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    METHOD FOR PRODUCTION OF LIQUID FUEL
    3.
    发明公开
    METHOD FOR PRODUCTION OF LIQUID FUEL 有权
    VERFAHREN ZUR HERSTELLUNG VONFLÜSSIGEMBRENNSTOFF

    公开(公告)号：EP2147964A1

    公开(公告)日：2010-01-27

    申请号：EP08740893.6

    申请日：2008-04-26

    申请人： Nippon Oil Corporation ,  JGC Catalysts and Chemicals Ltd.

    发明人： SEKI, Hiroyuki ,  HIGASHI, Masahiro ,  SAITO, Sumio ,  KURODA, Ryuzo ,  KAMEOKA, Takashi

    IPC分类号： C10G47/18 ,  B01J29/12 ,  B01J35/10

    CPC分类号： B01J29/084 ,  B01J21/02 ,  B01J21/12 ,  B01J29/126 ,  B01J37/0009 ,  B01J2229/20 ,  B01J2229/36 ,  B01J2229/42 ,  C10G45/52 ,  C10G45/54 ,  C10G45/62 ,  C10G45/64 ,  C10G47/18 ,  C10G2300/1022 ,  C10G2300/304 ,  C10G2300/307 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  C10G2300/4025 ,  C10G2400/06

    摘要： The present invention provides a method of producing a liquid fuel enabling production of middle distillate at a high yield from a feed oil containing paraffinic hydrocarbons having 20 to 100 carbon atoms as main components without losing the high cracking activity and also enabling provision of high quality gas oil included in the middle distillate.
    A feed oil containing paraffinic hydrocarbons having 20 to 100 carbon atoms as main components is subjected to hydrotreating in the present of a prespecified hydrotreating catalyst and under the conditions for hydrotreating including a temperature of 200 to 350 °C, a liquid hourly space velocity of 0.1 to 5.0 h -1 , and a partial pressure of hydrogen of 0.5 to 8 MPa to obtain an effluent oil, and then the effluent oil is fractionated to obtain middle distillate including a gas oil with a cetane number of 75 or over and a pour point of -27.5 °C or below at a yield of 55% or over against a total weight of the feed oil.

    摘要翻译： 本发明提供一种液体燃料的制造方法，其能够从含有20〜100个碳原子的链烷烃作为主要成分以高产率生产中间馏分，而不会失去高的裂解活性，并且还能够提供优质的气体 包含在中间馏分油中。 将含有20〜100个碳原子的链烷烃作为主成分的原料油在预先指定的加氢处理催化剂中进行加氢处理，在包括200〜350℃的温度的加氢处理条件下，液时空速为0.1 至5.0h -1，氢分压为0.5-8MPa，得到流出油，然后将流出物分馏，得到中间馏分，其中包括十六烷值为75或更大的瓦斯油，倾点 -27.5℃或更低，相对于原料油的总重量，产率为55％或更高。

    HYDRODESULFURIZATION CATALYST FOR HYDROCARBON OIL, PRODUCTION METHOD FOR SAME, AND HYDROREFINING METHOD FOR HYDROCARBON OIL
    5.
    发明公开
    HYDRODESULFURIZATION CATALYST FOR HYDROCARBON OIL, PRODUCTION METHOD FOR SAME, AND HYDROREFINING METHOD FOR HYDROCARBON OIL 审中-公开
    加氢脱硫催化剂的烃油，加工为油气石油生产国和HYDRO精炼过程

    公开(公告)号：EP2586529A1

    公开(公告)日：2013-05-01

    申请号：EP11798112.6

    申请日：2011-06-21

    申请人： JX Nippon Oil & Energy Corporation ,  JGC Catalysts And Chemicals Ltd.

