CALCIUM ALKYL PHENATE SULFIDE AND PREPARATION METHOD THEREOF, AND LUBRICATING OIL COMPRISING SAME
    4.
    发明公开
    CALCIUM ALKYL PHENATE SULFIDE AND PREPARATION METHOD THEREOF, AND LUBRICATING OIL COMPRISING SAME 审中-公开
    CALCIUMALKYLPHENATSCHWEFELWASSERSTOFF UND HERSTELLUNGSVERFAHRENDAFÜRSOWIESCHMIERÖLDAMIT

    公开(公告)号:EP3162877A1

    公开(公告)日:2017-05-03

    申请号:EP15881550

    申请日:2015-02-13

    Abstract: The present invention relates to the field of metal detergent, especially to a metal detergent and a preparation method thereof and a lubricant oil containing the metal detergent. The metal detergent provided by the present application is sulfurized calcium alkyl phenolate, the method for preparing the metal detergent includes the following steps: a) mixing alkyl phenol, a calcium source and base oil to obtain a mixed solution; b) mixing the mixed solution, ethylene glycol and a sulfur source to carry out sulfurization reaction to obtain a sulfurization reaction solution; c) implementing carbonation reaction between the sulfurization reaction solution and CO 2 to obtain a carbonation reaction solution; and d) extracting the carbonation reaction solution with a solvent, upon refining, to obtain sulfurized calcium alkyl phenolate; wherein the solvent includes solvent oil, water and oxygenous derivative of hydrocarbon. Experimental results show that the content of free alkyl phenol is below 1.5 wt% in the sulfurized calcium alkyl phenolate prepared using the preparation method provided by the present application.

    Abstract translation: 本发明涉及金属清净剂领域,特别涉及一种金属清净剂及其制备方法和含有该金属清净剂的润滑油。 本申请提供的金属清净剂为硫化烷基酚钙盐,其制备方法包括以下步骤:a)将烷基酚,钙源和基础油混合得到混合溶液; b)将混合溶液,乙二醇和硫源混合进行硫化反应得到硫化反应溶液; c)实施硫化反应液与CO 2的碳酸化反应,得到碳酸化反应液; 和d)用溶剂萃取碳酸化反应溶液,精制后得到硫化的烷基酚钙盐; 其中溶剂包括溶剂油,水和烃的含氧衍生物。 实验结果表明,用本申请提供的制备方法制备的硫化烷基酚钙盐中游离烷基酚的含量低于1.5wt%。

    Lubricating oil additives
    10.
    发明公开
    Lubricating oil additives 失效
    润滑油添加剂

    公开(公告)号:EP0389187A3

    公开(公告)日:1991-02-27

    申请号:EP90302808.2

    申请日:1990-03-15

    Abstract: A lubricating oil additive suitable as an extreme pressure/anti-wear additive comprises the product obtainable by reacting at elevated temperature a mixture comprising (i) sulphur, (ii) at least one C₁₀ to C₁₀₀ unsaturated carboxylic acid, or amide or acid salt thereof and (iii) at least one hydrocarbyl-substituted phenol, the amount of (iii) in the mixture being 15 to 65% w/w based on the combined weight of (i) (ii) and (iii). The reaction mixture can further comprise an olefin and/or, a mercaptan and/or a lubricating oil. The additive is also useful as an anti-oxidant. Additive concentrates and lubricating oil compositions comprise a lubricating oil and the additives of the present invention.

    Abstract translation: 适合作为极压/耐磨添加剂的润滑油添加剂包括通过在升高的温度下使包含(i)硫,(ii)至少一种C 10至C 100不饱和羧酸或其酰胺或其酸盐的混合物 和(iii)至少一种烃基取代的苯酚,基于(i)(ii)和(iii)的组合重量,混合物中(iii)的量为15至65%w / w。 反应混合物可进一步包含烯烃和/或硫醇和/或润滑油。 添加剂也可用作抗氧化剂。 添加剂浓缩物和润滑油组合物包含润滑油和本发明的添加剂。

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