-
1.
公开(公告)号:US12258292B2
公开(公告)日:2025-03-25
申请号:US18207135
申请日:2023-06-07
Applicant: NEMASKA LITHIUM INC.
Inventor: Jean-François Magnan , David-Nicolas Allen
Abstract: The present disclosure concerns an aluminosilicate having a Blaine fineness of about 500 m2/kg to about 3000 m2/kg and/or a specific surface area of about 4 m2/g to about 20 m2/g, as well as the uses thereof. The present disclosure also comprises a dry cementing composition and a mortar or concrete composition, the compositions comprising said aluminosilicate. The present disclosure also comprises a process for the manufacture of aluminosilicate. The process comprises: roasting a spodumene concentrate in an acid medium; leaching the acidic roast spodumene concentrate so as to obtain a mixture comprising a solid comprising the aluminosilicate and a leachate; and separating the aluminosilicate from the leachate in an acid medium, wherein said aluminosilicate contains a calcium concentration of less than about 5%.
-
公开(公告)号:US20230416874A1
公开(公告)日:2023-12-28
申请号:US18213844
申请日:2023-06-25
Applicant: NEMASKA LITHIUM INC.
Inventor: Guy BOURASSA , Gary PEARSE , Stephen Charles MACKIE , Mykolas GLADKOVAS , Peter SYMONS , J. David GENDERS , Jean-François MAGNAN , Geneviève CLAYTON
IPC: C22B26/12 , B01D61/42 , C22B3/44 , C01D7/07 , C25B1/16 , B01D61/44 , C25B9/70 , C25B9/19 , C22B4/02 , C25B1/14
CPC classification number: C22B26/12 , B01D61/422 , C22B3/44 , C01D7/07 , C25B1/16 , B01D61/445 , C25B9/70 , C25B9/19 , C22B4/02 , C25B1/14 , Y02E60/36 , C01B2203/0283 , B01D2311/2684
Abstract: There are provided processes comprising submitting an aqueous composition comprising lithium sulphate and/or bisulfate to an electrolysis or an electrodialysis for converting at least a portion of said sulphate into lithium hydroxide. During electrolysis or electrodialysis, the aqueous composition is at least substantially maintained at a pH having a value of about 1 to about 4; and converting said lithium hydroxide into lithium carbonate. Alternatively, lithium sulfate and/or lithium bisulfate can be submitted to a first electromembrane process that comprises a two-compartment membrane process for conversion of lithium sulfate and/or lithium bisulfate to lithium hydroxide, and obtaining a first lithium-reduced aqueous stream and a first lithium hydroxide-enriched aqueous stream; and submitting said first lithium-reduced aqueous stream to a second electromembrane process comprising a three-compartment membrane process to prepare at least a further portion of lithium hydroxide and obtaining a second lithium-reduced aqueous stream and a second lithium-hydroxide enriched aqueous stream.
-
公开(公告)号:US11697861B2
公开(公告)日:2023-07-11
申请号:US16185973
申请日:2018-11-09
Applicant: NEMASKA LITHIUM INC.
Inventor: Guy Bourassa , Gary Pearse , Stephen Charles Mackie , Mykolas Gladkovas , Peter Symons , J. David Genders , Jean-François Magnan , Geneviève Clayton
IPC: C22B26/12 , C01D7/07 , B01D61/42 , B01D61/44 , C25B1/14 , C25B9/19 , C25B9/70 , C22B3/44 , C22B4/02 , C25B1/16
CPC classification number: C22B26/12 , B01D61/422 , B01D61/445 , C01D7/07 , C22B3/44 , C22B4/02 , C25B1/14 , C25B1/16 , C25B9/19 , C25B9/70 , B01D2311/2684 , C01B2203/0283 , Y02E60/36
Abstract: There are provided processes comprising submitting an aqueous composition comprising lithium sulphate and/or bisulfate to an electrolysis or an electrodialysis for converting at least a portion of said sulphate into lithium hydroxide. During electrolysis or electrodialysis, the aqueous composition is at least substantially maintained at a pH having a value of about 1 to about 4; and converting said lithium hydroxide into lithium carbonate. Alternatively, lithium sulfate and/or lithium bisulfate can be submitted to a first electromembrane process that comprises a two-compartment membrane process for conversion of lithium sulfate and/or lithium bisulfate to lithium hydroxide, and obtaining a first lithium-reduced aqueous stream and a first lithium hydroxide-enriched aqueous stream; and submitting said first lithium-reduced aqueous stream to a second electromembrane process comprising a three-compartment membrane process to prepare at least a further portion of lithium hydroxide and obtaining a second lithium-reduced aqueous stream and a second lithium-hydroxide enriched aqueous stream.
-
4.
公开(公告)号:US20220324755A1
公开(公告)日:2022-10-13
申请号:US17628558
申请日:2019-11-27
Applicant: NEMASKA LITHIUM INC.
