公开(公告)号：US20060143896A1

公开(公告)日：2006-07-06

申请号：US10800544

申请日：2004-03-15

申请人： Matthew Zaluzec ,  David Cook ,  Ulrich Weiss ,  Maik Broda ,  Clemens Verpoort

发明人： Matthew Zaluzec ,  David Cook ,  Ulrich Weiss ,  Maik Broda ,  Clemens Verpoort

IPC分类号： B21B1/46

CPC分类号： B22D19/0009 ,  B22D19/0081 ,  B22D19/08 ,  C23C2/02 ,  C23C4/18 ,  C23C6/00 ,  F01L3/04 ,  F01L2101/00 ,  F01L2103/00 ,  Y10T29/49231 ,  Y10T29/49984

摘要： A method of manufacturing metallic components consisting of at least two different materials, one of them being an iron-based alloy and the other an aluminum-based alloy, and involving the steps of: depositing a metallic layer onto the body made from the iron-based alloy, said layer being an aluminum-based alloy, preferably based on Al—Si or Fe, placing the coated body in a casting mold and casting an aluminum-based alloy about the coated body. Prior to placing the body in the casting mold, the metallic layer of the body is sprayed and/or blasted with silicon powder and/or Borax (Na2B4O7—10H2O, hydrated sodium borate).

摘要翻译： 一种制造由至少两种不同材料组成的金属组件的方法，其中一种是铁基合金，另一种是铝基合金，包括以下步骤：将金属层沉积在由铁 - 所述层是铝基合金，优选基于Al-Si或Fe，将涂覆体放置在铸模中并且在涂覆体周围浇铸铝基合金。 在将本体放置在铸模中之前，用硅粉和/或硼砂（Na 2 B 4 O 4）喷射和/或喷射身体的金属层， N 2，水合硼酸钠）。

公开(公告)号：US4929596A

公开(公告)日：1990-05-29

申请号：US220251

申请日：1988-07-18

申请人： Gundolf Meyer ,  Erwin Schonfeld ,  Clemens Verpoort

发明人： Gundolf Meyer ,  Erwin Schonfeld ,  Clemens Verpoort

IPC分类号： B28B1/00 ,  H01B12/04 ,  H01B13/00 ,  H01L39/14 ,  H01L39/24

CPC分类号： H01L39/248 ,  Y10S505/704 ,  Y10S505/74 ,  Y10T29/49014

摘要： Production of a sheathed wire or multiple-filament conductor composed of ceramic high-temperature superconductor by mixing Y.sub.2 O.sub.3, CuO and BaO.sub.2 or BaO.sub.2 +BaO, loading the powder mixture (3) into the interior of a metal sheath (1) lined with Ag intermediate layer (2), slowly heating to a maximum permissible reaction/sintering temperature of 950.degree. C. in a period of at least 0.1 h, holding the sintering temperature for at least 1 h, cooling down to 200.degree. C. at at most 10.degree. to 100.degree. C./h to form a conducting core (4) composed of YBa.sub.2 Cu.sub.3 O.sub.6.5-7.5. Variants having a layer composed of CuO, diffusion barrier composed of Ni, Ta, Nb, V or having Ag intermediate layer doped with AgO or BaO.sub.2. Preferably reactive sintering under a pressure of 10 to 10.000 bar as hot isostatic pressing. Variant: reactive annealing of the powder mixture under oxygen pressure of 10 to 3000 bar at 600.degree. to 950.degree. C. Pulverizing of the body formed, loading into the metal sheath (1), fabrication, sintering to form a compact superconductor under an external pressure of 10 to 3000 bar at 500.degree. to 900.degree. C. Multiple-filament conductor with centrally arranged tracks of oxygen-releasing substances surrounded by peripheral superconductor tracks.

摘要翻译： 通过混合Y2O3，CuO和BaO2或BaO2 + BaO生产由陶瓷高温超导体组成的护套线或多丝导体，将粉末混合物（3）装入内衬有Ag中间体的金属护套（1）的内部 层（2），在至少0.1h的时间内缓慢加热至950℃的最大允许反应/烧结温度，保持烧结温度至少1小时，冷却至200℃至多10℃ DEG至100℃/ h以形成由YBa2Cu3O6.5-7.5组成的导电芯（4）。 具有由CuO组成的层，由Ni，Ta，Nb，V组成的扩散阻挡层或具有AgO或BaO 2的Ag中间层的变体。 优选在10至10,000巴的压力下进行热等静压。 变种：在600〜950℃的氧压力为10〜3000巴的粉末混合物的反应退火。形成的体积粉碎，装载到金属护套（1）中，制造，烧结以在外部形成紧凑的超导体 在500〜900℃下压力为10〜3000巴。多芯导体具有中心布置的由外围超导体轨道包围的释氧物质轨迹。

