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公开(公告)号：EP2339677A1
公开(公告)日：2011-06-29
申请号：EP08877280.1
申请日：2008-10-10
发明人： KIMURA, Hiroko , TAKEHIRO, Naoki
CPC分类号： H01M8/0202 , H01M8/0204 , H01M8/023 , H01M8/0241 , H01M8/0243 , H01M8/0247 , H01M8/0258 , H01M8/04119 , H01M8/04171 , H01M8/04223 , H01M8/04283 , H01M8/04291 , H01M8/04365 , H01M8/04746 , H01M8/04768 , H01M8/04791 , H01M8/04813 , H01M8/04835 , H01M8/08 , H01M8/1018 , H01M2008/1095
摘要： The present invention provides a fuel cell which is capable of improving electric power generation efficiency at a time of high-temperature operation. The fuel cell 10 comprising: a membrane electrode assembly 4; and a pair of gas separators 7, 8 sandwiching the membrane electrode assembly 4 therebetween, wherein at least one of the gas separator(s) 7 and/or 8 comprises a compact layer(s) 7c and/or 8c which is capable of preventing permeation of fluid and a porous layer(s) 7d and/or 8d which allows permeation of fluid, and the porous layer(s) 7d and/or 8d is impregnated with a water-soluble liquid having higher boiling point than that of water.
摘要翻译： 本发明提供一种能够提高高温运转时的发电效率的燃料电池。 燃料电池10包括：膜电极组件4; 以及将膜电极接合体4夹在中间的一对气体分离器7,8，其中，气体分离器7和/或8中的至少一个气体分离器7和/或8包括能够防止膜电极组件7和/或8c的致密层7c和/ 渗透流体和允许流体渗透的多孔层7d和/或8d，并且多孔层7d和/或8d用沸点高于水的水溶性液体浸渍。
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公开(公告)号：EP2917952A1
公开(公告)日：2015-09-16
申请号：EP12795091.3
申请日：2012-11-07
发明人： KANEKO, Keiichi , TAKEHIRO, Naoki , TANIGUCHI, Takumi , ARAI, Tatsuya , KITAO, Noriyuki , ADACHI, Makoto , KIMURA, Hiroko
CPC分类号： H01M4/925 , H01M4/8657 , H01M4/8828 , H01M4/8878 , H01M4/8885 , H01M4/921 , H01M4/926 , H01M2008/1095 , Y02E60/50
摘要： An object of the present invention is to provide a production method which can increase the activity of a catalyst particle comprising a core particle and an outermost layer, the core particle comprising at least one of palladium and a palladium alloy, and the outermost layer comprising at least one of platinum and a platinum alloy and covering the core particle. Disclosed is a method for producing a catalyst for fuel cells, in which a catalyst particle is supported by an electroconductive carrier, the method comprising the steps of: preparing a supported catalyst in which a catalyst particle comprising a core particle and an outermost layer is supported by an electroconductive carrier, the core particle comprising at least one of palladium and a palladium alloy, and the outermost layer comprising at least one of platinum and a platinum alloy and covering the core particle; acid treatment to bring the supported catalyst into contact with an acid solution which dissolves palladium more preferentially than platinum; and firing the supported catalyst at 80°C or more and less than 200°C in a reducing gas atmosphere after the acid treatment step.
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3.发明公开CORE-SHELL METAL NANOPARTICLES, AND METHOD FOR PRODUCING CORE-SHELL METAL NANOPARTICLES 审中-公开金属矿物金属矿物在VERFAHREN ZUR HERSTELLUNG VON KERN-HÜLLE-METALLNANOPARTIKELN
公开(公告)号：EP2557203A1
公开(公告)日：2013-02-13
申请号：EP10849439.4
申请日：2010-04-07
发明人： ARAI, Tatsuya , TAKEHIRO, Naoki , IIO, Atsuo , KIMURA, Hiroko
CPC分类号： C23C28/02 , C23C18/1651 , C23C18/31 , C23C18/54 , C23C28/023 , C25D3/48 , C25D3/50 , C25D3/62 , C25D5/10 , C25D7/006 , H01M4/921 , H01M4/926
摘要： An object of the present invention is to provide core-shell type metal nanoparticles having a high surface coverage of the core portion with the shell portion, and a method for producing the same.
