PRODUCTION OF POLYVINYLAMINE POWDER

    公开(公告)号:JPH07118333A

    公开(公告)日:1995-05-09

    申请号:JP26222293

    申请日:1993-10-20

    摘要: PURPOSE:To produce a powder of free polyvinylamine efficiently by a relatively simple and convenient process by adding an excess amt. of a basic compd. to an aq. soln. of polyvinylamine or its salt and separating the resulting deposit from the soln. CONSTITUTION:A powder of free polyvinylamine with a high purity hardly attainable by the conventional process is efficiently produced by adding an excess amt. of a basic compd. (e.g. NaOH) to an aq. soln. of polyvinylamine (usually one obtd. by hydrolyzing an N-vinylformamide or N-vinylacetamide polymer or by the Hofmann reaction of polyacrylamide) or its salt and separating the resulting deposit from the soln.

    HYDROPHILIC TACKY AGENT COMPOSITION

    公开(公告)号:JPH06346041A

    公开(公告)日:1994-12-20

    申请号:JP13869093

    申请日:1993-06-10

    申请人: SHOWA DENKO KK

    摘要: PURPOSE:To obtain the subject composition having no reduction in physical properties such as adhesion, tack and retaining power with time of a tacky agent even in the presence of a salt, an alcohol and an aqueous liquid, readily peelable with water in the case of removing a bonded material, capable of cleanly removing the tacky agent without leaving the tacky agent on a material to be bonded, having no irritation and high safety in bonding to the skin. CONSTITUTION:A hydrophilic tacky agent composition consists essentially of a mixture substantially obtained by blending an N-vinylacetamide polymer or copolymer with a polyhydric alcohol in the weight ratio of 70:30 to 40:60.

    NEW PERFLUOROPOLYMER
    100.
    发明专利

    公开(公告)号:JPH06340710A

    公开(公告)日:1994-12-13

    申请号:JP15126893

    申请日:1993-05-28

    摘要: PURPOSE:To provide a new perfluoropolymer cross-linked in a high density, high in thermal distortion temperature and having a high elastic modulus at high temperatures by trimerizing the cyano group of a perfluorovinyl ether compound having a cyano group and subsequently polymerizing the vinyl ether group of the trimerization product. CONSTITUTION:A cyano group-having perfluoro compound of the formula (R is 1-15C perfluoroalkylene group or perfluorooxyalkylene group) (e.g. perfluoro-4- oxa-6-heptenonitrile) is put in an autoclave, and reacted in the presence of copper powder at 150 deg.C for 3 days to trimerize the cyano group of the compound of the formula (triazine ring formation reaction). The produced perfluorovinyl ether group-having triazine derivative is subjected to the radical polymerization of its vinyl group in the presence of a radical polymerization initiator such as diisopropyl perfluorodicarbonate to provide the objective perfluoropolymer cross-linked in a high density.