Inventor: Jean-François MAGNAN , David-Nicolas ALLEN
Abstract: The present disclosure concerns an aluminosilicate having a Blaine fineness of about 500 m2/kg to about 3000 m2/kg and/or a specific surface area of about 4 m2/g to about 20 m2/g, as well as the uses thereof. The present disclosure also comprises a dry cementing composition and a mortar or concrete composition, the compositions comprising said aluminosilicate. The present disclosure also comprises a process for the manufacture of aluminosilicate. The process comprises: roasting a spodumene concentrate in an acid medium; leaching the acidic roast spodumene concentrate so as to obtain a mixture comprising a solid comprising the aluminosilicate and a leachate; and separating the aluminosilicate from the leachate in an acid medium, wherein said aluminosilicate contains a calcium concentration of less than about 5%.
-
公开(公告)号:US11083978B2
公开(公告)日:2021-08-10
申请号:US16328220
申请日:2017-08-28
Applicant: NEMASKA LITHIUM INC.
Inventor: Jean-François Magnan , Guy Bourassa , Nicolas Laroche , Bertin Ouellet , Clive Brereton , Steven Buchi , Tsuki Naka
Abstract: The present disclosure relates to processes for treating an aqueous composition comprising lithium sulfate and sulfuric acid. The processes comprise evaporatively crystallizing the aqueous composition comprising lithium sulfate and sulfuric acid under conditions to obtain crystals of lithium sulfate monohydrate and a lithium sulfate-reduced solution; and optionally separating the crystals of the lithium sulfate monohydrate from the lithium sulfate-reduced solution. The processes optionally further comprise concentrating the lithium sulfate-reduced solution under conditions to obtain an acidic condensate and a concentrate comprising sulfuric acid.
-
公开(公告)号:US20190136392A1
公开(公告)日:2019-05-09
申请号:US16053796
申请日:2018-08-03
Applicant: Nemaska Lithium Inc.
Inventor: Guy BOURASSA , Gary PEARSE , Stephen Charles MACKIE , Mykolas GLADKOVAS , Peter SYMONS , J. David GENDERS , Jean-François MAGNAN
Abstract: There are provided methods for preparing lithium hydroxide. For example, such methods can comprise submitting an aqueous composition comprising a lithium compound to an electrolysis under conditions suitable for converting at least a portion of said lithium compound into lithium hydroxide. There are also provided methods for preparing lithium sulphate.
-
公开(公告)号:US20170342573A1
公开(公告)日:2017-11-30
申请号:US15615280
申请日:2017-06-06
Applicant: Nemaska Lithium Inc.
Inventor: Guy BOURASSA , Gary PEARSE , Stephen Charles MACKIE , Mykolas GLADKOVAS , Peter SYMONS , J. David GENDERS , Jean-François MAGNAN
CPC classification number: C25B1/16 , B01D61/422 , B01D61/44 , C22B7/006 , C22B26/12
Abstract: There are provided methods for preparing lithium hydroxide. For example, such methods can comprise submitting an aqueous composition comprising a lithium compound to an electrolysis under conditions suitable for converting at least a portion of said lithium compound into lithium hydroxide. There are also provided methods for preparing lithium sulphate.
-
公开(公告)号:US20160265085A1
公开(公告)日:2016-09-15
申请号:US15031746
申请日:2014-10-23
Applicant: NEMASKA LITHIUM INC.
Inventor: Guy BOURASSA , Gary PEARSE , Stephen Charles MACKIE , Mykolas GLADKOVAS , Peter SYMONS , David J. GENDERS , Jean-Frangois MAGNAN , Geneviève CLAYTON
CPC classification number: C22B26/12 , B01D61/422 , B01D61/445 , B01D2311/2684 , C01B2203/0283 , C01D7/07 , C22B3/44 , C22B4/02 , C25B1/14 , C25B1/16 , C25B9/08 , C25B9/18 , Y02E60/366
Abstract: There are provided processes comprising submitting an aqueous composition comprising lithium sulphate and/or bisulfate to an electrolysis or an electrodialysis for converting at least a portion of said sulphate into lithium hydroxide. During electrolysis or electrodialysis, the aqueous composition is at least substantially maintained at a pH having a value of about 1 to about 4; and converting said lithium hydroxide into lithium carbonate. Alternatively, lithium sulfate and/or lithium bisulfate can be submitted to a first electromembrane process that comprises a two-compartment membrane process for conversion of lithium sulfate and/or lithium bisulfate to lithium hydroxide, and obtaining a first lithium-reduced aqueous stream and a first lithium hydroxide-enriched aqueous stream; and submitting said first lithium-reduced aqueous stream to a second electromembrane process comprising a three-compartment membrane process to prepare at least a further portion of lithium hydroxide and obtaining a second lithium-reduced aqueous stream and a second lithium-hydroxide enriched aqueous stream.
