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公开(公告)号：EP0562178B1
公开(公告)日：2002-10-09
申请号：EP92121312.0
申请日：1992-12-15
发明人： Fujii, Takeshi , Ishikawa, Manabu
CPC分类号： H01B1/24 , C08K3/04 , C08K3/34 , C08L71/12 , Y10S524/91 , C08L71/02 , C08L2666/04
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公开(公告)号：EP0675166A1
公开(公告)日：1995-10-04
申请号：EP95301136.8
申请日：1995-02-22
发明人： Fujii, Takeshi , Suzuki, Yasuro , Kihara, Hayato , Anbo, Takashi
IPC分类号： C08L71/12
CPC分类号： C08L71/123 , Y10S525/905 , C08L2666/04
摘要： A thermoplastic resin composition comprising:
(A) 1 to 99 % by weight of a polyphenylene ether resin,
(B) 99 to 1 % by weight of a polystyrene resin obtained by copolymerisation of a styrene compound, 100 to 500 ppm by weight of a compound containing a plurality of vinyl groups, and if necessary, a compound copolymerisable with the styrene compound, and/or a polystyrene resin obtained by copolymerisation of a styrene compound, 100 to 500 ppm by weight of a compound containing a plurality of vinyl groups, a rubber, and if necessary, a compound copolymerisable with the styrene compound, and having a weight average molecular weight of 150 thousand to 1 million and a number of branching points in a Z-average molecular weight of 2 to 20, and
(C) 0 to 100 parts by weight of a rubber per 100 parts by weight of the total amount of (A) and (B) [wherein, when (B) contains a rubber, said weight of (B) is the weight excluding the weight of said rubber].
According to the present invention, the thermoplastic resin composition having an excellent flowability and an excellent appearance of a molded article obtained can be provided.摘要翻译： 1。一种热塑性树脂组合物，其含有：（A）1〜99重量％聚苯醚树脂，（B）99〜1重量％苯乙烯化合物共聚而得到的聚苯乙烯树脂，100〜500重量ppm 含有多个乙烯基的化合物，根据需要可以含有与苯乙烯化合物共聚的化合物和/或苯乙烯化合物共聚而得到的聚苯乙烯树脂，100〜500重量ppm的含有多个乙烯基的化合物， 橡胶以及根据需要的与苯乙烯化合物可共聚的化合物，其重均分子量为15万〜100万，Z均分子量为2〜20的支化点数，（C） （A）和（B）的总量100重量份为0〜100重量份的橡胶[其中，（B）含有橡胶时，所述（B）的重量为不包括 所述橡胶]。 根据本发明，可以提供具有优异流动性和所得模塑制品的优异外观的热塑性树脂组合物。
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公开(公告)号：EP0337214B1
公开(公告)日：1993-11-10
申请号：EP89105726.7
申请日：1989-03-31
CPC分类号： C08L51/06 , C08L23/0884 , C08L23/10 , C08L23/16 , C08L63/00 , C08L67/00 , C08L67/02 , C08L2205/02 , C08L2205/03 , C08L2205/035 , C08L2666/02
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公开(公告)号：EP0498907A1
公开(公告)日：1992-08-19
申请号：EP91102010.5
申请日：1991-02-13
发明人： Fujii, Takeshi , Yamamoto, Masashi
CPC分类号： C08L23/10 , C08L23/0884 , C08L23/12 , C08L51/04 , C08L51/06 , C08L53/00 , C08L53/02 , C08L63/00 , C08L67/00 , C08L2205/03 , C08L2205/035 , C08L2666/18 , C08L2666/24 , C08L2666/02
摘要： The thermoplastic resin composition of the present invention comprises:
(a) a resin composition consisting of
(1) at least one polypropylene resin (E) selected from the group consisting of
(i) a graft polypropylene (A) obtained by graft polymerizing an unsaturated carboxylic acid or
a derivative thereof onto a polypropylene (C),
(ii) a graft polypropylene (B) obtained by graft polymerizing an unsaturated carboxylic acid
or a derivative thereof and an unsaturated aromatic monomer onto a polypropylene (C),
(iii) a composition (D) selected from the group consisting of
a composition of a polypropylene (C) and the graft polypropylene (A),
a composition of a polypropylene (C) and the graft polypropylene (B),
a composition of a polypropylene (C), the graft polypropylene (A) and
