摘要:
The present invention relates to a process for thermal cracking of heavy petroleum oil, in which when a thermal cracking facility having a cracking furnace, two or more of trains each comprising two reaction vessels and one distillation tower is operated, each train is operated by repeating a cycle comprising drawing the heavy petroleum oil from the cracking furnace, feeding the drawn heavy petroleum oil into the first reaction vessel and then feeding the drawn heavy petroleum oil into the second reaction vessel, steam is directly brought in contact with the heavy petroleum oil to be thermally cracked, and gaseous cracked substances produced and steam are introduced into the distillation tower to be distilled and separated, wherein phase delay is provided for the cycle repeated in each train so that the thermal cracking facility is operated with the different initiation time of feeding to the first reaction vessel in each train. According to the present invention, the instability of the flow-in quantity of the gaseous substances to the distillation tower is improved, and the improvement of separation performance, the increase of processing capacity of the facility and the like can be achieved.
摘要:
An integrated hydrotreating, steam pyrolysis and catalytic cracking process for the production of olefins and aromatic petrochemicals from a crude oil feedstock is provided. Crude oil and hydrogen are charged to a hydroprocessing zone under conditions effective to produce a hydroprocessed effluent, which is thermally cracked in the presence of steam in a steam pyrolysis zone to produce a mixed product stream. Heavy components are catalytically cracked, which are derived from one or more of the hydroprocessed effluent, a heated stream within the steam pyrolysis zone, or the mixed product stream catalytically cracking. Catalytically cracked products are produced, which are combined with the mixed product stream and the combined stream is separated, and olefins and aromatics are recovered as product streams.
摘要:
The present invention provides an improved fluidized catalytic cracking process coupled with a two stage regeneration process in which the activity of the circulating catalyst is independently controlled for cracking hydrocarbon feedstocks or the vapors at low severity to produce maximum light cycle oil/distillate in one riser whilst cracking recycle streams comprising heavy cycle oil (HCO), light cracked naphtha (LCN) etc. in a second riser operating at high severity to produce LPG.
摘要:
This invention relates to a process and an apparatus for regeneration of spent FCC catalyst using multiple reactors operation resulting in wide variation of coke on spent catalyst are disclosed. This process uses an up flow regenerator with divided injection of spent catalyst based on their coke content to control the residence time for its efficient regeneration and reduced hydrothermal deactivation. This system has the advantage of minimizing the exposure to the high temperature of low coked catalyst to the minimum possible time and high coke contained catalyst to the required time for its complete regeneration.
摘要:
A process is described for fluid catalytic cracking of hydrocarbons with high levels of basic nitrogen, where hydrocarbon feedstocks A and B with different levels of basic nitrogen are injected in a segregated fashion, into different risers of a multiple riser FCCU that possesses at least two risers. The injection of the feedstocks is made in such a way that feedstock A, to be injected in the riser with greater volume—main riser 7—possessing a level of basic nitrogen at least 200 ppm lower than the level of feedstock B to be injected into the riser with lower volume—secondary riser (8).
摘要:
An improved process for the conversion of normally gaseous methane-hydrocarbon mixtures (1), such as natural gas, to a normally liquid hydrocarbon product (10) comprises separating the methane component of the gaseous mixture from the heavier hydrocarbon component, cracking the separated heavier hydrocarbon component (3) at a relatively low temperature and optionally cracking the methane component at a relatively high temperature. The low temperature cracking product and any high temperature cracking product (11) are separated into a light product (31) of principally hydrogen and a heavy product (7) comprising unsaturated hydrocarbons. This heavy product is reacted with methane in the presence of an acidic alkalization catalyst. The resulting product mixture (9) is separated into a light product (61), a portion of which is recycled, and the normally liquid hydrocarbon product (10).
摘要:
The present invention relates to a process for thermal cracking of heavy petroleum oil, in which when a thermal cracking facility having a cracking furnace, two or more of trains each comprising two reaction vessels and one distillation tower is operated, each train is operated by repeating a cycle comprising drawing the heavy petroleum oil from the cracking furnace, feeding the drawn heavy petroleum oil into the first reaction vessel and then feeding the drawn heavy petroleum oil into the second reaction vessel, steam is directly brought in contact with the heavy petroleum oil to be thermally cracked, and gaseous cracked substances produced and steam are introduced into the distillation tower to be distilled and separated, wherein phase delay is provided for the cycle repeated in each train so that the thermal cracking facility is operated with the different initiation time of feeding to the first reaction vessel in each train. According to the present invention, the instability of the flow-in quantity of the gaseous substances to the distillation tower is improved, and the improvement of separation performance, the increase of processing capacity of the facility and the like can be achieved.
摘要:
This invention relates to a process and an apparatus for regeneration of spent FCC catalyst using multiple reactors operation resulting in wide variation of coke on spent catalyst are disclosed. This process uses an up flow regenerator with divided injection of spent catalyst based on their coke content to control the residence time for its efficient regeneration and reduced hydrothermal deactivation. This system has the advantage of minimizing the exposure to the high temperature of low coked catalyst to the minimum possible time and high coke contained catalyst to the required time for its complete regeneration.
摘要:
A fluid catalytic cracking apparatus and process is disclosed, providing for efficient conversion of heavy hydrocarbon feeds to light olefins, aromatics, and gasoline. A countercurrent flow reactor operating in bubbling or turbulent fluidization regimes is integrated with a fluid catalytic cracking riser reactor. A heavy hydrocarbon feed is catalytically cracked to naphtha and light olefins in the riser reactor, a co-current flow reactor. To enhance the yields and selectivity to light olefins, cracked hydrocarbon products from the riser reactor, such as C4 and naphtha range hydrocarbons, may be recycled and processed in the countercurrent flow reactor. The integration of the countercurrent flow reactor with a conventional FCC riser reactor and catalyst regeneration system may overcome heat balance issues commonly associated with two-stage cracking processes, may substantially increase the overall conversion and light olefins yield, and/or may increases the capability to process heavier feedstocks.