公开(公告)号：US07296610B2

公开(公告)日：2007-11-20

申请号：US10800544

申请日：2004-03-15

申请人： Matthew Zaluzec ,  David Cook ,  Ulrich Weiss ,  Maik Broda ,  Clemens Verpoort

发明人： Matthew Zaluzec ,  David Cook ,  Ulrich Weiss ,  Maik Broda ,  Clemens Verpoort

IPC分类号： B22D19/04 ,  B22D19/08

CPC分类号： B22D19/0009 ,  B22D19/0081 ,  B22D19/08 ,  C23C2/02 ,  C23C4/18 ,  C23C6/00 ,  F01L3/04 ,  F01L2101/00 ,  F01L2103/00 ,  Y10T29/49231 ,  Y10T29/49984

摘要： A method of manufacturing metallic components consisting of at least two different materials, one of them being an iron-based alloy and the other an aluminum-based alloy, and involving the steps of: depositing a metallic layer onto the body made from the iron-based alloy, said layer being an aluminum-based alloy, preferably based on Al—Si or Fe, placing the coated body in a casting mold and casting an aluminum-based alloy about the coated body. Prior to placing the body in the casting mold, the metallic layer of the body is sprayed and/or blasted with silicon powder and/or Borax (Na2B4O7—10H2O, hydrated sodium borate).

摘要翻译： 一种制造由至少两种不同材料组成的金属组件的方法，其中一种是铁基合金，另一种是铝基合金，包括以下步骤：将金属层沉积在由铁 - 所述层是铝基合金，优选基于Al-Si或Fe，将涂覆体放置在铸模中并且在涂覆体周围浇铸铝基合金。 在将本体放置在铸模中之前，用硅粉和/或硼砂（Na 2 B 4 O 4）喷射和/或喷射身体的金属层， N 2，水合硼酸钠）。

公开(公告)号：US5043320A

公开(公告)日：1991-08-27

申请号：US481302

申请日：1990-02-20

申请人： Gundolf Meyer ,  Erwin Schonfeld ,  Clemens Verpoort

发明人： Gundolf Meyer ,  Erwin Schonfeld ,  Clemens Verpoort

IPC分类号： B28B1/00 ,  H01B12/04 ,  H01B13/00 ,  H01L39/14 ,  H01L39/24 ,  B22F7/00

CPC分类号： H01L39/248 ,  Y10S505/704 ,  Y10S505/74 ,  Y10T29/49014

摘要： A powder-in-tube method is disclosed for making a composite superconducting oxide wire which comprises loading a copper tube with a mixture composed of rare earth metal oxide, BaO.sub.2 and copper oxide or the finished superconductor powder and subjecting the loaded tube to drawing and a heat treatment at a temperature of up to 950.degree. C., wherein prior to loading the copper tube, the tube is oxidized at least on its inside to form a copper oxide layer having a thickness of 1 to 100 .mu.m and then a silver intermediate layer is inserted to the oxidized copper tube.

公开(公告)号：US5174952A

公开(公告)日：1992-12-29

申请号：US578248

申请日：1990-09-06

申请人： Peter Jongenburger ,  Christoph Tonnes ,  Clemens Verpoort

发明人： Peter Jongenburger ,  Christoph Tonnes ,  Clemens Verpoort

IPC分类号： B22F3/10 ,  B22F3/15 ,  B22F5/04 ,  C22C33/02 ,  C22C38/18

CPC分类号： B22F3/15 ,  B22F3/1017 ,  C04B35/64 ,  C22C33/0285 ,  C04B2235/77

摘要： A process for the powder-metallurgical production of a workpiece by filling a binder-free and solvent-free, dry metal powder or ceramic powder into a mold, precompacting the powder by tapping and presintering it for 1/2 hour to 1 hour at 0.65 to 0.85 times the absolute melting temperature without significant shrinkage, adjacent powder particles being joined merely at their contact points by necking to give a skeletal formed body. The formed body is taken out of the mold and finish-sintered at at least 0.9 times the absolute melting temperature for at least 1 hour without additional support by a mold. Advantageously, the sintered body is additionally hot-isostatically pressed containerless in order to reach at least 98% of the theoretical density.

摘要翻译： 通过将无粘合剂和无溶剂的干燥金属粉末或陶瓷粉末填充到模具中来对工件进行粉末冶金生产的方法，通过攻丝预先粉碎粉末并将其预先烧结1/2小时至1小时，在0.65 到绝对熔融温度的0.85倍，而没有显着的收缩，相邻的粉末颗粒仅通过颈缩在接触点处接合，从而得到骨架成形体。 将成形体从模具中取出并在绝对熔融温度的至少0.9倍下进行至少1小时的精炼烧结，而无需额外的模具支撑。 有利地，烧结体另外被热等静压地无压缩以达到理论密度的至少98％。

