公开(公告)号：US20200299511A1

公开(公告)日：2020-09-24

申请号：US16064574

申请日：2016-12-21

Applicant: BASF SE

Inventor： Kostas S. AVRAMIDIS

IPC: C08L95/00 ,  C08L9/08 ,  C08L25/10 ,  C08L11/02 ,  C08L23/08

Abstract: Disclosed herein are asphalt compositions. In some embodiments, the asphalt compositions can include asphalt, a polymer, and a basic salt such as aluminum sulfate. In some embodiments, the asphalt compositions can include asphalt, a polymer, and an inorganic acid such as phosphoric acid. The asphalt compositions can include asphalt in an amount of from 50 wt % to 99.9 wt %, based on the weight of the asphalt composition. In some embodiments, the asphalt compositions can include a styrene-butadiene copolymer in an amount of from 0.05 wt % to 10 wt %, based on the weight of the asphalt composition. The basic salt can be present in an amount of from 0.01 wt % to 5 wt %, based on the weight of the asphalt compositions. The acid can be present in an amount of from 0.005 wt % to 0.1 wt %, based on the weight of the asphalt compositions. Methods of making and using the asphalt compositions are also disclosed.

公开(公告)号：US20160032138A1

公开(公告)日：2016-02-04

申请号：US14776778

申请日：2014-03-11

Applicant: BASF SE

Inventor： Kostas S. AVRAMIDIS

IPC: C09D147/00 ,  C09D125/10

Abstract: The present disclosure relates to compositions comprising a copolymer derived from polymerizing a hydrophobic monomer and/or a gas-phase monomer in the presence of a solid grade oligomer. In some embodiments, the hydrophobic monomer includes styrene and butadiene. In some embodiments, the copolymer is derived from polymerizing a gas-phase monomer. The present disclosure also relates to methods of making the disclosed compositions. The compositions disclosed herein can be used in a variety of applications including, but not limited to, asphalt compositions, paints, coatings, paper binding and coating compositions, foams, or adhesives.

Abstract translation: 本公开内容涉及包含在固体级低聚物存在下聚合疏水性单体和/或气相单体的共聚物的组合物。 在一些实施方案中，疏水单体包括苯乙烯和丁二烯。 在一些实施方案中，共聚物衍生自气相单体的聚合。 本公开还涉及制备所公开的组合物的方法。 本文公开的组合物可用于各种应用，包括但不限于沥青组合物，油漆，涂料，纸粘合剂和涂料组合物，泡沫或粘合剂。

公开(公告)号：US20230303842A1

公开(公告)日：2023-09-28

申请号：US18124661

申请日：2023-03-22

Applicant: BASF SE

Inventor： William J. KIRK ,  Kostas S. AVRAMIDIS

IPC: C08L95/00 ,  C08F265/04 ,  C08L9/08

CPC classification number: C08L95/005 ,  C08F265/04 ,  C08L9/08 ,  C08L2201/54

Abstract: Disclosed herein are asphalt compositions containing a block-copolymer additive, for example for use as a dispersant. In some embodiments, the asphalt compositions can include asphalt, a block-copolymer dispersant, and an SBR latex. The block-copolymers have a molecular weight exceeding 5000 g/mol with a polybutyl acrylate hydrophobic block that attaches to the asphalt particle and a sodium polystyrene sulfonate hydrophilic block for stability, wherein the block copolymer has a first block comprising of alkyl acrylate and a second block comprising units of an ethylenically unsaturated monomer with sulfonic acid groups.
The asphalt compositions can include asphalt in an amount of from 50 wt. % to 95 wt. %, based on the weight of the asphalt composition. In some embodiments, the asphalt compositions can include a styrene-butadiene copolymer in an amount of from 0.05 wt. % to 10 wt. %, based on the weight of the asphalt composition. Methods of making and using the asphalt compositions are also disclosed.

