymerizable group-containing and fluorine-containing adamantane derivative. Specifically provided are a fluorine-containing adamantane derivative represented by the general formula (I) below, a polymerizable group-containing and fluorine-containing adamantane derivative represented by the general formula (II) below, and a resin composition containing such a polymerizable group-containing and fluorine-containing adamantane derivative. In the formulas, X 1 and X 2 each represent OH or NH 2 , a, b and c each represent an integer of 0 or more and a + b + c ≥ 1, for example a = b = 0 and c = 1, Z 3 represents, for example, -C 2 H 4 -, s and t each represent an integer of 1 to 15, u represents an integer of 0 to 14, s + t + u = 16, for example s = 2, t = 14, u = 0, and X 3 represents, for example, -O-CO-CH=CH 2 .
摘要翻译： 提供能够提供具有良好耐热性，良好机械性能如表面硬度和低折射率的固化产物的含可聚合基团的含氟金刚烷衍生物，含有这种含聚合基团的金刚烷衍生物的树脂组合物， 和可用作制备含聚合基团的含氟金刚烷衍生物的反应中间体的含氟金刚烷衍生物。 具体地提供由以下通式（I）表示的含氟金刚烷衍生物，下述通式（II）表示的可聚合基团的含氟金刚烷衍生物和含有这样的可聚合基团的含氟金刚烷衍生物， 含氟和金属金刚烷衍生物。 在该式中，X 1和X 2分别表示OH或NH 2，a，b和c各自表示0以上的整数，a + b + c‰×1，例如a = b = 0，c = 1 Z 3表示例如-C 2 H 4 - ，s和t各自表示1〜15的整数，u表示0〜14的整数，s + t + u = 16，例如s = 2， t = 14，u = 0，X 3表示例如-O-CO-CH = CH 2。
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8.发明公开METHOD FOR PRODUCING 2-ADAMANTANOL AND 2-ADAMANTANONE 审中-公开VERFAHREN ZUR HERSTELLUNG VON 2-ADAMANTANOL UND 2-ADAMANTANON
公开(公告)号：EP1767513A1
公开(公告)日：2007-03-28
申请号：EP05755786.0
申请日：2005-06-30
发明人： KOJIMA, Akio , YAMANE, Hideki , OKAMOTO, Kenji
CPC分类号： C07C49/453 , C07C29/56 , C07C2603/74 , C07C35/37
摘要： The present invention is a process for producing 2-adamantanol and 2-adamantanone from 1-adamantanol, by using as a catalyst a substance comprising at least one kind of acid catalyst selected from Lewis acid(s) and solid acid(s) that coexist with at least one kind selected from the group consisting of carboxylic acids, sulfonic acids, and phosphoric acids, and provides a process suitable for mass production of 2-adamantanol and 2-adamantanone selectively with high efficiency without using sulfuric acid as a catalyst, thereby enabling laborsaving in waste acid treatment step and drastic reduction of the reaction time.
摘要翻译： 本发明是从1-金刚烷醇生产2-金刚烷醇和2-金刚烷酮的方法，通过使用选自共存的至少一种选自路易斯酸和固体酸的至少一种酸催化剂作为催化剂， 具有选自羧酸，磺酸和磷酸的至少一种，并且提供了适合于高效率地选择性地大量生产2-金刚烷醇和2-金刚烷酮的方法，而不使用硫酸作为催化剂，从而 在废酸处理步骤中实现劳动，并大大减少反应时间。
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9.发明公开ADAMANTANE DERIVATIVE, PROCESS FOR PRODUCTION THEREOF, RESIN COMPOSITION, AND CURED PRODUCT OF THE RESIN COMPOSITION 审中-公开金刚烷，对于其，组合物的方法和硬化树脂产品成分
公开(公告)号：EP2090564A1
公开(公告)日：2009-08-19
申请号：EP07830455.7
申请日：2007-10-24
摘要： Disclosed herein is an adamantane derivative represented by the following general formula (I):
(wherein R represents a hydrogen atom, a fluorine atom, a methyl group or a trifluoromethyl group; Y represents a hydrogen atom, a hydroxyl group, =O formed by two Ys together, a carboxyl group, or a hydrocarbon group having 1 to 20 carbon atoms or a cyclic hydrocarbon group having 3 to 20 carbon atoms; m is 13 and n is 3, or m is 12 and n is 4; and p is an integer of one or more), a production method thereof, a resin composition containing the adamantane derivative, and a cured product thereof. The present invention provides a cured product advantageous as various coating agents, a microlens, a film condenser, a colored composition for a liquid crystal color filter, a pattern organizer formed in nanoimprinting, and the like, having transparency, heat resistance, good mechanical properties, low volume shrinkage, and low coefficient of linear expansion, as well as liquid adamantyl group-containing (meth)acrylates to produce the cured product, the production method thereof, and the resin composition.摘要翻译： 在公开的是由下述通式（I）表示的金刚烷衍生物：（其中，R darstellt氢原子，氟原子，甲基或三氟甲基; Y代表氢原子，羟基，= O由形成 两个Y一起，羧基，或具有1至20个碳原子或具有3-20个碳原子的环状烃基的烃基; m为13且n为3，或m为12且n为4; p是 到一个或多个的完整性），及其制造方法，树脂组合物通过含有金刚烷衍生物，以及它们的固化产物。 本发明提供了一种固化产物有利的，因为各种涂布剂，显微透镜，薄膜电容器，用于液晶滤色器的着色组合物，图案组织者在纳米压印形成时，和类似物，具有透明性，耐热性，良好的机械性能 ，低体积收缩率，线膨胀系数低，以及液体含有金刚烷基的（甲基）丙烯酸酯，以产生固化产物，其制造方法，以及树脂组合物。
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10.发明公开ADAMANTYL GROUP-CONTAINING EPOXY-MODIFIED (METH)ACRYLATE AND RESIN COMPOSITION CONTAINING THE SAME 审中-公开丙烯酸缩水甘油酯（METH）丙烯酸酯在HARZZUSAMMENSETZUNG DAMIT
公开(公告)号：EP2014691A1
公开(公告)日：2009-01-14
申请号：EP07742230.1
申请日：2007-04-24
IPC分类号： C08F290/06 , C08G59/17
CPC分类号： C08F290/06 , C08F222/1006 , C08F290/061 , C08F290/064 , C08G59/186
摘要： The present invention provides an adamantyl group containing epoxy-modified (meth)acrylate and a resin composition containing it which are imparted by transparency, optical characteristics such as (durable) light resistance and the like, heat-resistance, and good mechanical properties.
For example, they are an adamantyl group containing epoxy-modified (meth)acrylate having the following general formula (I) and a composition containing it. In the formula, R 1 represents a hydrogen atom or a methyl group, and R 2 represents a halogen atom or an aliphatic hydrocarbon group which may contain a hetero atom. Plural R 2 may be the same or different, and m represents an integer of 0 to 4 and n represents an integer of 0 or more.摘要翻译： 本发明提供含有环氧改性的（甲基）丙烯酸金刚烷基和含有它的树脂组合物，它们通过透明性，耐光性等光学特性赋予耐热性和良好的机械性能。 例如，它们是含有具有以下通式（I）的环氧改性（甲基）丙烯酸酯和含有它的组合物的金刚烷基。 式中，R 1表示氢原子或甲基，R 2表示卤素原子或可含有杂原子的脂肪族烃基。 多个R 2可以相同或不同，m表示0〜4的整数，n表示0以上的整数。
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