    发明人： SEKI, Hiroyuki ,  YOSHIDA, Masanori ,  TAGAWA, Shogo ,  KAGAWA, Tomoyasu

    IPC分类号： B01J27/051 ,  B01J37/02 ,  B01J37/04 ,  B01J37/08 ,  B01J37/20 ,  C10G45/08

    CPC分类号： B01J27/051 ,  B01J21/063 ,  B01J21/12 ,  B01J23/882 ,  B01J27/19 ,  B01J35/0013 ,  B01J37/0045 ,  B01J37/0203 ,  B01J37/20 ,  C10G45/08 ,  C10G2300/1059 ,  C10G2300/1074 ,  C10G2300/202 ,  C10G2300/207 ,  C10G2300/4018

    摘要： The present invention provides a hydrodesulfurization catalyst exhibiting a high desulfurization activity when used for hydrotreating a hydrocarbon oil, particularly straight-run gas oil. The hydrodesulfurization catalyst is a catalyst produced by pre-sulfurizing a hydrodesulfurization catalyst Y comprising a support containing silica, alumina and titania and at least one type of metal component supported thereon and selected from VIA and VIII groups of the periodic table (comprising at least Mo), in which the total area of the diffraction peak area indicating the crystal structure of anatase titania (101) planes and the diffraction peak area indicating the crystal structure of rutile titania (110) planes in the support, measured by X-ray diffraction analysis being 1/4 or less of the alumina diffraction peak area assigned to γ-alumina (400) planes, the molybdenum is formed into molybdenum disulfide crystal and disposed in layers on the support by the pre-sulfurization, and the molybdenum disulfide crystal layers having an average length of longer than 3.5 nm and 7 nm or shorter in the plane direction and an average number of laminated layers of more than 1.0 and 1.9 or fewer.

    摘要翻译： 本发明提供了一种加氢脱硫催化剂具有高的脱硫活性当用于加氢处理烃油，特别是直馏瓦斯油。 加氢脱硫催化剂通过硫化预加氢脱硫催化剂Y包含载体包含二氧化硅，氧化铝和二氧化钛和至少一种类型的在其上的金属组分的载体的和从VIA选择和VIII组周期表的制备的催化剂（至少含有Mo ），其中，所述衍射峰面积的指示锐钛矿二氧化钛（101）面的晶体结构和衍射峰面积指示金红石二氧化钛（110）面的在载体上的晶体结构，通过X射线衍射分析测得的总面积 为1/4或更小分配给³氧化铝氧化铝衍射峰面积（400）晶面，所述钼形成为二硫化钼晶体和在层布置在由预硫化的支撑，并且具有二硫化钼晶体层 上在平面方向上和在平均数目大于1.0和1.9或叠层的长于3.5 nm和7纳米或更短的平均长度 少。

    HYDRODESULFURIZATION CATALYST FOR A HYDROCARBON OIL, MANUFACTURING METHOD THEREFOR, AND HYDROREFINING METHOD
    6.
    发明公开
    HYDRODESULFURIZATION CATALYST FOR A HYDROCARBON OIL, MANUFACTURING METHOD THEREFOR, AND HYDROREFINING METHOD 审中-公开
    HYDROENTSCHWEFELUNGSKATALYSATORFÜRKOHLENWASSERSTOFFÖL，HERSTELLUNGSVERFAHRENDAFÜRUND HYDRORAFFINATIONSVERFAHREN

    公开(公告)号：EP2484745A1

    公开(公告)日：2012-08-08

    申请号：EP10820343.1

    申请日：2010-09-14

    申请人： JX Nippon Oil & Energy Corporation ,  JGC Catalysts And Chemicals Ltd.

    发明人： SEKI, Hiroyuki ,  FUKUI, Yoshiaki ,  YOSHIDA, Masanori ,  TAGAWA, Shogo ,  KAGAWA, Tomoyasu

    IPC分类号： C10G45/04 ,  B01J21/06 ,  B01J27/19

    CPC分类号： B01J21/063 ,  B01J21/08 ,  B01J21/12 ,  B01J23/24 ,  B01J23/74 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/28 ,  C10G45/04 ,  C10G45/06 ,  C10G45/08 ,  C10G2300/1059 ,  C10G2300/1074 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2300/70