the graft polypropylene (B), and
(2) a saturated polyester resin (F)
(b) an epoxy group-containing copolymer (G), and
(c) at least one member selected from the group consisting of
(i) a rubbery substance (H),
(ii) a modified rubbery substance (I), and
(iii) a mixture of the rubbery substance (H) and the modified rubbery substance (I),
the content of the saturated polyester resin (F) in the thermoplastic resin composition being not more than 50% by weight; or
(a) either a graft resin composition (J) obtained by graft polymerizing an unsaturated carboxylic acid or
a derivative thereof onto a mixture of a polypropylene (C) and a rubbery substance (H), or
a graft resin composition (K) obtained by graft polymerizing an unsaturated carboxylic acid or
a derivative thereof and an unsaturated aromatic monomer onto a mixture of a polypropylene (C) and
a rubbery substance (H),
(b) a saturated polyester resin (F),
(c) an epoxy group-containing copolymer (G), and
(d) a polypropylene (C);
which thermoplastic resin composition is suitably used in the fields where high level of heat resistance, impact resistance, and especially low-temperature impact resistance are required.摘要翻译： 本发明的热塑性树脂组合物包含：（a）由（1）至少一种选自以下的聚丙烯树脂（E）组成的树脂组合物：（i）接枝聚丙烯（A） （C）;（ii）将不饱和羧酸或其衍生物与不饱和芳香族单体接枝聚合于聚丙烯（C）上而成的接枝聚丙烯（B）;（iii）聚丙烯 选自由聚丙烯（C）和接枝聚丙烯（A）的组合物，聚丙烯（C）和接枝聚丙烯（B）的组合物，聚丙烯（C） ，接枝聚丙烯（A）和接枝聚丙烯（B），和（2）饱和聚酯树脂（F）（b）含环氧基的共聚物（G），以及（c）至少一种选自 （i）橡胶状物质（H），（ii）一个月 （I）和橡胶状物质（H）与改性橡胶状物质（I）的混合物，热塑性树脂组合物中饱和聚酯树脂（F）的含量为50重量％ 以重量计; 或（a）通过将不饱和羧酸或其衍生物接枝聚合到聚丙烯（C）和橡胶状物质（H）的混合物上得到的接枝树脂组合物（J），或所得到的接枝树脂组合物（K） （C）与橡胶状物质（H）的混合物，（b）饱和聚酯树脂（F），（c）环氧基团与环氧基团的混合物接枝聚合不饱和羧酸或其衍生物和不饱和芳香族单体 （G），和（d）聚丙烯（C）; 该热塑性树脂组合物适用于需要高耐热性，耐冲击性，特别是耐低温冲击性的领域。
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公开(公告)号：EP0463497A1
公开(公告)日：1992-01-02
申请号：EP91109728.5
申请日：1991-06-13
发明人： Abe, Hiroomi , Fujii, Takeshi , Yamamoto, Masashi , Date, Shinji
CPC分类号： C08L23/10 , C08L23/0815 , C08L23/12 , C08L23/16 , C08L33/12 , C08L51/06 , C08L53/02 , C08L63/00 , C08L2205/03 , C08L2205/035 , C08L2666/22 , C08L2666/06 , C08L2666/02 , C08L2666/24 , C08L2666/04
摘要： The thermoplastic resin composition disclosed herein comprises:
(1) a resin composition (F) consisting of
(i) at least one member selected from the group consisting of
(a) a modified polypropylene to which has been graft copolymerized an unsaturated carboxylic acid or the derivative thereof,
(b) a modified polypropylene to which have been graft comodified an unsaturated aromatic monomer and either an unsaturated carboxylic acid or the derivative thereof,
(c) a mixture of the modified polypropylene (a) and a polypropylene,
(d) a mixture of the modified polypropylene (b) and a polypropylene,
(e) a modified mixture of a polypropylene and a rubbery substance to which mixture has been graft copolymerized an unsaturated carboxylic acid or the derivative thereof,
(f) a modified mixture of a polypropylene and a rubbery substance to which mixture have been graft copolymerized an unsaturated aromatic monomer and either an unsaturated carboxylic acid or the derivative thereof,
(g) a mixture of the modified mixture (e) and a polypropylene, and
(h) a mixture of the modified mixture (f) and a polypropylene, and
(ii) a thermoplastic copolymer (E) containing acid anhydride moiety of six-membered ring, and
(2) an epoxy group-containing copolymer (G).