公开(公告)号：US4869645A

公开(公告)日：1989-09-26

申请号：US167015

申请日：1988-03-11

申请人： Clemens Verpoort

发明人： Clemens Verpoort

IPC分类号： F01D5/28 ,  B21D53/78 ,  B22D19/00 ,  C22C19/05

CPC分类号： B22D19/00 ,  Y10T29/49337 ,  Y10T29/49988

摘要： A composite gas turbine blade consists of an airfoil (1) in an oxide-dispersion-hardened nickel-based superalloy, in the condition of longitudinally directed coarse columnar crystals, and a shroud plate (6) or a shroud and a root (7), the latter items in a non-dispersion-hardened nickel-based superalloy (cast alloy). The gas turbine blade is manufactured by casting in and casting round, using the non-dispersion-hardened superalloy mentioned, the tip end (2) and root end (3)--provided with depressions (4) and/or protrusions (5)--of the airfoil (1), after preheating the latter to a temperature of between 50.degree. and 300.degree. C. below the solidus temperature of the lowest melting phase of the airfoil material. The casting temperature for this should be a maximum of 100.degree. C. above the liquidus temperature of the highest melting phase of this non-dispersion-hardened alloy. Any melting onto the airfoil (1) and any metallurgical connection is to be avoided. It is advantageous to provide a thermally insulating, mechanically damping intermediate layer (16) of an oxide of at least one of the elements Cr, Al, Si, Ti and Zr with a thickness of 5 to 200 .mu.m between the airfoil (1), on the one hand, and the shroud plate (6) and the root (7), on the other.

摘要翻译： 复合燃气轮机叶片由纵向指向的粗柱状晶体的状态下的氧化物分散硬化的镍基超级合金中的翼型件（1）和护罩板（6）或护罩和根部（7）组成， ，后一项在非分散硬化的镍基超级合金（铸造合金）中。 燃气轮机叶片通过使用所提到的非分散硬化的超级合金铸造和铸造而制造，提供有凹陷（4）和/或突起（5）的末端（2）和根端（3） （1）的预热后，将其预热到比翼型材料的最低熔融相的固相线温度低50至300℃的温度。 其铸造温度应高于该非分散硬化合金最高熔融相的液相线温度以上100℃。 任何熔化到翼型（1）上和任何冶金连接都应避免。 有利的是在翼型件（1）和第二部件（1）之间提供厚度为5至200μm的元件Cr，Al，Si，Ti和Zr中的至少一种元素的氧化物的隔热机械阻尼中间层（16） （6）和根（7），另一方面。

公开(公告)号：US4817858A

公开(公告)日：1989-04-04

申请号：US192630

申请日：1988-05-11

申请人： Clemens Verpoort

发明人： Clemens Verpoort

IPC分类号： B23K20/00 ,  B23K20/02 ,  B23K20/233 ,  B23K20/24 ,  C22C19/05 ,  C22F1/10 ,  B21K3/04

CPC分类号： C22C19/056 ,  B23K20/02 ,  B23K20/233 ,  B23K20/24 ,  C22F1/10 ,  B23K2201/001 ,  Y10T29/49336

摘要： Method of manufacturing a workpiece of any given cross-sectional dimensions from an oxide-dispersion-hardened nickel-based superalloy available in the form of coarse-grained longitudinally directed columnar crystals by connecting previously very finely machined workpiece parts derived from a semi-finished product by diffusion-bonding using hot isostatic pressing, the workpiece parts being first heat-treated under a protective gas in the temperature range of 50.degree. to 100.degree. C. below the recrystallization temperature, under a pressure p.sub.k of not more than 5 MPa with the machined surfaces to be connected joined together, the workpiece then being heated at least to a critical temperature T.sub.K, above which no further cold working takes place, and the pressure then being gradually increased to the diffusion bonding pressure p.sub.max of 100 to 300 MPa with simultaneous increase in temperature are a heating rate of not more of 2.degree. C./min to the diffusion bonding temperature T.sub.D of 0 to 50.degree. C. below the recrystallization temperature, this condition being maintained for 1 to 24 hours. Safe variant: only raise the pressure when T.sub.D has been reached!Application: gas turbine blading of large dimensions.

摘要翻译： 通过将先前非常精细加工的半成品的工件部件连接起来，以粗粒度纵向柱状晶体的形式从由氧化物分散硬化的镍基超级合金制成任何给定横截面尺寸的工件的方法 通过使用热等静压进行扩散接合，首先在低于再结晶温度的50℃〜100℃的保护气体下，在压力pk不大于5MPa的条件下，首先对工件进行热处理， 要连接的加工表面连接在一起，然后将工件加热至少至临界温度TK，在此之上不再进行冷加工，然后将压力逐渐增加到100-300MPa的扩散粘合压力pmax，同时 温度升高对于0〜50℃的扩散接合温度TD为2℃/ min以上的加热速度 使再结晶温度下降，该条件保持1〜24小时。 安全型：仅在达到TD时提高压力！应用：大尺寸的燃气轮机叶片。