公开(公告)号：EP2616392A1

公开(公告)日：2013-07-24

申请号：EP11776594.1

申请日：2011-09-13

申请人： Council Of Scientific&industrial Research (An Indian Registered body incorporated under the Registration of Societies Act(Act XXXI of 1860)

发明人： SHINDE, Dhanraj, Bhagwanrao ,  PILLAI, Vijaymohanan, Kunjikrishnan

IPC分类号： C01B31/04

CPC分类号： C01B31/0438 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/182 ,  C01B32/184 ,  C25B1/00

摘要： A process for the transformation of carbon nanotubes (CNTs) to nanoribbons composed of a few layers of graphene by a two-step electrochemical approach is disclosed in this invention. This consists of the oxidation of CNTs at controlled potential, followed by reduction to form graphene nanoribbons (GNRs) having smooth edges and fewer defects, as evidenced by multiple characterization techni-ques, including Raman spectroscopy, atomic force micro-scopy, and transmission electron microscopy. This type of'unzipping" of CNTs (single-walled, multi- walled) in the presence of an interfacial electric field provides unique advantages with respect to the orientation of CNTs, which might make possible the production of GNRs with con-trolled widths and fewer defects. The extent of oxidation was confirmed by various characterization techniques like XRD, XPS and Raman spectroscopy. In the second step of experiments, the CNT oxide were reduced for different periods such as 4, 8, 12 hours at fixed negative potentials of -0.5 V, so as to get layers of graphene ribbons as tabulated herein.

公开(公告)号：EP3174827A1

公开(公告)日：2017-06-07

申请号：EP15826460.6

申请日：2015-07-29

申请人： Rutgers, the State University of New Jersey

发明人： NOSKER, Thomas ,  LYNCH, Jennifer ,  KEAR, Bernard ,  HENDRIX, Justin ,  CHIU, Gordon

IPC分类号： C01B32/182

CPC分类号： C08J5/005 ,  C01B31/0423 ,  C01B31/0438 ,  C01B32/19 ,  C01B32/20 ,  C01B2204/02 ,  C01B2204/04 ,  C08J2323/06 ,  C08J2325/06 ,  C08J2367/04 ,  C08J2371/10 ,  C08J2377/02 ,  C08J2377/06 ,  C08J2377/10 ,  C08J2381/04 ,  C08J2381/06 ,  C08K3/042 ,  C08L77/00

摘要： A graphene-reinforced polymer matrix composite comprising an essentially uniform distribution in a thermoplastic polymer of about 10% to about 50% of total composite weight of particles selected from graphite microp articles, single-layer graphene nanoparticles, multilayer graphene nanoparticles, and combinations thereof, where at least 50 wt % of the particles consist of single- and/or multi-layer graphene nanoparticles less than 50 nanometers thick along a c-axis direction. The graphene-reinforced polymer matrix is prepared by a method comprising (a) distributing graphite microparticles into a molten thermoplastic polymer phase comprising one or more matrix polymers; and (b) applying a succession of shear strain events to the molten polymer phase so that the matrix polymers exfoliate the graphite successively with each event until at least 50% of the graphite is exfoliated to form a distribution in the molten polymer phase of single- and multi-layer graphene nanoparticles less than 50 nanometers thick along a c-axis direction.

摘要翻译： 一种石墨烯增强的聚合物基质复合材料，其包含在热塑性聚合物中基本均匀分布的选自石墨微粒制品，单层石墨烯纳米粒子，多层石墨烯纳米粒子及其组合的颗粒的总复合重量的约10％至约50％ 其中至少50重量％的颗粒由沿着c轴方向小于50纳米厚的单层和/或多层石墨烯纳米颗粒组成。 该石墨烯增强的聚合物基体通过包括以下的方法制备：（a）将石墨微粒分布到包含一种或多种基体聚合物的熔融热塑性聚合物相中; 和（b）向熔融聚合物相施加一系列剪切应变事件，使得基体聚合物在每次事件中连续地剥离石墨，直到石墨的至少50％被剥离以在熔融聚合物相的单层中形成分布， 以及沿c轴方向小于50纳米厚的多层石墨烯纳米颗粒。