Abstract translation: 提供的方法包括将包含硫酸锂和/或硫酸氢盐的含水组合物递送到电解或电渗析中,以将至少一部分所述硫酸盐转化为氢氧化锂。 在电解或电渗析期间,水性组合物至少基本上保持在pH为约1至约4的pH; 并将所述氢氧化锂转化为碳酸锂。 或者,硫酸锂和/或硫酸氢锂可以进行第一电子过程,其包括用于将硫酸锂和/或硫酸氢锂转化为氢氧化锂的双室膜工艺,并获得第一锂还原水流和 第一个富含氢氧化锂的水流; 以及将所述第一锂还原水流提交到包括三室膜方法的第二电解方法中,以制备至少另一部分氢氧化锂并获得第二锂还原水流和第二富含氢氧化锂的水流。
-
公开(公告)号:US12168811B2
公开(公告)日:2024-12-17
申请号:US18213844
申请日:2023-06-25
Applicant: NEMASKA LITHIUM INC.
Inventor: Guy Bourassa , Gary Pearse , Stephen Charles Mackie , Mykolas Gladkovas , Peter Symons , J. David Genders , Jean-François Magnan , Geneviève Clayton
IPC: C22B26/12 , B01D61/42 , B01D61/44 , C01D7/07 , C22B3/44 , C22B4/02 , C25B1/14 , C25B1/16 , C25B9/19 , C25B9/21 , C25B9/70 , C25B15/027 , C25B15/031 , C25B15/08
Abstract: There are provided processes comprising submitting an aqueous composition comprising lithium sulphate and/or bisulfate to an electrolysis or an electrodialysis for converting at least a portion of said sulphate into lithium hydroxide. During electrolysis or electrodialysis, the aqueous composition is at least substantially maintained at a pH having a value of about 1 to about 4; and converting said lithium hydroxide into lithium carbonate. Alternatively, lithium sulfate and/or lithium bisulfate can be submitted to a first electromembrane process that comprises a two-compartment membrane process for conversion of lithium sulfate and/or lithium bisulfate to lithium hydroxide, and obtaining a first lithium-reduced aqueous stream and a first lithium hydroxide-enriched aqueous stream; and submitting said first lithium-reduced aqueous stream to a second electromembrane process comprising a three-compartment membrane process to prepare at least a further portion of lithium hydroxide and obtaining a second lithium-reduced aqueous stream and a second lithium-hydroxide enriched aqueous stream.
-
10.
公开(公告)号:US20240294395A1
公开(公告)日:2024-09-05
申请号:US18655232
申请日:2024-05-04
Applicant: NEMASKA LITHIUM INC.
Inventor: Guy BOURASSA , Jean-François MAGNAN , Nicolas LAROCHE , Thomas BIBIENNE , Mathieu CHARBONNEAU , Mickaël DOLLÉ
IPC: C01G53/04 , B01D61/44 , C01D1/28 , C01D15/02 , C01G51/00 , C01G51/04 , C01G53/00 , H01M4/505 , H01M4/525 , H01M10/0525 , H01M10/54
CPC classification number: C01G53/04 , B01D61/445 , C01D1/28 , C01D15/02 , C01G51/04 , C01G51/50 , C01G53/006 , C01G53/50 , H01M4/505 , H01M4/525 , H01M10/0525 , H01M10/54 , B01D2311/2642 , B01D2311/2673 , C01P2002/54 , C01P2002/72 , C01P2006/40
Abstract: A process for preparing metal oxide comprising (i) at least one metal chosen from nickel and cobalt and optionally (ii) at least one metal chosen from manganese, lithium and aluminum. The process comprising:
reacting a metal sulfate comprising (i) at least one metal chosen from nickel and cobalt and optionally (ii) at least one metal chosen from manganese, lithium and aluminum with lithium hydroxide and optionally a chelating agent to obtain a solid comprising a metal hydroxide comprising (i) at least one metal chosen from nickel and cobalt and optionally (ii) at least one metal chosen from manganese, lithium and aluminum, and a liquid comprising lithium sulfate, the metal sulfate comprising (i) at least one metal chosen from nickel and cobalt and optionally (ii) at least one metal chosen from manganese, lithium and aluminum;
separating the liquid and the solid from one another to obtain the metal hydroxide;
submitting the liquid comprising lithium sulfate to an electromembrane process for converting the lithium sulfate into lithium hydroxide; and
reusing at least a first portion of said lithium hydroxide obtained by the electromembrane process for reacting with the metal sulfate;
reacting at least a second portion of said lithium hydroxide obtained by the electromembrane process with the obtained metal hydroxide to obtain a mixture of metal hydroxides; and
roasting said mixture of metal hydroxides to obtain the metal oxide.
-
-
-
-
-
-
-
-
-