摘要:
A process for at least partially reactivating the catalytic activity of at least a partially deactivated catalyst following a reaction cycle, the catalyst having been used in a catalytic reaction process for hydrogenating an aromatic epoxide to produce a hydrogenated aliphatic epoxide; said process including contacting the at least partially deactivated catalyst with an oxygen-containing source at a temperature of less than about 100 °C and in the presence of a reactivation solvent for a pre-determined period of time sufficient to at least partially re-oxidize and reactivate the catalyst for further use; and a catalytic reaction process for hydrogenating an aromatic epoxide to produce a hydrogenated aliphatic epoxide including the above reactivating process step; and optionally including a step for washing the deactivated catalyst with a solvent prior to re-oxidizing the deactivated catalyst.
摘要:
Disclosed is a novel epoxy compound represented by the general formula (I), which is characterized by having a benzo- or naphtho-cycloalkane skeleton. (I) wherein X, Y and Z independently represent an alkyl group having 1 to 10 carbon atoms which may be substituted by a halogen atom, an aryl group having 6 to 20 carbon atoms which may be substituted by a halogen atom, an arylalkyl group having 7 to 20 carbon atoms which may be substituted by a halogen atom, a heterocyclic group having 2 to 20 carbon atoms which may be substituted by a halogen atom, or a halogen atom; k represents a number of 0 to 4; p represents a number of 0 to 8; r represents a number of 0 to 4; n represents a number of 0 to 10; x represents a number of 0 to 4; and y represents a number of 0 to 4, provided that the sum total of x and y ranges from 2 to 4, and the optical isomer which is present when n is not 0 may be of any type.
摘要:
Disclosed is an adamantane derivative which enables to obtain a cured product which is excellent in optical characteristics such as transparency and light resistance, long-term heat resistance, and electrical characteristics such as dielectric constant. Also disclosed are a resin composition containing such an adamantane derivative, and a sealing agent for electronic circuits and an optoelectronic member respectively using those. Specifically disclosed are an adamantane derivative represented by the general formula (I) below, a resin composition containing such an adamantane derivative, a sealing agent for electronic circuits and an optoelectronic member respectively using such a resin composition, and an adhesive of those. (I) In the general formula (I), Z represents a group selected from the groups represented by the general formula (II) or (III) below (wherein R 1 represents a hydrogen atom or an alkyl group having 1-4 carbon atoms); X represents a linking group which may contain an oxygen atom and a sulfur atom and is composed of an (m + 1)-valent hydrocarbon, and a part or all of the hydrogen atoms in a hydrocarbon as the linking group may be replaced with fluorine atoms; Y represents a group selected from -CO 2 - and -O-; W represents a group selected from a hydrogen atom, a halogen atom, a hydrocarbon group, a halogen-substituted hydrocarbon group, a cyclic hydrocarbon group, a halogen-substituted cyclic hydrocarbon group, a hydroxyl group, a carboxyl group and =O formed from two Ws combined together; m represents an integer of 2-4; n represents an integer of 1-4; and k represents an integer from 0 to 16 - n.
摘要翻译:公开的是这使得能够获得固化产品中的所有其具有优异的光学特性的金刚烷衍生物:如透明度和耐光性,长期耐热性和电特性:如介电常数。 所以圆盘游离缺失是一种树脂组合物包含寻求金刚烷衍生物,以及用于电子电路和光电子部件分别使用这些密封剂。 具体地说游离缺失盘分别由通式(I)表示的金刚烷衍生物的下方,含有寻求金刚烷衍生物,电子电路和在光电元件使用寻求的树脂组合物的密封剂的树脂组合物,以及粘合剂的那些。 (I)在通式(I)中,Z表示从由通式(II)或(III)所示(worin R 1表示氢原子或烷基具有1-4个碳原子基团表示的基团中的基团 ); X darstellt其可含有价的烃对氧原子和硫原子并且由第(m + 1),并且其一部分或全部在烃作为连接基团的氢原子的连接基团可以被氟代替 原子; Y表示选自-CO 2中的基团 - 和-O-; W¯¯darstellt选自氢原子,卤原子,烃基,卤素取代的烃基,环状烃基,卤素取代的环状烃基,羟基,羧基和= O从形成的基团 2个Ws的结合在一起; 米darstellt到2-4整数; Ñdarstellt在1-4整数; N - 并且在整数0至16k的darstellt。
摘要:
The hydroxy group of an epoxy-alcohol is selectively alkylated, without affecting the epoxy group, by reaction with an alkylating agent in the presence of a solvent and a strong base. As an example, Betaxolol (4) can be prepared according to scheme (1).
摘要:
A polyglycidyl compound having on average more than two, preferably more than two and a half, particularly preferably more than three, glycidyl groups per molecule and a Tg value (determined by DSC, heating rate = 20 °C/min) higher than 20 °C, based on a polyfunctional 1,1'-spirobisindane of formula (I) or on a mixture of different polyfunctional 1,1'-spirobisindanes of general formula (I) wherein Z is a direct single bond or -O-; more than two of R1, R2, R3 and R4 are -OH, -O-CO-R-CO-OH, -O-R-OH, -O-CO-NH-R-NH-CO-O-R-OH or -[O-CmH2m]n-OH, wherein m is an integer from 2 to 4, n is an integer from 1 to 20, and R is C1-C8alkylene, C5-C8cycloalkylene, C6-C14arylene or partially hydrated C6-C14arylene, and the remaining R1, R2, R3 and R4 are a hydrogen atom or -O-C1-C8alkyl, -O-C5-C8cycloalkyl,-O-C6-C14aryl, partially hydrated -O-C6-C14aryl or (meth)acrylate; and R5, R6, R7 and R8 are each independently of one another C1-C8alkyl, C5-C8cycloalkyl, C6-C14aryl, partially hydrated C6-C14aryl or a hydrogen atom, for the production of moulded articles, coatings, matrix materials or adhesives.
摘要:
Glycidyl ethers of hydroxyalkyl carbamates of the general formula I
in which R is a C 1-15 aliphatic or cycloaliphatic linking group; R' is H or C 1-3 alkyl, at least one R' being hydrogen; m is 0, 1, 2 or 3; n is 1, 2, 3 or 4; and m + n is 2, 3 or 4, are prepared which are suitable for resinous binders for coatings and as crosslinking agents for carboxyl-functional resins such as acrylic resins.