公开(公告)号：EP2830773A4

公开(公告)日：2016-03-09

申请号：EP13770399

申请日：2013-03-18

申请人： MURRAY SCOTT L ,  PEYTON JIM L ,  MORRIS KOREY

发明人： MURRAY SCOTT L ,  PEYTON JIM L ,  MORRIS KOREY

IPC分类号： B02C17/14 ,  B01F11/00 ,  B02C17/18 ,  B02C17/24 ,  B02C19/16 ,  B82Y30/00 ,  B82Y40/00 ,  C01B31/04

CPC分类号： B02C17/14 ,  B01F11/0025 ,  B01F11/0097 ,  B02C17/186 ,  B02C17/24 ,  B82Y30/00 ,  B82Y40/00 ,  C01B31/0423 ,  C01B31/0438 ,  C01B31/0469 ,  C01B32/182 ,  C01B32/19 ,  C01B32/225 ,  C01B2204/02 ,  C01B2204/04 ,  C01B2204/32 ,  C01P2006/12 ,  F16C3/02 ,  F16H1/20 ,  F16H1/22 ,  F16H37/065 ,  F16H53/00 ,  F16H53/02 ,  F16H55/17 ,  F16H2055/176 ,  Y10T74/19051 ,  Y10T74/1987 ,  Y10T74/19949 ,  Y10T74/2101 ,  Y10T428/2991

摘要： Apparatus and system of components to mechanically exfoliate particulate materials using a multi-axis approach to deliver predetermined forces to a particulate material, including containers to hold particulate material and media, also including media, and, the associated parameters for operating such equipment along with methods and compositions provided by the apparatus and methods.

公开(公告)号：EP2930143A1

公开(公告)日：2015-10-14

申请号：EP15154692.6

申请日：2015-02-11

申请人： Kabushiki Kaisha Toshiba

发明人： Yamazaki, Yuichi ,  Yoshida, Takashi ,  Nishida, Yasutaka ,  Miyazaki, Hisao ,  Aiga, Fumihiko ,  Sakai, Tadashi

IPC分类号： C01B31/04 ,  B82Y30/00 ,  H01B1/04 ,  H01L23/52 ,  H01L23/532

CPC分类号： C01B31/0438 ,  B82Y30/00 ,  C01B32/182 ,  H01B1/04 ,  H01L23/53276 ,  H01L2924/0002 ,  Y10S977/734 ,  Y10S977/932 ,  Y10T428/2982 ,  H01L2924/00

摘要： A wiring includes a graphene having a five-seven-membered ring-dense region. The graphene has a plurality of unit cells each including a five-seven-membered ring. The length of the unit cell is 1 nm or more. The shortest distance between most closely adjacent unit cells among the unit cells is 5 nm or less in the five-seven-membered ring-dense region.

摘要翻译： 布线包括具有五七元环稠密区域的石墨烯。 石墨烯具有多个单元电池，每个单元电池均包含五元七元环。 单元电池的长度为1nm以上。 单元电池中最接近相邻单位电池的最短距离在五七元环稠密区域中为5nm以下。

公开(公告)号：EP3174827A4

公开(公告)日：2018-03-07

申请号：EP15826460

申请日：2015-07-29

申请人： UNIV RUTGERS

发明人： NOSKER THOMAS ,  LYNCH JENNIFER ,  KEAR BERNARD ,  HENDRIX JUSTIN ,  CHIU GORDON

IPC分类号： C08K3/04 ,  C08J5/00

CPC分类号： C08J5/005 ,  C01B31/0423 ,  C01B31/0438 ,  C01B32/19 ,  C01B32/20 ,  C01B2204/02 ,  C01B2204/04 ,  C08J2323/06 ,  C08J2325/06 ,  C08J2367/04 ,  C08J2371/10 ,  C08J2377/02 ,  C08J2377/06 ,  C08J2377/10 ,  C08J2381/04 ,  C08J2381/06 ,  C08K3/042 ,  C08L77/00

摘要： A graphene-reinforced polymer matrix composite comprising an essentially uniform distribution in a thermoplastic polymer of about 10% to about 50% of total composite weight of particles selected from graphite microp articles, single-layer graphene nanoparticles, multilayer graphene nanoparticles, and combinations thereof, where at least 50 wt % of the particles consist of single- and/or multi-layer graphene nanoparticles less than 50 nanometers thick along a c-axis direction. The graphene-reinforced polymer matrix is prepared by a method comprising (a) distributing graphite microparticles into a molten thermoplastic polymer phase comprising one or more matrix polymers; and (b) applying a succession of shear strain events to the molten polymer phase so that the matrix polymers exfoliate the graphite successively with each event until at least 50% of the graphite is exfoliated to form a distribution in the molten polymer phase of single- and multi-layer graphene nanoparticles less than 50 nanometers thick along a c-axis direction.