The thermoplastic resin composition according to the present invention not only exhibits excellent processability but also produces remarkable advantages in that it gives far better physical properties than those expected from each polymer which constitutes the thermoplastic resin composition of the present invention.
The novel resin composition provided by the present invention can be easily processed into molded articles, films and sheets by a molding method generally used for thermoplastic resins such as injection molding, extrusion molding, etc, and can give products which have well-balanced properties among stiffness, heat resistance, impact resistance, scratch resistance, coatability, oil resistance, chemical resistance, water resistance, etc., and which are excellent in appearance uniformity and smoothness. The thermoplastic resin composition of the present invention is particularly suitable for use where well-balanced properties among heat resistance and impact resistance, low-temperature impact resistance in particular, are required.摘要翻译： 这里公开的热塑性树脂组合物包含：（1）一种树脂组合物（F），它由（ⅰ）至少一种选自（a）改性聚丙烯，其中已接枝共聚不饱和羧酸或 （b）改性聚丙烯，其中不饱和芳族单体与不饱和羧酸或其衍生物接枝共聚改性聚丙烯，（c）改性聚丙烯（a）和聚丙烯的混合物，（d） （b）改性聚丙烯（b）和聚丙烯的混合物，（e）聚丙烯和橡胶状物质的改性混合物，其中混合物已经与不饱和羧酸或其衍生物接枝共聚，（f）聚丙烯 和混合物已经与不饱和芳族单体和不饱和羧酸或其衍生物接枝共聚的橡胶状物质，（g）第 （e）改性混合物和聚丙烯以及（h）改性混合物（f）和聚丙烯的混合物，和（ii）含有六元环酸酐部分的热塑性共聚物（E）和（2） ）含环氧基的共聚物（G）。 根据本发明的热塑性树脂组合物不仅具有优异的可加工性，而且还产生显着的优点，因为它提供了比构成本发明的热塑性树脂组合物的每种聚合物预期的物理性能好得多的物理性能。 本发明提供的新型树脂组合物可以通过注射成型，挤出成型等热塑性树脂中通常使用的成型方法容易地加工成模制品，薄膜和片材，并且可以提供具有良好平衡性能的产品 刚性，耐热性，耐冲击性，耐刮擦性，涂布性，耐油性，耐化学性，耐水性等，并且外观均匀性和平滑性优异。 本发明的热塑性树脂组合物特别适用于要求耐热性和耐冲击性之间具有良好平衡的性能，特别是耐低温冲击性的用途。
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公开(公告)号：EP0335394A3
公开(公告)日：1990-12-05
申请号：EP89105627.7
申请日：1989-03-30
发明人： Okada, Takayuki , Mitsuno, Tatsuyuki , Fujii, Takeshi , Yamaguchi, Kentaro , Okada, Mitsuyuki , Tsuji, Mitsuji , Nishio, Takeyoshi , Yokoi, Toshio , Nomura, Takao
CPC分类号： C08L23/10 , C08K7/14 , C08L23/0884 , C08L23/12 , C08L23/16 , C08L51/06 , C08L53/00 , C08L63/00 , C08L67/00 , C08L67/02 , C08L2205/03 , C08L2205/035 , C08L2666/24 , C08L2666/18 , C08L2666/06 , C08L2666/02
摘要： There is disclosed a thermoplastic resin composition comprising a blend of
100 parts by weight of a resin composition composed of 1 to 99% by weight of a polypropylene type resin (C) selected from the group consisting of a modified polypropylene (A) obtained by graft copolymerizing an unsaturated carboxylic acid or a derivative thereof and an unsaturated aroamtic monomer onto polypropylene, and a composition composed of the modified polypropylene (A) and a polypropylene (B), and 