Disclosed is core-shell type metal nanoparticles comprising a core portion and a shell portion covering the core portion, wherein the core portion comprises a core metal material selected from metals and alloys, and wherein the shell portion comprises an alloy of a first shell metal material and a second shell metal material.摘要翻译： 本发明的目的是提供具有壳部分的芯部的高表面覆盖度的核 - 壳型金属纳米粒子及其制造方法。 公开了一种核 - 壳型金属纳米颗粒，其包括芯部和覆盖芯部的壳部，其中芯部包括选自金属和合金的芯金属材料，并且其中壳部包括第一壳金属材料 和第二壳金属材料。
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公开(公告)号：EP2854207B1
公开(公告)日：2019-06-05
申请号：EP13790011.4
申请日：2013-01-21
发明人： KIMURA, Hiroko , TAKEHIRO, Naoki
IPC分类号： H01M8/1018 , H01M4/92 , H01M4/86 , H01M4/88
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公开(公告)号：EP2917952B1
公开(公告)日：2016-04-13
申请号：EP12795091.3
申请日：2012-11-07
发明人： KANEKO, Keiichi , TAKEHIRO, Naoki , TANIGUCHI, Takumi , ARAI, Tatsuya , KITAO, Noriyuki , ADACHI, Makoto , KIMURA, Hiroko
CPC分类号： H01M4/925 , H01M4/8657 , H01M4/8828 , H01M4/8878 , H01M4/8885 , H01M4/921 , H01M4/926 , H01M2008/1095 , Y02E60/50
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6.发明公开METHOD FOR PRODUCING CATALYST FOR FUEL CELLS, AND FUEL CELL WHICH COMPRISES CATALYST FOR FUEL CELLS PRODUCED BY SAID PRODUCTION METHOD 审中-公开制造用于燃料电池和燃料电池的催化剂随着对燃料电池这个过程制得的催化剂
公开(公告)号：EP2854207A1
公开(公告)日：2015-04-01
申请号：EP13790011.4
申请日：2013-01-21
发明人： KIMURA, Hiroko , TAKEHIRO, Naoki
CPC分类号： H01M4/926 , H01M4/86 , H01M4/88 , H01M4/8817 , H01M4/8825 , H01M4/92 , H01M4/921 , H01M8/1018 , H01M2008/1095
摘要： The present invention is to provide a method for producing a catalyst for fuel cells with excellent durability, and a fuel cell comprising a catalyst for fuel cells produced by the production method. Disclosed is a method for producing a catalyst for fuel cells, the catalyst comprising fine catalyst particles, each of which comprises a palladium-containing core particle and a platinum-containing outermost layer covering the core particle, and carbon supports on which the fine catalyst particles are supported, wherein the method comprises the steps of: preparing carbon supports on which palladium-containing particles are supported; fining the carbon supports; and covering the palladium-containing particles with a platinum-containing outermost layer after the fining step.
摘要翻译： 本发明是一种用于制造用于燃料电池具有优异的耐久性的催化剂的方法，以及燃料电池，其包括用于通过该制造方法制造的燃料电池的催化剂。 公开了制备用于燃料电池的催化剂的方法，所述催化剂包含催化剂微粒，其每一个包括一个含钯核粒子和覆盖该核颗粒的含铂的最外层，和碳载体在其上的催化剂微粒 被支持，worin该方法包括以下步骤：制备碳载体上含钯粒子被支撑; 澄清的碳载体; 和覆盖所述含钯粒子与澄清步骤后含铂的最外层。
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7.发明公开METHOD FOR PRODUCING CORE-SHELL CATALYST PARTICLES 审中-公开VERFAHREN ZUR HERSTELLUNG VON KERN-SCHALE-KATALYSATORPARTIKELN
公开(公告)号：EP3106223A1
公开(公告)日：2016-12-21
申请号：EP14882348.7
申请日：2014-12-22
发明人： KANEKO, Keiichi , KIMURA, Hiroko , ADACHI, Makoto
CPC分类号： H01M4/925 , B22F1/025 , C23C18/1635 , C23C18/1637 , C23C18/1648 , C23C18/168 , C23C18/1689 , C23C18/1848 , C23C18/42 , C23C18/54 , C23C28/023 , C25D3/38 , C25D5/34 , C25D5/48 , C25D7/00 , C25D7/006 , H01M4/8657 , H01M4/8825 , H01M4/8832 , H01M4/8853 , H01M4/8878 , H01M4/921
摘要： The present invention is to provide a method for producing core-shell catalyst particles with high catalytic activity per unit mass of platinum. Disclosed is a method for producing core-shell catalyst particles including a core containing palladium and a shell containing platinum and covering the shell, wherein the method includes: a step of depositing copper on the surface of the palladium-containing particles by applying a potential that is nobler than the oxidation-reduction potential of copper to the palladium-containing particles in a copper ion-containing electrolyte, and a step of forming the shell by, after the copper deposition step and inside the reaction system kept at -3°C or more and 10°C or less, substituting the copper deposited on the surface of the palladium-containing particles with platinum by bringing the copper into contact with a platinum ion-containing solution in which platinum ions and a reaction inhibitor that inhibits a substitution reaction between the copper and the platinum, are contained.
摘要翻译： 本发明提供一种生产具有高铂催化活性的核 - 壳催化剂颗粒的方法。 公开了一种生产核 - 壳催化剂颗粒的方法，其包括含有钯和包含铂并且覆盖壳的壳的芯，其中所述方法包括：通过施加电位将钯沉积在含钯颗粒的表面上的步骤 比铜对含铜离子的电解质中的含钯颗粒的氧化还原电位更贵，并且在铜沉积步骤之后和反应体系内部保持在-3℃下形成壳的步骤或 更多和10℃或更低，通过使铜与含铂离子的溶液接触来代替沉积在含钯颗粒表面上的铜，其中铂离子和抑制剂之间的取代反应的反应抑制剂 铜和铂。
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8.发明公开FINE CATALYST PARTICLES AND METHOD FOR PRODUCING FINE CATALYST PARTICLES 审中-公开FEINE KATALYSATORPARTIKEL UND VERFAHREN ZUR HERSTELLUNG VON FEINEN KATALYSATORPARTIKELN
公开(公告)号：EP2596863A1
公开(公告)日：2013-05-29
申请号：EP10855007.0
申请日：2010-07-21
发明人： ARAI, Tatsuya , TAKEHIRO, Naoki , SEKIZAWA, Koshi , KIMURA, Hiroko , IIO, Atsuo
摘要： Disclosed is a catalyst particle having high catalyst activity and a method for producing the catalyst particle.
A catalyst particle comprising a core particle which contains a palladium alloy and an outermost layer which contains platinum, wherein an interlayer comprising only palladium as a simple substance is present between the core particle and the outermost layer.摘要翻译： 公开了具有高催化剂活性的催化剂颗粒和催化剂颗粒的制备方法。 一种催化剂颗粒，其包含含有钯合金的芯颗粒和含有铂的最外层，其中在核心颗粒和最外层之间存在仅包含钯作为单质的夹层。
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