公开(公告)号：US20180371251A1

公开(公告)日：2018-12-27

申请号：US16064570

申请日：2016-12-21

Applicant: BASF SE

Inventor： Kostas S. AVRAMIDIS ,  William J. KIRK

IPC: C08L95/00 ,  C08K3/32 ,  C08K3/30

Abstract: Disclosed herein are latex compositions and asphalt formulations comprising the latex compositions. In some embodiments, the latex compositions include a styrene-butadiene copolymer and polyphosphoric acid represented by the formula, Hn+2PnO3n+1, wherein n is an integer from 2 to 30. The latex composition can be used to prepare polymer-modified asphalt emulsions and hot mix asphalt compositions. The asphalt formulations can be prepared by contacting asphalt with a latex composition as described herein and a sulfur curing agent. Methods of coating a surface comprising applying an asphalt formulation as described herein to the surface are also disclosed.

公开(公告)号：US20230095635A1

公开(公告)日：2023-03-30

申请号：US17979213

申请日：2022-11-02

Applicant: BASF SE

Inventor： Kostas S. AVRAMIDIS ,  Armin A. BURGHART ,  Don M. CHO ,  Luke S. EGAN ,  Vanessa ADAMS

IPC: C08F283/06 ,  C08F2/20 ,  C08F220/56 ,  C08F2/00 ,  C08G77/04 ,  C08F220/06 ,  C08F301/00 ,  C08F212/08 ,  C08G75/24 ,  C09D151/08 ,  C08F220/18

Abstract: The present disclosure relates to compositions comprising a copolymer derived from a vinyl aromatic monomer, a (meth)acrylate monomer, an acid monomer, and a copolymerizable surfactant and compositions comprising the same. The (meth)acrylate monomer can be selected from a monomer having a theoretical glass transition temperature (Tg) for its corresponding homopolymer of 0° C. or less or a hydrophobic (meth)acrylate monomer. In some embodiments, the copolymer is further derived from an organosilane. The copolymers can have a theoretical glass transition temperature (Tg) from −60° C. to 80° C. and a number average particle size of 250 nm or less. The compositions can be used to prepare compositions such as coatings that have improved water resistance, blush resistance, and/or resistance to hydrostatic pressures. Methods of making the copolymers are also provided.

公开(公告)号：US20210340337A1

公开(公告)日：2021-11-04

申请号：US17281085

申请日：2019-09-25

Applicant: BASF SE

Inventor： Kostas S. AVRAMIDIS ,  Torben GAEDT ,  Martin WINKLBAUER ,  Christian SCHMIDTKE ,  Sophie PUTZIEN ,  Susanne SCHNEIDER

IPC: C08J3/12 ,  C08L9/08 ,  C08L5/00 ,  C08L33/02 ,  C08L39/06 ,  C08L31/04 ,  C08L95/00

Abstract: Provided herein are dispersible copolymer powders and asphalt compositions comprising the same. The dispersible copolymer powders comprise a core polymer having a glass transition temperature (Tg) of 40° C. or less and a shell comprising a water soluble protective colloid polymer having a Tg of 50° C. or greater. The core polymer can be derived from a vinyl aromatic monomer, a 1,3-diene monomer, and optionally one or more ethylenically-unsaturated monomers. The protective colloid polymer can be selected from a polyvinyl alcohol, a polyvinyl pyrrolidone, a polysaccharide, other water soluble polymers, or a combination thereof. Methods of preparing a styrene-butadiene modified asphalt without significantly increasing the viscosity, comprising adding the dispersible copolymer powder to an asphalt composition, wherein the addition of the copolymer polymer increases the viscosity of the asphalt by 100% or less at 135° C. within 2 hours of mixing are also described herein.

