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公开(公告)号:US20220356592A1
公开(公告)日:2022-11-10
申请号:US17754110
申请日:2020-09-15
Applicant: BASF SE
Inventor: Marco ARNOLD , Alexander FLUEGEL , Charlotte EMNET , Nadine ENGELHARDT
Abstract: Disclosed herein is a composition including copper ions and at least one additive including a polyalkyleneimine backbone including N-hydrogen atoms, where (a) the polyalkyleneimine backbone has a mass average molecular weight MW of from 600 g/mol to 100 000 g/mol, (b) the N-hydrogen atoms are each substituted by a polyoxyalkylene group including an oxyethylene and a C3 to C6 oxyalkylene unit, and (c) the average number of oxyalkylene units in the polyoxyalkylene groups is of from more than 10 to less than 30 per N-hydrogen atom in the polyalkyleneimine.
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公开(公告)号:US20200185224A1
公开(公告)日:2020-06-11
申请号:US16638318
申请日:2018-08-31
Applicant: BASF SE
Inventor: Marcel Patrik KIENLE , Cornelia ROEGER-GOEPFERT , Dieter MAYER , Marco ARNOLD , Alexander FLUEGEL , Charlotte EMNET
IPC: H01L21/288 , C25D5/02 , C25D3/38 , C25D7/12
Abstract: A composition for metal plating comprising a source of metal ions and at least one leveling agent comprising at least one polyaminoamide comprising a polymer fragment of formula (I) or derivatives thereof obtainable by complete or partial protonation or N-quarternisation.
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3.
公开(公告)号:US20190226107A1
公开(公告)日:2019-07-25
申请号:US16318540
申请日:2017-07-06
Applicant: BASF SE
Inventor: Marcel Patrik KIENLE , Dieter MAYER , Marco ARNOLD , Alexander FLUEGEL , Charlotte EMNET
IPC: C25D3/16 , C25D7/12 , C25D3/18 , H01L21/288 , H01L21/768 , H01L23/532 , H01L23/522
Abstract: A composition comprising: (a) cobalt ions, and (b) an additive of formula (I) wherein R1 is selected from X-Y; R2 is selected from R1 and R3; X is selected from linear or branched C1 to C10 alkanediyl, linear or branched C2 to C10 alkenediyl, linear or branched C2 to C10 alkynediyl, and (C2H3R6—O)n—H; Y is selected from OR3, NR3R4, N+R3R4R5 and NH—(C═O)—R3; R3, R4, R5 are the same or different and are selected from (i) H, (ii) C5 to C20 aryl, (iii) C1 to C10 alkyl (iv) C6 to C20 arylalkyl, (v) C6 to C20 alkylaryl, which may be substituted by OH, SO3H, COOH or a combination thereof, and (vi) (C2H3R6—O)n—H, and wherein R3 and R4 may together form a ring system, which may be interrupted by O or NR7; m, n are integers independently selected from 1 to 30; R6 is selected from II and C1 to C5 alkyl; R7 is selected from R6 and formula (II).
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公开(公告)号:US20250051950A1
公开(公告)日:2025-02-13
申请号:US18721238
申请日:2022-12-20
Applicant: BASF SE
Inventor: Charlotte EMNET , Lucas Benjamin HENDERSON , Alexander FLUEGEL , Sathana KITAYAPORN , Nadine ENGELHARDT
IPC: C25D3/38 , C25D5/02 , C25D7/12 , H01L21/768 , H01L23/532
Abstract: Disclosed herein is a composition for depositing copper on a semiconductor substrate, the composition including (a) copper ions; (b) an additive of formula S1 (c) a complexing agent; and (d) optionally a buffer or base to adjust the pH to a pH of from 7 to 13; where the pH of the composition is from 7 to 13 and where the composition is free of any cyanide.
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5.
公开(公告)号:US20230142238A1
公开(公告)日:2023-05-11
申请号:US17995186
申请日:2021-03-24
Applicant: BASF SE
Inventor: Marco ARNOLD , Alexander FLUEGEL , Charlotte EMNET , Nadine ENGELHARDT
IPC: C25D3/38
CPC classification number: C25D3/38
Abstract: Described herein is a composition including copper ions, an acid, and at least one polyaminoamide including, a group of formula L1
[A-B-A′-Z]n[Y—Z]m (L1)
where
B is a diacid fragment of formula L2
A, A′ are amine fragments independently selected from the group consisting of formula L3a
and formula L3b
Y is a co-monomer fragment;
Z is a coupling fragment of formula L4
n is an integer of from 1 to 400; and
m is 0 or an integer of from 1 to 400.-
6.
