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1.发明公开
公开(公告)号：EP3375821A1
公开(公告)日：2018-09-19
申请号：EP17809166.6
申请日：2017-06-09
发明人： ZHANG, Chuanhui , CAO, Min , JIANG, Sujun , HUANG, Xianbo , MAI, Jiehong , LONG, Jieming , SHI, Zhenguo , YAN, Kun , FAN, Liming
IPC分类号： C08L77/06
CPC分类号： C08K2201/004 , C08K2201/016 , C08L77/06 , C08L2205/025 , C08L2205/03
摘要： The present invention discloses a semiaromatic polyamide resin, a preparation method thereof, and a polyamide molding composition consisting of the same, which consists of following components:
(A) 20 to 95 wt% of a PA10T homopolymer derived from 1,10-decanediamine and terephthalic acid; and
(B) 5 to 80 wt% of a PA6T homopolymer derived from 1,6-hexanediamine and terephthalic acid.
Particularly, (A) + (B) =100 wt%.
In the present invention, by adding a certain amount of the PA10T homopolymer into the PA6T homopolymer, a melting point of the PA6T homopolymer can be significantly decreased to be below a decomposition temperature, and thereby a processability of the PA6T homopolymer is improved. The prepared semiaromatic polyamide resin has a decreased melting point, and may be processed normally. The polyamide molding composition consisting of the semiaromatic polyamide resin has a good processability, and has excellent surface properties.-
2.发明公开
公开(公告)号：EP3339351A1
公开(公告)日：2018-06-27
申请号：EP17809167.4
申请日：2017-03-29
申请人： Kingfa Sci. & Tech. Co., Ltd. , Zuhai Vanteque Specialty Engineering Plastics Co., Ltd. , Shanghai Kingfa Sci.&Tech.Dvpt.Co., Ltd.
发明人： ZHANG, Chuanhui , CAO, Min , JIANG, Sujun , SHI, Zhenguo , SUN, Xueke , FAN, Liming , CHEN, Mingqin , HUANG, Mujun , HUANG, Xianbo
IPC分类号： C08G69/14 , C08G69/16 , C08G69/36 , C08L77/02 , C08L77/00 , C08L23/20 , C08K7/14 , C08K3/34 , C08K5/5313
CPC分类号： C08G69/12 , C08G69/14 , C08G69/16 , C08G69/36 , C08K2201/003 , C08K2201/004 , C08K2201/016 , C08L77/02 , C08L2201/08
摘要： The present invention discloses a semiaromatic copolyamide resin and a polyamide molding composition consisting of the same, consisting of following repeat units:
(A) 26 to 80 mol% of units derived from para-amino benzoic acid;
(B) 4 to 70 mol% of units derived from 11-aminoundecanoic acid or undecanolactam, and 0 to 70 mol% of units derived from other amino acids having 6 to 36 carbon atoms or units consisting of a lactam;
(C) 0 to 37 mol% of units derived from a diamine unit having 4 to 36 carbon atoms; and
(D) 0 to 37 mol% of units derived from a diacid unit having 6 to 36 carbon atoms;
wherein, (A) + (B) + (C) + (D) = 100 mol%; and molar contents of the units derived from para-amino benzoic acid and those derived from 11-aminoundecanoic acid or undecanolactam are not equal to 50 mol% simultaneously.
The semiaromatic copolyamide resin of the present invention has property advantages such as high heat resistance, improved color property, excellent flowability and low water absorption, and the polyamide molding composition consisting of the same also has obvious advantage in the properties such as heat resistance, water absorption and color.-
公开(公告)号：EP4386050A1
公开(公告)日：2024-06-19
申请号：EP22869104.4
申请日：2022-09-08
发明人： YAN, Kun , XU, Xianjun , JIANG, Sujun , CAO, Min , MAI, Jiehong , YANG, Huixin , JIANG, Zhiqiang
摘要： The present invention relates to a polyester resin composition, a preparation method thereof and use thereof. The polyester resin composition includes a PCT resin, a white pigment, a reinforcing material, a polyester elastomer, and other additives. The polyester resin composition provided by the present invention has a strong binding force with a silica gel; when the polyester resin composition is made into an LED reflecting support, the LED reflecting support is not easy to separate from the silica gel in high temperature and high humidity environments, such that the service life of an LED lamp bead can be effectively prolonged; and meanwhile, the polyester resin composition has good toughness, and would not cause the problem of powder falling under repeated stress.
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公开(公告)号：EP3957676A1
公开(公告)日：2022-02-23
申请号：EP20802455.4
申请日：2020-04-10
发明人： HUANG, Xianbo , CHANG, Huan , YE, Nanbiao , CAO, Min , ZHANG, Chuanhui , YAN, Kun , PENG, Zhongquan
IPC分类号： C08G69/42
摘要： The invention discloses a flame-retardant semi-aromatic polyamide derived from the following monomers: a diacid monomer A: where A1 is terephthalic acid or terephthalic acid and other diacid, terephthalic acid accounts for 50 to 100 mol% of A1, and A2 is [(6-oxido-6H-dibenzo-(c,e)(1,2)-oxaphosphorin-6-ketone)-methyl]-butanedioic acid, A1+A2=100 mol%, A1=90 to 99 mol%, A2=1 to 10 mol%; and diamine monomer B: one or more of diamine monomers containing 4 to 36 carbon atoms. In the present invention, by an in situ polymerization, a specific flame-retardant monomer [(6-oxido-6H-dibenzo-(c,e)(1,2)-oxaphosphorin-6-ketone)-methyl]-butanedioic acid is copolymerized in a semi-aromatic polyamide chain segment, excellent mechanical properties and low water absorption can be obtained. At the same time, in a preparation method of the present invention a gradient heating method is used and by the in situ copolymerization, a semi-aromatic polyamide with an intrinsic flame-retardant property is synthesized, without a need to separately synthesize a flame-retardant precursor, which has simple operation steps, and reduces a production cost.