99 to 1% by weight of at least one sturated polyester resin (D), 0.1 to 300 parts by weiht of an epoxy group containing copolymer (E), 0.1 to 300 parts by weight of a modified ethylenic copolymer ruber (F) obtained by graft copolymerizing and an unsaturated carboxylic acid or a derivative thereof and an unsaturated aromatic monomer onto ethylenic copolymer ruber, and Up to 5 partsg by weight of a basic comdpound (G) optionally added as reaction accelerator, the content of the saturted polyester resin in the thermoplastic polyeste4r resin being less than 50% by weight. The thermoplastic resin composition of the present invention has high heat resistance and high impact resistance. in particular, high low-temperatuer impact resistance and is advantgeously used in automobilde parts, electric and electronic parts, etc.摘要翻译： 公开了一种热塑性树脂组合物，其包含100重量份的树脂组合物和100重量份的树脂组合物，所述树脂组合物由1至99重量％的选自由改性聚丙烯（A）通过接枝获得的聚丙烯类树脂（C） 将不饱和羧酸或其衍生物与不饱和芳香族单体共聚到聚丙烯上，以及由该改性聚丙烯（A）和聚丙烯（B）构成的组合物和99-1重量％的至少一种研磨的聚酯树脂（ D），0.1〜300重量份的含环氧基的共聚物（E），0.1〜300重量份的通过接枝共聚而得到的改性乙烯类共聚物橡胶（F）和不饱和羧酸或其衍生物以及不饱和羧酸 芳族单体加入烯属共聚物橡胶中，以及至多5重量份的作为反应促进剂任选加入的碱性化合物（G），饱和聚酯树脂在 rmoplastic聚酯树脂小于50重量％。 本发明的热塑性树脂组合物具有高耐热性和高耐冲击性。 特别是耐低温冲击性高，适用于汽车部件，电气电子部件等。
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公开(公告)号：EP0317359A2
公开(公告)日：1989-05-24
申请号：EP88310947.2
申请日：1988-11-21
发明人： Toyoshima, Yoshiki , Okada, Mitsuyuki , Fujii, Takeshi , Yamaguchi, Kentaro , Tsuji, Mitsuji , Shinonaga, Hideo
IPC分类号： C08F255/00 , C08F287/00 , C08F291/02 , C08J7/04
CPC分类号： C08J7/047 , C08F255/00 , C08F287/00 , C08F291/02 , C08J2351/00 , C08J2475/00 , Y10T428/31573 , Y10T428/31587 , C08F220/32 , C08F222/06
摘要： A modified polyolefin resin obtained by melt-kneading a mixture consisting of
100 parts by weight of a mixture consisting of
(A) 40-99% by weight of a polyolefin resin having a melt flow rate of 0.05-60 g/10 min and
(B) 60-1% by weight of a solid rubber having a number-average molecular weight of 10,000-200,000,
(C) 0.1-5 parts by weight of at least one compound selected from the group consisting of unsaturated carboxylic acids, the derivatives thereof and unsaturated epoxy compounds,
(D) 0.1-5 parts by weight of an unsaturated aromatic compound and
(E) 0.01-2 parts by weight of a free-radical initiator,
the molar ratio of (C)/(D) ranging from 1/0.1 inclusive to 1/1 exclusive.
According to the present invention, there is provided a modified polyolefin resin having the following merits:
(1) The amount of bound unsaturated carboxylic acid, a derivative thereof or unsaturated epoxy compound is high.
(2) The change of the melt flow rate during the modification is small.