公开(公告)号：US20210108017A1

公开(公告)日：2021-04-15

申请号：US16970392

申请日：2019-02-14

Applicant: BASF SE

Inventor： Michael KRAYER ,  Kostas S. AVRAMIDIS

IPC: C08F257/02 ,  C08F220/14 ,  C08F220/18 ,  C08F2/20

Abstract: Described herein are methods of making a composition, the method comprising polymerizing monomers comprising a hydrophobic monomer in the presence of a solid grade oligomer, thereby forming a (co)polymer derived from the hydrophobic monomer, wherein the (co)polymer is derived from 5% by weight to 100% by weight of the hydrophobic monomer based on the total monomer weight. The hydrophobic monomer has a solubility in water of 0.2 g/100 g or less as measured at 20° C. The hydrophobic monomer comprises a substituted or unsubstituted C10-C22 alkyl (meth)acrylate, a substituted or unsubstituted C8-C20 alkenyl (meth)acrylate, a substituted or unsubstituted C5-C12 cycloalkyl (meth)acrylate, or a combination thereof. In some examples, the hydrophobic monomer can comprise lauryl (meth)acrylate, stearyl (meth)acrylate, heptadecyl (meth)acrylate, linoleyl (meth)acrylate, behenyl acrylate, cyclohexyl (meth)acrylate, isodecyl (meth)acrylate), nonyl (meth)acrylate, tridecyl (meth)acrylate, pentadecyl (meth)acrylate, 3-methylbut-2-enyl methacrylate, 3,7-dimethylocta-2,6-dienyl (meth)acrylate, or a combination thereof.

公开(公告)号：US20250092177A1

公开(公告)日：2025-03-20

申请号：US18958283

申请日：2024-11-25

Applicant: BASF SE

Inventor： Kostas S. AVRAMIDIS ,  Armin A. BURGHART ,  Don M. CHO ,  Luke S. EGAN ,  Vanessa ADAMS

IPC: C08F283/06 ,  C08F2/00 ,  C08F2/20 ,  C08F212/08 ,  C08F220/06 ,  C08F220/18 ,  C08F220/56 ,  C08F301/00 ,  C08G75/24 ,  C08G77/04 ,  C09D151/08

Abstract: The present disclosure relates to compositions comprising a copolymer derived from a vinyl aromatic monomer, a (meth)acrylate monomer, an acid monomer, and a copolymerizable surfactant and compositions comprising the same. The (meth)acrylate monomer can be selected from a monomer having a theoretical glass transition temperature (Tg) for its corresponding homopolymer of 0° C. or less or a hydrophobic (meth)acrylate monomer. In some embodiments, the copolymer is further derived from an organosilane. The copolymers can have a theoretical glass transition temperature (Tg) from −60° C. to 80° C. and a number average particle size of 250 nm or less. The compositions can be used to prepare compositions such as coatings that have improved water resistance, blush resistance, and/or resistance to hydrostatic pressures. Methods of making the copolymers are also provided.

公开(公告)号：US20230303857A1

公开(公告)日：2023-09-28

申请号：US18125168

申请日：2023-03-23

Applicant: BASF SE

Inventor： Kostas S. AVRAMIDIS

IPC: C09D5/02 ,  C09D7/65 ,  C09D133/06 ,  E04D7/00

CPC classification number: C09D5/022 ,  C09D7/65 ,  C09D133/064 ,  E04D7/00

Abstract: Disclosed herein are elastomeric roof coatings containing a block-copolymer, for example for use as a dispersant. In some embodiments, the roof coating compositions can comprise an all-acrylic or styrene-acrylic latex comprising a block-copolymer used in the latex polymerization. The block-copolymers have a molecular weight exceeding 5000 g/mol wherein the block copolymer has a first block comprising of alkyl acrylate and a second block comprising units of an ethylenically unsaturated monomer with sulfonic acid groups.
The modified elastomeric roof coating compositions are advantageous for reasons of water resistance, wet adhesion, tensile strength, and elongation. Methods of making and using the elastomeric roof coating compositions are also disclosed.

公开(公告)号：US20210395415A1

公开(公告)日：2021-12-23

申请号：US17292534

申请日：2019-11-08

Applicant: BASF SE

Inventor： Kostas S. AVRAMIDIS ,  Barry R. FOWLER ,  John BENNETT ,  Bert A. TEMPLETON

IPC: C08F212/08 ,  D06N3/10 ,  D06N7/00

Abstract: Carpet binder compositions comprising a mineral filler and a copolymer produced by emulsion polymerization and derived from monomers comprising a vinyl aromatic monomer, a 1,3-diene monomer, and an additional monomer selected from a copolymerizable surfactant, a (meth)acrylate monomer, a carboxylic acid monomer, or a combination thereof are disclosed. The carpet binder compositions can be formulated with a non-polymerizable surfactant such as an aryl phosphate surfactant. The compositions exhibit superior wet and dry delamination strengths as well as suitable froth viscosities. As a result, such carpet binder compositions can be made at higher filler loadings.