公开(公告)号:US20210040635A1
公开(公告)日:2021-02-11
申请号:US17082765
申请日:2020-10-28
Applicant: BASF SE
Inventor: Marcel Patrik KIENLE , Dieter MAYER , Marco ARNOLD , Alexander FLUEGEL , Charlotte EMNET
IPC: C25D3/16 , C25D7/12 , C25D3/18 , H01L21/288 , H01L23/532 , H01L21/768 , H01L23/522
Abstract: A composition comprising (a) cobalt ions, and (b) an additive of formula I wherein R1 is selected from X-Y; R2 is selected from R1 and R3; X is selected from linear or branched C1 to C10 alkanediyl, linear or branched C2 to C10 alkenediyl, linear or branched C2 to C10 alkynediyl, and (C2H3R6—O)m—H; Y is selected from OR3, NR3R4, N+R3R4R5 and NH—(C═O)—R3; R3, R4, R5 are the same or different and are selected from (i) H, (ii) C5 to C20 aryl, (iii) C1 to C10 alkyl (iv) C6 to C20 arylalkyl, (v) C6 to C20 alkylaryl, which may be substituted by OH, SO3H, COOH or a combination thereof, and (vi) (C2H3R6—O)n—H, and wherein R3 and R4 may together form a ring system, which may be interrupted by O or NR7; m, n are integers independently selected from 1 to 30; R6 is selected from H and C1 to C5 alkyl; R7 is selected from R6 and
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公开(公告)号:US20250051949A1
公开(公告)日:2025-02-13
申请号:US18720906
申请日:2022-12-20
Applicant: BASF SE
Inventor: Charlotte EMNET , Lucas Benjamin HENDERSON , Alexander FLUEGEL , Sathana KITAYAPORN , Nadine ENGELHARDT
Abstract: Described herein is a composition for depositing copper on a semiconductor substrate, the composition including
(a) copper ions;
(b) a grain refiner of formula G1a or G1b or salts thereof; (c) a complexing agent; and
(d) optionally a buffer or a base to adjust the pH to a pH of from 7 to 13;
wherein
RG1 is selected from one or more H, C1 to C4 carboxyl, C1 to C4 alkyl, C1 to C6 alkoxy, halogen, and CN;
RG2 is selected from one or more H, C1 to C4 carboxyl, C1 to C4 alkyl, C1 to C6 alkoxy, halogen, and CN; and
XG1 is selected from C1 to 6 alkanediyl or a group —XG11—C(O)—O—XG12—;
XG11 is selected from a chemical bond or C1 to C4 alkandiyl;
XG12 is selected from a chemical bond or C1 to C4 alkandiyl; and wherein RG1 or RG2, comprises at least one C1 to C4 carboxyl group, or group XG1 is —XG11—C(O)—O—)—XG12—; wherein the pH of the composition is from 7 to 13.-
公开(公告)号:US20230235471A1
公开(公告)日:2023-07-27
申请号:US18001078
申请日:2021-06-07
Applicant: BASF SE
Inventor: Marco ARNOLD , Alexander FLUEGEL , Charlotte EMNET , Nadine ENGELHARDT
IPC: C25D3/38 , C08G73/02 , C08K3/08 , C08K5/3415 , C25D7/12
CPC classification number: C25D3/38 , C08G73/024 , C08K3/08 , C08K5/3415 , C25D7/12 , C08K2003/085
Abstract: Disclosed herein is a A polyalkanolamine including the structure of formula L1
A
L
n
B
L
m
wherein
AL is
BL is
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O-X
L21
o
-,
XL1, XL2, XL3 are independently selected from a C1 to C6 alkanediyl;
ArL is a 5 or 6 membered N-heteroaromatic ring system including from 1 to 4 N atoms, which may be unsubstituted or substituted by C1 to C6 alkyl;
n is an integer of from 2 to 350;
m is 0 or an integer of from 1 to 600;
o is 1 or an integer of from 2 to 25;
BL1 is a continuation of the backbone BL by branching;
XL11, XL12, XL13 are independently selected from a C1 to C6 alkanediyl;
XL21 is a C1 to C6 alkanediyl;
and derivatives thereof obtainable by N-protonation, N-quaternization, substitution, or polyalkoxylation.-
公开(公告)号:US20220333262A1
公开(公告)日:2022-10-20
申请号:US17754097
申请日:2020-09-15
Applicant: BASF SE
Inventor: Nadine ENGELHARDT , Alexander FLUEGEL , Marco ARNOLD , Charlotte EMNET
IPC: C25D1/00
Abstract: Disclosed herein is a composition for copper bump electrodeposition including copper ions and at least one additive including a polyalkyleneimine backbone including N-hydrogen atoms, where (a) the polyalkyleneimine backbone has a mass average molecular weight Mw of from 900 g/mol to 100 000 g/mol, (b) the N-hydrogen atoms are each substituted by a C2 to C6 polyoxyalkylene group, and (c) the average number of oxyalkylene units in the polyoxyalkylene group is from more than 10 to less than 30 per N-hydrogen atoms in the polyalkyleneimine.
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公开(公告)号:US20200347503A1
公开(公告)日:2020-11-05
申请号:US16762717
申请日:2018-11-19
Applicant: BASF SE
Inventor: Nadine ENGELHARDT , Dieter MAYER , Marco ARNOLD , Alexander FLUEGEL , Charlotte EMNET , Lucas Benjamin HENDERSON
Abstract: A cobalt electrodeposition composition comprising cobalt ions, and particular leveling agents comprising X1—CO—O—R11, X1—SO2—O—R11, X1—PO(OR11)2, X1—SO—O—R11 functional groups, wherein X1 is a divalent group selected from (i) a chemical bond (ii) aryl, (iii) C1 to C12 alkandiyl, which may be interrupted by O atoms, (iv) an arylalkyl group —X11—X12—, (v) an alkylaryl group —X12—X11—, and (vi) —(O—C2H3R12)mO—, R11 is selected from H and C1 to C4 alkyl. R12 is selected from H and C1 to C4 alkyl, X12 is a divalent aryl group, X11 is a divalent C1 to C15 alkandiyl group.
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