(3) The physical properties are of high grade.
(4) The coating affinity with urethane coatings and resistance to falling off of the coating layer are excellent.
The modified polyolefin resin of the present invention can be used for adhesives, covering materials, binders, laminate bonding agent and polymer alloy constituents.摘要翻译： 一种改性聚烯烃树脂，它是由100重量份由（A）40-99％（重量）熔体流动速率为0.05-60克/ 10分钟的聚烯烃树脂和（ B）60-1重量％的数均分子量为10,000-200,000的固体橡胶，（C）0.1-5重量份的至少一种选自不饱和羧酸，其衍生物 （D）0.1-5重量份的不饱和芳香族化合物和（E）0.01-2重量份的自由基引发剂，（C）/（D）的摩尔比范围为 1 / 0.1至1/1独占。 根据本发明，提供了一种改性聚烯烃树脂，其具有以下优点：（1）结合的不饱和羧酸，其衍生物或不饱和环氧化合物的量高。 （2）改性过程中熔体流动速率的变化很小。 （3）物理性质高。 （4）与氨基甲酸乙酯涂层的涂层亲和力和涂层脱落的性能优异。 本发明的改性聚烯烃树脂可用于粘合剂，覆盖材料，粘合剂，层压粘合剂和聚合物合金组分。
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公开(公告)号：EP0180302A3
公开(公告)日：1987-09-09
申请号：EP85305951
申请日：1985-08-21
CPC分类号： C08L51/06 , C08L77/00 , C08L2666/14 , C08L2666/04
摘要： A thermoplastic resin composition comprising a blend of a resin composition (D) and a copolymer (C) containing epoxy groups, said resin composition (D) being composed of (A) a polypropylene modified by an unsaturated carboxylic acid or anhydride thereof, with or without unmodified polypropylene, and (B) a polyamide resin has excellent physical properties and can be used to provide shaped articles, sheets and films having excellent appearance, uniformity and smoothness.
摘要翻译： 一种热塑性树脂组合物，其中含有树脂组合物（D）和含环氧基的共聚物（C）的共混物，所述树脂组合物（D）由（A）用不饱和羧酸或其酸酐改性的聚丙烯与 （B）聚酰胺树脂具有优异的物理性能，并且可用于提供具有优异的外观，均匀性和光滑度的成形制品，片材和膜。
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公开(公告)号：EP0368345B1
公开(公告)日：1994-04-20
申请号：EP89120899.3
申请日：1989-11-10
CPC分类号： C08L23/10 , C08L23/0869 , C08L23/16 , C08L51/06 , C08L63/00 , C08L77/10 , C08L2205/02 , C08L2205/03 , C08L2205/035 , C08L2666/02
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10.发明公开Thermoplastic resin composition and injection-molded article thereof 失效Thermoplastische Harzzusammensetzung und Spritzgussfaserteile daraus。
公开(公告)号：EP0580069A1
公开(公告)日：1994-01-26
申请号：EP93111287.4
申请日：1993-07-14
IPC分类号： C08L53/00
CPC分类号： C08L53/00 , C08L2666/02
摘要： A thermoplastic resin composition which contains a resin composition containing a crystalline polypropylene component, an ethylene-butene-1 copolymer rubber and an ethylene-propylene copolymer rubber; a modified polypropylene; a saturated polyester resin; and an epoxy group-containing copolymer; and optionally talc exhibits high low-temperature impact strength, stiffness and Rockwell hardness and a small coefficient of linear expansion, which composition gives an injection-molded article suitably used for a bumper for automobile.
摘要翻译： 一种含有结晶聚丙烯组分，乙烯 - 丁烯-1共聚物橡胶和乙烯 - 丙烯共聚物橡胶的树脂组合物的热塑性树脂组合物; 改性聚丙烯; 饱和聚酯树脂; 和含环氧基的共聚物; 并且任选的滑石显示出高的低温冲击强度，刚度和洛氏硬度和较小的线膨胀系数，该组合物给出适合用于汽车保险杠的注塑制品。
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