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27 条记录 (耗时 0.019 秒)

    N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding N-oxides and controlled radical polymerization therewith
    2.
    发明申请
    N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding N-oxides and controlled radical polymerization therewith 失效
    N-烷氧基-4,4-二氧基 - 多烷基 - 哌啶化合物，它们相应的N-氧化物和受控自由基聚合

    公开(公告)号：US20060149011A1

    公开(公告)日：2006-07-06

    申请号：US11364537

    申请日：2006-02-28

    申请人： Peter Nesvadba ,  Marie-Odile Zink ,  Wiebke Wunderlich

    发明人： Peter Nesvadba ,  Marie-Odile Zink ,  Wiebke Wunderlich

    IPC分类号： C08F4/00 ,  C07D491/10

    CPC分类号： C07D211/94 ,  C07D491/113 ,  C07D491/22 ,  C07D519/00 ,  C08F2/46 ,  C08F4/00

    摘要： The present invention relates to selected 1-alkoxy-2,2,6,6 tetramethyl piperidine, 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,3,6 dimethyl piperidine derivatives which are substituted in the 4 position by two oxygen atoms forming an open chain or cyclic ketal structure, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) said piperidine derivatives. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of 1-alkoxy-2,2,6,6 tetramethyl piperidine, 1-alkoxy-2,2 diethyl-6,6 dimethyl piperidine and 1-alkoxy-2,6 diethyl-2,3,6 dimethyl piperidine derivatives which are substituted in the 4 position by two oxygen atoms forming an open chain or cyclic ketal structure for controlled polymerization. The intermediate N-oxyl derivatives, a composition of the N-oxyl derivatives with ethylenically unsaturated monomers and a free radical initiator, as well as a process for polymerization are also subjects of the present invention.

    摘要翻译： 本发明涉及选择的1-烷氧基-2,2,6,6四甲基哌啶，1-烷氧基-2,2二乙基-6,6二甲基哌啶和1-烷氧基-2,6-二乙基-2,3,6-二甲基 哌啶衍生物，其在4位被两个形成开链或环状缩酮结构的氧原子取代，所述可聚合组合物包含a）至少一种烯属不饱和单体和b）所述哌啶衍生物。 本发明的另外的方面是使烯键式不饱和单体聚合的方法，以及使用1-烷氧基-2,2,6,6四甲基哌啶，1-烷氧基-2,2二乙基-6,6二甲基哌啶和1- 烷氧基-2,6-二乙基-2,3,6二甲基哌啶衍生物，其在4位被两个氧原子取代，形成用于受控聚合的开链或环状缩酮结构。 中间体N-氧基衍生物，具有烯键式不饱和单体的N-氧基衍生物和自由基引发剂的组合物以及聚合方法也是本发明的主题。

    Composition and method for color improvement of nitroxyl containing polymers
    4.
    发明授权
    Composition and method for color improvement of nitroxyl containing polymers 失效
    用于含硝酰基聚合物的组合物和颜色改进方法

    公开(公告)号：US06767949B1

    公开(公告)日：2004-07-27

    申请号：US10130866

    申请日：2002-05-22

    申请人： Rudolf Pfaendner ,  Michael Roth ,  Wiebke Wunderlich

    发明人： Rudolf Pfaendner ,  Michael Roth ,  Wiebke Wunderlich

    IPC分类号： C08L328

    CPC分类号： C08K5/32 ,  C08K5/3435

    摘要： The invention relates to a composition comprising, a) at least one oligomer, cooligomer, polymer or copolymer or blends thereof, containing a stable free nitroxyl radical (1); and b) a reducing agent; with the proviso that the composition is essentially free of a polymerizable monomer. A further subject is a process for improving the color of an oligomer, cooligomer, polymer or copolymer or blend thereof, containing a stable free nitroxyl radical (1); by adding a reducing agent to said polymer and heating said mixture to above the glass temperature in case of amorphous polymers or above the melting point in case of crystalline or semi-crystalline polymers

    摘要翻译： 本发明涉及一种组合物，其包含a）至少一种含有稳定的游离硝酰基（1）的低聚物，低聚物，聚合物或共聚物或其共混物; 和b）还原剂; 条件是组合物基本上不含可聚合单体。 另一个课题是改进含有稳定的游离硝酰基（1）的低聚物，低聚物，聚合物或共聚物或其共混物的颜色的方法。 通过在无定形聚合物的情况下向所述聚合物中加入还原剂并将所述混合物加热到玻璃化温度以上，或者在结晶或半结晶聚合物的情况下高于熔点

    Composition and process for enhancing controlled free radical polymerization
    6.
    发明授权
    Composition and process for enhancing controlled free radical polymerization 失效
    用于增强受控自由基聚合的组合物和方法

    公开(公告)号：US07323517B2

    公开(公告)日：2008-01-29

    申请号：US11299470

    申请日：2005-12-12

    申请人： Wiebke Wunderlich ,  Rudolf Pfaendner

    发明人： Wiebke Wunderlich ,  Rudolf Pfaendner

    IPC分类号： C08F293/00

    CPC分类号： C08F4/00

    摘要： The present invention relates to a composition and process for enhancing the controlled radical polymerization in the presence of nitroxyls and nitroxylethers by adding a chain transfer agent selected from the group consisting of mercaptanes, thioethers and disulfides to the polymerizable mixture. A further subject of the invention is the use of mercaptanes, thioethers and disulfides for increasing rate and yield of controlled radical polymerizations in the presence of a nitroxyl or a nitroxylether.

