摘要:
In an internal combustion engine, inside an engine exhaust passage, a hydrocarbon feed valve (15) and an exhaust purification catalyst (13) are arranged. The carrier (50) of the exhaust purification catalyst (13) is formed from a crystallized composite oxide of aluminum and an alkali earth metal. On this carrier (50), precious metal catalysts (51, 52) are carried. The concentration of hydrocarbons which flow into the exhaust purification catalyst (13) is made to vibrate by within a predetermined range of amplitude of a 200 ppm or more and within a predetermined range of period of 5 second or less, whereby the NO x which is contained in exhaust gas is reduced at the exhaust purification catalyst (13).
摘要:
In an internal combustion engine, a hydrocarbon feed valve and an exhaust purification catalyst are arranged in an engine exhaust passage. A first NOX removal method which reduces NOX contained in an exhaust gas by a reducing intermediate which is generated by injecting hydrocarbons from the hydrocarbon feed valve within a predetermined range of period and a second NOX removal method in which an air-fuel ratio of the exhaust gas flowing into the exhaust purification catalyst is made rich by a period which is longer than this predetermined range are used. The switching temperatures ST and ST0 of the exhaust purification catalyst at which temperature an NOX removal method is switched from the second NOX removal method to the first NOX removal method, are made lower if the amount of NOX in the exhaust gas flowing into the exhaust purification catalyst increases.
摘要:
In an internal combustion engine, a hydrocarbon feed valve (15) and an exhaust purification catalyst (13) are arranged in an engine exhaust passage. A first NO x removal method which reduces NO x contained in an exhaust gas by a reducing intermediate which is generated by injecting hydrocarbons from the hydrocarbon feed valve (15) within a predetermined range of period and a second NO x removal method in which an air-fuel ratio of the exhaust gas flowing into the exhaust purification catalyst (13) is made rich by a period which is longer than this predetermined range are used. The switching temperatures ST and ST o of the exhaust purification catalyst (13) at which temperature an NO x removal method is switched from the second NO x removal method to the first NO x removal method, are made lower if the amount of NO x in the exhaust gas flowing into the exhaust purification catalyst (13) increases.
摘要:
The NO x storage catalyst (22) and the NO x selective reduction catalyst (23) are arranged in the engine exhaust passage. In the engine low load operating region, a combustion is performed in the combustion chamber (5) under a lean base air-fuel ratio and the air-fuel ratio in the combustion chamber (5)is made rich when NO x should be released from the NO x storage catalyst(22). In the engine medium load operating region, the base air-fuel ratio is made smaller, a degree of richness of the air-fuel ratio is made smaller, and a period in which the air-fuel ratio is made rich is made shorter so that an amount of ammonia which is produced per unit time when the air-fuel ratio is made rich falls compared with the time of engine low load operation.
摘要:
An exhaust gas purifying apparatus for an internal combustion engine is provided with: a first catalyst (234) which is disposed in an exhaust passage of the internal combustion engine (200); a second catalyst (235) which is disposed in the exhaust passage on a downstream side of the first catalyst; a reducing agent supplying device (233) which is disposed on an upstream side of the first catalyst and which is configured to supply a reducing agent into the exhaust passage; and a reducing agent supply controlling device (100) which is configured to control the reducing agent supplying device such that an air-fuel ratio on the upstream side of the first catalyst becomes momentarily rich.
摘要:
An exhaust purification system of an internal combustion engine is provided with an exhaust purification catalyst where NO x which is contained in exhaust gas and modified hydrocarbons react. The exhaust purification catalyst carries precious metal catalysts and is formed with a basic exhaust gas flow surface part. The exhaust purification catalyst has the property of reducing NO x if making the concentration of hydrocarbons which flow into the exhaust purification catalyst vibrate by within a predetermined range of amplitude and within a predetermined range of period. The system estimates the holding ability by which the NO x in the exhaust gas is held on the basic exhaust gas flow surface part of the exhaust purification catalyst and, when the holding ability becomes less than a predetermined judgment value of the holding ability, makes the concentration of hydrocarbons which flow into the exhaust purification catalyst rise.
摘要:
An exhaust purification system of an internal combustion engine is provided with an exhaust purification catalyst which removes NO x and a post treatment device. The exhaust purification catalyst has the property of reducing NO x if making the concentration of hydrocarbons vibrate by within a predetermined range of amplitude and within a predetermined range of period and furthermore has the function of oxidizing hydrocarbons. The exhaust purification system feeds hydrocarbons to the exhaust purification catalyst and raises the temperature of the post treatment device as temperature elevation control. The exhaust purification catalyst has a high purification rate range where the NO x purification rate becomes higher than a predetermined rate. In the temperature elevation control, the total feed amount of hydrocarbons is set and the feed period of hydrocarbons is set in the high purification rate range in a region at the end at the short side of feed period of hydrocarbons.