    摘要： The present invention provides a hydrodesulfurization catalyst that exhibits a high desulfurization activity when used in hydrotreatment of hydrocarbon oil, in particular straight-run gas oil. The catalyst comprising at least one type of metal component selected from Groups VIA and VIII in the periodic table, supported on a silica-titania-alumina support where the total of the diffraction peak area indicating the crystal structure of anatase titania (101) planes and the diffraction peak area indicating the crystal structure of rutile titania (110) planes is 1/4 or less of the diffraction peak area indicating the aluminum crystal structure ascribed to y-alumina (400) planes, as measured by X-ray diffraction analysis, the catalyst having (a) a specific surface area (SA) of 150 m 2 /g or greater, (b) a total pore volume (PVo) of 0.30 ml/g or greater, (c) an average pore diameter (PD) of 6 to 15 nm (60 to 150 Å), and (d) the ratio of the pore volume (PVp) of pores having diameters within ±30 percent of the average pore diameter (PD) being 70 percent or greater of the total pore volume (PVo).

    摘要翻译： 本发明提供一种加氢脱硫催化剂，其在用于烃油，特别是直馏瓦斯油的加氢处理中表现出高的脱硫活性。 催化剂包含至少一种选自元素周期表VIA和VIII族的金属组分，负载在二氧化硅 - 二氧化钛 - 氧化铝载体上，其中表示锐钛型二氧化钛（101）晶体的晶体结构的衍射峰面积的总和为 表示金红石型二氧化钛（110）面的晶体结构的衍射峰面积，通过X射线衍射分析测定，表示归属于γ-氧化铝（400）面的铝结晶结构的衍射峰面积的1/4以下， （a）比表面积（SA）为150m 2 / g以上，（b）总孔容积（PVo）为0.30ml / g以上的催化剂，（c）平均孔径（PD） 6〜15nm（60〜150）的孔体积（PVp）为70nm以上，（d）直径在平均孔径（PD）的±30％以内的孔的孔体积（PVp） 体积（PVo）。

    METHOD OF HYDROGENOLYSIS OF WAX AND PROCESS FOR PRODUCING FUEL BASE
    10.
    发明公开
    METHOD OF HYDROGENOLYSIS OF WAX AND PROCESS FOR PRODUCING FUEL BASE 审中-公开
    VERFAHREN ZUR WACHSHYDROGENOLYSE UND VERFAHREN ZUR HERSTELLUNG EINER KRAFTSTOFFBASIS

    公开(公告)号：EP1953208A1

    公开(公告)日：2008-08-06

    申请号：EP07706962.3

    申请日：2007-01-18

    申请人： Nippon Oil Corporation

    发明人： SEKI, Hiroyuki ,  HIGASHI, Masahiro ,  HATAYAMA, Minoru

    IPC分类号： C10G65/10 ,  B01J29/12 ,  C10G47/18 ,  C10G47/20

    CPC分类号： B01J29/084 ,  B01J21/02 ,  B01J29/126 ,  B01J35/023 ,  B01J2229/20 ,  B01J2229/42 ,  C10G47/12 ,  C10G47/16 ,  C10G47/18 ,  C10G2300/1022 ,  C10G2300/4081

    摘要： The hydrocracking method of wax of the invention is a hydrocracking process wherein crude wax is subjected to hydrocracking and the untreated wax fraction that is produced after the hydrocracking is re-supplied for hydrocracking, and wherein hydrocracking of the mixture of the crude wax and untreated wax fraction is carried out in such a manner for a conversion ratio of 50-85 % by mass from the wax fraction with a boiling point of 360°C or above to the light fraction with a boiling point of below 360°C in the presence of a hydrocracking catalyst. It is thereby possible to simultaneously achieve both an increased heart-cut fraction yield (as the product of the hydrocracking) and a reduced normal paraffin content in the heart-cut fraction when the untreated wax is hydrocracked by a bottom recycling system.

    摘要翻译： 本发明的蜡的加氢裂化方法是加氢裂化方法，其中将粗蜡进行加氢裂化，再加氢裂化后产生的未处理的蜡馏分用于加氢裂化，其中粗蜡和未处理蜡的混合物的加氢裂化 从沸点为360℃以上的蜡馏分的转化率为50〜85质量％，沸点低于360℃的轻馏分在存在下进行， 加氢裂化催化剂。 因此，当未处理的蜡被底部回收系统加氢裂化时，可以同时实现增加的心切分数产率（作为加氢裂化产物）和降心馏分中降低的正链烷烃含量。