    摘要翻译： 本发明涉及通过将选自硫醇，硫醚和二硫化物的链转移剂加入到可聚合的混合物中，在硝酰氧基和硝酰氧基醚的存在下增强受控自由基聚合的组合物和方法。 本发明的另一个主题是在硝酰基或硝酰基醚的存在下使用硫醇，硫醚和二硫化物来提高受控自由基聚合的速率和产率。

    Method of producing comb or star copolymers using epoxy-functionalized nitroxylethers
    7.
    发明授权
    Method of producing comb or star copolymers using epoxy-functionalized nitroxylethers 失效
    使用环氧官能化硝酰基醚制备梳状或星型共聚物的方法

    公开(公告)号：US07291682B2

    公开(公告)日：2007-11-06

    申请号：US10524926

    申请日：2003-08-26

    申请人： Wiebke Wunderlich-Wippert ,  Rudolf Pfaendner ,  Francesco Fuso ,  Jochen Fink

    发明人： Wiebke Wunderlich-Wippert ,  Rudolf Pfaendner ,  Francesco Fuso ,  Jochen Fink

    IPC分类号： C08F283/06 ,  C08G65/22

    CPC分类号： C08G65/22 ,  C08F283/06 ,  C08F293/005 ,  C08F2438/02 ,  C08L71/02 ,  C08L2205/05 ,  C08L2666/04

    摘要： The present invention provides a method of forming comb or star copolymers. The comb or star copolymers are useful in surface modification of thermoplastic materials or as surfactants. The method is aimed at attaching a polymeric side chain differing in polarity and chemical structure from the backbone and forming a comb or star copolymer structure. In particular the process comprises polymerizing in a first step a polymer backbone from epoxy and nitroxylether group containing monomers and in a second step polymerizing under controlled radical conditions a comb or star structure onto this backbone. The epoxy group containing monomers are for example of the formula (II)

    摘要翻译： 本发明提供了形成梳状或星型共聚物的方法。 梳状或星形共聚物可用于热塑性材料或表面活性剂的表面改性。 该方法旨在将不同极性和化学结构的聚合物侧链与骨架连接并形成梳状或星型共聚物结构。 特别地，该方法包括在第一步骤中聚合来自环氧基和含硝酰基醚基团的单体的聚合物主链，并且在第二步中在受控自由基条件下将梳状或星形结构聚合到该主链上。 含环氧基的单体例如为式（II）

    N-alkoxy-4,4-dioxy-polyalkyl-piperidines as radical polymerization inhibitors
    8.
    发明授权
    N-alkoxy-4,4-dioxy-polyalkyl-piperidines as radical polymerization inhibitors 失效
    N-烷氧基-4,4-二氧基 - 多烷基 - 哌啶作为自由基聚合抑制剂

    公开(公告)号：US07235663B2

    公开(公告)日：2007-06-26

    申请号：US10450227

    申请日：2001-11-12

    申请人： Francesco Fuso ,  Wiebke Wunderlich ,  Andreas Kramer ,  Jochen Fink

    发明人： Francesco Fuso ,  Wiebke Wunderlich ,  Andreas Kramer ,  Jochen Fink

    IPC分类号： C07D319/10 ,  C07D323/04 ,  C08F4/00 ,  C08F2/16 ,  C08K5/3492

    CPC分类号： C07D405/12 ,  C07D211/94 ,  C07D491/10 ,  C08F4/00

    摘要： The present invention relates to selected glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds forming an open chain or cyclic ketal structure, a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) a glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine nitroxide initiator compound. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers and the use of glycidyl or carbonyl functional N-alkoxy-4,4-dioxy-polyalkyl-piperidine nitroxide initiators for radical polymerization.

    摘要翻译： 本发明涉及形成开链或环状缩酮结构的选择的缩水甘油基或羰基官能的N-烷氧基-4,4-二氧基 - 多烷基 - 哌啶化合物，可聚合组合物，其包含a）至少一种烯属不饱和单体和b）缩水甘油基 或羰基官能的N-烷氧基-4,4-二氧基 - 多烷基 - 哌啶氮氧根引发剂化合物。 本发明的另外的方面是用于使烯键式不饱和单体聚合的方法和使用缩水甘油基或羰基官能的N-烷氧基-4,4-二氧基 - 多烷基 - 哌啶氮氧根引发剂进行自由基聚合。

    Use of 2,2,6,6 tetraalkylpiperidine-N-oxyl radicals having long alkyl chains as polymerization regulators
    9.
    发明授权
    Use of 2,2,6,6 tetraalkylpiperidine-N-oxyl radicals having long alkyl chains as polymerization regulators 失效
    使用具有长烷基链的2,2,6,6四烷基哌啶-N-氧基作为聚合调节剂

