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1.发明授权Process for the production of acetic acid from methanol and carbon monoxide using supported rhodium catalyst 失效使用负载铑催化剂从甲醇和一氧化碳生产乙酸的方法
公开(公告)号：US5334755A
公开(公告)日：1994-08-02
申请号：US49303
申请日：1993-04-21
CPC分类号： B01J31/181 , B01J31/1658 , C07C51/12 , B01J2531/822
摘要： A liquid feed containing methanol, carbon monoxide, an alkyl iodide and a solvent is contacted with a supported rhodium catalyst to produce acetic acid at a temperature of 140.degree.-250.degree. C. and a pressure of 15-60 kg/cm.sup.2 G with a partial pressure of carbon monoxide of 7-30 kg/cm.sup.2 while maintaining (a) the water concentration of the product solution in the range of 0.5-10% by weight and (b) the carbonylation degree C.sub.r, defined in the specification, of the solution within the reactor at 0.15 or more. The solvent may be a carboxylic acid or a carboxylic acid ester.
摘要翻译： 将含有甲醇，一氧化碳，烷基碘和溶剂的液体原料与负载的铑催化剂接触，在140-250℃的温度和15-60kg / cm2G的压力下制备乙酸， 一氧化碳压力为7-30kg / cm2，同时维持（a）产品溶液的水浓度在0.5-10重量％的范围内，（b）溶液中规定的羰基化度Cr 在反应器内为0.15以上。 溶剂可以是羧酸或羧酸酯。
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公开(公告)号：US5880311A
公开(公告)日：1999-03-09
申请号：US413626
申请日：1995-03-30
申请人： Fumihiko Uemura , Hideki Sugiyama , Chieko Nagasawa , Takeshi Minami , Kazuhiko Hamato , Noriyuki Yoneda , Akihisa Yamaguchi
发明人： Fumihiko Uemura , Hideki Sugiyama , Chieko Nagasawa , Takeshi Minami , Kazuhiko Hamato , Noriyuki Yoneda , Akihisa Yamaguchi
CPC分类号： C07C51/12 , B01J8/007 , B01J8/1854 , B01J8/1863 , B01J8/222 , B01J8/226 , B01J8/228 , C07C45/50 , C07C67/36 , B01J2208/00176 , B01J2208/00203 , B01J2208/00212 , B01J2208/003
摘要： Catalyst particles are contacted with a liquid and a gas in a vertically extending cylindrical vessel. The particles and liquid are placed in the vessel into which the gas and liquid are continuously fed from the bottom thereof so that an upwardly flowing mixture comprising the particles, liquid and gas is formed. The mixture is introduced into a gas separating zone disposed adjacent to an upper portion of the vessel to separate the mixture by gravity into a gas phase, a supernatant liquid phase and a phase rich in the catalyst particles. The gas and supernatant phases are continuously withdrawn from the separating zone while the catalyst particles-rich phase is continuously recycled to the bottom of the vessel by gravity.
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公开(公告)号：US5576458A
公开(公告)日：1996-11-19
申请号：US407612
申请日：1995-03-21
CPC分类号： C07C51/47 , C07C51/12 , B01J31/165
摘要： In the production step, alcohol is reacted with carbon monoxide in a reaction solvent in the presence of a rhodium-containing solid catalyst obtained by immobilizing rhodium in an insoluble carrier (I) containing a pyridine ring in its resin structure and an alkyl iodide containing an alkyl group of 1 to 5 carbon atoms, to produce a reaction product having a water content of 0.5 to 10% by weight; and in the subsequent removing step, an organic carboxylic acid is separated and recovered from the reaction product, and the recovered organic carboxylic acid is contacted with an insoluble carrier (II) containing a pyridine ring in its resin structure, to remove an iodide contained in the organic carboxylic acid.
