METHOD OF PRODUCING BIODIESEL
    2.
    发明申请

    公开(公告)号:US20210380900A1

    公开(公告)日:2021-12-09

    申请号:US17284020

    申请日:2019-10-07

    Applicant: BASF SE

    Abstract: The present invention relates to a method of producing fatty acid alkyl ester from an organic oil source containing at least one free fatty acid, wherein the oil source has an acid number of at least 30 mg KOH/g oil source and wherein the method comprises the steps of a) reacting the oil source with glycerol at a temperature, which does not exceed 180° C. during the reaction, in the presence of a catalyst comprising at least one alkyl or aryl sulfonic acid or an homoanhydride thereof; and b) transesterification of the reaction product from step a) with an alkanol; and c) isolating the fatty acid alkyl ester from the reaction product of step b).

    PROCESS FOR THE PRODUCTION OF CARBOXYLIC ESTERS AND USE OF THESE AS PLASTICIZERS
    4.
    发明申请
    PROCESS FOR THE PRODUCTION OF CARBOXYLIC ESTERS AND USE OF THESE AS PLASTICIZERS 有权
    生产羧酸酯的方法和这些作为增塑剂的用途

    公开(公告)号:US20170044085A1

    公开(公告)日:2017-02-16

    申请号:US15305932

    申请日:2015-04-20

    Applicant: BASF SE

    Abstract: The invention relates to a method for producing carboxylic acid esters by reacting carboxylic acids and/or carboxylic acid anhydrides with at least one alcohol having at least 5 carbon atoms, selected from alkanols and cycloalkanols, in the presence of an ionic liquid and an acidic esterification catalyst. The invention also relates to the use of the thus obtained carboxylic acid esters as a plasticizer or in a plasticizer composition for thermoplastic polymers and elastomers.

    Abstract translation: 本发明涉及通过使羧酸和/或羧酸酐与至少一种选自烷醇和环烷醇的至少5个碳原子的醇在离子液体和酸性酯化反应的存在下反应生产羧酸酯的方法 催化剂。 本发明还涉及由此获得的羧酸酯作为增塑剂或增塑剂组合物用于热塑性聚合物和弹性体的用途。

    METHOD FOR PRODUCING CARBOXYLIC ACID ESTERS AND THE USE THEREOF AS PLASTICIZERS
    5.
    发明申请
    METHOD FOR PRODUCING CARBOXYLIC ACID ESTERS AND THE USE THEREOF AS PLASTICIZERS 审中-公开
    生产羧酸酯的方法及其作为增塑剂的用途

    公开(公告)号:US20160264509A1

    公开(公告)日:2016-09-15

    申请号:US15033296

    申请日:2014-10-30

    Applicant: BASF SE

    Abstract: The present invention relates to a process for the production of carboxylic esters by reaction of carboxylic acids and/or carboxylic anhydrides with at least one alcohol selected from alkanols having at least 5 carbon atoms, cycloalkanols, and alkoxy-alkanols, in the presence of an acidic esterification catalyst. The invention further relates to the use of the resultant carboxylic esters as plasticizers or in a plasticizer composition for thermoplastic polymers and elastomers.

    Abstract translation: 本发明涉及一种通过羧酸和/或羧酸酐与至少一种选自具有至少5个碳原子的链烷醇,环烷醇和烷氧基 - 链烷醇在醇存在下反应生产羧酸酯的方法。 酸性酯化催化剂。 本发明还涉及所得的羧酸酯作为增塑剂或用于热塑性聚合物和弹性体的增塑剂组合物的用途。

    LOW CORROSION ALKANE SULFONIC ACIDS FOR CONDENSATION REACTIONS

    公开(公告)号:US20190301027A1

    公开(公告)日:2019-10-03

    申请号:US16318146

    申请日:2017-07-10

    Applicant: BASF SE

    Abstract: The present invention relates to methods for adding an aqueous solution of alkane sulfonic acids to a reactor via a pipe or container, wherein a condensation reaction takes place after addition of the aqueous solution of alkane sulfonic acid and to methods for reducing or limiting corrosion by adding said aqueous solution to a reactor. The present invention also relates to the use of aqueous solutions of alkane sulfonic acids in the reduction or limitation of corrosion and to the use of such aqueous solutions in condensation reactions.

    METHOD OF REPROCESSING ALKANESULFONIC ACID
    7.
    发明申请

    公开(公告)号:US20180327352A1

    公开(公告)日:2018-11-15

    申请号:US15774722

    申请日:2016-11-08

    Applicant: BASF SE

    CPC classification number: C07C303/44 C07C309/04

    Abstract: The invention relates to a method of reprocessing alkanesulfonic acid employed in a chemical process as an agent, catalyst or solvent and comprising the steps of: (a) removing an alkanesulfonic acid-comprising stream from a reaction mixture generated in the chemical process, (b) feeding the alkanesulfonic acid-comprising stream into a melt crystallization as the starting melt to form crystals of the alkanesulfonic acid, of hydrates of the alkanesulfonic acid or of a mixture of both suspended in mother liquor, (c) performing a solid-liquid separation to remove the crystals from the mother liquor, (d) optionally washing the crystals to remove mother liquor adhering to the crystals, (e) recycling the washed or unwashed crystals removed from the mother liquor into the chemical process.

    PROCESS FOR PURIFYING ALKANESULFONIC ACIDS
    8.
    发明申请

    公开(公告)号:US20180319739A1

    公开(公告)日:2018-11-08

    申请号:US15774847

    申请日:2016-11-08

    Applicant: BASF SE

    Abstract: The invention relates to a process for purifying alkanesulfonic acids which comprises the steps of: (a) distilling a melt comprising crude alkanesulfonic acid (1) to completely or partly remove low boilers, wherein the low boilers are drawn off at the top of a distillation column (3) or of a one-stage evaporation apparatus and a material stream (7) comprising alkanesulfonic acid, high boilers and residual low boilers is withdrawn at the bottom of the distillation column (3) or of the one-stage evaporation apparatus, (b) sending the stream (7) comprising alkanesulfonic acid, high boilers and residual low boilers into a melt crystallization (9) as the starting melt to form crystals of the alkanesulfonic acid, of hydrates of the alkanesulfonic acid or of a mixture of both suspended in mother liquor, (c) performing a solid-liquid separation to remove the crystals from the mother liquor, (d) optionally washing the crystals to remove mother liquor adhering to the crystals.

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