    公开(公告)号：US06569940B1

    公开(公告)日：2003-05-27

    申请号：US09720440

    申请日：2000-12-22

    申请人： Wiebke Wunderlich ,  Margot Clauss ,  Michael Roth ,  Francesco Fuso

    发明人： Wiebke Wunderlich ,  Margot Clauss ,  Michael Roth ,  Francesco Fuso

    IPC分类号： C07D25106

    CPC分类号： C08F2/38 ,  C08F4/00

    摘要： The present invention relates to a polymerizable composition, comprising a) at least one ethylenically unsaturated monomer or oligomer, b) a radical source capable of starting polymerization of the ethylenically unsaturated monomer or oligomer and c) at least one compound of formula (I), wherein n is 1 or 2; R3, R4, R9, R10 are each independently of one another C1-C18alkyl, C2-C18alkenyl or C2-C18alkinyl; or R3 and R4 and/or R9 and R10 form together with the linking carbon atom a C3-C12cycloakyl radical; R5, R6, R7, R8 are each independently of one another hydrogen, C1-C18alkyl, C2-C18alkenyl or C2C18alkinyl; X is —O—, —O—C(O)—, —NR2— or —NR2—C(O)—; R2 is hydrogen, C1-C18alkyl or phenyl; if n is 1, R1 is C8-C36alkyl, C8-C36alkenyl or C8-C36alkinyl; if n is 2, R1 is C10-C36alkylen, C10-C36alkenylen or C10-C36alkinylen. Further objects of the present invention are a process for polymerization and the use of compounds of formula (I) for the polymerization of ethylenically unsaturated monomers.

    摘要翻译： 本发明涉及一种可聚合组合物，其包含a）至少一种烯键式不饱和单体或低聚物，b）能够启动烯属不饱和单体或低聚物聚合的自由基源，和c）至少一种式（I）化合物， 其中n为1或2; R 3，R 4，R 9，R 10各自独立地为C 1 -C 18烷基，C 2 -C 18烯基或C 2 -C 18炔基; 或R 3和R 4和/或R 9和R 10与连接碳原子一起形成C 3 -C 12环烷基; R5，R6，R7，R8各自独立地为氢，C1-C18烷基，C2-C18链烯基或C2C18炔基; X是-O - ， - O-C（O） - ， - NR2-或-NR2-C（O） - ; R2是氢，C1-C18烷基或苯基; 如果n为1，则R1为C8-C36烷基，C8-C36烯基或C8-C36炔基; 如果n为2，则R1为C10-C36亚烷基，C10-C36烯基或C10-C36炔基。 本发明的另外的目的是聚合方法和式（I）化合物用于烯属不饱和单体聚合的方法。

    DEGRADATION ACCELERATOR FOR POLYMERS AND POLYMER ARTICLE COMPRISING IT
    10.
    发明申请
    DEGRADATION ACCELERATOR FOR POLYMERS AND POLYMER ARTICLE COMPRISING IT 审中-公开
    聚合物和聚合物降解助剂包括它

    公开(公告)号：US20100222454A1

    公开(公告)日：2010-09-02

    申请号：US12670872

    申请日：2008-07-24

    申请人： Massimiliano Sala ,  Wiebke Wunderlich-Wippert ,  Stefano Gardi

    发明人： Massimiliano Sala ,  Wiebke Wunderlich-Wippert ,  Stefano Gardi

    IPC分类号： C08K5/07 ,  C08K5/3417 ,  C08K5/10 ,  C08K5/435 ,  C08K5/08

    CPC分类号： C08G63/6886 ,  C07C50/34 ,  C07C69/593 ,  C07C69/712 ,  C07C235/84 ,  C07C311/17 ,  C07C2601/14 ,  C07C2603/24 ,  C07D209/48 ,  C08G63/6856 ,  C08G65/40 ,  C08G65/4012 ,  C08K5/0033 ,  C08K5/3417

    摘要： Disclosed are a method for improving the degradation of natural and/or synthetic polymers or a polymer article made from such polymer(s) by light and/or heat and/or humidity, comprising the incorporation of a compound of formula (I) into said natural and/or synthetic polymers: Formula (I); wherein m is 1 or 2, n is 1 to 100, X is selected from certain benzophenone-derived moieties and R, R1; R2 are each selected from list of certain residues; novel compounds of said formula (I) and polymeric articles of improved degradability in the presence of light and/or heat and/or humidity being made of a composition comprising: A) a natural and/or a synthetic polymer and B) a degradation accelerator being a compound of said formula (I).

    摘要翻译： 公开了一种改善天然和/或合成聚合物或由这种聚合物通过光和/或热和/或湿度制成的聚合物制品的降解的方法，包括将式（I）化合物引入所述 天然和/或合成聚合物：式（I）; 其中m为1或2，n为1至100，X选自某些二苯甲酮衍生的部分，R，R 1; R2各自选自某些残基的列表; 所述式（I）的新型化合物和在光和/或热和/或湿度存在下具有改善的降解性的聚合物制品由包含以下组合物制成：A）天然和/或合成聚合物和B）降解促进剂 是所述式（I）的化合物。