公开(公告)号：EP3143388A1

公开(公告)日：2017-03-22

申请号：EP15725991.2

申请日：2015-05-13

申请人： Dräger Safety AG & Co. KGaA

发明人： SOMMER, Sabrina ,  METT, Frank

IPC分类号： G01N27/30 ,  G01N27/404

CPC分类号： G01N27/304 ,  C01B31/0438 ,  C01B31/0484 ,  C01B32/182 ,  C01B32/194 ,  C01B32/23 ,  G01N27/308 ,  G01N27/4045

摘要： The invention relates to an electrode (100) for an electrochemical gas sensor (1) wherein the electrode has a gas-permeable membrane, and wherein a graphene layer (3) is deposited on the gas-permeable membrane (4) as electrode material. An electrode (1) of this type is manufactured, for example, in that a dispersion of graphene or graphene oxide in a volatile liquid is applied onto a gas-permeable membrane and the volatile liquid is evaporated.

摘要翻译： 在电化学气体传感器用于电极（100）（1），所述worin电极具有透气膜（4）。 石墨烯层（3）是作为施加到电极材料的气体渗透膜（4）。 上电极（1）搜索被制备，例如，通过在挥发性液体到气体渗透膜施加石墨烯或氧化石墨烯分散体和蒸发挥发性液体。

公开(公告)号：EP2838837A4

公开(公告)日：2015-12-23

申请号：EP13777753

申请日：2013-03-15

申请人： SEERSTONE LLC

发明人： NOYES DALLAS B

IPC分类号： C01B31/02 ,  B01J23/28 ,  B01J23/30 ,  B01J23/75 ,  B01J23/755 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J35/00 ,  B01J35/02 ,  B01J35/06 ,  B01J35/08 ,  B01J37/16 ,  B01J37/18 ,  B82Y30/00 ,  B82Y40/00 ,  C01B31/04 ,  C01B31/06

CPC分类号： C01B32/05 ,  B01J23/28 ,  B01J23/30 ,  B01J23/75 ,  B01J23/755 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J23/8885 ,  B01J35/002 ,  B01J35/02 ,  B01J35/023 ,  B01J35/026 ,  B01J35/06 ,  B01J35/08 ,  B01J37/16 ,  B01J37/18 ,  B82Y30/00 ,  B82Y40/00 ,  C01B31/02 ,  C01B31/0206 ,  C01B31/0213 ,  C01B31/0233 ,  C01B31/04 ,  C01B31/0438 ,  C01B31/06 ,  C01B32/15 ,  C01B32/152 ,  C01B32/154 ,  C01B32/162 ,  C01B32/182 ,  C01B32/20 ,  C01B32/25 ,  C01B32/40 ,  C01B2202/06 ,  Y10T428/24917 ,  Y10T428/2958 ,  Y10T428/2982 ,  Y10T428/31678

摘要： A method of reducing a gaseous carbon oxide includes reacting a carbon oxide with a gaseous reducing agent in the presence of a non-ferrous catalyst. The reaction proceeds under conditions adapted to produce solid carbon of various allotropes and morphologies, the selective formation of which can be controlled by means of controlling reaction gas composition and reaction conditions including temperature and pressure. A method for utilizing a non-ferrous catalyst in a reactor includes placing the catalyst in a suitable reactor and flowing reaction gases comprising a carbon oxide with at least one gaseous reducing agent through the reactor where, in the presence of the catalyst, at least a portion of the carbon in the carbon oxide is converted to solid carbon and a tail gas mixture containing water vapor.

公开(公告)号：EP2616392B1

公开(公告)日：2015-04-15

申请号：EP11776594.1

申请日：2011-09-13

申请人： Council of Scientific & Industrial Research An Indian registered body incorporated under the Registration of Societies Act (Act XXI of 1860)

发明人： SHINDE, Dhanraj, Bhagwanrao ,  PILLAI, Vijaymohanan, Kunjikrishnan

IPC分类号： C01B31/04 ,  B82Y30/00 ,  B82Y40/00 ,  C25B1/00

CPC分类号： C01B31/0438 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/182 ,  C01B32/184 ,  C25B1/00