摘要翻译： 在制造工序中，使醇与反应溶剂中的一氧化碳反应，在含有固体催化剂的铑固体催化剂的存在下，将铑固定在其树脂结构中含有吡啶环的不溶性载体（I）中， 1〜5个碳原子的烷基，得到含水率为0.5〜10重量％的反应产物; 在随后的除去步骤中，将有机羧酸从反应产物中分离回收，回收的有机羧酸与其树脂结构中含有吡啶环的不溶性载体（II）接触，除去 有机羧酸。
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4.发明授权Supported rhodium catalyst, method of preparing same and process of producing acetic acid by methanol carbonylation using same 失效负载型铑催化剂，其制备方法和使用甲醇羰基化生产乙酸的方法
公开(公告)号：US5364963A
公开(公告)日：1994-11-15
申请号：US169639
申请日：1993-12-20
CPC分类号： B01J31/1658 , B01J31/181 , C07C51/12 , B01J2531/822 , Y10S502/507
摘要： A methanol carbonylation catalyst includes a rhodium complex supported on a porous, cross-linked vinylpyridine resin, wherein the vinylpyridine resin has a cross-linking degree of 30-60%, a pore volume of 0.1-0.4 ml/g and an average pore diameter of 20-100 nm. The catalyst may be prepared by contacting the pyridine ring-containing resin with an aqueous solution containing rhodium ion and then contacting the resulting rhodium ion-carrying resin with carbon monoxide and an alkyl iodide in an organic solvent to convert the rhodium ion to a rhodium complex bound to the resin. Acetic acid is produced by reacting carbon monoxide with methanol at a temperature of 140.degree.-250.degree. C. and a partial pressure of carbon monoxide of 7-30 kg/cm.sup.2 in the presence of an alkyl iodide and the above catalyst.
摘要翻译： 甲醇羰基化催化剂包括负载在多孔交联乙烯基吡啶树脂上的铑络合物，其中乙烯基吡啶树脂的交联度为30-60％，孔体积为0.1-0.4ml / g，平均孔径 为20-100nm。 催化剂可以通过使含吡啶环的树脂与含有铑离子的水溶液接触，然后使所得的含铑离子的树脂与一氧化碳和烷基碘在有机溶剂中接触来将铑离子转化成铑络合物 结合树脂。 在烷基碘和上述催化剂的存在下，一氧化碳与甲醇在140〜250℃的温度和一氧化碳分压为7〜30kg / cm 2下反应生成乙酸。
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公开(公告)号：US6080373A
公开(公告)日：2000-06-27
申请号：US939622
申请日：1997-09-29
申请人： Fumihiko Uemura , Hideki Sugiyama , Chieko Nagasawa , Takeshi Minami , Kazuhiko Hamato , Noriyuki Yoneda , Akihisa Yamaguchi
发明人： Fumihiko Uemura , Hideki Sugiyama , Chieko Nagasawa , Takeshi Minami , Kazuhiko Hamato , Noriyuki Yoneda , Akihisa Yamaguchi
CPC分类号： C07C51/12 , B01J8/007 , B01J8/1854 , B01J8/1863 , B01J8/222 , B01J8/226 , B01J8/228 , C07C45/50 , C07C67/36 , B01J2208/00176 , B01J2208/00203 , B01J2208/00212 , B01J2208/003
摘要： Catalyst particles are contacted with a liquid and a gas in a vertically extending cylindrical vessel. The particles and liquid are placed in the vessel into which the gas and liquid are continuously fed from the bottom thereof so that an upwardly flowing mixture comprising the particles, liquid and gas is formed. The mixture is introduced into a gas separating zone disposed adjacent to an upper portion of the vessel to separate the mixture by gravity into a gas phase, a supernatant liquid phase and a phase rich in the catalyst particles. The gas and supernatant phases are continuously withdrawn from the separating zone while the catalyst particles-rich phase is continuously recycled to the bottom of the vessel by gravity.
摘要翻译： 催化剂颗粒与垂直延伸的圆柱形容器中的液体和气体接触。 将颗粒和液体放置在容器中，气体和液体从其底部连续进料，从而形成包含颗粒，液体和气体的向上流动的混合物。 将混合物引入到与容器的上部相邻设置的气体分离区中，以通过重力将混合物分离成气相，上清液相和富含催化剂颗粒的相。 气体和上清液相从分离区连续取出，而富含催化剂颗粒的相通过重力连续循环到容器的底部。
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