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5.发明公开
公开(公告)号：EP4406992A1
公开(公告)日：2024-07-31
申请号：EP22871866.4
申请日：2022-09-15
发明人： YAN, Kun , XU, Xianjun , JIANG, Sujun , CAO, Min , MAI, Jiehong , YANG, Huixin , JIANG, Zhiqiang
IPC分类号： C08G69/40 , C08K7/14 , C08K5/5313 , C08K5/3492 , C08L77/06
摘要： Disclosed is a furan diacid-based polyamide resin, which is derived from the following repeating units: (A) 2,5-furandicarboxylic acid, (B) 1,4-cyclohexanedicarboxylic acid, and (C) 1,10-decanediamine, where based on the total molar percentage of the diacid units, (A) accounts for 5-45 mol% of the diacid units. On one hand, by selecting the bio-based 2,5-furandicarboxylic acid, the resin is more environmentally friendly, and has the advantages of a melting point of 290-336°C , low water absorption rate, and good size stability (a water absorption rate lower than that of a polyamide with the same amido bond density); on the other hand, the rigidity of cyclohexane is higher than that of an aromatic ring, such that more hard carbon layers can be formed during combustion. In addition, the furan diacid-based polyamide has a relatively high amido bond density, and can generate a relatively excellent synergistic effect with a flame retardant, such that the flame retardant effect is excellent under the synergistic effect of the two.
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6.发明公开POLYAMIDE RESIN AND USE THEREOF AND POLYAMIDE COMPOSITION CONSISTING OF SAME 审中-公开POLYAMIDHARZ UND VERWENDUNG DAVON SOWIE POLYAMIDZUSAMMENSETZUNG DARAUS
公开(公告)号：EP2944665A1
公开(公告)日：2015-11-18
申请号：EP14738201.4
申请日：2014-01-10
发明人： ZHANG, Chuanhui , CAI, Tongmin , ZENG, Xiangbin , CAO, Min , XIA, Shiyong , YE, Nanbiao , CHEN, Dahua , YUAN, Shaoyan
CPC分类号： C08G69/36 , C08G69/265 , C08L77/06 , C08L2201/02 , C08L2201/08
摘要： The present invention discloses a polyamide resin and its application and polyamide composition thereof. The repeating units of the described polyamide resin comprises the following components: dicarboxylic acid units composed 80-100mol% of polyamide resin; aliphatic diamines units having 2-14 carbon atoms composed 80-100mol% of polyamide resin; lactam or amino acid units having 6-14 carbon atoms composed 0-20mol% of polyamide resin; in the described polyamide resin, the bio-based carbon concentration is more than 45%; the described bio-based carbon mole concentration is calculated according to the formula below: bio-based carbon concentration=(bio-based carbon mole content/total organic carbon mole content)*100%. The described polyamide resin in the present invention has low gas volatile, hence the polyamide composition produced thereof has low gas volatile too, and can be applied to food-contact field. In addition, the surface condition after reflow soldering of the polyamide composition produced is good.
摘要翻译： 本发明公开了一种聚酰胺树脂及其应用及其聚酰胺组合物。 所述聚酰胺树脂的重复单元包含以下组分：由聚酰胺树脂组成的80-100摩尔％的二羧酸单元; 具有2〜14个碳原子的脂肪族二胺单元构成80〜100摩尔％的聚酰胺树脂; 具有6-14个碳原子的内酰胺或氨基酸单元组成0-20mol％的聚酰胺树脂; 在所述的聚酰胺树脂中，生物基碳浓度大于45％; 所述生物基碳摩尔浓度根据以下公式计算：生物基碳浓度=（生物基碳摩尔含量/总有机碳摩尔含量）* 100％。 本发明所述的聚酰胺树脂挥发性低，因此其制造的聚酰胺组合物的挥发性也低，可应用于食品接触场。 此外，所生产的聚酰胺组合物的回流焊接后的表面状态良好。
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7.发明公开
公开(公告)号：EP3957677A1
公开(公告)日：2022-02-23
申请号：EP20802867.0
申请日：2020-04-10
发明人： CHANG, Huan , HUANG, Xianbo , YE, Nanbiao , CAO, Min , ZHANG, Chuanhui , JIANG, Sujun , XIE, Mingchen , YAN, Kun , PENG, Zhongquan
IPC分类号： C08G69/42 , C08L77/06 , C08K5/5313
摘要： The invention discloses an in situ polymerized flame retardant, derived from the following monomers: a diacid monomer A: where A1 is terephthalic acid, A2 is a phosphorus aromatic ring-containing reactive flame-retardant diacid monomer, A1+A2=100 mol%, A1=50 to 90 mol%, A2=10 to 50 mol%; and a diamine monomer B: one or more of diamine monomers containing 4 to 36 carbon atoms. In the present invention, a novel flame retardant is obtained by in situ polymerization of the phosphorus aromatic ring-containing reactive flame-retardant diacid monomers in semi-aromatic polyamide oligomers, which has advantages of no precipitation in the semi-aromatic polyamide and no influence on other properties of the semi-aromatic polyamide and has an excellent flame-retardant property.
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